JPS5539277A - Oxidation-resistant ion exchange resin and method of using it - Google Patents
Oxidation-resistant ion exchange resin and method of using itInfo
- Publication number
- JPS5539277A JPS5539277A JP11337878A JP11337878A JPS5539277A JP S5539277 A JPS5539277 A JP S5539277A JP 11337878 A JP11337878 A JP 11337878A JP 11337878 A JP11337878 A JP 11337878A JP S5539277 A JPS5539277 A JP S5539277A
- Authority
- JP
- Japan
- Prior art keywords
- ion exchange
- exchange resins
- exchange resin
- halogenation
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/016—Modification or after-treatment of ion-exchangers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Abstract
PURPOSE: To make an ion exchange resin oxidation-resistant and enable chrome plating solution, etc. containing oxidizing agents to be treated by subjecting the ion exchange resins to halogenation.
CONSTITUTION: Sulfonated styrene-divinyl benzene copolymer, and other organic polymers having ion exchange ability are contacted with halogen such as chlorine, etc. under atmospheric pressure or pressure. At this time, temperature is made about -20W200°C, preferably 0W100°C and the amount of introduction of halogen is made more than about 0.05 mole, preferably 0.1W2 moles per monomer unit of the ion exchange resins. This halogenation may be executed in the absence of any solvent or in the presence of water, nitrobenzene, etc. The ion exchange resins treated in this way keeps low the amount of change of Cr6+ of chrome plating solution to Cr3+ and is extremely useful in removal of impurities such as Zn2+, Fe3+, etc. which increase gradually during the process.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11337878A JPS5539277A (en) | 1978-09-13 | 1978-09-13 | Oxidation-resistant ion exchange resin and method of using it |
DE19792936922 DE2936922A1 (en) | 1978-09-13 | 1979-09-12 | OXIDATION RESISTANT ION EXCHANGE RESINS AND USE THEREOF IN ELIMINATING CATIONS FROM OXIDIZER SOLUTIONS |
NL7906849A NL7906849A (en) | 1978-09-13 | 1979-09-13 | Anti-oxidation resistant ion exchange resins. |
GB7931761A GB2031906B (en) | 1978-09-13 | 1979-09-13 | Oxidation-resistant ion exchange resins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11337878A JPS5539277A (en) | 1978-09-13 | 1978-09-13 | Oxidation-resistant ion exchange resin and method of using it |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5539277A true JPS5539277A (en) | 1980-03-19 |
JPS6130820B2 JPS6130820B2 (en) | 1986-07-16 |
Family
ID=14610766
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11337878A Granted JPS5539277A (en) | 1978-09-13 | 1978-09-13 | Oxidation-resistant ion exchange resin and method of using it |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS5539277A (en) |
DE (1) | DE2936922A1 (en) |
GB (1) | GB2031906B (en) |
NL (1) | NL7906849A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57205146A (en) * | 1981-06-12 | 1982-12-16 | Toray Industries | Three-layer laminated polyolefin film |
JPS5818261A (en) * | 1981-07-25 | 1983-02-02 | 東レ株式会社 | Polyolefin laminated film which is easily bonded |
JPS5818259A (en) * | 1981-07-25 | 1983-02-02 | 東レ株式会社 | Polyolefin laminated film changed into mat |
JPS5880307A (en) * | 1981-11-06 | 1983-05-14 | Mitsubishi Chem Ind Ltd | Production of heat-resistant cation exchange resin |
JP2000516133A (en) * | 1996-07-30 | 2000-12-05 | キュノ インコーポレーテッド | Filter sheet and method for purifying photoresist composition using the filter sheet |
US7048857B2 (en) * | 2000-01-03 | 2006-05-23 | The Boc Group, Inc. | Method and apparatus for metal removal ion exchange |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3023455A1 (en) * | 1980-06-24 | 1982-01-14 | Hoechst Ag, 6000 Frankfurt | METHOD FOR FLUORINATING POLYMERS AND PERFLUORED ION EXCHANGERS |
US4973607A (en) * | 1988-09-23 | 1990-11-27 | The Dow Chemical Company | Cation exchange resins incorporating antioxidants |
EP0502619B1 (en) * | 1991-03-07 | 1997-01-08 | The Dow Chemical Company | Oxidation-resistant cation-exchange resins |
DE4232246A1 (en) * | 1992-09-25 | 1994-03-31 | Siemens Ag | Process for the destruction of an organic substance |
WO1998022217A1 (en) * | 1996-11-18 | 1998-05-28 | Kurita Water Industries Ltd. | Polymeric material for water treatment, cation-exchange resin, and anion-exchange resin |
-
1978
- 1978-09-13 JP JP11337878A patent/JPS5539277A/en active Granted
-
1979
- 1979-09-12 DE DE19792936922 patent/DE2936922A1/en not_active Withdrawn
- 1979-09-13 GB GB7931761A patent/GB2031906B/en not_active Expired
- 1979-09-13 NL NL7906849A patent/NL7906849A/en not_active Application Discontinuation
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57205146A (en) * | 1981-06-12 | 1982-12-16 | Toray Industries | Three-layer laminated polyolefin film |
JPS6223665B2 (en) * | 1981-06-12 | 1987-05-25 | Toray Industries | |
JPS5818261A (en) * | 1981-07-25 | 1983-02-02 | 東レ株式会社 | Polyolefin laminated film which is easily bonded |
JPS5818259A (en) * | 1981-07-25 | 1983-02-02 | 東レ株式会社 | Polyolefin laminated film changed into mat |
JPS6210192B2 (en) * | 1981-07-25 | 1987-03-04 | Toray Industries | |
JPS5880307A (en) * | 1981-11-06 | 1983-05-14 | Mitsubishi Chem Ind Ltd | Production of heat-resistant cation exchange resin |
JPH0131526B2 (en) * | 1981-11-06 | 1989-06-27 | Mitsubishi Kasei Kk | |
JP2000516133A (en) * | 1996-07-30 | 2000-12-05 | キュノ インコーポレーテッド | Filter sheet and method for purifying photoresist composition using the filter sheet |
US7048857B2 (en) * | 2000-01-03 | 2006-05-23 | The Boc Group, Inc. | Method and apparatus for metal removal ion exchange |
Also Published As
Publication number | Publication date |
---|---|
NL7906849A (en) | 1980-03-17 |
JPS6130820B2 (en) | 1986-07-16 |
GB2031906B (en) | 1982-12-22 |
GB2031906A (en) | 1980-04-30 |
DE2936922A1 (en) | 1980-03-27 |
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