JPS54100979A - Manufacture and application of adsorbent with high selective adsorbability - Google Patents

Manufacture and application of adsorbent with high selective adsorbability

Info

Publication number
JPS54100979A
JPS54100979A JP776478A JP776478A JPS54100979A JP S54100979 A JPS54100979 A JP S54100979A JP 776478 A JP776478 A JP 776478A JP 776478 A JP776478 A JP 776478A JP S54100979 A JPS54100979 A JP S54100979A
Authority
JP
Japan
Prior art keywords
adsorbent
solution
metal salt
protic solvent
soluble metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP776478A
Other languages
Japanese (ja)
Inventor
Akio Sasaki
Toshio Sakamoto
Yoshiko Ono
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unitika Ltd
Original Assignee
Unitika Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unitika Ltd filed Critical Unitika Ltd
Priority to JP776478A priority Critical patent/JPS54100979A/en
Publication of JPS54100979A publication Critical patent/JPS54100979A/en
Pending legal-status Critical Current

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  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

PURPOSE:To manufacture and adsorbent with a high selective adsorbability for soluble metal ions by the reaction of EGTA and a specific polyisocyanate in the presence of a soluble metal salt in a polar non-protic solvent of a specific permittivity or more. CONSTITUTION:EGTA (ethyleneglycol-bis(2-aminoethylether)-N,N,N',N'-tetraacetic acid) and a soluble metal salt are dissolved in a polar, non-protic solvent, e.g., N-methyl-2-pyrolidone, etc., having a permittivity of more than 30, and then the solution is added with stirring to a solution of a polyisocyanate of the formula (1) in the same polar non-protic solvent as the precious solution and heated at 80 to 120 deg.C in a current of dry nitrogen. The high polymer gel thus obtained is treated with a 1 to 5N hydrochloric acid solution to elute coordination metals, and then washed with sufficient water to remove acid in order to use it for adsorption treatment as carboxyl type adsorbent. Furthermore, the adsorbent can be used as an alkali metal salt type adsorbent after being treated with an alkali. The n as shown in the formula is 0, 1, 2, and 3.
JP776478A 1978-01-25 1978-01-25 Manufacture and application of adsorbent with high selective adsorbability Pending JPS54100979A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP776478A JPS54100979A (en) 1978-01-25 1978-01-25 Manufacture and application of adsorbent with high selective adsorbability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP776478A JPS54100979A (en) 1978-01-25 1978-01-25 Manufacture and application of adsorbent with high selective adsorbability

Publications (1)

Publication Number Publication Date
JPS54100979A true JPS54100979A (en) 1979-08-09

Family

ID=11674747

Family Applications (1)

Application Number Title Priority Date Filing Date
JP776478A Pending JPS54100979A (en) 1978-01-25 1978-01-25 Manufacture and application of adsorbent with high selective adsorbability

Country Status (1)

Country Link
JP (1) JPS54100979A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58174235A (en) * 1982-02-02 1983-10-13 イエ−リンノヴアシヨ−ン・ハンデルスアクチエボラグ Metal ion adsorbent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58174235A (en) * 1982-02-02 1983-10-13 イエ−リンノヴアシヨ−ン・ハンデルスアクチエボラグ Metal ion adsorbent
JPH0337976B2 (en) * 1982-02-02 1991-06-07 Ieerinnoashoon Handerusu Ab

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