JPS56113789A - Synthetic method of phosphoenol pyruvic acid - Google Patents

Synthetic method of phosphoenol pyruvic acid

Info

Publication number
JPS56113789A
JPS56113789A JP246980A JP246980A JPS56113789A JP S56113789 A JPS56113789 A JP S56113789A JP 246980 A JP246980 A JP 246980A JP 246980 A JP246980 A JP 246980A JP S56113789 A JPS56113789 A JP S56113789A
Authority
JP
Japan
Prior art keywords
compound
pyruvic acid
trialkylsilyl
tmsx
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP246980A
Other languages
Japanese (ja)
Other versions
JPS5826915B2 (en
Inventor
Tsujiaki Hata
Mitsuo Sekine
Koji Yamada
Tetsuaki Futaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JNC Corp
Original Assignee
Chisso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chisso Corp filed Critical Chisso Corp
Priority to JP246980A priority Critical patent/JPS5826915B2/en
Publication of JPS56113789A publication Critical patent/JPS56113789A/en
Publication of JPS5826915B2 publication Critical patent/JPS5826915B2/en
Expired legal-status Critical Current

Links

Abstract

PURPOSE: To obtain the titled compound useful as a biochemical reagent, etc. in high yield without separating an intermediate, by reacting a silylated pyruvic acid which has been reacted with a halogen with a dialkyl trialkylsilyl phosphite as starting materials, and treating the reaction product with a base.
CONSTITUTION: A silylated pyruvic acid, e.g. compound 1, is reacted with a halogen of the formula X (X is halogen, e.g. Cl or Br) to give a reaction solution in which one mole each trialkylsilyl α-halopyruvate and trimethylhalogenosilane (TMSX) are formed. The reaction solution is then treated with a dialkyl trialkylsilyl phosphite (DTSP) to give one mole TMSX and one mole tris (trialkylsilyl) ester of dialkylphosphoenol pyruvic acid. The resultant compound and 2mol in total TMSX formed are utilized to afford a compound 4 which is then treated with a base to give the titled compound of compound 5.
COPYRIGHT: (C)1981,JPO&Japio
JP246980A 1980-01-12 1980-01-12 Synthesis method of phosphoenolpyruvate Expired JPS5826915B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP246980A JPS5826915B2 (en) 1980-01-12 1980-01-12 Synthesis method of phosphoenolpyruvate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP246980A JPS5826915B2 (en) 1980-01-12 1980-01-12 Synthesis method of phosphoenolpyruvate

Publications (2)

Publication Number Publication Date
JPS56113789A true JPS56113789A (en) 1981-09-07
JPS5826915B2 JPS5826915B2 (en) 1983-06-06

Family

ID=11530168

Family Applications (1)

Application Number Title Priority Date Filing Date
JP246980A Expired JPS5826915B2 (en) 1980-01-12 1980-01-12 Synthesis method of phosphoenolpyruvate

Country Status (1)

Country Link
JP (1) JPS5826915B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02203910A (en) * 1989-02-03 1990-08-13 Fukagawa:Kk Pipe filter for air feed fan

Also Published As

Publication number Publication date
JPS5826915B2 (en) 1983-06-06

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