JPS55154989A - Novel furanose derivative and its preparation - Google Patents

Novel furanose derivative and its preparation

Info

Publication number
JPS55154989A
JPS55154989A JP6286379A JP6286379A JPS55154989A JP S55154989 A JPS55154989 A JP S55154989A JP 6286379 A JP6286379 A JP 6286379A JP 6286379 A JP6286379 A JP 6286379A JP S55154989 A JPS55154989 A JP S55154989A
Authority
JP
Japan
Prior art keywords
formula
tetrahydropyranyl
derivative shown
trans
novel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6286379A
Other languages
Japanese (ja)
Other versions
JPS5643474B2 (en
Inventor
Hiroshi Orui
Noriyoshi Sueda
Hiromi Kuzuhara
Sakae Emoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN Institute of Physical and Chemical Research
Original Assignee
RIKEN Institute of Physical and Chemical Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN Institute of Physical and Chemical Research filed Critical RIKEN Institute of Physical and Chemical Research
Priority to JP6286379A priority Critical patent/JPS55154989A/en
Publication of JPS55154989A publication Critical patent/JPS55154989A/en
Publication of JPS5643474B2 publication Critical patent/JPS5643474B2/ja
Granted legal-status Critical Current

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  • Epoxy Compounds (AREA)
  • Saccharide Compounds (AREA)

Abstract

NEW MATERIAL:A compound shown by the formula I (R is H or tetrahydropyranyl).
EXAMPLE: 5-Dioxy-1,2-O-isopropylidene-5-C-(1'-kept-2',5'-trans, trans-dienyl)-3- O-tetrahydro-pyranyl-α-D-xylo-pentfuranose.
USE: A synthetic intermediate for various kinds of organic compounds. Useful as a synthetic intermediate for Cerulenin, an antibiotic having antifungal and antimicrobial activity.
PROCESS: A tetrahydropiranyl derivative shown by the formula II (THP is tetrahydropyranyl) is reduced in the presence of metal Li, Na, etc. in a mixed solvent of t- butanol, THF, and ammonia, preferably by adding ammonium sulfate to give a tetrahydropyranyl derivative shown by he formula I. This compound is subjected to the removal of tetrahydropyranyl group in the presence of an acid catalyst to give an alcohol derivative shown by the formula I.
COPYRIGHT: (C)1980,JPO&Japio
JP6286379A 1979-05-22 1979-05-22 Novel furanose derivative and its preparation Granted JPS55154989A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6286379A JPS55154989A (en) 1979-05-22 1979-05-22 Novel furanose derivative and its preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6286379A JPS55154989A (en) 1979-05-22 1979-05-22 Novel furanose derivative and its preparation

Publications (2)

Publication Number Publication Date
JPS55154989A true JPS55154989A (en) 1980-12-02
JPS5643474B2 JPS5643474B2 (en) 1981-10-13

Family

ID=13212547

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6286379A Granted JPS55154989A (en) 1979-05-22 1979-05-22 Novel furanose derivative and its preparation

Country Status (1)

Country Link
JP (1) JPS55154989A (en)

Also Published As

Publication number Publication date
JPS5643474B2 (en) 1981-10-13

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