JPS5473710A - Production of 2-butene-1,4-diol derivative - Google Patents

Production of 2-butene-1,4-diol derivative

Info

Publication number
JPS5473710A
JPS5473710A JP13725577A JP13725577A JPS5473710A JP S5473710 A JPS5473710 A JP S5473710A JP 13725577 A JP13725577 A JP 13725577A JP 13725577 A JP13725577 A JP 13725577A JP S5473710 A JPS5473710 A JP S5473710A
Authority
JP
Japan
Prior art keywords
butene
catalyst
copper compound
production
diol derivative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13725577A
Other languages
Japanese (ja)
Inventor
Yuichi Doi
Masanori Ikeda
Nobuhiro Tamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP13725577A priority Critical patent/JPS5473710A/en
Publication of JPS5473710A publication Critical patent/JPS5473710A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: The hydration of a monoepoxide of 1,3-conjugated diene is conducted in the presence of water using a copper compound as a catalyst to form 2-butene-1,4- diol useful as an intermediate for chemicals in high selectivity.
CONSTITUTION: The hydration of a monoepoxide of 1,3-conjugated diene of formula I (R1-4 is H, hydrocarbyl wherein R1 and R4 may incorporate to form ring) is conducted in the presence of water a copper compound as a catalyst to produce 2-butene-1,4-diol derivative of formula II. As the copper compound, the bromide is suitable, especially cuprous bromide is preferred. The amount of the catalyst is 0.1W100wt% on the epoxide basis. The epoxide is, e.g., 3,4-epoxybutene-1. The reaction may be effected in an aqueous medium; however, the use of organic solvents is preferred. The reaction temperature is -10 -200°C.
COPYRIGHT: (C)1979,JPO&Japio
JP13725577A 1977-11-17 1977-11-17 Production of 2-butene-1,4-diol derivative Pending JPS5473710A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13725577A JPS5473710A (en) 1977-11-17 1977-11-17 Production of 2-butene-1,4-diol derivative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13725577A JPS5473710A (en) 1977-11-17 1977-11-17 Production of 2-butene-1,4-diol derivative

Publications (1)

Publication Number Publication Date
JPS5473710A true JPS5473710A (en) 1979-06-13

Family

ID=15194377

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13725577A Pending JPS5473710A (en) 1977-11-17 1977-11-17 Production of 2-butene-1,4-diol derivative

Country Status (1)

Country Link
JP (1) JPS5473710A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01149741A (en) * 1987-12-07 1989-06-12 Nippon Mining Co Ltd Production of 3-alkanols
US5530167A (en) * 1995-08-21 1996-06-25 Eastman Chemical Company Process for the preparation of 1,4-butenediol
WO1998002404A1 (en) * 1996-07-17 1998-01-22 Eastman Chemical Company PROCESS FOR THE PREPARATION OF 2-ALKENE-1,4-DIOLS AND 3-ALKENE-1,2-DIOLS FROM η,δ-EPOXYALKENES
US5856591A (en) * 1996-07-17 1999-01-05 Eastman Chem Co Process for the separation of 2-alkene-1,4-diols and 3-alkene-1,2-diols from catalysts
WO1999011592A1 (en) * 1997-09-04 1999-03-11 The Dow Chemical Company Process for the preparation of 1,4-butenediol from epoxybutene

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01149741A (en) * 1987-12-07 1989-06-12 Nippon Mining Co Ltd Production of 3-alkanols
JPH0446935B2 (en) * 1987-12-07 1992-07-31 Nippon Mining Co
US5530167A (en) * 1995-08-21 1996-06-25 Eastman Chemical Company Process for the preparation of 1,4-butenediol
WO1997007085A1 (en) * 1995-08-21 1997-02-27 Eastman Chemical Company Process for the preparation of 1,4-butenediol
WO1998002404A1 (en) * 1996-07-17 1998-01-22 Eastman Chemical Company PROCESS FOR THE PREPARATION OF 2-ALKENE-1,4-DIOLS AND 3-ALKENE-1,2-DIOLS FROM η,δ-EPOXYALKENES
US5856591A (en) * 1996-07-17 1999-01-05 Eastman Chem Co Process for the separation of 2-alkene-1,4-diols and 3-alkene-1,2-diols from catalysts
US5959162A (en) * 1996-07-17 1999-09-28 Eastman Chemical Company Process for the preparation of 2-alkene-1,4-diols and 3-alkene-1,2-diols from γ,δ-epoxyalkenes
WO1999011592A1 (en) * 1997-09-04 1999-03-11 The Dow Chemical Company Process for the preparation of 1,4-butenediol from epoxybutene

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