JPS5636433A - Preparation of glycerol tri meth acrylate - Google Patents

Preparation of glycerol tri meth acrylate

Info

Publication number
JPS5636433A
JPS5636433A JP11256279A JP11256279A JPS5636433A JP S5636433 A JPS5636433 A JP S5636433A JP 11256279 A JP11256279 A JP 11256279A JP 11256279 A JP11256279 A JP 11256279A JP S5636433 A JPS5636433 A JP S5636433A
Authority
JP
Japan
Prior art keywords
acrylate
meth
methyl
glycerine
pref
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11256279A
Other languages
Japanese (ja)
Inventor
Masayoshi Kubo
Kimio Inoue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daicel Corp
Original Assignee
Daicel Corp
Daicel Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daicel Corp, Daicel Chemical Industries Ltd filed Critical Daicel Corp
Priority to JP11256279A priority Critical patent/JPS5636433A/en
Publication of JPS5636433A publication Critical patent/JPS5636433A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To prepare the titled compound useful as a raw material of photosetting paint, etc., economically, without polymerization loss nor necessity for removing the moisture in the reaction system, by the ester exchange of methyl acrylate with glycerine in the presence of metallic lithium as a catalyst.
CONSTITUTION: Glycerol tri(meth)acrylate is prepared by the ester exchange reaction of methyl (meth)acrylate with glycerine in the presence of metallic lithium catalyst pref. in the presence of a polymerization inhibitor such as hydroquinone, diphenylamine, etc., at 70W110°C. The molar ratio of glycerine to methyl (meth) acrylate is 1 to about 6W30, and the amount of the catalyst is pref. about 1×10-4W 10-1wt% based on the total reaction system. The amount of the polymerization inhibitor is pref. about 0.1W5wt% based on the methyl (meth)acrylate.
COPYRIGHT: (C)1981,JPO&Japio
JP11256279A 1979-09-03 1979-09-03 Preparation of glycerol tri meth acrylate Pending JPS5636433A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11256279A JPS5636433A (en) 1979-09-03 1979-09-03 Preparation of glycerol tri meth acrylate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11256279A JPS5636433A (en) 1979-09-03 1979-09-03 Preparation of glycerol tri meth acrylate

Publications (1)

Publication Number Publication Date
JPS5636433A true JPS5636433A (en) 1981-04-09

Family

ID=14589777

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11256279A Pending JPS5636433A (en) 1979-09-03 1979-09-03 Preparation of glycerol tri meth acrylate

Country Status (1)

Country Link
JP (1) JPS5636433A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6270341A (en) * 1985-09-24 1987-03-31 Daicel Chem Ind Ltd Production of glycidol ester unsaturated monomer
JPH01246289A (en) * 1988-01-04 1989-10-02 Dow Corning Corp Preparation and stabilization of acryl functional halosilane
EP1468981A1 (en) * 2003-04-18 2004-10-20 Mitsubishi Gas Chemical Company, Inc. Production method of adamantyl acrylate compounds

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6270341A (en) * 1985-09-24 1987-03-31 Daicel Chem Ind Ltd Production of glycidol ester unsaturated monomer
JPH01246289A (en) * 1988-01-04 1989-10-02 Dow Corning Corp Preparation and stabilization of acryl functional halosilane
EP1468981A1 (en) * 2003-04-18 2004-10-20 Mitsubishi Gas Chemical Company, Inc. Production method of adamantyl acrylate compounds
US7067692B2 (en) 2003-04-18 2006-06-27 Mitsubishi Gas Chemical Company, Inc. Production method of adamantyl acrylate compounds

Similar Documents

Publication Publication Date Title
JPS5576829A (en) Beta,gamma-dihydropolyprenyl alcohol and hypotensive agent made from it
JPS5636433A (en) Preparation of glycerol tri meth acrylate
JPS51133227A (en) Preparation of 2-hydroxyalkyl (meth)acrylate
JPS53141216A (en) Preparation of methacrylic acid ester
JPS5334714A (en) Preparation of dialkylaminoalkyl acrylate and dialkylaminoalkyl methacrylate
JPS5212125A (en) Process for preparation of oligoester (meth)acrylate emulsion
JPS54125610A (en) Preparation of polymerizable polyacrylate
JPS5419911A (en) Preparation of dialkylaminoethyl ester of acrylic acid or methacrylic acid
JPS5498754A (en) 3-hydroxy-3-bromomethylphthalide derivative
JPS547486A (en) Photopolymerizable composition
JPS5334729A (en) Preparation of alpha-siloxy-alpha-cyanocarboxylic acid esters
JPS5221035A (en) Electron radiation curing coating composition
JPS54148757A (en) (2-fluoro-4-biphenylyl) ketene mercaptal s-oxide
JPS5439042A (en) Preparation of 2-(4-iso butylphenyl)-propionic acid
JPS57156438A (en) Preparation of methyl methacrylate
JPS52111513A (en) Preparation of 3,3-dimethyl-4-penthnoic acid methyl ester
JPS5518434A (en) Preparation of fixed cryptand
JPS5373533A (en) Preparation of aromatic dicarboxylic acid diaryl ester
JPS52133962A (en) Synthesis of 2-(6-methoxy-2-naphthyl)-propionic acid
JPS5473737A (en) Substituted diphenylamine and its preparation
JPS5412320A (en) Preparation of 2-acetyl-3, 3-dimethyl-4-pentenoic acid ester
JPS5587770A (en) Preparation of 2-(p-isobutylphenyl)propionic acid 2-pyridinemethyl ester
JPS51119731A (en) Tacky cement composition
JPS5421496A (en) Preparation of polyester having high polymerization degree
JPS5315333A (en) Organic peroxide composition