JPS56155020A - Preparation of cuprous oxide - Google Patents
Preparation of cuprous oxideInfo
- Publication number
- JPS56155020A JPS56155020A JP5433880A JP5433880A JPS56155020A JP S56155020 A JPS56155020 A JP S56155020A JP 5433880 A JP5433880 A JP 5433880A JP 5433880 A JP5433880 A JP 5433880A JP S56155020 A JPS56155020 A JP S56155020A
- Authority
- JP
- Japan
- Prior art keywords
- aqueous solution
- cuprous
- chloride
- nacl
- cupric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- ing And Chemical Polishing (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
PURPOSE: To prepare cuprous oxide having improved pigment characteristics through its precipitation, by reducing a waste liquor obtained after the etching of a copper plate using an aqueous solution of cupric chloride into a salt aqueous solution of cuprous chloride, followed by adjusting it to a pH in a specific range with an alkali aqueous solution.
CONSTITUTION: A waste liquor obtained by etching a copper plate using an aqueous solution of cupric chloride, comprising 0.1W200g/l Cu, 0W300g/l NaCl, and 3W100g/l free hydrochloric acid, is heated to 50°C, air is introduced to the solution so that cuprous ion contained is oxidized into cupric ion. NaCl and HCl are then added to the solution, which is brought into contact with metal copper in nitrogen flow so that cupric chloride is reduced into cuprous chloride, to give a salt aqueous solution of cuprous chloride comprising 50W100g/l Cu, 230W280g/l NaCl, and 0.01W10g/l free hydrochloric acid. An aqueous solution of NaOH is added to the salt aqueous solution, which is adjusted to pH 8.5W12.5 to precipitate cuprous oxide, which is collected from the aqueous solution.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5433880A JPS5950603B2 (en) | 1980-04-25 | 1980-04-25 | Production method of cuprous oxide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5433880A JPS5950603B2 (en) | 1980-04-25 | 1980-04-25 | Production method of cuprous oxide |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56155020A true JPS56155020A (en) | 1981-12-01 |
JPS5950603B2 JPS5950603B2 (en) | 1984-12-10 |
Family
ID=12967811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5433880A Expired JPS5950603B2 (en) | 1980-04-25 | 1980-04-25 | Production method of cuprous oxide |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5950603B2 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59174526A (en) * | 1983-03-24 | 1984-10-03 | Nippon Chem Ind Co Ltd:The | Manufacture of cuprous oxide |
KR100379903B1 (en) * | 2000-05-30 | 2003-04-14 | 주식회사 명진화학 | Preparation of highly pure copper oxide from waste etchant |
KR100390588B1 (en) * | 2000-08-01 | 2003-07-07 | 서안켐텍 주식회사 | Process for preparing cuprous oxide |
KR100415645B1 (en) * | 1998-12-21 | 2004-03-19 | 주식회사 포스코 | METHOD FOR PRODUCING A HIGH-PURITY CuO |
CN107662939A (en) * | 2017-09-24 | 2018-02-06 | 盐城师范学院 | A kind of quick controllable method for preparing in interface of the stannous chloride nano-sheet crystals material of iron ion induction |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7394791B2 (en) | 1997-12-17 | 2008-07-01 | Interdigital Technology Corporation | Multi-detection of heartbeat to reduce error probability |
ES2626289T3 (en) | 2001-06-13 | 2017-07-24 | Intel Corporation | Method and apparatus for transmitting heartbeat signal at a lower level than the heartbeat request |
-
1980
- 1980-04-25 JP JP5433880A patent/JPS5950603B2/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59174526A (en) * | 1983-03-24 | 1984-10-03 | Nippon Chem Ind Co Ltd:The | Manufacture of cuprous oxide |
JPH0240612B2 (en) * | 1983-03-24 | 1990-09-12 | Nippon Chemical Ind | |
KR100415645B1 (en) * | 1998-12-21 | 2004-03-19 | 주식회사 포스코 | METHOD FOR PRODUCING A HIGH-PURITY CuO |
KR100379903B1 (en) * | 2000-05-30 | 2003-04-14 | 주식회사 명진화학 | Preparation of highly pure copper oxide from waste etchant |
KR100390588B1 (en) * | 2000-08-01 | 2003-07-07 | 서안켐텍 주식회사 | Process for preparing cuprous oxide |
CN107662939A (en) * | 2017-09-24 | 2018-02-06 | 盐城师范学院 | A kind of quick controllable method for preparing in interface of the stannous chloride nano-sheet crystals material of iron ion induction |
CN107662939B (en) * | 2017-09-24 | 2019-08-06 | 盐城师范学院 | A kind of quick controllable method for preparing in interface of the stannous chloride nano-sheet crystals material of iron ion induction |
Also Published As
Publication number | Publication date |
---|---|
JPS5950603B2 (en) | 1984-12-10 |
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