JPS55130929A - Preparation of linalool - Google Patents

Preparation of linalool

Info

Publication number
JPS55130929A
JPS55130929A JP3707579A JP3707579A JPS55130929A JP S55130929 A JPS55130929 A JP S55130929A JP 3707579 A JP3707579 A JP 3707579A JP 3707579 A JP3707579 A JP 3707579A JP S55130929 A JPS55130929 A JP S55130929A
Authority
JP
Japan
Prior art keywords
hotrienol
dimethyl
linalool
hydroperoxide
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3707579A
Other languages
Japanese (ja)
Other versions
JPS6319495B2 (en
Inventor
Zenzaburo Kumazawa
Yasuo Ito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YOTSUKAICHI GOSEI KK
Original Assignee
YOTSUKAICHI GOSEI KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YOTSUKAICHI GOSEI KK filed Critical YOTSUKAICHI GOSEI KK
Priority to JP3707579A priority Critical patent/JPS55130929A/en
Publication of JPS55130929A publication Critical patent/JPS55130929A/en
Publication of JPS6319495B2 publication Critical patent/JPS6319495B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE: To obtain the title compound useful as an intermediate for perfume compounds, squalane, or vitamin E, or a perfume material, simply by selectively reducing hotrienol or a compound wherein the 3-position is hydroperoxide.
CONSTITUTION: 3,7-Dimethyl-1,5,7-octatrien-3-ol(hotrienol) or 3,7-dimethyl-1,5,7- octatriene-3-hydroperoxide(DOH) of formula I (R is OH or O-OH) is selectively reduced by an alkali metal-ammonia or an amine to give 3,7-dimethyl-1,6-octadien- 3-ol(linalool) of formula II. The hotrienol can be obtained in high yield by dimerizing isoprene, and by reducing the oxidation product.
EFFECT: Scarcely contaminated with non-terpene impurities.
COPYRIGHT: (C)1980,JPO&Japio
JP3707579A 1979-03-30 1979-03-30 Preparation of linalool Granted JPS55130929A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3707579A JPS55130929A (en) 1979-03-30 1979-03-30 Preparation of linalool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3707579A JPS55130929A (en) 1979-03-30 1979-03-30 Preparation of linalool

Publications (2)

Publication Number Publication Date
JPS55130929A true JPS55130929A (en) 1980-10-11
JPS6319495B2 JPS6319495B2 (en) 1988-04-22

Family

ID=12487425

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3707579A Granted JPS55130929A (en) 1979-03-30 1979-03-30 Preparation of linalool

Country Status (1)

Country Link
JP (1) JPS55130929A (en)

Also Published As

Publication number Publication date
JPS6319495B2 (en) 1988-04-22

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