JPS5643247A - Preparation of tertiary amine - Google Patents
Preparation of tertiary amineInfo
- Publication number
- JPS5643247A JPS5643247A JP11902279A JP11902279A JPS5643247A JP S5643247 A JPS5643247 A JP S5643247A JP 11902279 A JP11902279 A JP 11902279A JP 11902279 A JP11902279 A JP 11902279A JP S5643247 A JPS5643247 A JP S5643247A
- Authority
- JP
- Japan
- Prior art keywords
- carboxylic acid
- mixture
- tertiary amine
- amine
- reducing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003512 tertiary amines Chemical class 0.000 title abstract 4
- 150000001734 carboxylic acid salts Chemical class 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- -1 cyclic amine Chemical class 0.000 abstract 3
- SYNHCENRCUAUNM-UHFFFAOYSA-N Nitrogen mustard N-oxide hydrochloride Chemical compound Cl.ClCC[N+]([O-])(C)CCCl SYNHCENRCUAUNM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003638 chemical reducing agent Substances 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Abstract
PURPOSE: To prepare a tertiary amine without reducing the catalytic activity and selectivity, by reacting a mono- or polyhydric alcohol, an aldehyde or a ketone with a cyclic amine or an aliphatic oxyamine in the presence of particular colloidal catalyst.
CONSTITUTION: A tertiary amine is prepared by reacting a mono- or polyhydric alcohol, an aldehyde or a ketone with a cyclic primary or secondary amine or an aliphatic primary or sencondary oxyamine corresponding to the objective tertiary amine, at 150W300°C, in the presence of a catalyst obtained by reducing a mixture of (A) a carboxylic acid salt of copper or silver or their intramolecular complex, (B) a carboxylic acid salt of a VIII-group element, Mn or Zn or their intramolecular complex, and (C) a carboxylic acid or its alkali or alkaline earth metal salt, or a mixture of (A), (B) and (C) wherein both (A) and (B) are carboxylic acid salts, or a mixture of (A), (B) and (C) wherein one of (A) and (B) is a carboxylic acid salt and the other is an intramolecular complex, with a reducing agent selected from H, a mixture of H and an amine, and other reducing agents.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54119022A JPS6011020B2 (en) | 1979-09-17 | 1979-09-17 | Production method of tertiary amine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54119022A JPS6011020B2 (en) | 1979-09-17 | 1979-09-17 | Production method of tertiary amine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5643247A true JPS5643247A (en) | 1981-04-21 |
| JPS6011020B2 JPS6011020B2 (en) | 1985-03-22 |
Family
ID=14751038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54119022A Expired JPS6011020B2 (en) | 1979-09-17 | 1979-09-17 | Production method of tertiary amine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6011020B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008018148A1 (en) * | 2006-08-11 | 2008-02-14 | Kokura Synthetic Industries, Ltd. | Process for producing amino compound |
-
1979
- 1979-09-17 JP JP54119022A patent/JPS6011020B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6011020B2 (en) | 1985-03-22 |
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