JPS5724323A - Preparation of antrhaquinone - Google Patents
Preparation of antrhaquinoneInfo
- Publication number
- JPS5724323A JPS5724323A JP9748080A JP9748080A JPS5724323A JP S5724323 A JPS5724323 A JP S5724323A JP 9748080 A JP9748080 A JP 9748080A JP 9748080 A JP9748080 A JP 9748080A JP S5724323 A JPS5724323 A JP S5724323A
- Authority
- JP
- Japan
- Prior art keywords
- toluene
- vanadium
- reaction
- penta
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain anthraquinone useful as an intermediate for dyes or an additive for preparing paper or pulp, by reacting inexpensive toluene as a starting material with a gas containing oxygen in the vapor phase in the presence of a catalyst containing vanadium directly in one stage.
CONSTITUTION: Toluene (or a mixture containing slight amounts of benzene and xylene may be usable) is reacted with a gas containing oxygen in the vapor phase in the presence of a catalyst containing vanadium, preferably tetra- or penta-valent oxide of vanadium or a mixture of the tetra- with the penta-valent vanadium oxides) to give anthraquinone. The mixing ratio between the toluene and the air is preferably 1.2vol% or less or 7vol% or more in vol% of toluene vapor in the air, and the reaction is carried out at a temperature in the range of 300W400°C. The unreacted toluene after the reaction is recycled through the reaction system for reuse.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9748080A JPS5724323A (en) | 1980-07-18 | 1980-07-18 | Preparation of antrhaquinone |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9748080A JPS5724323A (en) | 1980-07-18 | 1980-07-18 | Preparation of antrhaquinone |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5724323A true JPS5724323A (en) | 1982-02-08 |
Family
ID=14193441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9748080A Pending JPS5724323A (en) | 1980-07-18 | 1980-07-18 | Preparation of antrhaquinone |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5724323A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4727208A (en) * | 1986-09-12 | 1988-02-23 | The Dow Chemical Company | Oxidative coupling with methyl-substituted benzenes |
US4814537A (en) * | 1986-09-12 | 1989-03-21 | The Dow Chemical Company | Oxidative coupling of methyl-substituted benzenes |
-
1980
- 1980-07-18 JP JP9748080A patent/JPS5724323A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4727208A (en) * | 1986-09-12 | 1988-02-23 | The Dow Chemical Company | Oxidative coupling with methyl-substituted benzenes |
WO1988001993A1 (en) * | 1986-09-12 | 1988-03-24 | The Dow Chemical Company | Oxidative coupling with methyl-substituted benzenes |
US4814537A (en) * | 1986-09-12 | 1989-03-21 | The Dow Chemical Company | Oxidative coupling of methyl-substituted benzenes |
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