JPH1160442A - Cosmetic - Google Patents
CosmeticInfo
- Publication number
- JPH1160442A JPH1160442A JP9243484A JP24348497A JPH1160442A JP H1160442 A JPH1160442 A JP H1160442A JP 9243484 A JP9243484 A JP 9243484A JP 24348497 A JP24348497 A JP 24348497A JP H1160442 A JPH1160442 A JP H1160442A
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- Prior art keywords
- cosmetic
- hydrocarbons
- raw materials
- oil
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【0001】[0001]
【発明の属する技術分野】本願発明は、臭気、着色、経
時安定性、皮膚刺激性などの問題のない、植物由来の抽
出物を還元処理してなる炭化水素を主成分として含有す
ることを特徴とする、のびが良く、使用感がさっぱりと
しており、高い保湿効果、美白効果、および柔軟効果な
どを有する化粧料に関する。TECHNICAL FIELD The present invention is characterized in that it contains, as a main component, a hydrocarbon obtained by reducing a plant-derived extract, which has no problems such as odor, coloring, stability over time, and skin irritation. The present invention relates to a cosmetic that has good spreadability, a refreshing feeling in use, and has a high moisturizing effect, a whitening effect, a softening effect, and the like.
【0002】[0002]
【従来の技術】従来より、植物油はその優れた潤滑作
用、保湿効果、および良好な使用感から化粧品の原料と
して広範囲に利用されている。しかし、植物油配合化粧
品は、硬化植物油を使用した場合を除き保存安定性は悪
く、製品系において劣化臭や着色を引き起こし、さらに
は過酸化物を生成し皮膚に刺激を与える要因ともなる。
そのため例えば配合量に限度があり機能が充分に発揮で
きなかったり、合成油と併用するなどの方法がとられて
いた。2. Description of the Related Art Conventionally, vegetable oils have been widely used as raw materials for cosmetics because of their excellent lubricating action, moisturizing effect, and good usability. However, vegetable oil-containing cosmetics have poor storage stability except when hardened vegetable oils are used, causing deterioration odor and coloring in product systems, and furthermore, generate peroxides and become a factor that irritates the skin.
For this reason, for example, methods have been employed in which the compounding amount is limited and the function cannot be sufficiently exhibited, or a method is used in combination with a synthetic oil.
【0003】また前記硬化植物油は酸化安定性の低下原
因となる不飽和脂肪酸を水素添加により飽和脂肪酸に変
えることで酸化安定性を高めた油脂であるが、融点が高
いために化粧料への配合作業性が著しく低く、またグリ
ース様の使用感を与えるという欠点がある。一方、合成
油は安全性、加水分解安定性などに問題がある場合が多
く、また、近年の天然志向の傾向から必ずしも消費者の
ニーズに沿うものではない。[0003] The above-mentioned hardened vegetable oil is an oil or fat whose oxidative stability is enhanced by converting unsaturated fatty acids, which cause a decrease in oxidative stability, to saturated fatty acids by hydrogenation. There are drawbacks that the workability is extremely low and that a grease-like feeling is given. On the other hand, synthetic oils often have problems in safety, hydrolytic stability, and the like, and do not always meet the needs of consumers due to the tendency toward nature in recent years.
【0004】[0004]
【発明が解決しようとする課題】本願発明の目的は、植
物由来の油性抽出物を配合し、臭気、着色、経時安定
性、皮膚刺激性などの問題のない、のびが良く、使用感
がさっぱりとした、高い保湿効果、美白効果、および柔
軟効果などを有する化粧料を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to blend an oily extract derived from a plant, to have no problem of odor, coloring, stability with time, skin irritation, etc. An object of the present invention is to provide a cosmetic having a high moisturizing effect, a whitening effect, a softening effect, and the like.
【0005】[0005]
【課題を解決するための手段】前記目的を達成するた
め、本願発明者らは鋭意検討の結果、オリーブ、大豆、
アマランサスおよびパームの種実並びに米ヌカから選ば
れる少なくとも1種の植物原料に含まれる炭化水素の還
元処理物を含有させた化粧料が、臭気、着色、経時安定
性、皮膚刺激性などの問題のない、のびが良く、使用感
がさっぱりとした、高い保湿効果、美白効果、および柔
軟効果などを有する良好な機能を持つことを見出し、本
発明を完成するに至った。Means for Solving the Problems In order to achieve the above object, the present inventors have made intensive studies and found that olives, soybeans,
Cosmetics containing a reduced product of hydrocarbons contained in at least one plant material selected from amaranth and palm seeds and rice bran have no problems such as odor, coloring, stability over time and skin irritation The present invention has been found to have good functions of having a good moisturizing effect, a whitening effect, a softening effect, etc., with good spreadability and a refreshing feeling of use, and completed the present invention.
【0006】[0006]
【発明の実施の形態】本願発明の化粧料に含有させる炭
化水素の還元処理物の出発原料は植物素材、すなわちオ
リーブ、大豆、アマランサスおよびパームの種実並びに
米ヌカである。また、これらの植物素材を圧搾、または
ヘキサン等の有機溶剤を用いる抽出等の常法で処理して
得られる油脂として、原油、その脱ガム油、脱酸油、ま
たは脱色油などが使用でき、これらは通常の食用油の製
造工程から採取できる。また本願発明では、かかる植物
性油脂を常法により脱臭処理する際に得られる脱臭留出
物を原料とすることもできる。本発明においては、かく
して得られるオリーブ油、大豆油、アマランサス油、パ
ーム油、米ヌカ油等またはそれらの脱臭留出物が原料と
して利用できるが、とりわけオリーブ油および米ヌカ油
が好ましく、さらには特にオリーブ油または米ヌカ油の
各脱臭留出物が有利である。これらの原料は必ずしも単
一種類でなくともよく、二種類以上を混合してもよい。
また、混合は原料段階または原料の各処理段階で適宜行
えばよい。BEST MODE FOR CARRYING OUT THE INVENTION The starting materials of the hydrocarbon-reduced product contained in the cosmetic of the present invention are plant materials, that is, olive, soybean, amaranth and palm seeds, and rice bran. In addition, as a fat obtained by pressing these plant materials by a conventional method such as pressing or extraction using an organic solvent such as hexane, crude oil, its degummed oil, deoxidized oil, or decolorized oil can be used, These can be collected from the usual edible oil production process. Further, in the present invention, a deodorized distillate obtained when deodorizing such a vegetable oil or fat by an ordinary method can be used as a raw material. In the present invention, the thus obtained olive oil, soybean oil, amaranthus oil, palm oil, rice bran oil or the like or a deodorized distillate thereof can be used as a raw material. Or each deodorized distillate of rice bran oil is advantageous. These raw materials do not necessarily have to be a single kind, and two or more kinds may be mixed.
The mixing may be appropriately performed at the raw material stage or at each processing stage of the raw material.
【0007】本願発明の化粧料には、炭化水素の還元処
理物を含有させるために、上記原料の油性抽出物を配合
する。該油性抽出物は、炭化水素含量が90重量%以上
となるように原料から抽出したものを用いることが望ま
しい。炭化水素含量が90重量%未満、つまり炭化水素
以外の成分が10重量%以上であると、製品系において
劣化臭や着色等の保存安定性の低下の原因となる場合が
ある。高純度の炭化水素を含有する油性抽出物を得るに
は、前記植物素材から得られる原油、その脱ガム油、脱
酸油、もしくは脱色油、またはそれらの脱臭留出物から
トリグリセリド、遊離脂肪酸等をケン化分解、エステル
化等の処理により分別した後、蒸留処理を行えばよい。The cosmetic of the present invention is blended with an oily extract of the above-mentioned raw material so as to contain a reduced product of a hydrocarbon. As the oily extract, it is desirable to use one extracted from the raw material so that the hydrocarbon content becomes 90% by weight or more. When the hydrocarbon content is less than 90% by weight, that is, when the content of components other than hydrocarbons is 10% by weight or more, the storage stability such as deteriorating odor and coloring may be reduced in a product system. In order to obtain an oily extract containing a high-purity hydrocarbon, a crude oil obtained from the plant material, a degummed oil, a deoxidized oil, or a decolorized oil, or a triglyceride, a free fatty acid, or the like from a deodorized distillate thereof May be separated by a treatment such as saponification decomposition or esterification, followed by distillation treatment.
【0008】さらに上記炭化水素成分には、還元処理が
施される。還元処理を施すことにより、抽出物の安定性
を向上させるとともに、色を改良することが可能であ
る。還元処理には水素添加が挙げられる。処理の度合
は、求める安定性や色度により適宜調整すればよい。ま
た、得られた炭化水素還元処理物をさらに公知の方法で
脱色、脱臭してもよい。[0008] Further, the hydrocarbon component is subjected to a reduction treatment. By performing the reduction treatment, it is possible to improve the stability of the extract and to improve the color. The reduction treatment includes hydrogenation. The degree of processing may be appropriately adjusted depending on the required stability and chromaticity. Further, the obtained hydrocarbon reduced product may be further decolorized and deodorized by a known method.
【0009】上記方法で得た炭化水素の還元処理物は、
炭素数25〜35の分岐および直鎖の炭化水素を主成分
として有し、分子量が340〜480であり、かつ沸点
が390〜490℃である。The reduced product of the hydrocarbon obtained by the above method is
It has a branched and straight chain hydrocarbon having 25 to 35 carbon atoms as a main component, has a molecular weight of 340 to 480, and has a boiling point of 390 to 490 ° C.
【0010】かかる植物由来の炭化水素還元処理物を主
成分とする油性抽出物を化粧料として配合するに当たっ
ての配合量は、最終組成物の総量に対し、0.01〜1
00重量%である。0.01重量%未満であると所望の
効果が得られない。該抽出物そのものを化粧料として用
いてもよく、この場合配合量は100重量%となる。ま
た、本発明の化粧料の種類としては、特に限定されるも
のではないが、とりわけ皮膚に対して使用する公知の各
種化粧品を対象とすることが望ましく、例えばコールド
クリーム、バニシングクリーム、クレンジングクリー
ム、エモリエントクリーム、サンスクリーンクリーム等
の各種クリーム、乳液、化粧水、ファンデーション、洗
顔料、口紅、美容液、パック剤等があげられる。トイレ
タリー製品についても同様に制限はないが、石鹸、入浴
剤等を好適に例示できる。The amount of the oily extract containing the plant-derived hydrocarbon-reduced product as the main component is 0.01 to 1 based on the total amount of the final composition.
00% by weight. If it is less than 0.01% by weight, the desired effect cannot be obtained. The extract itself may be used as a cosmetic, in which case the blending amount will be 100% by weight. Further, the type of the cosmetic of the present invention is not particularly limited, but it is particularly desirable to target various known cosmetics used for the skin, such as cold cream, burnishing cream, cleansing cream, Various creams such as emollient cream and sunscreen cream, emulsions, lotions, foundations, facial cleansers, lipsticks, serums, packs and the like can be mentioned. Although there is no limitation on toiletry products as well, soaps, bath additives and the like can be preferably exemplified.
【0011】本発明の化粧料は、植物由来の炭化水素還
元処理物を主成分とする油性抽出物と他の公知の成分を
用いて、常法により調製することができる。すなわち公
知の油性成分、水溶性成分、界面活性剤、保湿剤、増粘
剤、防腐剤、顔料、粉体、pH調製剤、抗酸化剤、紫外
線吸収剤、香料、色素、精製水等を適宜に配合すればよ
い。The cosmetic of the present invention can be prepared by a conventional method using an oily extract containing a plant-derived hydrocarbon-reduced product as a main component and other known components. That is, known oil components, water-soluble components, surfactants, humectants, thickeners, preservatives, pigments, powders, pH adjusters, antioxidants, ultraviolet absorbers, fragrances, pigments, purified water, etc. May be blended.
【0012】[0012]
【実施例】以下、実施例および比較例にて本発明を説明
する。実施例中の%は重量%を示す。尚、本発明は、こ
こに挙げた実施例に限定されるものではない。The present invention will be described below with reference to examples and comparative examples. % In Examples shows% by weight. Note that the present invention is not limited to the embodiments described here.
【0013】参考製造例(本発明に用いる抽出物の調
製) 米ヌカ油脱臭留出物100gに水酸化ナトリウムを添加
し、加水分解させケン化物を除去した後、減圧蒸留にて
油性抽出物を濃縮した。さらに水素添加処理を施し、安
定性の高い、炭化水素を主成分とする目的抽出物25g
を得た。上記で調製した抽出物試料0.25gを1N水
酸化カリウム/エタノール溶液50ml中でケン化し、
石油エーテル50mlで不ケン化物の抽出を3回繰り返
した。その後、石油エーテル層を水洗、脱水し、溶媒留
去を行った。抽出物を300mlのジエチルエーテル/
ヘキサン(1/99)に溶解させ、シリカゲル12gの
カラムに負荷させた後、溶媒留去を行い回収された重量
すなわち炭化水素画分は0.23g(92%含量)であ
った。また、分子量は340〜480であり、沸点は3
90〜490℃であるものが主成分であった。さらに同
試料をガスクロマトグラフィー(GLC)に供して組成
を分析した。なお指標として、炭素数24、30及び3
5の直鎖飽和炭化水素を用いた。Reference Production Example (Preparation of Extract Used in the Present Invention) Sodium hydroxide was added to 100 g of deodorized distillate of rice bran oil, and hydrolyzed to remove saponified product. Concentrated. 25g of target extract which is subjected to hydrogenation treatment and has high stability and is mainly composed of hydrocarbons
I got 0.25 g of the extract sample prepared above was saponified in 50 ml of 1N potassium hydroxide / ethanol solution,
The extraction of unsaponifiables was repeated three times with 50 ml of petroleum ether. Thereafter, the petroleum ether layer was washed with water and dehydrated, and the solvent was distilled off. The extract was mixed with 300 ml of diethyl ether /
After being dissolved in hexane (1/99) and loaded on a 12 g column of silica gel, the solvent was distilled off, and the recovered weight, that is, the hydrocarbon fraction was 0.23 g (92% content). The molecular weight is 340-480, and the boiling point is 3
Those having a temperature of 90 to 490 ° C. were the main components. Further, the same sample was subjected to gas chromatography (GLC) to analyze the composition. In addition, as an index, carbon number 24, 30 and 3
5 straight-chain saturated hydrocarbons were used.
【0014】このGLC条件は次のとおりである。GL
C装置:ヒューレットパッカード社製5890、カラ
ム:DB−17HT(15m×0.319mm、fil
m thickness:0.15μm、J&W SC
IENTIFIC社製)、注入法スプリット法(スプリ
ット比1/10)、カラム温度:270℃、キャリアガ
ス:ヘリウム。GLC分析の結果得られたチャートを図
1に示した。この結果、同試料は、炭素数25〜35の
炭化水素を主成分として有することが認められた。The GLC conditions are as follows. GL
C apparatus: 5890 manufactured by Hewlett-Packard Company, column: DB-17HT (15 m × 0.319 mm, fill
mthickness: 0.15 μm, J & W SC
IENTIFIC), injection method, split method (split ratio 1/10), column temperature: 270 ° C., carrier gas: helium. The chart obtained as a result of the GLC analysis is shown in FIG. As a result, it was confirmed that this sample had a hydrocarbon having 25 to 35 carbon atoms as a main component.
【0015】以下の実施例には、参考製造例で調整した
米ヌカ油抽出物を使用した。実施例中の官能試験は下記
のごとく実施した。 〔官能試験〕20人のパネラーによる実用テストを行い
「さっぱりした使用感を感じる」「十分にのびが良い」
「十分に保湿効果がある」「十分に柔軟効果がある」と
答えたパネラーの人数を示した。In the following examples, rice bran oil extract prepared in Reference Production Example was used. The sensory tests in the examples were performed as follows. [Sensory test] Perform a practical test by 20 panelists, "feel refreshing usability", "good enough spread"
The number of panelists who answered "sufficiently moisturizing effect" and "sufficiently softening effect" was shown.
【0016】実施例1(クリーム) 表1に示す処方及び、下記の製造方法によりクリームを
調製した。また比較のためのクリームを同様に調製し、
両クリームの官能評価を実施した。その結果を表2に示
す。本発明のクリームは肌に対する伸びがよく、さっぱ
りした使用感や十分な保湿効果、柔軟効果が認められ
た。Example 1 (Cream) A cream was prepared according to the formulation shown in Table 1 and the following production method. Also prepare a cream for comparison in the same way,
Sensory evaluation of both creams was performed. Table 2 shows the results. The cream of the present invention showed good stretch on the skin, and showed a refreshing feeling of use, a sufficient moisturizing effect, and a softening effect.
【0017】[0017]
【表1】 [Table 1]
【0018】〔製造方法〕 1〜6、9、10および12を加熱しながら混合し、70
〜80℃に保つ。 13に7、8および11を加えて加熱しながら混合し、7
0〜80℃に保つ。 の混合物にの混合物を徐々に加えながら攪拌し、
均一に乳化する。 を水浴に置き、室温になるまで攪拌を続けてクリー
ムを得る。[Manufacturing method] 1 to 6, 9, 10 and 12 were mixed while heating.
Keep at ~ 80 ° C. Add 7, 8 and 11 to 13 and mix while heating.
Keep at 0-80 ° C. Stir while gradually adding the mixture to the mixture of
Emulsify uniformly. In a water bath and continue to stir to room temperature to obtain a cream.
【0019】[0019]
【表2】 [Table 2]
【0020】実施例2(乳液) 表3に示す処方及び、下記の製造方法により乳液を調製
した。また比較のための乳液を同様に調製し、両乳液の
官能評価を実施した。その結果を表4に示す。本発明の
乳液は肌に対する伸びがよく、さっぱりした使用感や十
分な保湿効果、柔軟効果が認められた。Example 2 (Emulsion) An emulsion was prepared according to the formulation shown in Table 3 and the following production method. In addition, emulsions for comparison were prepared in the same manner, and the sensory evaluation of both emulsions was performed. Table 4 shows the results. The emulsion of the present invention showed good stretch on the skin, and showed a refreshing feeling of use, a sufficient moisturizing effect, and a softening effect.
【0021】[0021]
【表3】 [Table 3]
【0022】〔製造方法〕 1〜8、11および13を加熱しながら混合し、70〜8
0℃に保つ。 14に9、10および12を加えて加熱しながら混合し、7
0〜80℃に保つ。 の混合物にの混合物を徐々に加えながら攪拌し、
均一に乳化する。 を水浴に置き、室温になるまで攪拌を続けて乳液を
得る。[Manufacturing method] 1-8, 11 and 13 were mixed while heating, and 70-8
Keep at 0 ° C. Add 9, 10 and 12 to 14 and mix while heating.
Keep at 0-80 ° C. Stir while gradually adding the mixture to the mixture of
Emulsify uniformly. In a water bath and continue stirring until it reaches room temperature to obtain an emulsion.
【0023】[0023]
【表4】 [Table 4]
【0024】実施例3(化粧水) 表5に示す処方及び、下記の製造方法により化粧水を調
製した。また比較のための化粧水を同様に調製し、両化
粧水の官能評価を実施した。その結果を表6に示す。本
発明の化粧水は肌に対する伸びがよく、さっぱりした使
用感や十分な保湿効果が認められた。Example 3 (Lotion) A lotion was prepared according to the formulation shown in Table 5 and the following production method. In addition, a lotion for comparison was prepared in the same manner, and the sensory evaluation of both lotions was performed. Table 6 shows the results. The lotion of the present invention showed good stretch on the skin, and showed a refreshing feeling of use and a sufficient moisturizing effect.
【0025】[0025]
【表5】 [Table 5]
【0026】〔製造方法〕 12に1〜3および7〜9を加え、室温下で溶解する。 13に4〜6および10、11を加え、室温下で溶解する。 の混合物にの混合物を徐々に加えながら攪拌し、
均一に乳化する。[Manufacturing method] 1 to 3 and 7 to 9 are added to 12 and dissolved at room temperature. 13. Add 4-6 and 10, 11 to 13 and dissolve at room temperature. Stir while gradually adding the mixture to the mixture of
Emulsify uniformly.
【0027】[0027]
【表6】 [Table 6]
【0028】[0028]
【発明の効果】本発明によれば、オリーブ、大豆、アマ
ランサスおよびパームの種実並びに米ヌカから選ばれる
少なくとも1種の植物原料に含まれる炭化水素の還元処
理物(炭素数25〜35)を含有させた化粧料が提供さ
れる。本化粧料は臭気、着色、経時安定性、皮膚刺激性
などの問題がなく、加えて伸びが良く、使用感がさっぱ
りとし、高い保湿効果、および柔軟効果を奏する。According to the present invention, it contains a reduced product of hydrocarbons (25 to 35 carbon atoms) contained in at least one plant material selected from olive, soybean, amaranth and palm seeds and rice bran. Provided cosmetics are provided. This cosmetic does not have problems such as odor, coloring, stability with time, and skin irritation, and also has good elongation, a refreshing feeling in use, and a high moisturizing effect and a softening effect.
【図1】 参考製造例で得られた抽出物のガスクロマト
グラフィー分析のチャートである。FIG. 1 is a chart of gas chromatography analysis of an extract obtained in Reference Production Example.
Claims (3)
ームの種実並びに米ヌカから選ばれる少なくとも1種の
植物原料に含まれる炭化水素の還元処理物を含有するこ
とを特徴とする化粧料。1. A cosmetic comprising a reduced product of hydrocarbons contained in at least one plant material selected from olive, soybean, amaranth and palm seeds and rice bran.
25〜35のものを主成分とすることを特徴とする請求
項1記載の化粧料。2. The cosmetic according to claim 1, wherein the hydrocarbon-reduced product mainly has 25 to 35 carbon atoms.
340〜480で、かつ沸点が390〜490℃である
ものを主成分とすることを特徴とする請求項1または2
記載の化粧料。3. The hydrocarbon-reduced product is mainly composed of a product having a molecular weight of 340 to 480 and a boiling point of 390 to 490 ° C.
The cosmetic described.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24348497A JP3727760B2 (en) | 1997-08-26 | 1997-08-26 | Cosmetics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24348497A JP3727760B2 (en) | 1997-08-26 | 1997-08-26 | Cosmetics |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005210752A Division JP2005306888A (en) | 2005-07-21 | 2005-07-21 | Cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH1160442A true JPH1160442A (en) | 1999-03-02 |
JP3727760B2 JP3727760B2 (en) | 2005-12-14 |
Family
ID=17104585
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP24348497A Expired - Lifetime JP3727760B2 (en) | 1997-08-26 | 1997-08-26 | Cosmetics |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3727760B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1752138A2 (en) | 2005-08-11 | 2007-02-14 | Henkel Kommanditgesellschaft auf Aktien | Amaranth seed oil in hair compositions |
JP2015229656A (en) * | 2014-06-05 | 2015-12-21 | 花王株式会社 | Skin external preparation |
JP2020535135A (en) * | 2017-09-26 | 2020-12-03 | アモーレパシフィック コーポレーションAmorepacific Corporation | A skin moisturizing external preparation composition containing 1,2,3,4,6-penta-O-galloyl-β-D-glucose. |
-
1997
- 1997-08-26 JP JP24348497A patent/JP3727760B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1752138A2 (en) | 2005-08-11 | 2007-02-14 | Henkel Kommanditgesellschaft auf Aktien | Amaranth seed oil in hair compositions |
JP2015229656A (en) * | 2014-06-05 | 2015-12-21 | 花王株式会社 | Skin external preparation |
JP2020535135A (en) * | 2017-09-26 | 2020-12-03 | アモーレパシフィック コーポレーションAmorepacific Corporation | A skin moisturizing external preparation composition containing 1,2,3,4,6-penta-O-galloyl-β-D-glucose. |
Also Published As
Publication number | Publication date |
---|---|
JP3727760B2 (en) | 2005-12-14 |
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