JPS54150497A - Hydroxy end group*chloroalkylene ether* * and its preparation - Google Patents

Hydroxy end group*chloroalkylene ether* * and its preparation

Info

Publication number
JPS54150497A
JPS54150497A JP6024779A JP6024779A JPS54150497A JP S54150497 A JPS54150497 A JP S54150497A JP 6024779 A JP6024779 A JP 6024779A JP 6024779 A JP6024779 A JP 6024779A JP S54150497 A JPS54150497 A JP S54150497A
Authority
JP
Japan
Prior art keywords
hydroxyl
chloroalkylene
ether
preparation
arsenic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6024779A
Other languages
Japanese (ja)
Other versions
JPS6332813B2 (en
Inventor
Ai Yangu Chiyungu
Ruizu Baabaa Jiyunia Rooren
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of JPS54150497A publication Critical patent/JPS54150497A/en
Publication of JPS6332813B2 publication Critical patent/JPS6332813B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
    • C08G18/5006—Polyethers having heteroatoms other than oxygen having halogens having chlorine and/or bromine atoms
    • C08G18/5009—Polyethers having heteroatoms other than oxygen having halogens having chlorine and/or bromine atoms having chlorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/223—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2684—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Catalysts (AREA)

Abstract

Colorless hydroxyl-terminated poly(chloroalkylene ethers) of the formula <IMAGE> wherein R<1> and R<2> = hydrogen or methyl; R<3> and R<4> = hydrogen, lower alkyl containing 1 to 10 carbon atoms or lower chloroalkyl containing 1 to 2 carbon atoms provided that at least one of R<3> or R<4> is lower chloroalkyl; R<5> = residue of a hydroxyl material which originally contained 1 to 6 hydroxyls; b = integer of 1 to 50; d = integer of 1 to 6. The ethers may be prepared by reaction of a hydroxyl material containing 1 to 6 hydroxyl groups with a chloro-alkylene oxide in the presence of a novel catalyst system comprising (i) a fluorinated acid selected from the group consisting of bis (fluorinated aliphatic sulfonyl) alkanes and acids of the formula HmXFn+m wherein X is selected from the group consisting of boron, phosphorous, arsenic and antimony; m is 0 or 1, n is 3 when X is boron and n is 5 when X is phosphorous, arsenic and antimony; and <IMAGE>
JP6024779A 1978-05-17 1979-05-16 Hydroxy end group*chloroalkylene ether* * and its preparation Granted JPS54150497A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US90674478A 1978-05-17 1978-05-17

Publications (2)

Publication Number Publication Date
JPS54150497A true JPS54150497A (en) 1979-11-26
JPS6332813B2 JPS6332813B2 (en) 1988-07-01

Family

ID=25422907

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6024779A Granted JPS54150497A (en) 1978-05-17 1979-05-16 Hydroxy end group*chloroalkylene ether* * and its preparation

Country Status (9)

Country Link
JP (1) JPS54150497A (en)
AU (1) AU534485B2 (en)
BR (1) BR7903018A (en)
CA (1) CA1187107A (en)
CH (1) CH653693A5 (en)
DE (1) DE2919834A1 (en)
FR (1) FR2426060A1 (en)
GB (2) GB2021606B (en)
IT (1) IT1116819B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5655330A (en) * 1979-09-18 1981-05-15 Minnesota Mining & Mfg Amorphous hydroxyllterminated poly*haloalkyleneether*
JPS5966420A (en) * 1982-09-15 1984-04-14 ザ・ビ−・エフ・グツドリツチ・カンパニ− Poly(glycidyl ether) block copolymer and manufacture
JPS5981333A (en) * 1982-09-29 1984-05-11 ザ・ビ−・エフ・グツドリツチ・カンパニ− Block copolymer and manufacture
JPS59113029A (en) * 1982-11-12 1984-06-29 ザ　ビ−．エフ．グツドリツチ　カンパニ− Graft copolymer, manufacture and use
JP2020117571A (en) * 2019-01-21 2020-08-06 東ソー株式会社 Thermoplastic polyurethane resin and thermoplastic polyurethane resin composition

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405497A (en) * 1979-09-18 1983-09-20 Minnesota Mining And Manufacturing Company Catalyst system containing a fluorinated acid and a polyvalent tin compound
US4431845A (en) * 1980-12-04 1984-02-14 Minnesota Mining And Manufacturing Company Method for the preparation of hydroxyl-terminated poly(haloalkylene ethers)
US4393199A (en) 1981-05-12 1983-07-12 S R I International Cationic polymerization
CA1197832A (en) * 1982-06-01 1985-12-10 Kang Yang Catalysts for alkoxylation reactions
US4483941A (en) * 1982-09-02 1984-11-20 Conoco Inc. Catalysts for alkoxylation reactions
US4879419A (en) * 1985-07-01 1989-11-07 Minnesota Mining And Manufacturing Company Hydroxyl-terminated polyepichlorohydrin polymers
GB2224740B (en) * 1985-08-30 1990-08-22 Minnesota Mining & Mfg Hydroxyl-terminated polyepichlorohydrin and derivatives
US5117010A (en) * 1991-08-15 1992-05-26 Ciba-Geigy Corporation Process for the preparation of addition products of epoxides and alcohols
TW224108B (en) * 1992-05-06 1994-05-21 Ciba Geigy
CN103497322B (en) * 2013-09-09 2015-05-27 江苏雅克科技股份有限公司 Preparation method and application for reaction-type halogen-containing flame-retardant polyether polyol

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5329399A (en) * 1976-08-31 1978-03-18 Bayer Ag Process for producing polyetherrpolyol

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2327053A (en) * 1939-11-18 1943-08-17 Shell Dev Production of hydroxy ethers
DE1281420B (en) * 1963-09-23 1968-10-31 Olin Mathieson Process for the preparation of linear or branched polyalkylene glycol ethers
US3305565A (en) * 1964-07-08 1967-02-21 Shell Oil Co Polyepihalohydrin preparation using fluoboric acid catalyst
FR94928E (en) * 1965-04-23 1970-01-23 Oreal New nonionic surfactants and their preparation process.
DE1793581C3 (en) * 1965-04-23 1974-02-28 L'oreal, Paris Polychloride and process for their preparation. Eliminated from: 1593217
GB1047557A (en) * 1965-05-04 1966-11-09 Shell Int Research Polymers of epoxy-halo-substituted alkanes
CH568343A5 (en) * 1972-05-15 1975-10-31 Solvay
US3850856A (en) * 1973-08-20 1974-11-26 Goodrich Co B F Hydroxyl-ended epihalohydrin polymers by cationic polymerization

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5329399A (en) * 1976-08-31 1978-03-18 Bayer Ag Process for producing polyetherrpolyol

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5655330A (en) * 1979-09-18 1981-05-15 Minnesota Mining & Mfg Amorphous hydroxyllterminated poly*haloalkyleneether*
JPS5966420A (en) * 1982-09-15 1984-04-14 ザ・ビ−・エフ・グツドリツチ・カンパニ− Poly(glycidyl ether) block copolymer and manufacture
JPS5981333A (en) * 1982-09-29 1984-05-11 ザ・ビ−・エフ・グツドリツチ・カンパニ− Block copolymer and manufacture
JPS59113029A (en) * 1982-11-12 1984-06-29 ザ　ビ−．エフ．グツドリツチ　カンパニ− Graft copolymer, manufacture and use
JPH0546374B2 (en) * 1982-11-12 1993-07-13 Goodrich Co B F
JP2020117571A (en) * 2019-01-21 2020-08-06 東ソー株式会社 Thermoplastic polyurethane resin and thermoplastic polyurethane resin composition

Also Published As

Publication number Publication date
IT7949061A0 (en) 1979-05-16
JPS6332813B2 (en) 1988-07-01
IT1116819B (en) 1986-02-10
GB2021606B (en) 1982-12-01
GB2104403A (en) 1983-03-09
GB2021606A (en) 1979-12-05
AU4710079A (en) 1979-11-22
AU534485B2 (en) 1984-02-02
CH653693A5 (en) 1986-01-15
CA1187107A (en) 1985-05-14
DE2919834C2 (en) 1991-02-28
GB2104403B (en) 1983-07-13
DE2919834A1 (en) 1979-11-22
FR2426060B1 (en) 1983-05-20
BR7903018A (en) 1979-12-04
FR2426060A1 (en) 1979-12-14

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