JPS5711931A - Production of allyl alcohol - Google Patents
Production of allyl alcoholInfo
- Publication number
- JPS5711931A JPS5711931A JP8687380A JP8687380A JPS5711931A JP S5711931 A JPS5711931 A JP S5711931A JP 8687380 A JP8687380 A JP 8687380A JP 8687380 A JP8687380 A JP 8687380A JP S5711931 A JPS5711931 A JP S5711931A
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- organolithium compound
- amine
- conducted
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: The reaction between an organolithium compound and 3,4-epoxybutene-1 in the presence of an amine such as N,N,N',N'-tetramethylethylenediamine gives the titled compound selectively, which mainly consists of the Z-type and used as a perfume or its intermediate.
CONSTITUTION: The reaction between an organolithium compound of RLi (R is alkyl, aralkyl, which may be substituted with functional groups) and 3,4-epoxy- butene-1 of formula I is conducted in the presence of an amine, any one of primary, secondary and tertiary amines, to produce a monosubstituted allyl alcohol mainly consisting of the Z-type of formula II such as 2-octen-1-ole. The organic part in the organolithium compound is varied to give various kinds of the oobjective compounds readily.
EFFECT: The reaction can be conducted through the shortest process with simple operations under mild conditions to give the product with high structural and conformational selectivety.
USE: Intermediate of medicines and agricultural chemicals.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8687380A JPS5711931A (en) | 1980-06-25 | 1980-06-25 | Production of allyl alcohol |
DE8080107288T DE3068252D1 (en) | 1979-11-22 | 1980-11-21 | Process for preparing predominantly z-substituted allylic alcohols |
EP80107288A EP0029603B1 (en) | 1979-11-22 | 1980-11-21 | Process for preparing predominantly z-substituted allylic alcohols |
US07/529,730 US5004843A (en) | 1979-11-22 | 1990-05-29 | Process for producing allylic alcohols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8687380A JPS5711931A (en) | 1980-06-25 | 1980-06-25 | Production of allyl alcohol |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5711931A true JPS5711931A (en) | 1982-01-21 |
JPS6328051B2 JPS6328051B2 (en) | 1988-06-07 |
Family
ID=13898936
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8687380A Granted JPS5711931A (en) | 1979-11-22 | 1980-06-25 | Production of allyl alcohol |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5711931A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0234727A (en) * | 1988-07-22 | 1990-02-05 | Kawasaki Steel Corp | Method and device for cooling metallic strip |
JPH0234729A (en) * | 1988-07-22 | 1990-02-05 | Kawasaki Steel Corp | Method for controlling injection of water into dip cooler in continuous annealing furnace |
JPH0234728A (en) * | 1988-07-22 | 1990-02-05 | Kawasaki Steel Corp | Method for controlling injection of water into dip cooler in continuous annealing furnace |
JPH03500292A (en) * | 1987-09-28 | 1991-01-24 | イーストマン ケミカル カンパニー | Method for producing 1,4-disubstituted 2-butenes |
-
1980
- 1980-06-25 JP JP8687380A patent/JPS5711931A/en active Granted
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03500292A (en) * | 1987-09-28 | 1991-01-24 | イーストマン ケミカル カンパニー | Method for producing 1,4-disubstituted 2-butenes |
JPH0234727A (en) * | 1988-07-22 | 1990-02-05 | Kawasaki Steel Corp | Method and device for cooling metallic strip |
JPH0234729A (en) * | 1988-07-22 | 1990-02-05 | Kawasaki Steel Corp | Method for controlling injection of water into dip cooler in continuous annealing furnace |
JPH0234728A (en) * | 1988-07-22 | 1990-02-05 | Kawasaki Steel Corp | Method for controlling injection of water into dip cooler in continuous annealing furnace |
JPH0583617B2 (en) * | 1988-07-22 | 1993-11-26 | Kawasaki Steel Co | |
JPH0583618B2 (en) * | 1988-07-22 | 1993-11-26 | Kawasaki Steel Co |
Also Published As
Publication number | Publication date |
---|---|
JPS6328051B2 (en) | 1988-06-07 |
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