JPS55100331A - Preparation of aldehyde - Google Patents
Preparation of aldehydeInfo
- Publication number
- JPS55100331A JPS55100331A JP561379A JP561379A JPS55100331A JP S55100331 A JPS55100331 A JP S55100331A JP 561379 A JP561379 A JP 561379A JP 561379 A JP561379 A JP 561379A JP S55100331 A JPS55100331 A JP S55100331A
- Authority
- JP
- Japan
- Prior art keywords
- dicoordinating
- norbornane
- olefin
- trans
- halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To prepare a straight chain aldehyde useful as an industrial raw material, etc., selectively, by hydroformylating an olefin with H2 and CO in the presence of platinum and a halide of IVb group element as catalysts and a complex of a dicoordinating ligand having a specific structure.
CONSTITUTION: An olefin, e.g. 2W20C alkene, etc., is hydroformylated with H2 and CO in a solvent or in the absence of a solvent at 40W200°C and 5W500 bar in the presence of platinum catalyst, a halide of one or more metals selected from IVb group elements in the periodic table, e.g. SnCl2, etc., as a co-catalyst and a dicoordinating ligand expressed by the formula (n is 1W2; R is aryl) as a reaction accelerator, to give a straight chain aldehyde, e.g. butylaldehyde, etc. The reaction accelerator is, e.g. trans-2,3-bis(diphenyl-hosphinomethyl)norbornane, trans-2,3- bis(di-p-toluylphosphinomethyl)norbornane, etc.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP561379A JPS55100331A (en) | 1979-01-23 | 1979-01-23 | Preparation of aldehyde |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP561379A JPS55100331A (en) | 1979-01-23 | 1979-01-23 | Preparation of aldehyde |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55100331A true JPS55100331A (en) | 1980-07-31 |
JPS5726653B2 JPS5726653B2 (en) | 1982-06-05 |
Family
ID=11616034
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP561379A Granted JPS55100331A (en) | 1979-01-23 | 1979-01-23 | Preparation of aldehyde |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55100331A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57212133A (en) * | 1981-06-24 | 1982-12-27 | Mitsubishi Chem Ind Ltd | Preparation of aldehyde |
-
1979
- 1979-01-23 JP JP561379A patent/JPS55100331A/en active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57212133A (en) * | 1981-06-24 | 1982-12-27 | Mitsubishi Chem Ind Ltd | Preparation of aldehyde |
JPH0153261B2 (en) * | 1981-06-24 | 1989-11-13 | Mitsubishi Chem Ind |
Also Published As
Publication number | Publication date |
---|---|
JPS5726653B2 (en) | 1982-06-05 |
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