JPS55154992A - Novel furanose derivative and its preparation - Google Patents
Novel furanose derivative and its preparationInfo
- Publication number
- JPS55154992A JPS55154992A JP6286079A JP6286079A JPS55154992A JP S55154992 A JPS55154992 A JP S55154992A JP 6286079 A JP6286079 A JP 6286079A JP 6286079 A JP6286079 A JP 6286079A JP S55154992 A JPS55154992 A JP S55154992A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- novel
- preparation
- cooch
- synthetic intermediate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Epoxy Compounds (AREA)
- Saccharide Compounds (AREA)
Abstract
NEW MATERIAL:A compound shown by the formula I (Bn is -CH2-C6H5; R is -CH=CH-COOCH3, -CH2-CH2-COOCH3, etc.).
EXAMPLE: 3-O-benzyl-5, 6-dideoxydehydro-1, 2-O-isopropylidene-6-C-methoxycarbonyl-α-D-xylohexofuranose.
USE: A synthetic intermediate for various kinds of organic compounds. Especially a synthetic intermediate for Cerulenin, an antibiotic having both antifungal and antimirobial activities.
PROCESS: A saturated alcohol derivative shown by the formula II (Bn is -CH2-C6H5) is oxidized with oxalyl chloride, trifluoroacetic anhydride, etc. in the presence of dimethyl sulfoxide to give a saturated aldehyde derivative shown by the formula I.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6286079A JPS55154992A (en) | 1979-05-22 | 1979-05-22 | Novel furanose derivative and its preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6286079A JPS55154992A (en) | 1979-05-22 | 1979-05-22 | Novel furanose derivative and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55154992A true JPS55154992A (en) | 1980-12-02 |
JPS5643476B2 JPS5643476B2 (en) | 1981-10-13 |
Family
ID=13212463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6286079A Granted JPS55154992A (en) | 1979-05-22 | 1979-05-22 | Novel furanose derivative and its preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55154992A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4497649A (en) * | 1983-08-18 | 1985-02-05 | Chevron Research Company | 5-O-Acyl-5-C-alkyl-3-O-arylmethyl or substituted arylmethyl-1,2-O-alkylidene-αD-gluco-pentofuranose and β-L-ido-pentofuranose herbicides |
US4534785A (en) * | 1984-03-15 | 1985-08-13 | Chevron Research Company | Herbicidal 5-deoxy-3-O-arylmethyl or substituted arylmethyl-1,2-O-ethylene-alpha-D-xylofuranose derivatives |
US5185436A (en) * | 1987-09-25 | 1993-02-09 | Association Pour La Recherche Therapeutique Anti-Cancereuse | Esters of normal butyric acid and their use as pharmaceuticals |
-
1979
- 1979-05-22 JP JP6286079A patent/JPS55154992A/en active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4497649A (en) * | 1983-08-18 | 1985-02-05 | Chevron Research Company | 5-O-Acyl-5-C-alkyl-3-O-arylmethyl or substituted arylmethyl-1,2-O-alkylidene-αD-gluco-pentofuranose and β-L-ido-pentofuranose herbicides |
US4534785A (en) * | 1984-03-15 | 1985-08-13 | Chevron Research Company | Herbicidal 5-deoxy-3-O-arylmethyl or substituted arylmethyl-1,2-O-ethylene-alpha-D-xylofuranose derivatives |
US5185436A (en) * | 1987-09-25 | 1993-02-09 | Association Pour La Recherche Therapeutique Anti-Cancereuse | Esters of normal butyric acid and their use as pharmaceuticals |
Also Published As
Publication number | Publication date |
---|---|
JPS5643476B2 (en) | 1981-10-13 |
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