IT1116819B - PROCEDURE AND CATALYST FOR THE PREPARATION OF POLES (CHLOROALKYLENE ETHERS) AND PRODUCT OBTAINED - Google Patents

PROCEDURE AND CATALYST FOR THE PREPARATION OF POLES (CHLOROALKYLENE ETHERS) AND PRODUCT OBTAINED

Info

Publication number
IT1116819B
IT1116819B IT49061/79A IT4906179A IT1116819B IT 1116819 B IT1116819 B IT 1116819B IT 49061/79 A IT49061/79 A IT 49061/79A IT 4906179 A IT4906179 A IT 4906179A IT 1116819 B IT1116819 B IT 1116819B
Authority
IT
Italy
Prior art keywords
ethers
hydroxyl
poles
catalyst
procedure
Prior art date
Application number
IT49061/79A
Other languages
Italian (it)
Other versions
IT7949061A0 (en
Original Assignee
Minnesota Mining & Mfg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining & Mfg filed Critical Minnesota Mining & Mfg
Publication of IT7949061A0 publication Critical patent/IT7949061A0/en
Application granted granted Critical
Publication of IT1116819B publication Critical patent/IT1116819B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
    • C08G18/5006—Polyethers having heteroatoms other than oxygen having halogens having chlorine and/or bromine atoms
    • C08G18/5009—Polyethers having heteroatoms other than oxygen having halogens having chlorine and/or bromine atoms having chlorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/223—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2684—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Catalysts (AREA)

Abstract

Colorless hydroxyl-terminated poly(chloroalkylene ethers) of the formula <IMAGE> wherein R<1> and R<2> = hydrogen or methyl; R<3> and R<4> = hydrogen, lower alkyl containing 1 to 10 carbon atoms or lower chloroalkyl containing 1 to 2 carbon atoms provided that at least one of R<3> or R<4> is lower chloroalkyl; R<5> = residue of a hydroxyl material which originally contained 1 to 6 hydroxyls; b = integer of 1 to 50; d = integer of 1 to 6. The ethers may be prepared by reaction of a hydroxyl material containing 1 to 6 hydroxyl groups with a chloro-alkylene oxide in the presence of a novel catalyst system comprising (i) a fluorinated acid selected from the group consisting of bis (fluorinated aliphatic sulfonyl) alkanes and acids of the formula HmXFn+m wherein X is selected from the group consisting of boron, phosphorous, arsenic and antimony; m is 0 or 1, n is 3 when X is boron and n is 5 when X is phosphorous, arsenic and antimony; and <IMAGE>
IT49061/79A 1978-05-17 1979-05-16 PROCEDURE AND CATALYST FOR THE PREPARATION OF POLES (CHLOROALKYLENE ETHERS) AND PRODUCT OBTAINED IT1116819B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US90674478A 1978-05-17 1978-05-17

Publications (2)

Publication Number Publication Date
IT7949061A0 IT7949061A0 (en) 1979-05-16
IT1116819B true IT1116819B (en) 1986-02-10

Family

ID=25422907

Family Applications (1)

Application Number Title Priority Date Filing Date
IT49061/79A IT1116819B (en) 1978-05-17 1979-05-16 PROCEDURE AND CATALYST FOR THE PREPARATION OF POLES (CHLOROALKYLENE ETHERS) AND PRODUCT OBTAINED

Country Status (9)

Country Link
JP (1) JPS54150497A (en)
AU (1) AU534485B2 (en)
BR (1) BR7903018A (en)
CA (1) CA1187107A (en)
CH (1) CH653693A5 (en)
DE (1) DE2919834A1 (en)
FR (1) FR2426060A1 (en)
GB (2) GB2021606B (en)
IT (1) IT1116819B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405497A (en) * 1979-09-18 1983-09-20 Minnesota Mining And Manufacturing Company Catalyst system containing a fluorinated acid and a polyvalent tin compound
DE3035138A1 (en) * 1979-09-18 1981-04-02 Minnesota Mining and Manufacturing Co., 55101 Saint Paul, Minn. AMORPHE POLY- (HALOGENALKYLENAETHER) WITH HYDROXYL END GROUPS AND TWO-COMPONENT CATALYST SYSTEM
US4431845A (en) * 1980-12-04 1984-02-14 Minnesota Mining And Manufacturing Company Method for the preparation of hydroxyl-terminated poly(haloalkylene ethers)
US4393199A (en) 1981-05-12 1983-07-12 S R I International Cationic polymerization
CA1197832A (en) * 1982-06-01 1985-12-10 Kang Yang Catalysts for alkoxylation reactions
US4483941A (en) * 1982-09-02 1984-11-20 Conoco Inc. Catalysts for alkoxylation reactions
US4485211A (en) * 1982-09-15 1984-11-27 The B. F. Goodrich Company Poly(glycidyl ether)block copolymers and process for their preparation
US4451618A (en) * 1982-09-29 1984-05-29 The B. F. Goodrich Company Block copolymers and process for their preparation
US4540742A (en) * 1982-11-12 1985-09-10 The B. F. Goodrich Company Graft copolymers and process for their preparation
US4879419A (en) * 1985-07-01 1989-11-07 Minnesota Mining And Manufacturing Company Hydroxyl-terminated polyepichlorohydrin polymers
CA1339576C (en) * 1985-08-30 1997-12-09 Minnesota Mining And Manufacturing Company Hydroxyl-termitated polyepichlorohydrin and derivatives
US5117010A (en) * 1991-08-15 1992-05-26 Ciba-Geigy Corporation Process for the preparation of addition products of epoxides and alcohols
TW224108B (en) * 1992-05-06 1994-05-21 Ciba Geigy
CN103497322B (en) * 2013-09-09 2015-05-27 江苏雅克科技股份有限公司 Preparation method and application for reaction-type halogen-containing flame-retardant polyether polyol
JP7387987B2 (en) * 2019-01-21 2023-11-29 東ソー株式会社 Thermoplastic polyurethane resin and thermoplastic polyurethane resin composition

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2327053A (en) * 1939-11-18 1943-08-17 Shell Dev Production of hydroxy ethers
DE1281420B (en) * 1963-09-23 1968-10-31 Olin Mathieson Process for the preparation of linear or branched polyalkylene glycol ethers
US3305565A (en) * 1964-07-08 1967-02-21 Shell Oil Co Polyepihalohydrin preparation using fluoboric acid catalyst
DE1793581C3 (en) * 1965-04-23 1974-02-28 L'oreal, Paris Polychloride and process for their preparation. Eliminated from: 1593217
FR94928E (en) * 1965-04-23 1970-01-23 Oreal New nonionic surfactants and their preparation process.
GB1047557A (en) * 1965-05-04 1966-11-09 Shell Int Research Polymers of epoxy-halo-substituted alkanes
CH568343A5 (en) * 1972-05-15 1975-10-31 Solvay
US3850856A (en) * 1973-08-20 1974-11-26 Goodrich Co B F Hydroxyl-ended epihalohydrin polymers by cationic polymerization
DE2639083C2 (en) * 1976-08-31 1983-02-10 Bayer Ag, 5090 Leverkusen Process for the production of polyether polyols and their use as starting materials for polyurethane plastics

Also Published As

Publication number Publication date
BR7903018A (en) 1979-12-04
AU4710079A (en) 1979-11-22
FR2426060A1 (en) 1979-12-14
GB2021606B (en) 1982-12-01
JPS6332813B2 (en) 1988-07-01
JPS54150497A (en) 1979-11-26
FR2426060B1 (en) 1983-05-20
GB2021606A (en) 1979-12-05
DE2919834C2 (en) 1991-02-28
DE2919834A1 (en) 1979-11-22
CA1187107A (en) 1985-05-14
GB2104403B (en) 1983-07-13
CH653693A5 (en) 1986-01-15
GB2104403A (en) 1983-03-09
AU534485B2 (en) 1984-02-02
IT7949061A0 (en) 1979-05-16

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