JPH11261114A - Light-emitting diode - Google Patents

Light-emitting diode

Info

Publication number
JPH11261114A
JPH11261114A JP10377128A JP37712898A JPH11261114A JP H11261114 A JPH11261114 A JP H11261114A JP 10377128 A JP10377128 A JP 10377128A JP 37712898 A JP37712898 A JP 37712898A JP H11261114 A JPH11261114 A JP H11261114A
Authority
JP
Japan
Prior art keywords
light
emitting element
light emitting
emitting diode
wavelength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10377128A
Other languages
Japanese (ja)
Other versions
JP3366586B2 (en
Inventor
Yoshiaki Tadatsu
芳昭 多田津
Shuji Nakamura
修二 中村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nichia Chemical Industries Ltd
Original Assignee
Nichia Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Nichia Chemical Industries Ltd filed Critical Nichia Chemical Industries Ltd
Priority to JP37712898A priority Critical patent/JP3366586B2/en
Publication of JPH11261114A publication Critical patent/JPH11261114A/en
Application granted granted Critical
Publication of JP3366586B2 publication Critical patent/JP3366586B2/en
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Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/45001Core members of the connector
    • H01L2224/45099Material
    • H01L2224/451Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
    • H01L2224/45138Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
    • H01L2224/45144Gold (Au) as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48257Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a die pad of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/49Structure, shape, material or disposition of the wire connectors after the connecting process of a plurality of wire connectors
    • H01L2224/491Disposition
    • H01L2224/49105Connecting at different heights
    • H01L2224/49107Connecting at different heights on the semiconductor or solid-state body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73251Location after the connecting process on different surfaces
    • H01L2224/73265Layer and wire connectors

Abstract

PROBLEM TO BE SOLVED: To enable an LED to be improved in visibility and in brightness. SOLUTION: A light-emitting diode is equipped with a light-emitting device 11 composed of laminated gallium nitride compound semiconductors of N-type and P-type on a metal, a resin formed like a convex lens in cross section wrapped around the light-emitting device 11, and fluorescent dye 5 or fluorescent pigment contained in this resin and excited by a visible light which is emitted from the light-emitting device 11 to emit a visible light of a wavelength longer than that of excitation light.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は発光素子を樹脂モー
ルドで包囲してなる発光ダイオード(以下LEDとい
う)に係り、特に一種類の発光素子で多種類の発光がで
き、さらに高輝度な波長変換発光ダイオードに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a light emitting diode (hereinafter referred to as "LED") in which a light emitting element is surrounded by a resin mold. It relates to a light emitting diode.

【0002】[0002]

【従来の技術】一般に、LEDは図1に示すような構造
を有している。1は1mm角以下に切断された例えばG
aAlAs、GaP等よりなる発光素子、2はメタルス
テム、3はメタルポスト、4は発光素子を包囲する樹脂
モールドである。発光素子1の裏面電極はメタルステム
2に銀ペースト等で接着され電気的に接続されており、
発光素子1の表面電極は他端子であるメタルポスト3か
ら伸ばされた金線によりその表面でワイヤボンドされ、
さらに発光素子1は透明な樹脂モールド4でモールドさ
れている。
2. Description of the Related Art Generally, an LED has a structure as shown in FIG. 1 is cut into 1 mm square or less, for example, G
A light emitting element made of aAlAs, GaP, or the like, 2 is a metal stem, 3 is a metal post, and 4 is a resin mold surrounding the light emitting element. The back electrode of the light emitting element 1 is electrically connected to the metal stem 2 by bonding with a silver paste or the like.
The surface electrode of the light emitting element 1 is wire-bonded on its surface by a gold wire extended from a metal post 3 as another terminal,
Further, the light emitting element 1 is molded with a transparent resin mold 4.

【0003】通常、樹脂モールド4は、発光素子の発光
を空気中に効率よく放出する目的で、屈折率が高く、か
つ透明度の高い樹脂が選択されるが、他に、その発光素
子の発光色を変換する目的で、あるいは色を補正する目
的で、その樹脂モールド4の中に着色剤として無機顔
料、または有機顔料が混入される場合がある。
Usually, a resin having a high refractive index and a high transparency is selected for the resin mold 4 in order to efficiently emit light emitted from the light emitting element into the air. In some cases, an inorganic pigment or an organic pigment is mixed as a colorant into the resin mold 4 for the purpose of converting the color or correcting the color.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、従来、
樹脂モールドに着色剤を添加して波長を変換するという
技術はほとんど実用化されておらず、着色剤により色補
正する技術がわずかに使われているのみである。なぜな
ら、樹脂モールドに、波長を変換できるほどの非発光物
質である着色剤を添加すると、LEDそのもの自体の輝
度が大きく低下してしまうからである。
However, conventionally,
The technique of adding a colorant to a resin mold to convert the wavelength has hardly been put to practical use, and the technique of correcting the color with a colorant is only slightly used. This is because the addition of a coloring agent, which is a non-light-emitting substance that can convert the wavelength, to the resin mold significantly reduces the brightness of the LED itself.

【0005】ところで、現在、LEDとして実用化され
ているのは、赤外、赤、黄色、緑色発光のLEDであ
り、青色または紫外のLEDは未だ実用化されていな
い。青色、紫外発光の発光素子はII−VI族のZnS
e、IV−IV族のSiC、III−V族のGaN等の
半導体材料を用いて研究が進められ 最近、その中でも
一般式がGaXAl1-XN(但しXは0≦X≦1であ
る。)で表される窒化ガリウム系化合物半導体が、常温
で、比較的優れた発光を示すことが発表され注目されて
いる。また、窒化ガリウム系化合物半導体を用いて、初
めてpn接合を実現したLEDが発表されている(応用
物理、60巻、2号、p163〜p166、199
1)。それによるとpn接合の窒化ガリウム系化合物半
導体を有するLEDの発光波長は、主として430nm
付近にあり、さらに370nm付近の紫外域にも発光ピ
ークを有している。その波長は上記半導体材料の中で最
も短い波長である。しかし、そのLEDは発光波長が示
すように紫色に近い発光色を有しているため視感度が悪
いという欠点がある。
[0005] By the way, currently, LEDs that are put to practical use as LEDs are LEDs that emit infrared, red, yellow, and green light, and LEDs that emit blue or ultraviolet light have not been put to practical use yet. The blue and ultraviolet light-emitting elements are II-VI group ZnS.
e, studies have been made using semiconductor materials such as SiC of the IV-IV group and GaN of the III-V group, and recently, among them, the general formula is Ga X Al 1 -XN (where X is 0 ≦ X ≦ 1). The gallium nitride-based compound semiconductor represented by the formula (1) shows relatively excellent light emission at room temperature and has been attracting attention. Also, an LED that realizes a pn junction for the first time using a gallium nitride-based compound semiconductor has been announced (Applied Physics, Vol. 60, No. 2, p163-p166, 199).
1). According to this, the emission wavelength of an LED having a pn junction gallium nitride-based compound semiconductor is mainly 430 nm.
And also has an emission peak in the ultraviolet region around 370 nm. The wavelength is the shortest wavelength among the semiconductor materials. However, the LED has an emission color close to purple as indicated by the emission wavelength, and thus has a disadvantage that visibility is poor.

【0006】本発明はこのような事情を鑑みなされたも
ので、その目的とするところは、発光素子を有するLE
Dの視感度を良くし、またその輝度を向上させることに
ある。
The present invention has been made in view of such circumstances, and an object thereof is to provide an LE having a light emitting element.
It is to improve the visibility of D and to improve its luminance.

【0007】[0007]

【課題を解決するための手段】本発明の発光ダイオード
は、メタル上に配置されると共に、n型及びp型に積層
されてなる窒化ガリウム系化合物半導体である発光素子
と、この発光素子を包囲する断面が凸レンズ状の樹脂
と、発光素子を包囲する前記凸レンズ状の樹脂中にあっ
て、発光素子からの可視光により励起されて、励起波長
よりも長波長の可視光を出す蛍光染料又は蛍光顔料とを
有する。
According to the present invention, there is provided a light emitting diode which is a gallium nitride-based compound semiconductor which is disposed on a metal and is stacked in n-type and p-type, and surrounds the light-emitting element. The cross section to be formed is in a convex lens-shaped resin and in the convex lens-shaped resin surrounding the light emitting element, and is excited by visible light from the light emitting element, and emits visible light having a longer wavelength than the excitation wavelength. And a pigment.

【0008】本発明の請求項2の発光ダイオードは、4
20〜440nm付近の波長によって励起される蛍光体
染料又は蛍光顔料を使用する。
According to the second aspect of the present invention, there is provided a light emitting diode comprising:
A fluorescent dye or a fluorescent pigment excited by a wavelength around 20 to 440 nm is used.

【0009】本発明の請求項3の発光ダイオードの発光
素子は、メタルに対向する面の反対側に位置する同一面
に一対の電極をワイヤボンディングしている。さらに、
一方の電極は、窒化ガリウム系化合物半導体がエッチン
グされてn型層の表面を露出させた部分に接続されたオ
ーミック電極である。
According to a third aspect of the present invention, in the light emitting device of the light emitting diode, a pair of electrodes are wire-bonded to the same surface opposite to the surface facing the metal. further,
One electrode is an ohmic electrode connected to a portion where the gallium nitride-based compound semiconductor is etched to expose the surface of the n-type layer.

【0010】[0010]

【発明の実施の形態】図2は本発明のLEDの構造を示
す一実施例である。11はサファイア基板の上にGaA
lNがn型およびp型に積層されてなる青色発光素子、
2および3は図1と同じくメタルステム、メタルポス
ト、4は発光素子を包囲する樹脂モールドである。発光
素子11の裏面はサファイアの絶縁基板であり裏面から
電極を取り出せないため、GaAlN層のn電極をメタ
ルステム2と電気的に接続するため、GaAlN層をエ
ッチングしてn型層の表面を露出させてオーミック電極
を付け、金線によって電気的に接続する手法が取られて
いる。また他の電極は図1と同様にメタルポスト3から
伸ばした金線によりp型層の表面でワイヤボンドされて
いる。さらに樹脂モールド4には420〜440nm付
近の波長によって励起されて480nmに発光ピークを
有する波長を発光する蛍光染料5が添加されている。
FIG. 2 is an embodiment showing the structure of an LED according to the present invention. 11 is GaAs on a sapphire substrate
a blue light-emitting element in which 1N is stacked in n-type and p-type,
Reference numerals 2 and 3 denote a metal stem and a metal post as in FIG. 1, and reference numeral 4 denotes a resin mold surrounding the light emitting element. Since the back surface of the light emitting element 11 is a sapphire insulating substrate and electrodes cannot be taken out from the back surface, the GaAlN layer is etched to expose the surface of the n-type layer to electrically connect the n electrode of the GaAlN layer to the metal stem 2. Then, an ohmic electrode is attached, and a method of electrically connecting with a gold wire is adopted. The other electrodes are wire-bonded on the surface of the p-type layer by gold wires extending from the metal posts 3 as in FIG. Further, a fluorescent dye 5 that emits at a wavelength having an emission peak at 480 nm when excited by a wavelength around 420 to 440 nm is added to the resin mold 4.

【0011】[0011]

【発明の効果】本発明の発光ダイオードの蛍光染料又は
蛍光顔料は、発光素子から励起される短波長の光で励起
されて、励起波長よりも長波長光を発光する。逆に長波
長の光によって励起されて短波長の光を発光する蛍光顔
料もあるが、それはエネルギー効率が非常に悪く微弱に
しか発光しない。前記したように窒化ガリウム系化合物
半導体はLEDに使用される半導体材料中で最も短波長
側にその発光ピークを有するものである。そのためそれ
を発光素子の材料として使用した場合、その発光素子を
包囲する樹脂モールドに蛍光染料又は蛍光顔料を添加す
るこにより、最も好適にそれら蛍光物質を励起すること
ができる。したがって、青色LEDの色補正はいうにお
よばず、蛍光染料、蛍光顔料の種類によって数々の波長
の光を変換することができる。さらに、本発明の発光ダ
イオードは、短波長の光を長波長に変えるので、エネル
ギー効率がよく、添加する蛍光染料又は蛍光顔料が微量
で済み、輝度の低下の点からも非常に好都合である。
The fluorescent dye or fluorescent pigment of the light emitting diode of the present invention is excited by short wavelength light excited by the light emitting element, and emits light having a wavelength longer than the excitation wavelength. Conversely, some fluorescent pigments emit short-wavelength light when excited by long-wavelength light, but they have very poor energy efficiency and emit only weakly. As described above, a gallium nitride-based compound semiconductor has an emission peak on the shortest wavelength side among semiconductor materials used for an LED. Therefore, when it is used as a material for a light emitting element, the fluorescent substance can be most preferably excited by adding a fluorescent dye or a fluorescent pigment to a resin mold surrounding the light emitting element. Therefore, light of various wavelengths can be converted depending on the type of fluorescent dye or fluorescent pigment, not to mention color correction of the blue LED. Furthermore, since the light emitting diode of the present invention converts short-wavelength light into long-wavelength light, it has good energy efficiency, requires only a small amount of fluorescent dye or fluorescent pigment to be added, and is extremely advantageous in terms of reduction in luminance.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 従来の一LEDの構造を示す模式断面図。FIG. 1 is a schematic cross-sectional view showing the structure of a conventional LED.

【図2】 本発明のLEDの一実施例の構造を示す模式
断面図。
FIG. 2 is a schematic sectional view showing the structure of an embodiment of the LED of the present invention.

【符号の説明】[Explanation of symbols]

11・・・発光素子 2・・・メタルステム 3・・・メタルポスト 4・・・樹脂モールド 5・・・蛍光染料 11 light emitting element 2 metal stem 3 metal post 4 resin mold 5 fluorescent dye

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 メタル上に配置されると共に、n型及び
p型に積層されてなる窒化ガリウム系化合物半導体であ
る発光素子と、この発光素子を包囲する断面が凸レンズ
状の樹脂と、発光素子を包囲する前記凸レンズ状の樹脂
中にあって、発光素子からの可視光により励起されて、
励起波長よりも長波長の可視光を出す蛍光染料又は蛍光
顔料とを有することを特徴とする発光ダイオード。
1. A light-emitting element which is a gallium nitride-based compound semiconductor which is disposed on a metal and stacked in n-type and p-type, a resin having a convex lens-shaped cross section surrounding the light-emitting element, and a light-emitting element. In the convex lens-shaped resin surrounding, excited by visible light from the light emitting element,
A light emitting diode comprising: a fluorescent dye or a fluorescent pigment that emits visible light having a wavelength longer than the excitation wavelength.
【請求項2】 前記蛍光体染料又は蛍光顔料が420〜
440nm付近の波長によって励起される請求項1記載
の発光ダイオード。
2. The method according to claim 2, wherein the fluorescent dye or the fluorescent pigment is 420 to
The light emitting diode according to claim 1, wherein the light emitting diode is excited by a wavelength around 440 nm.
【請求項3】 前記発光素子は、メタルに対向する面の
反対側に位置する同一面に一対の電極がワイヤボンディ
ングされると共に一方の電極は窒化ガリウム系化合物半
導体がエッチングされてn型層の表面を露出させた部分
に接続されたオーミック電極を有する請求項1記載の発
光ダイオード。
3. The light-emitting element has a pair of electrodes wire-bonded to the same surface located on a side opposite to a surface facing the metal, and one of the electrodes is formed by etching a gallium nitride-based compound semiconductor to form an n-type layer. The light-emitting diode according to claim 1, further comprising an ohmic electrode connected to a portion where the surface is exposed.
JP37712898A 1998-12-28 1998-12-28 Light emitting diode Expired - Lifetime JP3366586B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP37712898A JP3366586B2 (en) 1998-12-28 1998-12-28 Light emitting diode

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US7084435B2 (en) 2001-07-26 2006-08-01 Matsushita Electric Works, Ltd. Light emitting device using LED
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US7320632B2 (en) 2000-06-15 2008-01-22 Lednium Pty Limited Method of producing a lamp
US7352127B2 (en) 2000-06-15 2008-04-01 Lednium Pty Limited LED lamp with light-emitting junction arranged in three-dimensional array
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JP2007274009A (en) * 2000-09-21 2007-10-18 Sharp Corp Semiconductor light emitting device and luminous display device using the same
US7084435B2 (en) 2001-07-26 2006-08-01 Matsushita Electric Works, Ltd. Light emitting device using LED
US7704762B2 (en) 2002-06-14 2010-04-27 Lednium Technology Pty Limited Lamp and method of producing a lamp
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US6853010B2 (en) 2002-09-19 2005-02-08 Cree, Inc. Phosphor-coated light emitting diodes including tapered sidewalls, and fabrication methods therefor
US9608166B2 (en) 2003-08-14 2017-03-28 Cree, Inc. Localized annealing of metal-silicon carbide ohmic contacts and devices so formed
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US7183587B2 (en) 2003-09-09 2007-02-27 Cree, Inc. Solid metal block mounting substrates for semiconductor light emitting devices
USRE45796E1 (en) 2004-12-23 2015-11-10 Cree, Inc. Light emitting diode arrays for direct backlighting of liquid crystal displays
US7518160B2 (en) 2005-10-31 2009-04-14 Kyocera Corporation Wavelength converter, lighting system, and lighting system assembly
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