JPS54132562A - Synthesis of m-isopropenylphenol oligomer - Google Patents

Synthesis of m-isopropenylphenol oligomer

Info

Publication number
JPS54132562A
JPS54132562A JP3959978A JP3959978A JPS54132562A JP S54132562 A JPS54132562 A JP S54132562A JP 3959978 A JP3959978 A JP 3959978A JP 3959978 A JP3959978 A JP 3959978A JP S54132562 A JPS54132562 A JP S54132562A
Authority
JP
Japan
Prior art keywords
solvent
solid catalyst
oligomer
acidic solid
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3959978A
Other languages
Japanese (ja)
Inventor
Shunsuke Matsushima
Kazuhiko Hata
Kentaro Mashita
Shuichi Kanekawa
Shinji Nakao
Kiyoshi Nakai
Kunimasa Kamio
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP3959978A priority Critical patent/JPS54132562A/en
Priority to US06/024,424 priority patent/US4260831A/en
Priority to DE19792913185 priority patent/DE2913185A1/en
Publication of JPS54132562A publication Critical patent/JPS54132562A/en
Priority to US06/212,511 priority patent/US4408086A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

PURPOSE: To prepare the title oligomer rich in polymer component having a polymerization degree of ≥3, and useful as a raw material of epoxy resin having improved mechanical strength, by polymerizing m-siopropenylphenol at a specific high temperature.
CONSTITUTION: m-Isopropenylphenol is polymerized at 135W230°C in the presence or absence of solvent to obtain an oligomer containing large amount of polymer having a degree of polymerization of ≥3. When the reaction temperature is about 130W160°C, the use of a small amount of solvent is preferable to reduce the viscovity of the product. The presence of acidic solid catalyst is effective to accelerate the reaction, and to prevent the pollution of waste water. Especially an acidic solid catalyst of MHSO4 (M is alkali metal) gives a high molecular weight loigomer, and particularly the use of the above catalyst in a fixed layer gives a sufficiently pure oligoner without further purification process.
COPYRIGHT: (C)1979,JPO&Japio
JP3959978A 1978-04-03 1978-04-03 Synthesis of m-isopropenylphenol oligomer Pending JPS54132562A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP3959978A JPS54132562A (en) 1978-04-03 1978-04-03 Synthesis of m-isopropenylphenol oligomer
US06/024,424 US4260831A (en) 1978-04-03 1979-03-27 Oligomerization of m-isopropenylphenol
DE19792913185 DE2913185A1 (en) 1978-04-03 1979-04-02 M-ISOPROPENYLPHENOL OLIGOMERS, THE PROCESS FOR THEIR PRODUCTION AND THEIR USE
US06/212,511 US4408086A (en) 1978-04-03 1980-12-03 Oligomerization of m-isopropenylphenol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3959978A JPS54132562A (en) 1978-04-03 1978-04-03 Synthesis of m-isopropenylphenol oligomer

Publications (1)

Publication Number Publication Date
JPS54132562A true JPS54132562A (en) 1979-10-15

Family

ID=12557569

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3959978A Pending JPS54132562A (en) 1978-04-03 1978-04-03 Synthesis of m-isopropenylphenol oligomer

Country Status (1)

Country Link
JP (1) JPS54132562A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS624239A (en) * 1985-06-28 1987-01-10 Mitsui Toatsu Chem Inc Production of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spiroindane
JPS6210030A (en) * 1985-07-09 1987-01-19 Mitsui Toatsu Chem Inc Production of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane
JPS6242941A (en) * 1985-08-19 1987-02-24 Mitsui Toatsu Chem Inc Production of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS624239A (en) * 1985-06-28 1987-01-10 Mitsui Toatsu Chem Inc Production of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spiroindane
JPS6210030A (en) * 1985-07-09 1987-01-19 Mitsui Toatsu Chem Inc Production of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane
JPS6242941A (en) * 1985-08-19 1987-02-24 Mitsui Toatsu Chem Inc Production of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane

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