JPS54154740A - Preparation of acetyl cyclic sesquiterpene - Google Patents
Preparation of acetyl cyclic sesquiterpeneInfo
- Publication number
- JPS54154740A JPS54154740A JP6256178A JP6256178A JPS54154740A JP S54154740 A JPS54154740 A JP S54154740A JP 6256178 A JP6256178 A JP 6256178A JP 6256178 A JP6256178 A JP 6256178A JP S54154740 A JPS54154740 A JP S54154740A
- Authority
- JP
- Japan
- Prior art keywords
- mole
- acetic
- cyclic
- hydrochloric acid
- catalyst system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Abstract
PURPOSE: To obtain the title compound useful as perfumes in high yield, by acetylating a cyclic sesquiterpene with acetic arhydride in the presence of a catalyst system prepared through action of hydrochloric acid gas on zinc oxide or ferric chloride in acetic acid.
CONSTITUTION: One mole of cyclic sesquiterpene, e.g. α-cedrene, having at least one double bond is acetylated with acetic anhydride in the presence of a catalyst, obtained by action of hydrochloric acid gas on 0.1W0.3 mole each of zinc oxide or ferric chloride in acetic acid, to give an acetylated cyclic sesquterpene, e.g. acetylcedrene. The amount of the hydrochloric acid present in the catalyst system is preferably adjusted to 0.1W0.3 mole per mole of the cyclic sesquiterpene.
EFFECT: Preparation of the catalyst system and acetylation can be carried out in the same vessel. The amount of the acetic anhydride is very small.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6256178A JPS6022691B2 (en) | 1978-05-25 | 1978-05-25 | Method for producing acetyl cyclic sesquiterpene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6256178A JPS6022691B2 (en) | 1978-05-25 | 1978-05-25 | Method for producing acetyl cyclic sesquiterpene |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS54154740A true JPS54154740A (en) | 1979-12-06 |
JPS6022691B2 JPS6022691B2 (en) | 1985-06-03 |
Family
ID=13203808
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6256178A Expired JPS6022691B2 (en) | 1978-05-25 | 1978-05-25 | Method for producing acetyl cyclic sesquiterpene |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6022691B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012017274A (en) * | 2010-07-07 | 2012-01-26 | Kao Corp | New oxygen-containing sesquiterpene compound |
-
1978
- 1978-05-25 JP JP6256178A patent/JPS6022691B2/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012017274A (en) * | 2010-07-07 | 2012-01-26 | Kao Corp | New oxygen-containing sesquiterpene compound |
Also Published As
Publication number | Publication date |
---|---|
JPS6022691B2 (en) | 1985-06-03 |
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