JPH1150032A - Connection member for circuit and circuit board - Google Patents
Connection member for circuit and circuit boardInfo
- Publication number
- JPH1150032A JPH1150032A JP20952097A JP20952097A JPH1150032A JP H1150032 A JPH1150032 A JP H1150032A JP 20952097 A JP20952097 A JP 20952097A JP 20952097 A JP20952097 A JP 20952097A JP H1150032 A JPH1150032 A JP H1150032A
- Authority
- JP
- Japan
- Prior art keywords
- circuit
- connecting member
- connection terminal
- epoxy resin
- circuit connecting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/30—Assembling printed circuits with electric components, e.g. with resistor
- H05K3/32—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
- H05K3/321—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Wire Bonding (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、回路基板同士また
はICチップ等の電子部品と回路基板の接続に用いられ
る回路用接続部材及び回路板に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a circuit connecting member and a circuit board used for connecting circuit boards to each other or an electronic component such as an IC chip and the circuit board.
【0002】[0002]
【従来の技術】回路基板同士またはICチップや電子部
品と回路基板の接続とを電気的に接続する際には、接着
剤または導電粒子を分散させた異方導電接着剤が用いら
れている。すなわち、これらの接着剤を電極間に配置し
て、加熱、加圧によって電極同士を接続後、加圧方向に
導電性を持たせることによって電気的接続を行うことが
できる。例えば、特開平3−16147では、エポキシ
樹脂をベースとした回路接続用接着剤が提案されてい
る。2. Description of the Related Art An adhesive or an anisotropic conductive adhesive in which conductive particles are dispersed is used to electrically connect circuit boards to each other or to connect an IC chip or electronic component to a circuit board. That is, these adhesives are arranged between the electrodes, and after the electrodes are connected to each other by heating and pressing, electrical connection can be performed by giving conductivity in the pressing direction. For example, JP-A-3-16147 proposes an adhesive for circuit connection based on an epoxy resin.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、エポキ
シ樹脂をベース樹脂とした従来の接着剤を用いた接着剤
は、熱衝撃試験、PCT試験などの信頼性試験を行うと
接続基板の熱膨張率差に基づく内部応力によって接続部
において接続抵抗の増大や接着剤の剥離が生じるという
問題がある。特に、チップを接着剤を介して直接基板に
搭載する場合、接続基板としてFR−4基材を用いたプ
リント基板、あるいはポリイミドやポリエステルを基材
とするフレキシブル配線板を用いると、接続後チップと
の熱膨張率差に基づく内部応力によってチップ及び基板
の反りが発生しやすい。本発明は、回路基板同士または
ICチップ等の電子部品と回路基板の接続に用いられ優
れた接続信頼性を可能とする回路用接続部材及び接続信
頼性に優れる回路板を提供するものである。However, an adhesive using a conventional adhesive using an epoxy resin as a base resin has a difference in the coefficient of thermal expansion of the connection substrate when a reliability test such as a thermal shock test or a PCT test is performed. There is a problem that the connection stress increases in the connection portion and the adhesive is peeled off due to the internal stress based on the above. In particular, when the chip is directly mounted on a substrate via an adhesive, a printed circuit board using an FR-4 base material as a connection substrate, or a flexible wiring board based on polyimide or polyester is used as a connection substrate. Warpage of the chip and the substrate is likely to occur due to the internal stress based on the difference in thermal expansion coefficient of the chip. The present invention provides a circuit connecting member which is used for connecting circuit boards to each other or an electronic component such as an IC chip and enables excellent connection reliability, and a circuit board having excellent connection reliability.
【0004】[0004]
【課題を解決するための手段】本発明の回路用接続部材
は、相対峙する回路電極を加熱、加圧によって、加圧方
向の電極間を電気的に接続する回路用接続部材であっ
て、その回路用接続部材が (A)0.02〜1ミクロンの直径を有するゴム粒子が
分散したエポキシ樹脂 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有することを特徴とする。A circuit connecting member according to the present invention is a circuit connecting member for electrically connecting opposing circuit electrodes by heating and pressurizing, thereby electrically connecting the electrodes in the pressing direction. The circuit connecting member comprises: (A) an epoxy resin in which rubber particles having a diameter of 0.02 to 1 micron are dispersed; and (B) an adhesive composition containing a latent curing agent of an epoxy resin as an essential component. Features.
【0005】また本発明の回路用接続部材は、相対峙す
る回路電極を加熱、加圧によって、加圧方向の電極間を
電気的に接続する回路用接続部材であって、その回路用
接続部材が (C)ゴムエマルジョンとエポキシ樹脂の混合物 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有することを特徴とする。ゴムエマルジ
ョンとエポキシ樹脂の混合物(C)において、ゴムエマ
ルジョンに分散するゴム粒子の直径は、0.02から1
ミクロンであることが好ましい。上記の回路用接続部材
では、接着剤組成物にフェノキシ樹脂を含有することが
でき、フェノキシ樹脂の重量平均分子量は20000〜
60000が好ましい。また上記の回路用接続部材で
は、接着剤組成物に、平均粒径1〜18ミクロンの導電
粒子を分散することができ、導電性粒子の含有量は、接
着剤組成物100容量部に対して、0.1〜20容量部
が好ましい。回路用接続部材の形状はフィルム状である
ことができ、回路用接続部材の接続後の面積は、接続す
る前の面積に対して2.0〜5.0倍であるようにする
ことができる。[0005] A circuit connecting member of the present invention is a circuit connecting member for electrically connecting opposing circuit electrodes by heating and pressurizing the electrodes in the pressing direction. (C) a mixture of a rubber emulsion and an epoxy resin; and (B) an adhesive composition containing a latent curing agent for the epoxy resin as an essential component. In the mixture (C) of the rubber emulsion and the epoxy resin, the diameter of the rubber particles dispersed in the rubber emulsion is from 0.02 to 1
Preferably it is microns. In the circuit connecting member, the adhesive composition may contain a phenoxy resin, and the phenoxy resin has a weight average molecular weight of 20,000 to 2,000.
60000 is preferred. In the circuit connecting member, conductive particles having an average particle diameter of 1 to 18 microns can be dispersed in the adhesive composition, and the content of the conductive particles is based on 100 parts by volume of the adhesive composition. , 0.1 to 20 parts by volume is preferred. The shape of the circuit connecting member may be a film shape, and the area of the circuit connecting member after connection may be 2.0 to 5.0 times the area before connection. .
【0006】本発明の回路板は、第一の接続端子を有す
る第一の回路部材と、第二の接続端子を有する第二の回
路部材とを、第一の接続端子と第二の接続端子を対向し
て配置し、前記対向配置した第一の接続端子と第二の接
続端子の間に回路用接続部材を介在させ、加熱加圧して
前記対向配置した第一の接続端子と第二の接続端子を電
気的に接続させた回路板であって、前記回路用接続部材
が、 (A)0.02〜1ミクロンの直径を有するゴム粒子が
分散したエポキシ樹脂 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有する接着剤であることを特徴とする。[0006] The circuit board of the present invention comprises a first circuit member having a first connection terminal and a second circuit member having a second connection terminal, the first connection terminal and the second connection terminal. Are arranged facing each other, a circuit connecting member is interposed between the first connecting terminal and the second connecting terminal arranged opposite to each other, and the first connecting terminal and the second arranged facing each other are heated and pressurized. A circuit board in which connection terminals are electrically connected, wherein the circuit connection member comprises: (A) an epoxy resin in which rubber particles having a diameter of 0.02 to 1 micron are dispersed; and (B) an epoxy resin potential. It is an adhesive containing an adhesive composition containing a curing agent as an essential component.
【0007】また本発明の回路板は、第一の接続端子を
有する第一の回路部材と、第二の接続端子を有する第二
の回路部材とを、第一の接続端子と第二の接続端子を対
向して配置し、前記対向配置した第一の接続端子と第二
の接続端子の間に回路用接続部材を介在させ、加熱加圧
して前記対向配置した第一の接続端子と第二の接続端子
を電気的に接続させた回路板であって、前記回路用接続
部材が、 (C)ゴムエマルジョンとエポキシ樹脂の混合物 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有する接着剤であることを特徴とする。Further, the circuit board of the present invention comprises a first circuit member having a first connection terminal and a second circuit member having a second connection terminal, the first connection member being connected to the second connection member. Terminals are arranged to face each other, a circuit connecting member is interposed between the first and second connection terminals, and the first and second connection terminals are heated and pressurized to form a second connection terminal. A circuit board in which the connection terminals are electrically connected, wherein the circuit connection member comprises: (C) a mixture of a rubber emulsion and an epoxy resin; and (B) an adhesive containing a latent curing agent of an epoxy resin as an essential component. It is characterized in that it is an adhesive containing the composition.
【0008】[0008]
【発明の実施の形態】本発明に用いるエポキシ樹脂は、
エピクロルヒドリンとビスフェノールAやF、AD等か
ら誘導されるビスフェノール型エポキシ樹脂、エピクロ
ルヒドリンとフェノールノボラックやクレゾールノボラ
ックから誘導されるエポキシノボラック樹脂やナフタレ
ン環を含んだ骨格を有するナフタレン系エポキシ樹脂、
グリシジルアミン、グリシジルエステル、ビフェニル、
脂環式等の1分子内に2個以上のグリシジル基を有する
各種のエポキシ化合物等を単独にあるいは2種以上を混
合して用いることが可能である。これらのエポキシ樹脂
は、不純物イオン(Na+、C1−等)や、加水分解性
塩素等を300ppm以下に低減した高純度品を用いる
ことがエレクトロンマイグレーション防止のために好ま
しい。DESCRIPTION OF THE PREFERRED EMBODIMENTS The epoxy resin used in the present invention is:
Bisphenol type epoxy resin derived from epichlorohydrin and bisphenol A or F, AD, etc., epoxy novolak resin derived from epichlorohydrin and phenol novolak or cresol novolak or naphthalene-based epoxy resin having a skeleton containing a naphthalene ring,
Glycidylamine, glycidyl ester, biphenyl,
Various epoxy compounds having two or more glycidyl groups in one molecule, such as alicyclic compounds, can be used alone or in combination of two or more. For these epoxy resins, it is preferable to use high-purity products in which impurity ions (Na +, C1-, etc.), hydrolyzable chlorine and the like are reduced to 300 ppm or less, in order to prevent electron migration.
【0009】本発明のゴム粒子は、0.02〜1ミクロ
ンの直径を有しエポキシ樹脂に分散される。ゴム粒子は
一次粒子として均一にエポキシ樹脂に分散することがで
きる。0.02〜1ミクロンの直径を有すゴム粒子は、
全ゴム粒子の70容量%以上が好ましく、90容量%以
上がより好ましい。0.02〜1ミクロンの直径を有す
るゴム粒子が分散したエポキシ樹脂(A)は、ゴムエマ
ルジョンを前記エポキシ樹脂に直接混合、脱水処理して
得らことができる。The rubber particles of the present invention have a diameter of 0.02 to 1 micron and are dispersed in an epoxy resin. The rubber particles can be uniformly dispersed in the epoxy resin as primary particles. Rubber particles having a diameter of 0.02 to 1 micron
It is preferably at least 70% by volume of all rubber particles, more preferably at least 90% by volume. The epoxy resin (A) in which rubber particles having a diameter of 0.02 to 1 micron are dispersed can be obtained by directly mixing a rubber emulsion with the epoxy resin and performing a dehydration treatment.
【0010】本発明では、ゴムエマルジョンとエポキシ
樹脂の混合物(C)を使用することができる。この場
合、ゴムエマルジョンに分散するゴム粒子の直径は、
0.02から1ミクロンであることが好ましい。0.0
2〜1ミクロンの直径を有すゴム粒子は、全ゴム粒子の
70容量%以上であることが好ましく、90容量%以上
であることがより好ましい。In the present invention, a mixture (C) of a rubber emulsion and an epoxy resin can be used. In this case, the diameter of the rubber particles dispersed in the rubber emulsion is
Preferably it is between 0.02 and 1 micron. 0.0
The rubber particles having a diameter of 2 to 1 micron are preferably at least 70% by volume, more preferably at least 90% by volume of the total rubber particles.
【0011】本発明のゴムエマルジョンは、乳化重合、
懸濁重合や溶液重合から得られるゴムの水分散体とした
ものであり、例えば、アクリルエマルジョン、SBR、
NBRなどがあげられ、単独あるいは2種以上を混合し
たものが用いられ、特に、(メタ)アクリル酸エステル
系モノマを乳化重合して得られる、ガラス転移温度が室
温以下のアクリルゴムエマルジョンが好適である。前記
ゴム粒子の粒子径は、0.02〜1ミクロン程度が好ま
しいが、エポキシ樹脂組成物にした際の硬化物性や作業
性の点から0.1〜0.6ミクロンがより好ましい。こ
のような粒径のゴム粒子は、全ゴム粒子の70容量%以
上であることが好ましく、90容量%以上であることが
より好ましい。[0011] The rubber emulsion of the present invention can be obtained by emulsion polymerization,
It is an aqueous dispersion of rubber obtained from suspension polymerization or solution polymerization, for example, acrylic emulsion, SBR,
NBR and the like are used singly or as a mixture of two or more kinds. In particular, an acrylic rubber emulsion having a glass transition temperature of room temperature or lower, which is obtained by emulsion polymerization of a (meth) acrylate-based monomer, is suitable. is there. The particle size of the rubber particles is preferably about 0.02 to 1 micron, but more preferably 0.1 to 0.6 micron from the viewpoint of the cured physical properties and workability of the epoxy resin composition. The rubber particles having such a particle size are preferably 70% by volume or more of all the rubber particles, and more preferably 90% by volume or more.
【0012】本発明でゴムエマルジョンとエポキシ樹脂
を混合・脱水して得られるエポキシ樹脂組成物は、ゴム
エマルジョンを、エポキシ樹脂に直接混合して、常圧
下、または減圧下で撹拌しながら水を除去して得られ
る。この際、水を除去後さらに高圧ホモジナイザで処理
するとエポキシ樹脂組成物の粘度が低くなり、接着剤組
成物を作製時の作業性が向上する。エポキシ樹脂組成物
中に分散されるゴム粒子量は、エポキシ樹脂100重量
部に対して1重量部〜60重量部が好ましく、さらに好
ましくは2重量部から30重量部である。The epoxy resin composition obtained by mixing and dewatering a rubber emulsion and an epoxy resin in the present invention is obtained by directly mixing a rubber emulsion with an epoxy resin and removing water while stirring under normal pressure or reduced pressure. Is obtained. At this time, if the treatment is further performed with a high-pressure homogenizer after removing the water, the viscosity of the epoxy resin composition decreases, and the workability at the time of preparing the adhesive composition is improved. The amount of rubber particles dispersed in the epoxy resin composition is preferably from 1 to 60 parts by weight, more preferably from 2 to 30 parts by weight, per 100 parts by weight of the epoxy resin.
【0013】エポキシ樹脂の潜在性硬化剤としては、イ
ミダゾール系、ヒドラジド系、三フッ化ホウ素ーアミン
錯体、スルホニウム塩、アミンイミド、ジアミノマレオ
ニトリル、メラミンおよびその誘導体、ポリアミンの
塩、ジシアンジアミド等、及びこれらの変性物があり、
これらは単独あるいは2種以上の混合体として使用でき
る。これらはアニオンまたはカチオン重合性の触媒型硬
化剤であり、速硬化性を得やすく、また化学当量的な考
慮が少なくてよいことから好ましい。硬化剤としては、
その他にポリアミン類、ポリメルカプタン、ポリフェノ
ール、酸無水物等の重付加型の適用や前記触媒型硬化剤
との併用も可能である。Examples of the latent curing agents for epoxy resins include imidazoles, hydrazides, boron trifluoride-amine complexes, sulfonium salts, amine imides, diamino maleonitriles, melamines and derivatives thereof, polyamine salts, dicyandiamide and the like. There are denatured products,
These can be used alone or as a mixture of two or more. These are anionic or cationically polymerizable catalytic curing agents, and are preferred because they can easily obtain fast curing properties and require little consideration of chemical equivalents. As a curing agent,
In addition, polyaddition of polyamines, polymercaptans, polyphenols, acid anhydrides and the like can be applied, or the catalyst can be used in combination with the catalyst type curing agent.
【0014】アニオン重合型の触媒型硬化剤としては、
第3アミン類やイミダゾール類を配合したエポキシ樹脂
は、160〜200℃程度の中温で数10秒〜数時間程
度の加熱により硬化するために可使時間(ポットライ
フ)が比較的長い。カチオン重合型の触媒型硬化剤とし
ては、エネルギー線照射により樹脂を硬化させる感光性
オニウム塩、例えば、芳香族ジアゾニウム塩、芳香族ス
ルホニウム塩等が主として用いられる。またエネルギー
線照射以外に加熱によっても活性化してエポキシ樹脂を
硬化させるものとして、脂肪族スルホニウム塩等があ
る。この種の硬化剤は速硬化性という特徴を有すること
から好ましい。The anionic polymerization type catalyst type curing agent includes:
Epoxy resins containing tertiary amines or imidazoles have a relatively long pot life because they are cured by heating at a medium temperature of about 160 to 200 ° C. for several tens of seconds to several hours. As the cationic polymerization type catalyst-type curing agent, a photosensitive onium salt that cures a resin by irradiation with energy rays, for example, an aromatic diazonium salt, an aromatic sulfonium salt, or the like is mainly used. In addition, aliphatic sulfonium salts and the like can be activated by heating in addition to energy beam irradiation to cure the epoxy resin. This type of curing agent is preferred because it has the characteristic of fast curing.
【0015】これらの硬化剤をポリウレタン系、ポリエ
ステル系等の高分子物質や、Ni、Cu等の金属薄膜及
びケイ酸カルシウム等の無機物で被覆してマイクロカプ
セル化したものは、可使時間が延長できるため好まし
い。When these curing agents are microencapsulated by coating them with a polymeric substance such as polyurethane or polyester, a metal thin film such as Ni or Cu, or an inorganic substance such as calcium silicate, the pot life is extended. It is preferable because it is possible.
【0016】上記で得た接着剤組成物中には、通常の添
加剤等として例えば、充填剤、軟化剤、促進剤、老化防
止剤、着色剤、難燃剤、チキソトロピック剤、カップリ
ング剤及びフェノール樹脂やメラミン樹脂、イソシアネ
ート類等の硬化剤等を含有することもできる。[0016] In the adhesive composition obtained above, for example, fillers, softeners, accelerators, antioxidants, coloring agents, flame retardants, thixotropic agents, coupling agents, and the like as ordinary additives. A curing agent such as a phenol resin, a melamine resin, and an isocyanate may be contained.
【0017】本発明に用いるフェノキシ樹脂について説
明する。フェノキシ樹脂は、高速液体クロマトグラフィ
ー(HLC)から求められた重量平均分子量が1000
0以上の高分子量エポキシ樹脂に相当し、エポキシ樹脂
と同様に他にビスフェノールA型、AD型、AF型等の
種類がある。これらはエポキシ樹脂と構造が類似してい
ることから相溶性がよく、また接着性も良好な特徴を有
する。分子量の大きい程フィルム形成性が容易に得ら
れ、また接続時の流動性に影響する溶融粘度を広範囲に
設定できる。重量平均分子量としては10000〜80
000のものが溶融粘度や他の樹脂との相溶性等の点か
らより好ましく、20000〜60000のフェノキシ
樹脂がより好ましい。これらの樹脂は、水酸基やカルボ
キシル基等の極性基等を含有すると、エポキシ樹脂との
相溶性が向上し、均一な外観や特性を有するフィルムが
得られることや、硬化時の反応促進による短時間硬化を
得る点からも好ましい。配合量としては、フィルム形成
性や硬化反応の促進の点から樹脂成分全体に対して20
〜80重量%とするのが好ましい。また溶融粘度調整等
のために、スチレン系樹脂やアクリル樹脂等を適宜混合
してもよい。The phenoxy resin used in the present invention will be described. The phenoxy resin has a weight average molecular weight of 1000 determined by high performance liquid chromatography (HLC).
It corresponds to a high molecular weight epoxy resin of 0 or more, and similarly to the epoxy resin, there are other types such as bisphenol A type, AD type and AF type. Since these have similar structures to epoxy resins, they have good compatibility and good adhesiveness. The larger the molecular weight, the more easily the film-forming properties can be obtained, and the melt viscosity which affects the fluidity at the time of connection can be set in a wide range. The weight average molecular weight is 10,000 to 80
000 is more preferable in view of the melt viscosity and compatibility with other resins, and 20,000 to 60,000 phenoxy resin is more preferable. When these resins contain a polar group such as a hydroxyl group or a carboxyl group, the compatibility with the epoxy resin is improved, and a film having a uniform appearance and properties can be obtained. It is preferable from the viewpoint of obtaining curing. The compounding amount is 20 parts with respect to the entire resin component from the viewpoint of promoting film forming property and curing reaction.
It is preferably set to 80% by weight. In addition, a styrene-based resin, an acrylic resin, or the like may be appropriately mixed for melt viscosity adjustment or the like.
【0018】導電性粒子としては、Au、Ag、Ni、
Cu、はんだ等の金属粒子やカーボン等があり、これら
及び非導電性のガラス、セラミック、プラスチック等に
前記した導通層を被覆等により形成したものでもよい。
プラスチックを核とした場合や熱溶融金属粒子の場合、
加熱加圧により変形性を有するので接続時に電極との接
触面積が増加し信頼性が向上するので好ましい。導電性
粒子は、接着剤成分100体積に対して0.1〜30体
積%の広範囲で用途により使い分ける。過剰な導電性粒
子による隣接回路の短絡等を防止するためには0.1〜
10体積%とするのがより好ましい。As the conductive particles, Au, Ag, Ni,
There are metal particles such as Cu and solder, carbon, and the like, and the conductive layer described above may be formed by coating the above conductive layer with non-conductive glass, ceramic, plastic, or the like.
In the case of plastic core or hot melt metal particles,
Heat and pressure are preferable because they have deformability, so that the contact area with the electrode increases during connection and reliability is improved. The conductive particles are properly used in a wide range of 0.1 to 30% by volume with respect to 100 parts by volume of the adhesive component. In order to prevent a short circuit of an adjacent circuit due to excessive conductive particles, 0.1 to
More preferably, the content is 10% by volume.
【0019】本発明の接着剤組成物は一液型接着剤とし
て、とりわけ液晶パネルや半導体チップ接着用のフィル
ム状接着剤として特に有用である。この場合例えば、上
記で得た接着剤組成物を溶剤あるいはエマルジョンの場
合の分散液等として液状化して、離形紙等の剥離性基材
上に形成し、あるいは不織布等の基材に前記配合液を含
浸させて剥離性基材上に形成し、硬化剤の活性温度以下
で乾燥し、溶剤あるいは分散液等を除去すればよい。こ
の時、用いる溶剤は芳香族炭化水素系と含酸素系の混合
溶剤が、材料の溶解性を向上させるため好ましい。ここ
に含酸素系溶剤のSP値は8.1〜10.7の範囲とす
ることが潜在性硬化剤の保護上好ましく、酢酸エステル
類がより好ましい。また溶剤の沸点は150℃以下が適
用できる。沸点が150℃を超すと乾燥に高温を要し、
潜在性硬化剤の活性温度に近いことから潜在性の低下を
招き、低温では乾燥時の作業性が低下する。このため沸
点が60〜150℃が好ましく、70〜130℃がより
好ましい。The adhesive composition of the present invention is particularly useful as a one-part adhesive, especially as a film adhesive for bonding a liquid crystal panel or a semiconductor chip. In this case, for example, the adhesive composition obtained above is liquefied as a solvent or a dispersion in the case of an emulsion, and is formed on a release substrate such as release paper, or is mixed with a substrate such as a nonwoven fabric. The solution may be impregnated to form on the peelable substrate, dried at a temperature lower than the activation temperature of the curing agent, and the solvent or the dispersion may be removed. At this time, a mixed solvent of an aromatic hydrocarbon type and an oxygen-containing type is preferably used as the solvent for improving the solubility of the material. Here, the SP value of the oxygen-containing solvent is preferably in the range of 8.1 to 10.7 from the viewpoint of protection of the latent curing agent, and acetates are more preferable. Further, the boiling point of the solvent can be 150 ° C. or less. When the boiling point exceeds 150 ° C, high temperature is required for drying,
Since the temperature is close to the activation temperature of the latent curing agent, the potential is reduced, and at low temperatures, the workability during drying is reduced. For this reason, the boiling point is preferably from 60 to 150C, more preferably from 70 to 130C.
【0020】接着剤の接続後の面積と接続前の面積の比
は、以下の手段によって測定する。すなわち、厚さ50
μm、大きさ5mm角の接着剤を厚さ1.1mm、大き
さ15mm角のガラス板2枚に挟んでおく。これを、加
熱圧着機によって加熱温度180℃、加圧18kgf/
cm2、加圧時間20秒の条件で加熱、加圧を行い、加
熱、加圧前の接着剤面積(A)及び、加熱、加圧の接着
剤面積(B)を画像処理装置を用いて測定することによ
って、接着剤の接続後の面積と接続前の面積の比(B/
A)を求めることができる。接着剤の接続後の面積と接
続前の面積の比(B/A)が2.0未満になると、接続
電極間、または接続電極と導電粒子界面の溶融接着剤の
排除性が低下するため、接続電極間または接続電極と導
電粒子間の電気的導通を確保でき難くなる。一方、接着
剤の接続後の面積と接続前の面積の比(B/A)が5.
0を越えると接続時の接着剤の流動性が高すぎるため、
気泡がでやすく、結果として信頼性が低下する傾向にあ
る。The ratio of the area after connection of the adhesive to the area before connection is measured by the following means. That is, the thickness 50
A 5 μm square adhesive having a thickness of 5 μm is sandwiched between two glass plates having a thickness of 1.1 mm and a size of 15 mm square. This was heated at 180 ° C. and pressurized at 18 kgf /
Heating and pressurizing are performed under the conditions of cm 2 and pressurizing time of 20 seconds, and the area of the adhesive before heating and pressing (A) and the area of the adhesive before heating and pressing (B) are measured using an image processing apparatus. By measuring, the ratio of the area after connection of the adhesive to the area before connection (B /
A) can be obtained. If the ratio (B / A) of the area after the connection of the adhesive to the area before the connection is less than 2.0, the releasability of the molten adhesive between the connection electrodes or at the interface between the connection electrode and the conductive particles is reduced. It becomes difficult to secure electrical conduction between the connection electrodes or between the connection electrodes and the conductive particles. On the other hand, the ratio (B / A) of the area after connection of the adhesive to the area before connection is 5.
If it exceeds 0, the fluidity of the adhesive at the time of connection is too high,
Air bubbles tend to be generated, and as a result, reliability tends to decrease.
【0021】フィルム状接着剤の場合、接着剤層を多層
化することもできる。例えば、異方導電性を付与するた
めに導電粒子を充填させた接着フィルムと導電粒子を充
填していない接着剤層をラミネート化した二層構成異方
導電フィルムや導電粒子を充填させた接着フィルムの両
側に導電粒子を充填していない接着剤層をラムネート化
した三層構成異方導電フィルムを用いることができる。
これらの多層構成異方導電フィルムは接続電極上に効率
良く、導電粒子を捕獲できるため、狭ピッチ接続に有利
である。また、回路部材との接着性を考慮して、回路部
材1及び2に対してそれぞれ接着性に優れる接着フィル
ムをラミネートして多層化することもできる。In the case of a film-like adhesive, the adhesive layer can be multi-layered. For example, a two-layer anisotropic conductive film or an adhesive film filled with conductive particles in which an adhesive film filled with conductive particles and an adhesive layer not filled with conductive particles to impart anisotropic conductivity are laminated. Can be used a three-layered anisotropic conductive film in which an adhesive layer not filled with conductive particles on both sides is turned into a raminate.
These multi-layered anisotropic conductive films are advantageous for narrow pitch connection because they can efficiently capture conductive particles on connection electrodes. Also, in consideration of the adhesiveness with the circuit member, the circuit members 1 and 2 may be laminated with an adhesive film having excellent adhesiveness to form a multilayer.
【0022】本発明の回路板で用いられる回路部材とし
ては、半導体チップ、トランジスタ、ダイオ−ド、サイ
リスタ等の能動素子、コンデンサ、抵抗体、コイル等の
受動素子等の電子部品、プリント基板、ポリイミドやポ
リエステルを基材としたフレキシル配線板やITOなど
が回路形成されたガラス基板があげられる。半導体チッ
プや基板の電極パッド上には、めっきで形成されるバン
プや金ワイヤの先端をトーチ等により溶融させ、金ボー
ルを形成し、このボールを電極パッド上に圧着した後、
ワイヤを切断して得られるワイヤバンプなどの突起電極
を設け、接続端子として用いることができる。上記の回
路部材には接続端子が通常は多数(場合によっては単数
でも良い)設けられており、前記回路部材の少なくとも
1組をそれらの回路部材に設けられた接続端子の少なく
とも一部を対向配置し、対向配置した接続端子間に接着
剤を介在させ、加熱加圧して対向配置した接続端子どう
しを電気的に接続して回路板とする。回路部材の少なく
とも1組を加熱加圧することにより、対向配置した接続
端子どうしは、直接接触により又は導電粒子を介して電
気的に接続される。Circuit components used in the circuit board of the present invention include electronic components such as active elements such as semiconductor chips, transistors, diodes and thyristors, passive elements such as capacitors, resistors and coils, printed circuit boards, and polyimides. And a glass substrate on which a circuit such as a flexible wiring board made of polyester or ITO is formed. On the electrode pads of the semiconductor chip and substrate, the tip of the bump or gold wire formed by plating is melted with a torch or the like, a gold ball is formed, and this ball is pressed on the electrode pad,
A protruding electrode such as a wire bump obtained by cutting a wire is provided and can be used as a connection terminal. The above-mentioned circuit members are usually provided with a large number of connection terminals (in some cases, a single terminal may be provided), and at least one set of the circuit members is disposed so that at least a part of the connection terminals provided on the circuit members is opposed to each other. Then, an adhesive is interposed between the opposed connection terminals and heated and pressed to electrically connect the opposed connection terminals to form a circuit board. By heating and pressing at least one set of the circuit members, the connection terminals arranged opposite to each other are electrically connected by direct contact or via conductive particles.
【0023】[0023]
実施例1 ビスフェノールAとエピクロルヒドリンから、ビスフェ
ノールA型フェノキシ樹脂(平均分子量30000)6
0gを一般的方法により作製し、これを重量比でトルエ
ン(沸点110.6℃、SP値8.90)/酢酸エチル
(沸点77.1℃、SP値9.10)=50/50の混
合溶剤に溶解して、固形分30重量%のビスフェノール
型Aフェノキシ樹脂溶液とした。アクリル酸エチル80
重量部、メタクリル酸メチル10重量部、メタクリル酸
グリシジル10重量部を末端アルキル基含有ポリマであ
る乳化剤とともに乳化重合して得たアクリルゴムエマル
ジョン20重量部と80重量部のビスフェノールA型エ
ポキシ樹脂を混合撹拌、加熱して水を除いた後、高圧ホ
モジナイザによって処理して直径0.3ミクロンのアク
リルゴム粒子が一次分散された液状エポキシ樹脂を得
た。このアクリルゴム粒子分散液状エポキシ樹脂30重
量部を前記の固形分30重量%のビスフェノール型Aフ
ェノキシ樹脂溶液(樹脂重量部:30部)と混合した。
ついでこの混合溶液に潜在性硬化剤であるノバキュア3
941HPS(イミダゾール変性体を核とし、その表面
をポリウレタンで被覆してなる平均粒径5μmのマイク
ロカプセル型硬化剤を、液状ビスフェノールF型エポキ
シ樹脂中に分散してなるマスターバッチ型硬化剤、活性
温度125℃、旭化成工業株式会社製商品名)40部を
加え、さらに導電性粒子(ポリスチレンを核とする粒子
の表面に、厚み0.2μmのニッケル層を設け、さらに
このニッケル層の外側に、厚み0.02μmの金層を設
け、平均粒径5μm、比重2.5の導電性粒子を作製)
を5容量部(接着剤組成物100容量部に対して)配合
分散させ、厚み80μmのフッ素樹脂フィルムに塗工装
置を用いて塗布し、75℃、10分の熱風乾燥により接
着剤層の厚みが50μmの回路用接続部材を得た。 (回路の接続)上述の回路用接続部材を用いて、金バン
プ(面積:80μmx80μm、高さ:15μm)付き
チップ(10mmx10mm)とライン幅50μm、ピ
ッチ100μm、厚み18μmのNi/Auめっき銅回
路を有するフレキシブル回路板(FPC)の接続を以下
に示すように行った。回路用接続部材(12mmx12
mm)をNi/AuめっきCu回路プリント基板に80
℃、10kgf/cm2で貼りつけた後、フッ素樹脂フ
ィルムを剥離し、チップのバンプとNi/AuめっきC
u回路FPCの位置あわせを行った。ついで、170
℃、30g/バンプ、20秒の条件でチップ上方から加
熱、加圧を行い、本接続を行った。本接続後の接続抵抗
は、1バンプあたり最高で6mΩ、平均で2mΩ、絶縁
抵抗は108Ω以上であり、これらの値は−55〜12
5℃の熱衝撃試験1000サイクル処理、PCT試験
(121℃、2気圧)200時間、260℃のはんだバ
ス浸漬10秒後においても変化がなく、良好な接続信頼
性を示した。Example 1 Bisphenol A type phenoxy resin (average molecular weight 30,000) 6 from bisphenol A and epichlorohydrin
0 g was prepared by a general method, and this was mixed in a weight ratio of toluene (boiling point 110.6 ° C., SP value 8.90) / ethyl acetate (boiling point 77.1 ° C., SP value 9.10) = 50/50. It was dissolved in a solvent to obtain a bisphenol-A phenoxy resin solution having a solid content of 30% by weight. Ethyl acrylate 80
20 parts by weight of an acrylic rubber emulsion obtained by emulsion polymerization of 10 parts by weight of methyl methacrylate, 10 parts by weight of methyl methacrylate, and 10 parts by weight of glycidyl methacrylate with an emulsifier which is a polymer having a terminal alkyl group, and 80 parts by weight of a bisphenol A type epoxy resin. After stirring and heating to remove water, the mixture was treated with a high-pressure homogenizer to obtain a liquid epoxy resin in which acrylic rubber particles having a diameter of 0.3 μm were primarily dispersed. 30 parts by weight of the acrylic rubber particle-dispersed liquid epoxy resin was mixed with the bisphenol-A phenoxy resin solution (resin weight: 30 parts) having a solid content of 30% by weight.
Then, Novacure 3 as a latent curing agent was added to the mixed solution.
941 HPS (a masterbatch-type curing agent obtained by dispersing a microcapsule-type curing agent having an average particle diameter of 5 μm having a modified imidazole core as a core and covering the surface with polyurethane in a liquid bisphenol F-type epoxy resin, activation temperature At 125 ° C., 40 parts of Asahi Kasei Kogyo Co., Ltd. were added, and a nickel layer having a thickness of 0.2 μm was further provided on the surface of the conductive particles (particles having polystyrene as a core). A gold layer of 0.02 μm was provided to produce conductive particles having an average particle size of 5 μm and a specific gravity of 2.5)
Was dispersed in 5 parts by volume (based on 100 parts by volume of the adhesive composition), applied to a fluororesin film having a thickness of 80 μm using a coating device, and dried at 75 ° C. for 10 minutes with hot air to obtain a thickness of the adhesive layer. Of 50 μm was obtained. (Circuit Connection) Using the above-described circuit connecting member, a chip (10 mm × 10 mm) with a gold bump (area: 80 μm × 80 μm, height: 15 μm) and a Ni / Au plated copper circuit having a line width of 50 μm, a pitch of 100 μm, and a thickness of 18 μm were formed. The connection of the flexible circuit board (FPC) was performed as shown below. Circuit connection member (12 mm x 12
mm) on a Ni / Au plated Cu circuit printed circuit board.
After sticking at 10 ° C and 10 kgf / cm 2 , the fluororesin film was peeled off, and the bumps on the chip and Ni / Au plating C
The alignment of the u circuit FPC was performed. Then 170
Heating and pressurizing were performed from above the chip under the conditions of 30 ° C., 30 g / bump, and 20 seconds, and the main connection was performed. The connection resistance after this connection is 6 mΩ at the maximum per bump, 2 mΩ on average, and the insulation resistance is 10 8 Ω or more. These values are −55 to 12
Even after 1000 cycles of thermal shock test at 5 ° C., 200 hours of PCT test (121 ° C., 2 atm) and 10 seconds after immersion in a solder bath at 260 ° C., good connection reliability was exhibited.
【0024】実施例2 ビスフェノールAとエピクロルヒドリンから、ビスフェ
ノールA型フェノキシ樹脂(平均分子量30000)6
0gを一般的方法により作製し、これを重量比でトルエ
ン(沸点110.6℃、SP値8.90)/酢酸エチル
(沸点77.1℃、SP値9.10)=50/50の混
合溶剤に溶解して、固形分30重量%のビスフェノール
型Aフェノキシ樹脂溶液とした。アクリル酸エチル80
重量部、メタクリル酸メチル10重量部、メタクリル酸
グリシジル10重量部を末端アルキル基含有ポリマであ
る乳化剤とともに乳化重合して得たアクリルゴムエマル
ジョン20重量部と80重量部のビスフェノールA型エ
ポキシ樹脂を混合撹拌、加熱して水を除いた後、高圧ホ
モジナイザによって処理して直径0.3ミクロンのアク
リルゴム粒子が一次分散された液状エポキシ樹脂を得
た。このアクリルゴム粒子分散液状エポキシ樹脂30重
量部を前記の固形分30重量%のビスフェノール型Aフ
ェノキシ樹脂溶液(樹脂重量部:30部)と混合した。
ついでこの混合溶液に潜在性硬化剤であるノバキュア3
941HPS(イミダゾール変性体を核とし、その表面
をポリウレタンで被覆してなる平均粒径5μmのマイク
ロカプセル型硬化剤を、液状ビスフェノールF型エポキ
シ樹脂中に分散してなるマスターバッチ型硬化剤、活性
温度125℃、旭化成工業株式会社製商品名)40部を
加え、さらに導電性粒子(ポリスチレンを核とする粒子
の表面に、厚み0.2μmのニッケル層を設け、さらに
このニッケル層の外側に、厚み0.02μmの金層を設
け、平均粒径5μm、比重2.5の導電性粒子を作製)
を5容量部(接着剤組成物100容量部に対して)配合
分散させ、厚み80μmのフッ素樹脂フィルムに塗工装
置を用いて塗布し、75℃、10分の熱風乾燥により接
着剤層の厚みが25μmの接着フィルムaを得た。つい
で、前記フィルム塗工用溶液の作製の中で導電粒子を分
散しない以外は同様な方法で作製したフィルム塗工用溶
液を厚み80μmのフッ素樹脂フィルムに塗工装置塗布
し、75℃、10分乾燥し厚み25μmの接着フィルム
bを作製した。 (回路の接続)上述の回路用接続部材を用いて、金バン
プ(面積:80μmx80μm、高さ:15μm)付き
チップ(10mmx10mm)とライン幅50μm、ピ
ッチ100μm、厚み18μmのNi/Auめっき銅回
路を有するフレキシブル回路板(FPC)の接続を以下
に示すように行った。回路用接続部材(12mmx12
mm)の接着フィルムb側ををNi/AuめっきCu回
路プリント基板に80℃、10kgf/cm2で貼りつ
けた後、フッ素樹脂フィルムを剥離し、チップのバンプ
とNi/AuめっきCu回路FPCの位置あわせを行っ
た。ついで、170℃、30g/バンプ、20秒の条件
でチップ上方から加熱、加圧を行い、本接続を行った。
本接続後の接続抵抗は、1バンプあたり最高で4mΩ、
平均で2mΩ、絶縁抵抗は108Ω以上であり、これら
の値は−55〜125℃の熱衝撃試験1000サイクル
処理、PCT試験(121℃、2気圧)200時間、2
60℃のはんだバス浸漬10秒後においても変化がな
く、良好な接続信頼性を示した。Example 2 Bisphenol A-type phenoxy resin (average molecular weight 30,000) was prepared from bisphenol A and epichlorohydrin.
0 g was prepared by a general method, and this was mixed in a weight ratio of toluene (boiling point 110.6 ° C., SP value 8.90) / ethyl acetate (boiling point 77.1 ° C., SP value 9.10) = 50/50. It was dissolved in a solvent to obtain a bisphenol-A phenoxy resin solution having a solid content of 30% by weight. Ethyl acrylate 80
20 parts by weight of an acrylic rubber emulsion obtained by emulsion polymerization of 10 parts by weight of methyl methacrylate, 10 parts by weight of methyl methacrylate, and 10 parts by weight of glycidyl methacrylate with an emulsifier which is a polymer having a terminal alkyl group, and 80 parts by weight of a bisphenol A type epoxy resin. After stirring and heating to remove water, the mixture was treated with a high-pressure homogenizer to obtain a liquid epoxy resin in which acrylic rubber particles having a diameter of 0.3 μm were primarily dispersed. 30 parts by weight of the acrylic rubber particle-dispersed liquid epoxy resin was mixed with the bisphenol-A phenoxy resin solution (resin weight: 30 parts) having a solid content of 30% by weight.
Then, Novacure 3 as a latent curing agent was added to the mixed solution.
941 HPS (a masterbatch-type curing agent obtained by dispersing a microcapsule-type curing agent having an average particle diameter of 5 μm having a modified imidazole core as a core and covering the surface with polyurethane in a liquid bisphenol F-type epoxy resin, activation temperature At 125 ° C., 40 parts of Asahi Kasei Kogyo Co., Ltd. were added, and a nickel layer having a thickness of 0.2 μm was further provided on the surface of the conductive particles (particles having polystyrene as a core). A gold layer of 0.02 μm was provided to produce conductive particles having an average particle size of 5 μm and a specific gravity of 2.5)
Was dispersed in 5 parts by volume (based on 100 parts by volume of the adhesive composition), applied to a fluororesin film having a thickness of 80 μm using a coating device, and dried at 75 ° C. for 10 minutes with hot air to obtain a thickness of the adhesive layer. Was 25 μm. Then, a film coating solution prepared in the same manner except that the conductive particles were not dispersed in the preparation of the film coating solution was applied to a fluororesin film having a thickness of 80 μm by a coating apparatus, and the coating was performed at 75 ° C. for 10 minutes. After drying, an adhesive film b having a thickness of 25 μm was prepared. (Circuit Connection) Using the above-described circuit connecting member, a chip (10 mm × 10 mm) with a gold bump (area: 80 μm × 80 μm, height: 15 μm) and a Ni / Au plated copper circuit having a line width of 50 μm, a pitch of 100 μm, and a thickness of 18 μm were formed. The connection of the flexible circuit board (FPC) was performed as shown below. Circuit connection member (12 mm x 12
mm) on a Ni / Au plated Cu circuit printed circuit board at 80 ° C. and 10 kgf / cm 2 , the fluororesin film is peeled off, and the chip bumps and the Ni / Au plated Cu circuit FPC are removed. Alignment was performed. Then, heating and pressurization were performed from above the chip under the conditions of 170 ° C., 30 g / bump, and 20 seconds, and the main connection was performed.
The connection resistance after this connection is up to 4 mΩ per bump,
The average is 2 mΩ and the insulation resistance is 10 8 Ω or more. These values are 1000 cycles of thermal shock test at −55 to 125 ° C., PCT test (121 ° C., 2 atm) for 200 hours,
There was no change even after 10 seconds of immersion in the solder bath at 60 ° C., indicating good connection reliability.
【0025】[0025]
【発明の効果】以上のように本発明の回路接続部材及び
回路板によれば、回路接続界面でのストレスを緩和で
き、信頼性試験後においても接続部での接続抵抗の増大
や接着剤の剥離がなく、接続信頼性が大幅に向上する。As described above, according to the circuit connecting member and the circuit board of the present invention, the stress at the circuit connecting interface can be reduced, the connection resistance at the connecting portion can be increased even after the reliability test, and the adhesive can be used. There is no peeling, and connection reliability is greatly improved.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 井坂 和博 茨城県つくば市和台48 日立化成工業株式 会社筑波開発研究所内 (72)発明者 渡辺 治 茨城県つくば市和台48 日立化成工業株式 会社筑波開発研究所内 (72)発明者 小島 和良 茨城県つくば市和台48 日立化成工業株式 会社筑波開発研究所内 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Kazuhiro Isaka 48 Wadai, Tsukuba, Ibaraki Prefecture, Hitachi Chemical Co., Ltd.Tsukuba R & D Co., Ltd. Within the Research Laboratory (72) Inventor Kazuyoshi Kojima 48 Wadai, Tsukuba, Ibaraki Prefecture Within Tsukuba Development Laboratory, Hitachi Chemical Co., Ltd.
Claims (12)
て、加圧方向の電極間を電気的に接続する回路用接続部
材であって、その回路用接続部材が (A)0.02〜1ミクロンの直径を有するゴム粒子が
分散したエポキシ樹脂 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有することを特徴とする回路用接続部
材。1. A circuit connecting member for electrically connecting opposing circuit electrodes by heating and pressurizing the electrodes in a pressurizing direction, wherein the circuit connecting member comprises (A) 0.02 Epoxy resin in which rubber particles having a diameter of 1 micron are dispersed. (B) A circuit connecting member comprising an adhesive composition containing a latent curing agent of an epoxy resin as an essential component.
て、加圧方向の電極間を電気的に接続する回路用接続部
材であって、その回路用接続部材が (C)ゴムエマルジョンとエポキシ樹脂の混合物 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有することを特徴とする回路用接続部
材。2. A circuit connecting member for electrically connecting opposing circuit electrodes by heating and pressurizing the electrodes in a pressing direction, the circuit connecting member comprising (C) a rubber emulsion and an epoxy. Resin mixture (B) A circuit connecting member comprising an adhesive composition containing a latent curing agent of an epoxy resin as an essential component.
直径が、0.02から1ミクロンである請求項2記載の
回路用接続部材。3. The circuit connecting member according to claim 2, wherein the diameter of the rubber particles dispersed in the rubber emulsion is 0.02 to 1 μm.
されている請求項1〜3各項記載の回路用接続部材。4. The circuit connecting member according to claim 1, wherein the adhesive composition contains a phenoxy resin.
000〜60000である請求項4記載の回路用接続部
材。5. A phenoxy resin having a weight average molecular weight of 20.
The circuit connecting member according to claim 4, wherein the number is from 000 to 60000.
ロンの導電粒子が分散されている請求項1〜5各項記載
の回路用接続部材。6. The circuit connecting member according to claim 1, wherein conductive particles having an average particle diameter of 1 to 18 microns are dispersed in the adhesive composition.
00容量部に対して、0.1〜20容量部である請求項
6記載の回路用接続部材。7. The adhesive composition according to claim 1, wherein the content of the conductive particles is
7. The circuit connecting member according to claim 6, wherein the amount is 0.1 to 20 parts by volume with respect to 00 parts by volume.
項記載の回路用接続部材。8. The circuit connecting member according to claim 1, wherein the shape is a film.
する前の面積に対して2.0〜5.0倍である請求項1
〜8各項記載の回路用接続部材。9. The area after connection of the circuit connecting member is 2.0 to 5.0 times the area before connection.
Item 8. The circuit connecting member according to any one of Items 8 to 8.
と、第二の接続端子を有する第二の回路部材とを、第一
の接続端子と第二の接続端子を対向して配置し、前記対
向配置した第一の接続端子と第二の接続端子の間に回路
用接続部材を介在させ、加熱加圧して前記対向配置した
第一の接続端子と第二の接続端子を電気的に接続させた
回路板であって、前記回路用接続部材が、 (A)0.02〜1ミクロンの直径を有するゴム粒子が
分散したエポキシ樹脂 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有する接着剤であることを特徴とする回
路板。10. A first circuit member having a first connection terminal and a second circuit member having a second connection terminal are arranged with the first connection terminal and the second connection terminal facing each other. Then, a circuit connecting member is interposed between the first connection terminal and the second connection terminal arranged opposite to each other, and the first connection terminal and the second connection terminal arranged opposite to each other by heating and pressing are electrically connected. Wherein the circuit connecting member comprises: (A) an epoxy resin in which rubber particles having a diameter of 0.02 to 1 micron are dispersed; (B) an epoxy resin latent curing agent as an essential component. A circuit board, which is an adhesive containing the adhesive composition described above.
と、第二の接続端子を有する第二の回路部材とを、第一
の接続端子と第二の接続端子を対向して配置し、前記対
向配置した第一の接続端子と第二の接続端子の間に回路
用接続部材を介在させ、加熱加圧して前記対向配置した
第一の接続端子と第二の接続端子を電気的に接続させた
回路板であって、前記回路用接続部材が、 (C)ゴムエマルジョンとエポキシ樹脂の混合物 (B)エポキシ樹脂の潜在性硬化剤を必須成分とする接
着剤組成物を含有する接着剤であることを特徴とする回
路板。11. A first circuit member having a first connection terminal and a second circuit member having a second connection terminal are arranged with the first connection terminal and the second connection terminal facing each other. Then, a circuit connecting member is interposed between the first connection terminal and the second connection terminal arranged opposite to each other, and the first connection terminal and the second connection terminal arranged opposite to each other by heating and pressing are electrically connected. Wherein the circuit connecting member comprises: (C) a mixture of a rubber emulsion and an epoxy resin; and (B) an adhesive containing an adhesive composition containing a latent curing agent of an epoxy resin as an essential component. A circuit board characterized by being an agent.
の直径が、0.02から1ミクロンである請求項11記
載の回路板。12. The circuit board according to claim 11, wherein the diameter of the rubber particles dispersed in the rubber emulsion is 0.02 to 1 micron.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20952097A JPH1150032A (en) | 1997-08-04 | 1997-08-04 | Connection member for circuit and circuit board |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20952097A JPH1150032A (en) | 1997-08-04 | 1997-08-04 | Connection member for circuit and circuit board |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007122765A Division JP2007305994A (en) | 2007-05-07 | 2007-05-07 | Circuit connecting member, and circuit board |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH1150032A true JPH1150032A (en) | 1999-02-23 |
Family
ID=16574160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP20952097A Withdrawn JPH1150032A (en) | 1997-08-04 | 1997-08-04 | Connection member for circuit and circuit board |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH1150032A (en) |
Cited By (15)
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JP2001064619A (en) * | 1999-09-01 | 2001-03-13 | Hitachi Chem Co Ltd | Film-like adhesive for connection to circuit |
JP2002097439A (en) * | 2000-09-21 | 2002-04-02 | Hitachi Chem Co Ltd | Adhesive composition, circuit connection material, adhesive composition for circuit connection, connected body, and semiconductor device |
JP2002203871A (en) * | 2000-12-28 | 2002-07-19 | Hitachi Chem Co Ltd | Adhesive composite, method for connecting circuit terminal using the same and structure of connecting circuit terminal |
WO2003099952A1 (en) * | 2002-05-27 | 2003-12-04 | Ajinomoto Co., Inc. | Adhesive film and prepreg |
JP2005194413A (en) * | 2004-01-08 | 2005-07-21 | Hitachi Chem Co Ltd | Adhesive film for circuit connection and circuit connection structure |
JP2006137954A (en) * | 2005-11-16 | 2006-06-01 | Hitachi Chem Co Ltd | Adhesive for circuit connection |
JP2007009022A (en) * | 2005-06-29 | 2007-01-18 | Sekisui Chem Co Ltd | Sheet-like adhesive, method for producing electronic part device and electronic part device |
JP2008084545A (en) * | 2006-09-25 | 2008-04-10 | Sumitomo Electric Ind Ltd | Adhesive for electrode connection |
JP2009124076A (en) * | 2007-11-19 | 2009-06-04 | Asahi Kasei Electronics Co Ltd | Connection structure and manufacturing method of connection structure |
JP2009275102A (en) * | 2008-05-14 | 2009-11-26 | Hitachi Chem Co Ltd | Circuit connecting material |
US7795325B2 (en) | 2002-11-29 | 2010-09-14 | Hitachi Chemical Co., Ltd. | Adhesive composition, adhesive composition for circuit connection, connected body semiconductor device |
KR20130072156A (en) | 2011-12-21 | 2013-07-01 | 히타치가세이가부시끼가이샤 | Circuit connecting material, connection structure and method for producing connection structure |
TWI448532B (en) * | 2001-11-14 | 2014-08-11 | ||
US11384266B2 (en) | 2005-02-17 | 2022-07-12 | 3M Innovative Properties Company | Surfacing and/or joining method |
KR20220162734A (en) | 2020-04-10 | 2022-12-08 | 쇼와덴코머티리얼즈가부시끼가이샤 | Adhesive composition, adhesive film, connection structure and manufacturing method thereof |
-
1997
- 1997-08-04 JP JP20952097A patent/JPH1150032A/en not_active Withdrawn
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2001064619A (en) * | 1999-09-01 | 2001-03-13 | Hitachi Chem Co Ltd | Film-like adhesive for connection to circuit |
JP2002097439A (en) * | 2000-09-21 | 2002-04-02 | Hitachi Chem Co Ltd | Adhesive composition, circuit connection material, adhesive composition for circuit connection, connected body, and semiconductor device |
JP2002203871A (en) * | 2000-12-28 | 2002-07-19 | Hitachi Chem Co Ltd | Adhesive composite, method for connecting circuit terminal using the same and structure of connecting circuit terminal |
TWI448532B (en) * | 2001-11-14 | 2014-08-11 | ||
WO2003099952A1 (en) * | 2002-05-27 | 2003-12-04 | Ajinomoto Co., Inc. | Adhesive film and prepreg |
US7795325B2 (en) | 2002-11-29 | 2010-09-14 | Hitachi Chemical Co., Ltd. | Adhesive composition, adhesive composition for circuit connection, connected body semiconductor device |
JP2005194413A (en) * | 2004-01-08 | 2005-07-21 | Hitachi Chem Co Ltd | Adhesive film for circuit connection and circuit connection structure |
US11384266B2 (en) | 2005-02-17 | 2022-07-12 | 3M Innovative Properties Company | Surfacing and/or joining method |
JP2007009022A (en) * | 2005-06-29 | 2007-01-18 | Sekisui Chem Co Ltd | Sheet-like adhesive, method for producing electronic part device and electronic part device |
JP2006137954A (en) * | 2005-11-16 | 2006-06-01 | Hitachi Chem Co Ltd | Adhesive for circuit connection |
JP4626495B2 (en) * | 2005-11-16 | 2011-02-09 | 日立化成工業株式会社 | Adhesive for circuit connection |
JP2008084545A (en) * | 2006-09-25 | 2008-04-10 | Sumitomo Electric Ind Ltd | Adhesive for electrode connection |
JP2009124076A (en) * | 2007-11-19 | 2009-06-04 | Asahi Kasei Electronics Co Ltd | Connection structure and manufacturing method of connection structure |
JP2009275102A (en) * | 2008-05-14 | 2009-11-26 | Hitachi Chem Co Ltd | Circuit connecting material |
KR20130072156A (en) | 2011-12-21 | 2013-07-01 | 히타치가세이가부시끼가이샤 | Circuit connecting material, connection structure and method for producing connection structure |
KR20220162734A (en) | 2020-04-10 | 2022-12-08 | 쇼와덴코머티리얼즈가부시끼가이샤 | Adhesive composition, adhesive film, connection structure and manufacturing method thereof |
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