JPS5030832A - - Google Patents
Info
- Publication number
- JPS5030832A JPS5030832A JP49050194A JP5019474A JPS5030832A JP S5030832 A JPS5030832 A JP S5030832A JP 49050194 A JP49050194 A JP 49050194A JP 5019474 A JP5019474 A JP 5019474A JP S5030832 A JPS5030832 A JP S5030832A
- Authority
- JP
- Japan
- Prior art keywords
- radicals
- carbon atoms
- mono
- rings
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 239000012948 isocyanate Substances 0.000 abstract 4
- 150000002513 isocyanates Chemical class 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/04—Preparation of derivatives of isocyanic acid from or via carbamates or carbamoyl halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1458595 Isocyanate preparation ATLANTIC RICHFIELD CO 3 May 1974 [4 May 1973 8 March 1973] 19578/74 Heading C2C Isocyanates are prepared by thermally decomposing an ester of a carbamic acid having the formula R(NHCOOR<SP>1</SP>) x or (RNHCOO) x R<SP>1</SP> wherein each R is an optionally substituted mono-, di- or tri-valent organic radical selected from saturated and monoolefinic unsaturated straight and branched chain aliphatic and cyclealiphatic radicals of not more than 32 carbon atoms, alkoxyalkyl radicals of not more than 32 carbon atoms, and aryl, aralkyl and alkaryl radicals having 1 to 5 rings; each R<SP>1</SP> is an optionally substituted mono-, di- or tri-valent organic radical selected from saturated and monoolefinic unsaturated straight and branched chain aliphatic and cycloaliphatic radicals of not more than 32 carbon atoms, alkoxy-alkyl radicals of not more than 32 carbon atoms, and aryl, aralkyl and alkaryl radicals containing 1 to 3 rings; and x is 1, 2 or 3; at from 175‹ to 350‹ C. while said ester is dissolved in an inert solvent to produce an isocyanate and an alcohol, the solvent being a compound or mixture of compounds which is (a) a solvent for said ester, (b) liquid and stable at the decomposition temperature and (c) nonreactive with isocyanate product, and selected from optionally halo- and mono-nitro-substituted C 4 to C 32 aliphatic hydrocarbons, cycloaliphatic hydrocarbons, aromatic hydrocarbons having 1 to 3 rings, (C 1 to C 15 alkyl)benzenes, halo- and mono-nitro-derivatives of the aromatic hydrocarbons and alkylbenzenes, and C 4 to C 32 ethers, ketones and carboxylic esters and their sulphur analogues.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35730173A | 1973-05-04 | 1973-05-04 | |
| US44929174A | 1974-03-08 | 1974-03-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5030832A true JPS5030832A (en) | 1975-03-27 |
Family
ID=26999595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP49050194A Pending JPS5030832A (en) | 1973-05-04 | 1974-05-04 |
Country Status (21)
| Country | Link |
|---|---|
| JP (1) | JPS5030832A (en) |
| AR (1) | AR202301A1 (en) |
| AU (1) | AU477106B2 (en) |
| CA (1) | CA1023379A (en) |
| CH (1) | CH598199A5 (en) |
| DD (1) | DD112990A5 (en) |
| DE (1) | DE2421503B2 (en) |
| ES (1) | ES425950A1 (en) |
| FR (1) | FR2228056B1 (en) |
| GB (1) | GB1458595A (en) |
| HU (1) | HU171538B (en) |
| IL (1) | IL44694A (en) |
| IN (1) | IN141148B (en) |
| LU (1) | LU69986A1 (en) |
| MY (1) | MY7700322A (en) |
| NL (1) | NL7405881A (en) |
| NO (1) | NO140794C (en) |
| PH (1) | PH11683A (en) |
| RO (1) | RO63097A (en) |
| SE (1) | SE419539B (en) |
| YU (1) | YU120074A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5219624A (en) * | 1975-08-07 | 1977-02-15 | Mitsui Toatsu Chem Inc | Process for preparation of isocyanates |
| JPS5488222A (en) * | 1977-12-20 | 1979-07-13 | Mitsubishi Chem Ind Ltd | Preparation of isocyanate from carbamate |
| JPS5576484U (en) * | 1978-11-13 | 1980-05-26 | ||
| JPH02231461A (en) * | 1989-03-06 | 1990-09-13 | Mitsubishi Gas Chem Co Inc | Production method of xylene diisocyanate |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2819826A1 (en) | 1978-05-05 | 1979-11-08 | Bayer Ag | PROCESS FOR THE PRODUCTION OF URETHANES |
| DE3009489A1 (en) | 1980-03-12 | 1981-09-17 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING URETHANES |
| US4487713A (en) * | 1981-06-26 | 1984-12-11 | Exxon Research & Engineering Co. | Production of isocyanates from esters of aromatic carbamic acids (urethanes) |
| DE4141402A1 (en) * | 1991-12-16 | 1993-06-17 | Bayer Ag | METHOD FOR PRODUCING HIGH-PURITY AROMATIC DI- AND / OR POLYURETHANES |
| DE10209095A1 (en) | 2002-03-01 | 2003-09-11 | Basf Ag | Process for the preparation of isocyanates |
| KR101429834B1 (en) * | 2009-12-24 | 2014-08-12 | 미쓰이 가가쿠 가부시키가이샤 | Method for treatment of isocyanate residue, and method for treatment of carbonate |
-
1974
- 1974-04-02 CA CA196,577A patent/CA1023379A/en not_active Expired
- 1974-04-11 AU AU67801/74A patent/AU477106B2/en not_active Expired
- 1974-04-16 SE SE7405108A patent/SE419539B/en unknown
- 1974-04-23 IL IL44694A patent/IL44694A/en unknown
- 1974-04-24 PH PH15776A patent/PH11683A/en unknown
- 1974-04-24 IN IN927/CAL/1974A patent/IN141148B/en unknown
- 1974-04-29 YU YU01200/74A patent/YU120074A/en unknown
- 1974-05-02 NL NL7405881A patent/NL7405881A/xx unknown
- 1974-05-03 NO NO741607A patent/NO140794C/en unknown
- 1974-05-03 LU LU69986A patent/LU69986A1/xx unknown
- 1974-05-03 GB GB1957874A patent/GB1458595A/en not_active Expired
- 1974-05-03 CH CH608974A patent/CH598199A5/xx not_active IP Right Cessation
- 1974-05-03 DE DE2421503A patent/DE2421503B2/en not_active Ceased
- 1974-05-03 DD DD178284A patent/DD112990A5/xx unknown
- 1974-05-03 AR AR253577A patent/AR202301A1/en active
- 1974-05-03 ES ES425950A patent/ES425950A1/en not_active Expired
- 1974-05-03 RO RO7400078670A patent/RO63097A/en unknown
- 1974-05-03 HU HU74AA00000769A patent/HU171538B/en unknown
- 1974-05-03 FR FR747415446A patent/FR2228056B1/fr not_active Expired
- 1974-05-04 JP JP49050194A patent/JPS5030832A/ja active Pending
-
1977
- 1977-12-31 MY MY1977322A patent/MY7700322A/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5219624A (en) * | 1975-08-07 | 1977-02-15 | Mitsui Toatsu Chem Inc | Process for preparation of isocyanates |
| JPS5488222A (en) * | 1977-12-20 | 1979-07-13 | Mitsubishi Chem Ind Ltd | Preparation of isocyanate from carbamate |
| JPS5576484U (en) * | 1978-11-13 | 1980-05-26 | ||
| JPH02231461A (en) * | 1989-03-06 | 1990-09-13 | Mitsubishi Gas Chem Co Inc | Production method of xylene diisocyanate |
Also Published As
| Publication number | Publication date |
|---|---|
| NO741607L (en) | 1974-11-05 |
| YU120074A (en) | 1982-06-18 |
| AU477106B2 (en) | 1976-10-14 |
| CA1023379A (en) | 1977-12-27 |
| CH598199A5 (en) | 1978-04-28 |
| GB1458595A (en) | 1976-12-15 |
| IL44694A0 (en) | 1974-06-30 |
| MY7700322A (en) | 1977-12-31 |
| IL44694A (en) | 1978-06-15 |
| NO140794C (en) | 1979-11-14 |
| SE419539B (en) | 1981-08-10 |
| HU171538B (en) | 1978-02-28 |
| AU6780174A (en) | 1975-10-16 |
| FR2228056A1 (en) | 1974-11-29 |
| NL7405881A (en) | 1974-11-06 |
| AR202301A1 (en) | 1975-05-30 |
| RO63097A (en) | 1978-06-15 |
| DD112990A5 (en) | 1975-05-12 |
| NO140794B (en) | 1979-08-06 |
| DE2421503B2 (en) | 1978-12-21 |
| LU69986A1 (en) | 1974-11-28 |
| PH11683A (en) | 1978-05-19 |
| FR2228056B1 (en) | 1979-02-09 |
| IN141148B (en) | 1977-01-22 |
| DE2421503A1 (en) | 1974-11-21 |
| ES425950A1 (en) | 1976-09-16 |
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