JPS5490134A - Preparation of terephthalic acid - Google Patents
Preparation of terephthalic acidInfo
- Publication number
- JPS5490134A JPS5490134A JP15557977A JP15557977A JPS5490134A JP S5490134 A JPS5490134 A JP S5490134A JP 15557977 A JP15557977 A JP 15557977A JP 15557977 A JP15557977 A JP 15557977A JP S5490134 A JPS5490134 A JP S5490134A
- Authority
- JP
- Japan
- Prior art keywords
- oxidation
- catalyst
- bromine
- terephthalic acid
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare a high purity terephthalic acid, and to reduce the loss of bromine catalyst, by the liquid-phase oxidation of p-xylene or its oxidation intermediate, in the presence of a Co-Mn-Br catalyst wherein the bromine component is a lower aliphatic carboxylic acid bromoalkyl ester.
CONSTITUTION: Terephthalic acid is prepared by the liquid phase oxidation of p-xylene or its oxidation intermediate with gas containing molecular oxygen, in acetic acid solvent, in the presenece of an oxidation catalyst comprising Co, Mn and Br, wherein the Br component is a lower aliphatic carboxylic acid bromoalkyl ester, e.g. dibromoethyl acetate, dibromopropyl acetate, etc.
EFFECT: The addition of bromine component during the recycling of the reaction mother liquor can be reduced, since the oxidation loss of the bromine component of this invention is low.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52155579A JPS5933579B2 (en) | 1977-12-26 | 1977-12-26 | Method for producing terephthalic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52155579A JPS5933579B2 (en) | 1977-12-26 | 1977-12-26 | Method for producing terephthalic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5490134A true JPS5490134A (en) | 1979-07-17 |
JPS5933579B2 JPS5933579B2 (en) | 1984-08-16 |
Family
ID=15609121
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52155579A Expired JPS5933579B2 (en) | 1977-12-26 | 1977-12-26 | Method for producing terephthalic acid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5933579B2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60251494A (en) * | 1984-05-28 | 1985-12-12 | 松下冷機株式会社 | Controller with voice announcer for vending machine |
-
1977
- 1977-12-26 JP JP52155579A patent/JPS5933579B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS5933579B2 (en) | 1984-08-16 |
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