JPS5676419A - Production of water-swellable polymer - Google Patents
Production of water-swellable polymerInfo
- Publication number
- JPS5676419A JPS5676419A JP15463279A JP15463279A JPS5676419A JP S5676419 A JPS5676419 A JP S5676419A JP 15463279 A JP15463279 A JP 15463279A JP 15463279 A JP15463279 A JP 15463279A JP S5676419 A JPS5676419 A JP S5676419A
- Authority
- JP
- Japan
- Prior art keywords
- alkali metal
- polymer
- water
- metal acrylate
- neutralization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To obtain a highly water-absorbing, sanitarily safe polymer, by dispersing an aqueous alkali metal acrylate solution containing hydroxyethyl cellulose into a solvent in the presence of a sorbitan fatty acid ester.
CONSTITUTION: A 35wt%Wsaturated aqueous alkali metal acrylate solution containing a water-soluble radical polymerization initiator and hydroxyethyl cellulose is dispersed in an aliphatic hydrocarbon type solvent in the presence of a sorbitan fatty acid ester, HLB 3W6, and the resulting dispersion is polymerized in the absence of a crosslinking agent. In the production of an alkali metal acrylate polymer, the neutralization of acrylic acid must be performed by use of an alkali metal hydroxide before starting the polymerization, because the polymer is difficult to grind into powder. The degree of neutralization is 50W95mol%. As the apliphatic hydrocarbon which can be used, n-hexane is particularly preferred.
USE: Napkins, paper-diapers, etc.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15463279A JPS5676419A (en) | 1979-11-29 | 1979-11-29 | Production of water-swellable polymer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15463279A JPS5676419A (en) | 1979-11-29 | 1979-11-29 | Production of water-swellable polymer |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5676419A true JPS5676419A (en) | 1981-06-24 |
Family
ID=15588434
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15463279A Pending JPS5676419A (en) | 1979-11-29 | 1979-11-29 | Production of water-swellable polymer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5676419A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4459396A (en) * | 1981-08-20 | 1984-07-10 | Kao Soap Co., Ltd. | Process for producing water-absorbent materials having excellent water absorption properties |
JPS6295308A (en) * | 1985-10-21 | 1987-05-01 | Mitsubishi Petrochem Co Ltd | Production of highly water-absorbing polymer bead |
EP0242529A2 (en) * | 1986-04-19 | 1987-10-28 | Starchem Gmbh | Process for the preparation of water absorbent and water-swellable polysaccharide graft polymers |
JPS63118375A (en) * | 1986-06-04 | 1988-05-23 | Seitetsu Kagaku Co Ltd | Water-absorptive composition |
JPH02191604A (en) * | 1988-06-28 | 1990-07-27 | Nippon Shokubai Kagaku Kogyo Co Ltd | Water-absorbing resin and production thereof |
US5783678A (en) * | 1995-03-24 | 1998-07-21 | Nippon Shokubai Co., Ltd. | Acrylic ester derivative and producing of the same and acrylic-ester-based polymer |
US5792855A (en) * | 1993-08-03 | 1998-08-11 | Nippon Shokubai Co., Ltd. | Water-absorbent resins and manufacturing methods thereof |
US6087002A (en) * | 1988-06-28 | 2000-07-11 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Water absorbent resin |
-
1979
- 1979-11-29 JP JP15463279A patent/JPS5676419A/en active Pending
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4459396A (en) * | 1981-08-20 | 1984-07-10 | Kao Soap Co., Ltd. | Process for producing water-absorbent materials having excellent water absorption properties |
JPS6295308A (en) * | 1985-10-21 | 1987-05-01 | Mitsubishi Petrochem Co Ltd | Production of highly water-absorbing polymer bead |
EP0242529A2 (en) * | 1986-04-19 | 1987-10-28 | Starchem Gmbh | Process for the preparation of water absorbent and water-swellable polysaccharide graft polymers |
JPS63118375A (en) * | 1986-06-04 | 1988-05-23 | Seitetsu Kagaku Co Ltd | Water-absorptive composition |
JPH0534383B2 (en) * | 1986-06-04 | 1993-05-21 | Sumitomo Seika Kk | |
JPH02191604A (en) * | 1988-06-28 | 1990-07-27 | Nippon Shokubai Kagaku Kogyo Co Ltd | Water-absorbing resin and production thereof |
US6087002A (en) * | 1988-06-28 | 2000-07-11 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Water absorbent resin |
US5792855A (en) * | 1993-08-03 | 1998-08-11 | Nippon Shokubai Co., Ltd. | Water-absorbent resins and manufacturing methods thereof |
US5783678A (en) * | 1995-03-24 | 1998-07-21 | Nippon Shokubai Co., Ltd. | Acrylic ester derivative and producing of the same and acrylic-ester-based polymer |
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