JPS5442386A - Adsorbent having excellent selective adsorbability and it manufacture and adsorption method - Google Patents
Adsorbent having excellent selective adsorbability and it manufacture and adsorption methodInfo
- Publication number
- JPS5442386A JPS5442386A JP10908477A JP10908477A JPS5442386A JP S5442386 A JPS5442386 A JP S5442386A JP 10908477 A JP10908477 A JP 10908477A JP 10908477 A JP10908477 A JP 10908477A JP S5442386 A JPS5442386 A JP S5442386A
- Authority
- JP
- Japan
- Prior art keywords
- egta
- adsorbent
- manufacture
- reaction
- specific
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
PURPOSE: To manufacture an adsorbent having excellent selective adsorbability for specific metal ions by reacting EGTA and specific polysocyanate in a polar aprotic colvent of more than specific permittivity.
CONSTITUTION: EGTA(ethyleneglycol-bis(2-aminoethylether)-N,N,N',N'-terta-acetic acid) is reacted with the polyisocyanate which is represented by the formula 1 in a polar aprotic solvent of a permittivity of more than 30, e.g., DNF, hexamethylphosphoramide(HMPA), dimethyksulfoxide, etc. The N in the formula is an integer of 0, 1, 2, 3, etc. The polymer obtained from this reaction, having bridged structure by the reacrion of the both terminal groups CO2H of EGTA in its partial portion and branched structure by the reaction of a majority of EGTA component with isocyanate, can easily be isolated in the form of precipitate by the addition of a non-solvent, e.g., water, alcohol, etc. to the reaction system.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10908477A JPS5442386A (en) | 1977-09-09 | 1977-09-09 | Adsorbent having excellent selective adsorbability and it manufacture and adsorption method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10908477A JPS5442386A (en) | 1977-09-09 | 1977-09-09 | Adsorbent having excellent selective adsorbability and it manufacture and adsorption method |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5442386A true JPS5442386A (en) | 1979-04-04 |
Family
ID=14501185
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10908477A Pending JPS5442386A (en) | 1977-09-09 | 1977-09-09 | Adsorbent having excellent selective adsorbability and it manufacture and adsorption method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5442386A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04120464A (en) * | 1989-12-15 | 1992-04-21 | F Hoffmann La Roche Ag | Method of determining calcium and magnesium |
-
1977
- 1977-09-09 JP JP10908477A patent/JPS5442386A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04120464A (en) * | 1989-12-15 | 1992-04-21 | F Hoffmann La Roche Ag | Method of determining calcium and magnesium |
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