JPS5554581A - Improved electrolyzing method of aqueous alkali chloride solution - Google Patents

Improved electrolyzing method of aqueous alkali chloride solution

Info

Publication number
JPS5554581A
JPS5554581A JP12689678A JP12689678A JPS5554581A JP S5554581 A JPS5554581 A JP S5554581A JP 12689678 A JP12689678 A JP 12689678A JP 12689678 A JP12689678 A JP 12689678A JP S5554581 A JPS5554581 A JP S5554581A
Authority
JP
Japan
Prior art keywords
ion exchange
aqueous alkali
membrane
fluorine
surface layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12689678A
Other languages
Japanese (ja)
Other versions
JPS6240433B2 (en
Inventor
Kiyotaka Arai
Manabu Kazuhara
Yoshio Oda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to JP12689678A priority Critical patent/JPS5554581A/en
Publication of JPS5554581A publication Critical patent/JPS5554581A/en
Publication of JPS6240433B2 publication Critical patent/JPS6240433B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE: To enhance current efficiency and lower voltage by modifying the surface layer of the fluorine-contained cation exchange membrance which has COOH groups as ion exchange groups and is limited in ion exchange capacity, under the specific conditions thereby producing alkali hydroxide of low concentration.
CONSTITUTION: The surface layer portions of the fluorine-contained cation exchange membrane of the dry resin which has COOH groups as ion exchange groups and is of 1.1W2, particularly 1.2W1.7 milli equivalent/g in ion exchange capacity are contacted with an aqueous alkali hydroxide solution of a concentration above 40% at 80°C or more. Thereby, the ion exchange capacity of the membrane surface layer portions is lowered to 45W95% (0.8W1.3 mill equivalent/g dry resin) that of the membrane body portions. Next, the aqueous alkali chloride solution is electrolyzed by using the resultant moldified fluorine-contained cation exchange membrane, whereby alkali hydroxide and Cl2 of concentrations 15W30% are produced.
COPYRIGHT: (C)1980,JPO&Japio
JP12689678A 1978-10-17 1978-10-17 Improved electrolyzing method of aqueous alkali chloride solution Granted JPS5554581A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12689678A JPS5554581A (en) 1978-10-17 1978-10-17 Improved electrolyzing method of aqueous alkali chloride solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12689678A JPS5554581A (en) 1978-10-17 1978-10-17 Improved electrolyzing method of aqueous alkali chloride solution

Publications (2)

Publication Number Publication Date
JPS5554581A true JPS5554581A (en) 1980-04-21
JPS6240433B2 JPS6240433B2 (en) 1987-08-28

Family

ID=14946547

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12689678A Granted JPS5554581A (en) 1978-10-17 1978-10-17 Improved electrolyzing method of aqueous alkali chloride solution

Country Status (1)

Country Link
JP (1) JPS5554581A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0479108U (en) * 1990-11-20 1992-07-09

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5281098A (en) * 1975-12-29 1977-07-07 Tokuyama Soda Co Ltd Electrolysis of aqueous solution of alkali metals

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5281098A (en) * 1975-12-29 1977-07-07 Tokuyama Soda Co Ltd Electrolysis of aqueous solution of alkali metals

Also Published As

Publication number Publication date
JPS6240433B2 (en) 1987-08-28

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