JPS56122390A - Preparation of bissilylated ethylene - Google Patents
Preparation of bissilylated ethyleneInfo
- Publication number
- JPS56122390A JPS56122390A JP2476180A JP2476180A JPS56122390A JP S56122390 A JPS56122390 A JP S56122390A JP 2476180 A JP2476180 A JP 2476180A JP 2476180 A JP2476180 A JP 2476180A JP S56122390 A JPS56122390 A JP S56122390A
- Authority
- JP
- Japan
- Prior art keywords
- group
- formula
- titled compound
- disilane
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To obtain the titled compound useful as a raw material for preparing vinyl silane, adhesive, etc. industrially advantageously, by reacting a disilane, a readily obtainable raw material, with acetlylene in the presence of a catalytic amount of a phosphorus complex of VIII group element.
CONSTITUTION: A disilane shown by the formula I (X is Cl or a monofunctional group selected from the group consisting of 1W4C alkoxy; R1 is monofunctional hydrocarbon group; a and b are 0W3) is reacted with acetylene in the presence of a catalytic amount of a phosphorus complex of VIII group element (e.g., 0 functional Pd.phosphine complex), to give the titled compound shown by the formula II. Methyl group is preferable as R1 in the formula I because it is readily obtainable and does not cause side reactions. X is preferably Cl is preferably Cl or methoxy group. Almost all of the titled compound which is prepared are cis isomer.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2476180A JPS56122390A (en) | 1980-02-29 | 1980-02-29 | Preparation of bissilylated ethylene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2476180A JPS56122390A (en) | 1980-02-29 | 1980-02-29 | Preparation of bissilylated ethylene |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS56122390A true JPS56122390A (en) | 1981-09-25 |
Family
ID=12147125
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2476180A Pending JPS56122390A (en) | 1980-02-29 | 1980-02-29 | Preparation of bissilylated ethylene |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56122390A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4921917A (en) * | 1987-10-01 | 1990-05-01 | Dow Corning Corporation | Pre-ceramic methylpolysilanes |
JPH04352790A (en) * | 1990-06-13 | 1992-12-07 | Agency Of Ind Science & Technol | Organosilicon compound with bissilylalkene skeleton, its production and electrically conductive material using the same |
JPH04364192A (en) * | 1990-03-07 | 1992-12-16 | Agency Of Ind Science & Technol | Production of organic bisgermylethylenes and new organic germylethylenes |
WO2014097574A1 (en) * | 2012-12-20 | 2014-06-26 | 信越化学工業株式会社 | Novel alkoxysilyl-ethylene-group-terminated silicon-containing compound, room-temperature-curable organopolysiloxane composition, and molded article obtained by curing said composition |
WO2014097573A1 (en) * | 2012-12-20 | 2014-06-26 | 信越化学工業株式会社 | Novel ethynyl-group-containing organopolysiloxane compound, method for producing straight-chain organopolysiloxane compound containing ethynyl group at both molecular chain ends, method for producing alkoxysilyl-ethynyl-group-terminated organosiloxane polymer, room-temperature-curable composition, and molded article that is cured product of same |
WO2015093139A1 (en) * | 2013-12-17 | 2015-06-25 | 信越化学工業株式会社 | Multicomponent room temperature-curable organopolysiloxane composition, cured product of said composition, and molded product comprising said cured product |
JPWO2016157948A1 (en) * | 2015-04-03 | 2018-02-15 | 信越化学工業株式会社 | Room temperature curable organopolysiloxane composition and molded article which is a cured product of the composition |
-
1980
- 1980-02-29 JP JP2476180A patent/JPS56122390A/en active Pending
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4921917A (en) * | 1987-10-01 | 1990-05-01 | Dow Corning Corporation | Pre-ceramic methylpolysilanes |
JPH04364192A (en) * | 1990-03-07 | 1992-12-16 | Agency Of Ind Science & Technol | Production of organic bisgermylethylenes and new organic germylethylenes |
JPH04352790A (en) * | 1990-06-13 | 1992-12-07 | Agency Of Ind Science & Technol | Organosilicon compound with bissilylalkene skeleton, its production and electrically conductive material using the same |
JP2676002B2 (en) * | 1990-06-13 | 1997-11-12 | 工業技術院長 | Method for producing bissilylalkene compound |
JP5960843B2 (en) * | 2012-12-20 | 2016-08-02 | 信越化学工業株式会社 | Process for producing alkoxysilyl-ethylene group-terminated organosiloxane polymer, room temperature curable composition and molded product which is cured product thereof |
US9475969B2 (en) | 2012-12-20 | 2016-10-25 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane compound having ethynyl groups, method for preparing linear organopolysiloxane compound having ethynyl groups at both terminals of molecular chain, method for preparing organopolysiloxane polymer having alkoxysilyl-ethylene group at terminal, room temperature curable composition and molded product which is cured product thereof |
US9644124B2 (en) | 2012-12-20 | 2017-05-09 | Shin-Etsu Chemical Co., Ltd. | Silicon-containing compound having alkoxysilyl-ethylene group at its terminal, room temperature-curable organopolysiloxane composition, and molded product obtained by curing the composition |
CN104870524A (en) * | 2012-12-20 | 2015-08-26 | 信越化学工业株式会社 | Novel ethynyl-group-containing organopolysiloxane compound, method for producing straight-chain organopolysiloxane compound containing ethynyl group at both molecular chain ends, method for producing alkoxysilyl-ethynyl-group-terminated organosiloxane polymer, room-temperature-curable composition, and molded article that is cured product of same |
CN104884461A (en) * | 2012-12-20 | 2015-09-02 | 信越化学工业株式会社 | Novel alkoxysilyl-ethylene-group-terminated silicon-containing compound, room-temperature-curable organopolysiloxane composition, and molded article obtained by curing said composition |
EP2937352A4 (en) * | 2012-12-20 | 2016-07-20 | Shinetsu Chemical Co | Novel alkoxysilyl-ethylene-group-terminated silicon-containing compound, room-temperature-curable organopolysiloxane composition, and molded article obtained by curing said composition |
WO2014097574A1 (en) * | 2012-12-20 | 2014-06-26 | 信越化学工業株式会社 | Novel alkoxysilyl-ethylene-group-terminated silicon-containing compound, room-temperature-curable organopolysiloxane composition, and molded article obtained by curing said composition |
JPWO2014097574A1 (en) * | 2012-12-20 | 2017-01-12 | 信越化学工業株式会社 | Novel alkoxysilyl-ethylene group-terminated silicon-containing compound, room temperature curable organopolysiloxane composition, and molded product obtained by curing the composition |
JP5997778B2 (en) * | 2012-12-20 | 2016-09-28 | 信越化学工業株式会社 | Novel alkoxysilyl-ethylene group-terminated silicon-containing compound, room temperature curable organopolysiloxane composition, and molded product obtained by curing the composition |
WO2014097573A1 (en) * | 2012-12-20 | 2014-06-26 | 信越化学工業株式会社 | Novel ethynyl-group-containing organopolysiloxane compound, method for producing straight-chain organopolysiloxane compound containing ethynyl group at both molecular chain ends, method for producing alkoxysilyl-ethynyl-group-terminated organosiloxane polymer, room-temperature-curable composition, and molded article that is cured product of same |
JPWO2014097573A1 (en) * | 2012-12-20 | 2017-01-12 | 信越化学工業株式会社 | Process for producing alkoxysilyl-ethylene group-terminated organosiloxane polymer, room temperature curable composition and molded product which is cured product thereof |
CN105829449A (en) * | 2013-12-17 | 2016-08-03 | 信越化学工业株式会社 | Multicomponent room temperature-curable organopolysiloxane composition, cured product of said composition, and molded product comprising said cured product |
JPWO2015093139A1 (en) * | 2013-12-17 | 2017-03-16 | 信越化学工業株式会社 | Multi-component room temperature curable organopolysiloxane composition, cured product of the composition, and molded product comprising the cured product |
WO2015093139A1 (en) * | 2013-12-17 | 2015-06-25 | 信越化学工業株式会社 | Multicomponent room temperature-curable organopolysiloxane composition, cured product of said composition, and molded product comprising said cured product |
US9850349B2 (en) | 2013-12-17 | 2017-12-26 | Shin-Etsu Chemical Co., Ltd. | Multicomponent room temperature-curable organopolysiloxane composition, cured product of said composition, and molded product comprising said cured product |
CN105829449B (en) * | 2013-12-17 | 2019-07-05 | 信越化学工业株式会社 | The solidfied material of multicomponent system normal temperature cured organic polysiloxane composition and the composition and molding including the solidfied material |
JPWO2016157948A1 (en) * | 2015-04-03 | 2018-02-15 | 信越化学工業株式会社 | Room temperature curable organopolysiloxane composition and molded article which is a cured product of the composition |
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