JPS57167932A - Dimerization of lower alpha-olefin - Google Patents

Dimerization of lower alpha-olefin

Info

Publication number
JPS57167932A
JPS57167932A JP56054055A JP5405581A JPS57167932A JP S57167932 A JPS57167932 A JP S57167932A JP 56054055 A JP56054055 A JP 56054055A JP 5405581 A JP5405581 A JP 5405581A JP S57167932 A JPS57167932 A JP S57167932A
Authority
JP
Japan
Prior art keywords
catalyst
dimerization
olefin
trialkylaluminum
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP56054055A
Other languages
Japanese (ja)
Other versions
JPS6219407B2 (en
Inventor
Hiroshi Sato
Masanobu Noguchi
Hideto Toshima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP56054055A priority Critical patent/JPS57167932A/en
Publication of JPS57167932A publication Critical patent/JPS57167932A/en
Publication of JPS6219407B2 publication Critical patent/JPS6219407B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: On the dimerization of a lower α-olefin in the presence of a catalyst composed of four components, a nickel compound, trialkylaluminum, a phosphorus-containing compound and a halogenated phenol, a catalyst amount of water is added to increase the activity of the catalyst.
CONSTITUTION: On the dimerization of a lower α-olefin using a catalyst that is composed of (A) at least one selected from organic acid salts, inorganic salts and complexes of nickel, (B) a trialkylaluminum, (C) at least one selected from trivalent phosphorus compounds of formulaI, II, and III (R1, R2, R3 are alkyl, cycloalkyl, alkenyl, phenyl; n=1W3). (D) at least one selected from halogenated phenols of formula IV (X1W5 are halogen, H, at least one is halogen), a catalyst amount of water is added, preferably at a molar ratio of 0.1W2.0 to the trialkylaluminum.
COPYRIGHT: (C)1982,JPO&Japio
JP56054055A 1981-04-09 1981-04-09 Dimerization of lower alpha-olefin Granted JPS57167932A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56054055A JPS57167932A (en) 1981-04-09 1981-04-09 Dimerization of lower alpha-olefin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56054055A JPS57167932A (en) 1981-04-09 1981-04-09 Dimerization of lower alpha-olefin

Publications (2)

Publication Number Publication Date
JPS57167932A true JPS57167932A (en) 1982-10-16
JPS6219407B2 JPS6219407B2 (en) 1987-04-28

Family

ID=12959924

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56054055A Granted JPS57167932A (en) 1981-04-09 1981-04-09 Dimerization of lower alpha-olefin

Country Status (1)

Country Link
JP (1) JPS57167932A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01221335A (en) * 1988-02-29 1989-09-04 Sumitomo Chem Co Ltd Dimerization of lower alpha-olefin
US5349115A (en) * 1992-05-08 1994-09-20 Sumitomo Chemical Co., Ltd. Dimerization of low α-olefins
US5414160A (en) * 1992-10-16 1995-05-09 Mitsubishi Kasei Corporation Method for dimerizing butenes, dimeric composition of butenes and method for producing alcohols by means thereof
US5446213A (en) * 1992-06-10 1995-08-29 Mitsubishi Kasei Corporation Dimerization method of lower olefins and alcohol production with dimerized products
US5910618A (en) * 1993-03-04 1999-06-08 Sumitomo Chemical Company, Limited Process for preparing 2,3-dimethyl-2-butene
RU2701511C1 (en) * 2018-11-27 2019-09-27 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр"Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН) Catalyst for dimerisation of ethylene in butenes and method of its preparation

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01221335A (en) * 1988-02-29 1989-09-04 Sumitomo Chem Co Ltd Dimerization of lower alpha-olefin
US4992610A (en) * 1988-02-29 1991-02-12 Sumitomo Chemical Company, Limited Dimerization of lower α-olefins
US5349115A (en) * 1992-05-08 1994-09-20 Sumitomo Chemical Co., Ltd. Dimerization of low α-olefins
US5446213A (en) * 1992-06-10 1995-08-29 Mitsubishi Kasei Corporation Dimerization method of lower olefins and alcohol production with dimerized products
US5414160A (en) * 1992-10-16 1995-05-09 Mitsubishi Kasei Corporation Method for dimerizing butenes, dimeric composition of butenes and method for producing alcohols by means thereof
US5910618A (en) * 1993-03-04 1999-06-08 Sumitomo Chemical Company, Limited Process for preparing 2,3-dimethyl-2-butene
RU2701511C1 (en) * 2018-11-27 2019-09-27 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр"Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН) Catalyst for dimerisation of ethylene in butenes and method of its preparation

Also Published As

Publication number Publication date
JPS6219407B2 (en) 1987-04-28

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