JPS57108032A - Preparation of allylic ether - Google Patents
Preparation of allylic etherInfo
- Publication number
- JPS57108032A JPS57108032A JP55183952A JP18395280A JPS57108032A JP S57108032 A JPS57108032 A JP S57108032A JP 55183952 A JP55183952 A JP 55183952A JP 18395280 A JP18395280 A JP 18395280A JP S57108032 A JPS57108032 A JP S57108032A
- Authority
- JP
- Japan
- Prior art keywords
- expressed
- iii
- alcohol
- allylic ether
- ruthenium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain an allylic ether useful as an intermediate for medicines or perfumes or as a perfume economically and in high yield, by reacting an allyl alcohol with an alcohol in the presence of a ruthenium (III) salt.
CONSTITUTION: An allyl alcohol expressed by formulaI(R1, R2, R3, R4 and R5 are H, alkyl, alkenyl or aryl) is reacted with an alcohol expressed by the formula R6OH (R6 is alkyl or alkenyl) in the presence of a ruthenium (III) salt expressed by the formula RuXYZ (X, Y and Z are halogen, H, alkoxyl, acyloxy, silyl or OH), e.g. RuCl3, RuBr3 or Ru3O(OAc)7, at room temperature W80°C to give an allylic ether expressec by formulas II and III. The compound expressed by formulaIis easily available as an industrial raw material.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55183952A JPS57108032A (en) | 1980-12-26 | 1980-12-26 | Preparation of allylic ether |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55183952A JPS57108032A (en) | 1980-12-26 | 1980-12-26 | Preparation of allylic ether |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57108032A true JPS57108032A (en) | 1982-07-05 |
Family
ID=16144682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55183952A Pending JPS57108032A (en) | 1980-12-26 | 1980-12-26 | Preparation of allylic ether |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57108032A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3428146A1 (en) * | 2017-07-14 | 2019-01-16 | International Flavors & Fragrances Inc. | Novel organoleptic compounds |
-
1980
- 1980-12-26 JP JP55183952A patent/JPS57108032A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3428146A1 (en) * | 2017-07-14 | 2019-01-16 | International Flavors & Fragrances Inc. | Novel organoleptic compounds |
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