JPH11198238A - End-processed continuous member made of thermoplastic resin reinforced with continuous fiber, and net obtained therefrom - Google Patents

End-processed continuous member made of thermoplastic resin reinforced with continuous fiber, and net obtained therefrom

Info

Publication number
JPH11198238A
JPH11198238A JP10004953A JP495398A JPH11198238A JP H11198238 A JPH11198238 A JP H11198238A JP 10004953 A JP10004953 A JP 10004953A JP 495398 A JP495398 A JP 495398A JP H11198238 A JPH11198238 A JP H11198238A
Authority
JP
Japan
Prior art keywords
thermoplastic resin
fiber
continuous fiber
resin
net
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10004953A
Other languages
Japanese (ja)
Inventor
Minoru Toyama
稔 登山
Koichi Saito
晃一 斉藤
Takashi Niifuku
隆志 新福
Masanori Ishikawa
真範 石川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JNC Corp
Original Assignee
Chisso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chisso Corp filed Critical Chisso Corp
Priority to JP10004953A priority Critical patent/JPH11198238A/en
Publication of JPH11198238A publication Critical patent/JPH11198238A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide end-processed continuous members and a net obtained therefrom, capable of not only providing excellent tensile characteristics and size stability and eliminating the looseness, etc., of the net under a high load or due to temperature change, but also shortening a working period because in-place workability, etc., are also excellent. SOLUTION: This end-processed continuous member is a covered continuous member formed of a fiber-containing resin in which continuous reinforcing fibers are impregnated with a thermoplastic resin, and which is covered with a thermoplastic resin layer, and a holding part is provided which is formed by folding each of both ends of the covered continuous member back in a ring shape. Further, a net is formed by combining two or more of the end-processed continuous members in the form of a lattice and thermally welding them at their intersecting points. Alternatively, the end-processed continuous members are used as longitudinal materials 4, while the covered continuous members or their fragments are used as lateral materials 5, and faces positioned in the direction of each thickness of both the longitudinal materials 4 and the lateral materials 5 are brought into contact with one another to be arranged in the form of a lattice, whereby there contacting faces may also be thermally welded. Furthermore, in this net, at least two end-processed continuous members may be optionally combined so as to intersect with one another, and at least one point of intersection may be thermally welded together.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、連続繊維強化熱可
塑性樹脂製末端加工長尺体及びそれより得られるネット
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an end-processed elongated body made of a continuous fiber reinforced thermoplastic resin and a net obtained therefrom.

【0002】[0002]

【従来技術】携帯電話の普及に伴い、金属フェンスによ
る電波障害が懸念されており、樹脂製のネットが注目を
浴びるようになってきた。延伸PETを使用したネットや
ガラス長繊維マット強化樹脂製柵(特開昭61−128
599号公報)が発明されているが、前者は、真夏等高
温下でのネットの緩みが問題となっており、後者は、ネ
ットの緩み等はないものの使用強度に劣るという欠点を
有している。また、後者の場合、強度を向上させるため
にネット単糸の本数を増やしたり、該単糸中のガラスコ
ンテントを高くしたりする方法があるが、ネット単糸の
本数を増やすと得られネットが高価なものとなってしま
ったり、ガラスコンテントの高い単糸は極めて製造し難
いのが現状であった。
2. Description of the Related Art With the spread of portable telephones, there is a concern that radio interference caused by metal fences has occurred, and resin nets have been receiving attention. Fences made of net or glass long fiber mat reinforced resin using stretched PET (JP-A-61-128)
No. 599) has been invented, but the former has a problem that the net is loose under a high temperature such as midsummer, and the latter has a drawback that the net is not loose but the use strength is inferior. I have. In the case of the latter, there is a method of increasing the number of single yarns of the net in order to improve the strength, or increasing the glass content in the single yarn. At present, single yarns that are expensive or have high glass content are extremely difficult to manufacture.

【0003】また、ガラス連続繊維強化ネットが、特開
平7-173824号公報に開示されているが、これは、ガラス
連続繊維強化シートに複数の穴をあけて得たものであっ
て、製造し難い上、フェンス用のネットとして対応して
いないため、支柱や枠への取り付けができないものであ
った。特願平09-157615にも提案済みであるが、フェン
ス用のネットとして用いられる場合、支柱や枠への取付
けに問題があり、施工に時間がかかる等の問題点が有っ
た。
Further, a glass continuous fiber reinforced net is disclosed in Japanese Patent Application Laid-Open No. 7-173824, which is obtained by perforating a glass continuous fiber reinforced sheet with a plurality of holes, and which is manufactured by the method. It was difficult and it was not compatible with fence nets, so it could not be mounted on pillars or frames. Although it has been proposed in Japanese Patent Application No. 09-157615, there was a problem in that when used as a net for fences, there was a problem in attaching to a support or a frame, and it took a long time for construction.

【0004】[0004]

【発明が解決しようとする課題】引張り特性および寸法
安定性に優れ、高荷重下や温度変化によるネットのゆる
み等が解消されるだけでなく、現場施工性等にも優れて
いるため工期の短縮が可能な連続繊維強化熱可塑性樹脂
製末端加工長尺体及びそれを用いた連続繊維強化熱可塑
性樹脂製ネットを提供することにある。
The present invention is excellent in tensile properties and dimensional stability, not only eliminates loosening of the net due to high load or temperature change, but also has excellent on-site workability and the like, and shortens the construction period. It is an object of the present invention to provide a continuous fiber reinforced thermoplastic resin end-processed elongated body capable of performing the above and a continuous fiber reinforced thermoplastic resin net using the same.

【0005】[0005]

【課題を解決するための手段】本発明者等は、上記目的
を達成すべく鋭意検討した結果、連続繊維強化熱可塑性
樹脂製長尺体の両末端が輪状に折り返されたものをフェ
ンス部材として用いることにより目的を達成することを
見いだし、本発明に達した。即ち、本発明は以下の構成
からなる。 (1)連続した補強用繊維に熱可塑性樹脂を含浸してな
る繊維含有樹脂に熱可塑性樹脂層を被覆してなる被覆長
尺体であって、該被覆長尺体の両端を輪状に折り返され
てなる保持部を設けたことを特徴とする連続繊維強化熱
可塑性樹脂製末端加工長尺体。 (2)前記連続繊維強化熱可塑性樹脂製末端加工長尺体
が2体以上格子状に組み合わせられ且つ交点が熱溶着さ
れてなることを特徴とする連続繊維強化熱可塑性樹脂製
ネット。 (3)前記連続繊維強化熱可塑性樹脂製末端加工長尺体
を縦材とし前記被覆長尺体またはその断片を横材として
該縦材と横材の各々の厚さ方向の面同志を接触させて格
子状に配置し該接触面を熱溶着してなることを特徴とす
る連続繊維強化熱可塑性樹脂製ネット。 (4)前記連続繊維強化熱可塑性樹脂製末端加工長尺体
が交互に2体以上交差するように組み合わせられ且つ1
以上の交点が熱溶着されてなることを特徴とする連続繊
維強化熱可塑性樹脂製ネット。
Means for Solving the Problems The present inventors have conducted intensive studies to achieve the above object, and as a result, a continuous fiber reinforced thermoplastic resin long body whose both ends are looped back is used as a fence member. It has been found that the object can be achieved by using the same, and the present invention has been achieved. That is, the present invention has the following configurations. (1) A coated long body obtained by coating a thermoplastic resin layer on a fiber-containing resin obtained by impregnating a continuous reinforcing fiber with a thermoplastic resin, wherein both ends of the coated long body are folded in a ring shape. An end-processed elongated body made of a continuous fiber-reinforced thermoplastic resin, comprising a holding portion comprising: (2) A continuous fiber reinforced thermoplastic resin net characterized in that two or more continuous fiber reinforced thermoplastic resin end-processed elongated bodies are combined in a lattice and the intersections are heat-welded. (3) The continuous fiber-reinforced thermoplastic resin end-processed elongated body is used as a vertical member, and the coated long member or a fragment thereof is used as a horizontal member, and the vertical member and the horizontal member are brought into contact with each other in the thickness direction. A continuous fiber reinforced thermoplastic resin net, wherein the contact surfaces are heat-welded. (4) Two or more of the continuous fiber-reinforced thermoplastic resin end-processed elongated bodies are combined so as to intersect alternately, and 1
A continuous fiber reinforced thermoplastic resin net characterized in that the above intersections are heat welded.

【0006】以下、上記(1)の発明を本発明(1)、
上記(2)の発明を本発明(2)、上記(3)の発明を
本発明(3)、上記(4)の発明を本発明(4)とい
う。本発明(1)の特徴は、連続した補強用繊維に熱可
塑性樹脂を含浸してなる繊維含有樹脂に熱可塑性樹脂層
を被覆してなる被覆長尺体の両端を輪状に折り返されて
なる保持部を設けたことを特徴とするものであり、本発
明(3)〜(4)は、本発明(1)をネットの構成部材
として用いるものである。
Hereinafter, the invention of the above (1) will be referred to as the present invention (1),
The invention of the above (2) is called the present invention (2), the invention of the above (3) is called the present invention (3), and the invention of the above (4) is called the present invention (4). A feature of the present invention (1) is that a coated long body obtained by coating a thermoplastic resin layer on a fiber-containing resin obtained by impregnating a continuous reinforcing fiber with a thermoplastic resin has both ends folded in a ring shape. The present inventions (3) and (4) use the present invention (1) as a component of a net.

【0007】[0007]

【発明実施の形態】本発明(1)の構成について以下に
詳述する。本発明(1)の連続繊維強化熱可塑性樹脂製
末端加工長尺体は、被覆長尺体の両端に保持部を設けた
ものである。該被覆長尺体は、繊維含有樹脂に熱可塑性
樹脂層を被覆してなるものである。該繊維含有樹脂は、
連続した補強用繊維に熱可塑性樹脂を含浸してなるもの
である。該保持部は、該被覆長尺体の両端を輪状に折り
返されてなるものである。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The structure of the present invention (1) will be described in detail below. The continuous fiber-reinforced thermoplastic resin end-molded long body of the present invention (1) is provided with holding portions at both ends of the coated long body. The coated long body is obtained by coating a fiber-containing resin with a thermoplastic resin layer. The fiber-containing resin,
A continuous reinforcing fiber is impregnated with a thermoplastic resin. The holding portion is formed by folding both ends of the coated elongated body into a ring shape.

【0008】本発明(1)の形状は、長尺体である。こ
こで、長尺体とは長手方向の長さが幅方向の長さに対し
て極めて長いものの総称の意味であり、例えば、幅方向
の断面が矩形、円、楕円形、三角形等の任意の形状を包
含する。例えば、幅方向の断面が矩形の例を図6に示
す。被覆長尺体13は、補強用繊維9及び熱可塑性樹脂
10からなる繊維含有樹脂11に熱可塑性樹脂層12を
被覆してなる。
The shape of the present invention (1) is a long body. Here, the elongate body is a generic term meaning that the length in the longitudinal direction is extremely long with respect to the length in the width direction. For example, the cross section in the width direction is an arbitrary shape such as a rectangle, a circle, an ellipse, and a triangle. Shape. For example, FIG. 6 shows an example in which the cross section in the width direction is rectangular. The coated long body 13 is obtained by coating a fiber-containing resin 11 composed of a reinforcing fiber 9 and a thermoplastic resin 10 with a thermoplastic resin layer 12.

【0009】本発明(1)の両端に設けられる保持部の
形状は、輪状に折り返されてなるものである。この「輪
状に折り返されてなるもの」とは、閉環構造のものでも
開環構造のものでもよく、少なくとも支柱や枠材に通さ
れて長尺体全体を保持可能な形状であればどのような構
造でもよい。また、開環構造の場合、保持部に適当な弾
性を持たせて本発明(1)の着脱を容易にするようにす
ることもできる。また、閉環構造の場合、折り返し部分
を溶着して強固な輪構造とすることもできる。例えば、
保持部の構造としては、図1に示すような構造が挙げら
れる。図1は長尺体を線状に記載し、その片末端のみを
示した。保持部1が開環構造であるものとしては、図1
の(a)や(b)が、閉環構造であるものとしては、図
1(c)が例示できる。図(b)において、保持部の開
口部2は、使用時に広げて支柱等に装着するようにでき
る。図(c)は、溶着部3を設けた例である。この溶着
部は、長尺体を機械的に折り返した後に溶着されるが、
その溶着される折り返し接触部分が少なくとも15mm
であることが好ましい。該接触部分が10mmより短い
場合、溶着部の強度が不足し破損する場合がある。
The shape of the holding portions provided at both ends of the present invention (1) is formed by folding back in a ring shape. The term “circularly folded” may be a closed-ring structure or an open-ring structure, and any shape may be used so long as it can be passed through at least a support or a frame material and can hold the entire elongated body. The structure may be used. In the case of a ring-opened structure, the holding portion may have appropriate elasticity so that the present invention (1) can be easily attached and detached. In the case of a ring-closed structure, the folded portion can be welded to form a strong ring structure. For example,
As a structure of the holding portion, a structure as shown in FIG. 1 is exemplified. FIG. 1 shows the elongated body in a linear shape, and shows only one end thereof. FIG. 1 shows that the holding portion 1 has a ring-opened structure.
FIG. 1 (c) can be illustrated as an example in which (a) and (b) have a closed ring structure. In FIG. 2 (b), the opening 2 of the holding portion can be widened at the time of use and mounted on a column or the like. FIG. 3C shows an example in which a welding portion 3 is provided. This welded part is welded after mechanically turning the long body,
The folded contact portion to be welded is at least 15 mm
It is preferred that If the contact portion is shorter than 10 mm, the strength of the welded portion may be insufficient and the weld may be damaged.

【0010】本発明(1)の長尺体は、それ自体で保持
部を支柱や枠材に通することにより、フェンス乃至柵と
しての機能を発揮させることもできるが、後述するよう
に、これを構成部材とすることにより、より一層の機能
を発揮させることができる。次に本発明(2)について
説明する。本発明(2)は、上記本発明(1)の連続繊
維強化熱可塑性樹脂製末端加工長尺体が2体以上格子状
に組み合わせられ且つ交点が熱溶着されてなることを特
徴とする連続繊維強化熱可塑性樹脂製ネットである。こ
こで、「2体以上格子状に」とは、格子を形成する部材
を縦材と横材とすれば、該縦材と横材の各々を本発明
(1)で構成すると共に、かつ格子の交点が少なくとも
該縦材1体と横材1体から構成されることを意味する。
従って、本発明(2)の交点は、縦材1体と横材1体か
ら構成されてもよいし、縦材2体以上と横材2体以上か
ら構成されていてもよい。本発明(2)において該交点
は熱溶着されるが、ネットとして機能すれば必ずしも全
部の交点が熱溶着されなければならないことを意味しな
い。
The elongated body of the present invention (1) can also function as a fence or a fence by passing the holding portion through a support or a frame material by itself. By using as a constituent member, further functions can be exhibited. Next, the present invention (2) will be described. The present invention (2) is characterized in that two or more continuous fiber-reinforced thermoplastic resin-terminated elongated bodies of the above-mentioned present invention (1) are combined in a lattice pattern and the intersections are heat-welded. It is a reinforced thermoplastic resin net. Here, "two or more lattices" means that if the members forming the lattice are a vertical member and a horizontal member, each of the vertical member and the horizontal member is constituted by the present invention (1), and Means that at least one cross member is composed of one vertical member and one horizontal member.
Therefore, the intersection of the present invention (2) may be composed of one vertical member and one horizontal member, or may be composed of two or more vertical members and two or more horizontal members. In the present invention (2), the intersections are heat-welded, but if they function as a net, it does not necessarily mean that all the intersections must be heat-welded.

【0011】本発明(2)の具体的構造例を図2及び図
3に示した。図2は、本発明(1)として帯状長尺体を
用いて平面に格子状に重ね本発明(2)のネットを構成
し、その端部を除いた格子部を平面に対し垂直方向から
見た図である。図3は、図2のA−Aに沿った線で切断
した断面を示す図である。図3の(a)及び(b)は、
縦材4と横材5とが各々1体で交点6を接触、形成して
いるが、同図3の(c)では、1体の縦材4と2体の横
材5とで交点6を形成している。同様に図3の(d)で
は2体の縦材4と2体の横材5とで交点6を形成し、図
3の(e)では2体の縦材4と3体の横材5とで交点6
を形成している。上記(a)〜(e)の交点構造は、同
一の格子部に組み合わせて使用することができる。
FIGS. 2 and 3 show specific structural examples of the present invention (2). FIG. 2 shows a net according to the present invention (2), which is formed by using a strip-shaped long body in a grid pattern as the present invention (1), and the grid portion excluding its ends is viewed from a direction perpendicular to the plane. FIG. FIG. 3 is a diagram illustrating a cross section cut along a line AA in FIG. 2. (A) and (b) of FIG.
The vertical member 4 and the horizontal member 5 each contact and form the intersection 6 with one body, but in FIG. 3C, one vertical member 4 and two horizontal members 5 form the intersection 6. Is formed. Similarly, in FIG. 3D, an intersection 6 is formed by two vertical members 4 and two horizontal members 5, and in FIG. 3E, two vertical members 4 and three horizontal members 5 are formed. Intersection 6 with
Is formed. The intersection structures (a) to (e) can be used in combination with the same lattice part.

【0012】次に本発明(3)について説明する。本発
明(3)は、本発明(1)を縦材とし前記被覆長尺体ま
たはその断片を横材として該縦材と横材の各々の厚さ方
向の面同志を接触させて格子状に配置し該接触面を熱溶
着してなることを特徴とする連続繊維強化熱可塑性樹脂
製ネットである。
Next, the present invention (3) will be described. In the present invention (3), the present invention (1) is used as a vertical member, and the coated long body or a fragment thereof is used as a horizontal member, and the vertical member and the horizontal member are brought into contact with each other in the thickness direction to form a lattice. A continuous fiber reinforced thermoplastic resin net, which is arranged and heat-welded to the contact surface.

【0013】本発明(3)は、上記本発明(2)と類似
するが、本発明(2)において横材として本発明(1)
自体を用いるのではなく、その被覆長尺体またはその断
片を横材として用い、かつ該縦材と横材の各々の厚さ方
向の面同志を接触させて格子状に配置し該接触面を熱溶
着してなるネットである。従って、横材の本発明(1)
として帯状長尺体を用いて平面に格子状に本発明(3)
のネットを構成し、その端部を除いた格子部を平面に対
し垂直方向から見た図は図2と同様である。本発明
(3)の具体例を図3に準じた断面で示すと図4の様に
示すことができる。
The present invention (3) is similar to the above-mentioned present invention (2). However, in the present invention (2), the present invention (1) is used as a cross member.
Rather than using itself, the coated elongate body or a fragment thereof is used as a horizontal member, and the vertical member and the horizontal member are arranged in a grid by contacting the surfaces in the thickness direction of each member, and the contact surface is formed. It is a net formed by heat welding. Therefore, the present invention of the cross member (1)
The present invention (3)
FIG. 2 is the same as FIG. 2 when the lattice portion excluding the ends is viewed from the direction perpendicular to the plane. FIG. 4 shows a specific example of the present invention (3) in a cross section according to FIG.

【0014】図4において、縦材4と横材5は接触面7
で熱溶着される。また、縦材の両最側部4Eに本発明
(1)の保持部を各々少なくとも1以上、熱溶着等で設
けてもよい。接触面7は、両者矩形面で完全一致し、断
面を垂直方向から見た図が図4のように略線状となって
いるが、接触面の形状はこれに限定されるものでなく、
また、両者の形状及び接触面は必ずしも完全一致してい
なくともよい。
In FIG. 4, the vertical member 4 and the horizontal member 5 are in contact with the contact surface 7.
And heat welded. Further, at least one or more holding portions of the present invention (1) may be provided on both outermost portions 4E of the vertical member by heat welding or the like. The contact surface 7 is completely coincident with both rectangular surfaces, and the cross-section viewed from the vertical direction is substantially linear as shown in FIG. 4, but the shape of the contact surface is not limited to this.
Further, the shape and the contact surface of both do not necessarily have to completely match.

【0015】尚、本発明(3)において、縦材及び横材
は便宜的に用いた用語であり、縦材を横材、横材を縦材
に読み替えても本発明(3)の思想は同じである。次に
本発明(4)について説明する。本発明(4)は、本発
明(1)の連続繊維強化熱可塑性樹脂製末端加工長尺体
が交互に2体以上交差するように組み合わせられ且つ1
以上の交点が熱溶着されてなることを特徴とする連続繊
維強化熱可塑性樹脂製ネットである。ここで、「交互に
2体以上交差するように」とは、少なくとも2体の本発
明(1)の長尺体が少なくとも1点で接触・交差するよ
うに配置されることを言う。このような接触・交差の態
様を有する本発明(4)を具体的に示すと図5の例を挙
げることができる。尚、長尺体としては、簡単のため線
で表した。
In the present invention (3), the vertical members and the horizontal members are terms used for convenience, and even if the vertical members are replaced by the horizontal members and the horizontal members are replaced by the vertical members, the concept of the present invention (3) is not changed. Is the same. Next, the present invention (4) will be described. The present invention (4) is a combination of two or more continuous fiber-reinforced thermoplastic resin-terminated elongated bodies of the present invention (1), which alternately intersect with each other.
A continuous fiber reinforced thermoplastic resin net characterized in that the above intersections are heat-welded. Here, "alternately intersect two or more bodies" means that at least two long bodies of the present invention (1) are arranged so as to contact and intersect at at least one point. FIG. 5 shows an example of the present invention (4) having such a mode of contact and intersection. In addition, the elongate body was represented by a line for simplicity.

【0016】図5は、複数の本発明(1)の長尺体を平
面に配置し、それを垂直方向から見た図である。図
(a)は、2体の本発明(1)の長尺体8a及び8bを
この順に重ね交点6を形成し、この交点を熱溶着したも
のである。図(b)は、3体の本発明(1)の長尺体8
a、8b及び8cをこの順に重ね交点6を形成し、この
交点を熱溶着したものである。図(c)は、3体の本発
明(1)の長尺体8a、8b及び8cをこの順に重ね交
点6a、6b及び6cを形成し、これらの交点を熱溶着
したものである。図(d)は、図(c)に示したネット
に更に本発明(1)の長尺体8d、8e及び8fをこの
順に重ね、上記交点6a、6b及び6cでこれら長尺体
を熱溶着したものであり、他の交点は、熱溶着せずにそ
のままの状態としたものである。
FIG. 5 is a view in which a plurality of long bodies of the present invention (1) are arranged on a plane and viewed from a vertical direction. FIG. 2A shows an example in which two long bodies 8a and 8b of the present invention (1) are overlapped in this order to form an intersection 6, and this intersection is heat-welded. FIG. 4B shows three long bodies 8 of the present invention (1).
a, 8b and 8c are overlapped in this order to form an intersection 6 and this intersection is heat-welded. FIG. 3 (c) shows three elongated bodies 8a, 8b and 8c of the present invention (1) stacked in this order to form intersections 6a, 6b and 6c, and these intersections are heat-welded. FIG. 5D shows that the long bodies 8d, 8e and 8f of the present invention (1) are further superimposed on the net shown in FIG. 5C in this order, and these long bodies are heat-welded at the intersections 6a, 6b and 6c. The other intersections were left as they were without heat welding.

【0017】本発明(2)〜(4)の長尺体同志の配置
あるいは組み合わせの関係は、人手や既製の織機や編機
を用いることにより得ることができ、それら長尺体同志
の熱溶着の方法あるいは保持部の熱溶着の方法は、任意
の周知の方法が適用され、例えば、熱プレスや熱板溶着
機、超音波溶着機に供されることに行うことができる。
In the present invention (2) to (4), the relationship of the arrangement or combination of the long bodies can be obtained by hand or using a ready-made loom or knitting machine. Any well-known method is applied to the method of (1) or the method of heat-welding the holding portion. For example, the method can be applied to a hot press, a hot plate welding machine, or an ultrasonic welding machine.

【0018】本発明(1)の構成素材等について説明す
る。 [熱可塑性樹脂]本発明(1)の繊維含有樹脂及び熱可
塑性樹脂層に用いられる熱可塑性樹脂としては、下記の
ものあるいはその改質樹脂を例示できる。 ・ポリオレフィン樹脂:ポリエチレン樹脂、ポリプロピ
レン樹脂、ポリ−1−ブテン樹脂、ポリ−4−メチル−
1−ペンテン樹脂、プロピレン−エチレン共重合体樹脂
及びプロピレン−1−ブテン共重合体樹脂の1種以上; ・ポリエステル樹脂:ポリエチレンテレフタレート、ポ
リブチレンテレフタレート及びポリエチレンテレフタレ
ートイソフタレートの1種以上; ・ポリアミド樹脂(ナイロン):ポリアミド−6、ポリ
アミド−7、ポリアミド−66、ポリアミド−610、
ポリアミド−11及びポリアミド−12; ・ポリアセタール; ・ポリウレタン; ・上記の2種以上からなる組成物及び2種以上からなる
ポリマーアロイ。
The constituent materials of the present invention (1) will be described. [Thermoplastic resin] Examples of the thermoplastic resin used for the fiber-containing resin and the thermoplastic resin layer of the present invention (1) include the following or modified resins thereof.・ Polyolefin resin: polyethylene resin, polypropylene resin, poly-1-butene resin, poly-4-methyl-
At least one of 1-pentene resin, propylene-ethylene copolymer resin and propylene-1-butene copolymer resin; polyester resin: at least one of polyethylene terephthalate, polybutylene terephthalate and polyethylene terephthalate isophthalate; polyamide resin (Nylon): polyamide-6, polyamide-7, polyamide-66, polyamide-610,
Polyamide-11; Polyamide-12; Polyacetal; Polyurethane; A composition comprising two or more of the above and a polymer alloy comprising two or more of the above.

【0019】これらの中では、汎用性及び機械的強度等
の観点から、結晶性ポリオレフィン、特に結晶性ポリプ
ロピレンが好ましく用いられる。熱可塑性樹脂が、ポリ
オレフィン(ポリ−α−オレフィン)の様に分子末端基
に補強用繊維、特にガラス繊維に対する界面接着性を付
与するための反応性官能基又は極性官能基を有しない場
合には、該樹脂を不飽和酸又はその酸無水物等の誘導体
で改質する方策及び/又は不飽和酸で改質された重合体
を非改質樹脂に必要量配合する方策等を施すことが有用
である。
Of these, crystalline polyolefins, particularly crystalline polypropylene, are preferably used from the viewpoints of versatility and mechanical strength. In the case where the thermoplastic resin does not have a reactive functional group or a polar functional group for imparting interfacial adhesion to reinforcing fibers, particularly glass fibers, to the molecular terminal groups, like polyolefin (poly-α-olefin). It is useful to take measures such as modifying the resin with a derivative such as an unsaturated acid or an acid anhydride thereof and / or blending a required amount of the polymer modified with the unsaturated acid into the unmodified resin. It is.

【0020】上記の改質剤として用い得る不飽和酸は通
常は脂肪族不飽和酸であって例えばアクリル酸、メタク
リル酸、マレイン酸、シトラコン酸及びメサコン酸から
選ばれる1種以上であって、好ましくはマレイン酸であ
る。また、改質剤として用い得る不飽和酸無水物等の誘
導体は通常は脂肪族不飽和酸無水物であって例えば無水
マレイン酸及び無水イタコン酸から選ばれる1種以上で
あって、好ましくは無水マレイン酸(マレイン酸無水
物)である。
The unsaturated acid which can be used as the above modifier is generally an aliphatic unsaturated acid, for example, one or more selected from acrylic acid, methacrylic acid, maleic acid, citraconic acid and mesaconic acid, Preferably it is maleic acid. Derivatives such as unsaturated acid anhydrides that can be used as a modifier are usually aliphatic unsaturated acid anhydrides, for example, one or more selected from maleic anhydride and itaconic anhydride, and are preferably anhydrides. Maleic acid (maleic anhydride).

【0021】本発明においては、このような改質剤を用
いる際に、必要に応じて有機過酸化物を組み合わせて用
いてもよい。有機過酸化物の例としては、例えば、2,5-
ジメチル(t-ブチルパーオキシ)ヘキサン、1,3-ビス(t-
ブチル-オキシイソプロピル)ベンゼン、ジクミルパーオ
キサイド及びベンゾイルパーオキサイド等を挙げること
ができる。
In the present invention, when such a modifier is used, an organic peroxide may be used in combination, if necessary. Examples of organic peroxides include, for example, 2,5-
Dimethyl (t-butylperoxy) hexane, 1,3-bis (t-
(Butyl-oxyisopropyl) benzene, dicumyl peroxide and benzoyl peroxide.

【0022】熱可塑性樹脂としては、上記のような非改
質樹脂及び改質樹脂を単独で用いてもよいし、組み合わ
せて樹脂組成物として用いてもよい。補強用繊維との強
固な結合を有した繊維含有樹脂を実現するためには、改
質樹脂を少なくとも用いることが好ましい。このような
改質樹脂または改質樹脂組成物は例えば、基材となる非
改質樹脂と、改質剤と、有機過酸化物とを、ヘンシェル
ミキサー(商品名)等の混合手段で混合した後、押出機に
供給して溶融混練し、次にこの溶融混練物を押し出し成
形することにより製造することができる。
As the thermoplastic resin, the above-mentioned non-modified resin and modified resin may be used alone or in combination as a resin composition. In order to realize a fiber-containing resin having a strong bond with a reinforcing fiber, it is preferable to use at least a modified resin. Such a modified resin or modified resin composition is, for example, a non-modified resin serving as a base material, a modifier, and an organic peroxide were mixed by a mixing means such as a Henschel mixer (trade name). Thereafter, it is supplied to an extruder to be melt-kneaded, and then the melt-kneaded product is extruded to be manufactured.

【0023】また、熱可塑性樹脂は、必要に応じて各種
の下記添加剤を1種以上配合することができる: ・酸化防止剤、耐熱安定剤、紫外線吸収剤、樹脂状破壊
防止剤、帯電防止剤、潤滑剤、可塑剤、離型剤、難燃剤
(耐炎剤)、難燃助剤及び結晶化促進剤(造核剤;結晶
化剤)並びに染料及び顔料等。
The thermoplastic resin may contain one or more of the following various additives as required: an antioxidant, a heat stabilizer, an ultraviolet absorber, a resinous destruction inhibitor, an antistatic agent. Agents, lubricants, plasticizers, mold release agents, flame retardants (flame retardants), flame retardant aids and crystallization promoters (nucleating agents; crystallization agents), dyes and pigments.

【0024】これらの添加剤はマトリックスとなる上記
の熱可塑性樹脂に予め配合された形で用いてもよく、マ
スターバッチの形で用いてもよい。また、繊維含有樹脂
の熱可塑性樹脂と熱可塑性樹脂層の熱可塑性樹脂とは互
いに同じ樹脂か相溶性のある樹脂であると、その界面間
の結合性を強固にできるために好ましい。 [補強用繊維]本発明において繊維含有樹脂を形成する
連続した補強用繊維は、単繊維の集束体、通常はロービ
ング状のものから開繊されて得ることができる。ロービ
ング以外にもガラスヤーンやトウなどを利用することが
できる。
These additives may be used in a form previously blended with the above-mentioned thermoplastic resin serving as a matrix, or may be used in the form of a master batch. Further, it is preferable that the thermoplastic resin of the fiber-containing resin and the thermoplastic resin of the thermoplastic resin layer be the same resin or a compatible resin, since the bonding property between the interfaces can be strengthened. [Reinforcing Fiber] The continuous reinforcing fiber forming the fiber-containing resin in the present invention can be obtained by opening a bundle of single fibers, usually a roving-like fiber. In addition to roving, glass yarn or tow can be used.

【0025】その材質からみれば、この補強用繊維は無
機繊維および有機繊維に大別される。無機繊維として
は、例えば、ガラス繊維、岩綿(ロックウール)、石
綿、石英繊維、金属繊維、ウィスカー(ホイスカー)及
び炭素繊維等が挙げられる。それらの中で、その性状及
び入手容易性等の点で通常的にはガラス繊維が好ましく
用いられる。ガラス繊維としては、硬質ガラスが好まし
く、特に、無アルカリガラスであるEガラスが好ましく
用いられる。このガラス繊維は樹脂強化用として通常的
に製造されて市販されているガラスロービングであっ
て、通常的にはその平均繊維径4〜30μm、フィラメント
集束本数400〜10000本及びTex番手300〜
20000のものであるが、好ましくは平均繊維径9〜2
3μmのものである。必要に応じて、これらのガラスロー
ビングを合糸して用いることもできる。
According to the material, the reinforcing fibers are roughly classified into inorganic fibers and organic fibers. Examples of the inorganic fiber include glass fiber, rock wool (rock wool), asbestos, quartz fiber, metal fiber, whisker (whisker), and carbon fiber. Among them, glass fibers are usually preferably used in view of their properties and availability. As the glass fiber, hard glass is preferable, and in particular, E glass which is non-alkali glass is preferably used. This glass fiber is a commercially available glass roving that is usually manufactured for resin reinforcement, and usually has an average fiber diameter of 4 to 30 μm, a number of filament bundles of 400 to 10,000, and a Tex count of 300 to
20,000, preferably an average fiber diameter of 9 to 2
It is 3 μm. If necessary, these glass rovings can be combined and used.

【0026】また、この無機補強用繊維は、例えば、シ
ラン系カップリング剤、チタネート系カップリング剤、
ボロン系カップリング剤、アルミネート系カップリング
剤の少なくとも何れかのような表面処理剤で表面処理し
て用いてもよい。この無機補強用繊維に表面処理が施さ
れると、ポリプロピレン等の疎水性樹脂に対する親和性
が高められ、その開繊物の間にポリプロピレン等の樹脂
が含浸されやすくなる。
The inorganic reinforcing fibers include, for example, silane coupling agents, titanate coupling agents,
A surface treatment with a surface treatment agent such as at least one of a boron-based coupling agent and an aluminate-based coupling agent may be used. When the surface treatment is applied to the inorganic reinforcing fibers, the affinity for a hydrophobic resin such as polypropylene is increased, and the resin such as polypropylene is easily impregnated between the spread fibers.

【0027】上記の無機補強用繊維は、単独で用いても
よく、また2種以上を組み合わせて用いてもよい。他
方、有機補強用繊維としては通常、ポリエステル繊維、
ポリアミド繊維(ナイロン)、アラミド繊維等が例示で
き、ポリエステル繊維としてはPET(ポリエチレンテ
レフタレート)繊維及びPBT(ポリ−1,4−ブチレ
ンテレフタレート)等が常用され、他方、ポリアミド繊
維としては6−ポリアミド繊維、7−ポリアミド繊維、
11−ポリアミド繊維、12−ポリアミド繊維および
6,12−ポリアミド繊維、6,6−ポリアミド繊維、
6,7−ポリアミド繊維、6,10−ポリアミド繊維及
び6,12−ポリアミド繊維から選ばれる1種以上並び
に6−/6,6−共縮合ポリアミド繊維等を挙げること
ができる。 [繊維含有樹脂]繊維含有樹脂を作製する方法として
は、長尺体の長さ方向(樹脂の流れ方向)に略平行に配
列された連続した補強用繊維の内部に上記の溶融状態の
熱可塑性樹脂を含浸させる手順を挙げることができる。
補強用繊維に樹脂を含浸させる際には、補強用繊維を平
面上に可能な限り均一に開繊し、その開繊物に樹脂を均
一に含浸させると、得られる長尺体の機械的強度を向上
させることができる点で好ましい。
The above inorganic reinforcing fibers may be used alone or in combination of two or more. On the other hand, as the organic reinforcing fiber, usually, polyester fiber,
Polyamide fiber (nylon), aramid fiber and the like can be exemplified. As polyester fiber, PET (polyethylene terephthalate) fiber and PBT (poly-1,4-butylene terephthalate) are commonly used, while 6-polyamide fiber is used as polyamide fiber. , 7-polyamide fiber,
11-polyamide fiber, 12-polyamide fiber and 6,12-polyamide fiber, 6,6-polyamide fiber,
One or more kinds selected from 6,7-polyamide fibers, 6,10-polyamide fibers and 6,12-polyamide fibers, and 6- / 6,6-co-condensed polyamide fibers can be mentioned. [Fiber-containing resin] As a method for producing the fiber-containing resin, the above-mentioned molten thermoplastic resin is embedded inside continuous reinforcing fibers arranged substantially parallel to the length direction of the long body (flow direction of the resin). A procedure for impregnating the resin may be mentioned.
When impregnating the reinforcing fiber with the resin, the reinforcing fiber is spread as evenly as possible on a flat surface, and the resin is uniformly impregnated into the spread fiber, and the mechanical strength of the obtained long body is obtained. This is preferable in that it can improve

【0028】補強用繊維に樹脂を含浸させる方法は、補
強用繊維に樹脂を含浸させ得る方法であれば如何なる方
法であってもよい。例えば、この含浸方法として特公昭
63−37694号公報、特公平4−41886号公報
及び特開昭61−229534号公報等に開示されてい
る方法を挙げることができる。この種の繊維含有樹脂
は、例えば、ロービング等の補強用繊維を平面上に均一
に開繊した後に、押出機内で溶融混練されている樹脂を
この補強用繊維に均一に含浸させて形成させることがで
きる。
The method of impregnating the reinforcing fibers with the resin may be any method that can impregnate the resin into the reinforcing fibers. For example, examples of the impregnation method include the methods disclosed in JP-B-63-37694, JP-B-4-41886, and JP-A-61-229534. This type of fiber-containing resin is formed, for example, by uniformly opening a reinforcing fiber such as a roving on a plane, and then uniformly impregnating the reinforcing fiber with a resin melt-kneaded in an extruder. Can be.

【0029】繊維含有樹脂の肉厚は、特に制限されるべ
きものではないが、1.5mm以下が好ましい。2.0mmより厚
い場合は、剛性が高すぎ取り扱いに支障を来すだけでな
く、長尺体の端部に形成される保持部が破損する場合が
ある。補強用繊維は繊維含有樹脂中に好ましくは10〜
80重量%、更に好ましくは30〜70重量%の量で含
まれる。この量で補強用繊維を使用することによって補
強用繊維に熱可塑性樹脂が充分に含浸される寄与で、補
強用繊維が熱可塑性樹脂によって相互に一体的に結合さ
れる。そして、補強用繊維の含有量が5重量%以下であ
ると、引張強度等の補強効果が充分には発現しない場合
がある。他方、補強用繊維の含有量が90重量%以上に
達すると、却って充分な補強効果が発現されない場合が
ある。その原因は、熱可塑性樹脂が補強用繊維に充分に
含浸しないことにあると解される。 [熱可塑性樹脂層]熱可塑性樹脂層とは、上記の繊維含
有樹脂の全面に上記特定性状の熱可塑性樹脂で形成され
た層である。熱可塑性樹脂層の厚みは、特に制限される
べきものではないが、0.1mm以上が好ましく、0.
1〜1.0mmの範囲が好ましい。熱可塑性樹脂層の厚
さが0.05mmより薄い場合は、保持部の溶着強度が
得られず、他方、1.2mmより厚い場合には、剛性が
高すぎ取り扱いに支障を来す場合がある。
The thickness of the fiber-containing resin is not particularly limited, but is preferably 1.5 mm or less. When the thickness is more than 2.0 mm, the rigidity is too high, which may hinder handling, and may damage the holding portion formed at the end of the elongated body. The reinforcing fiber is preferably 10 to 10 in the fiber-containing resin.
80% by weight, more preferably 30-70% by weight. By using the reinforcing fibers in this amount, the reinforcing fibers are sufficiently integrally impregnated with the thermoplastic resin, and the reinforcing fibers are integrally bonded to each other by the thermoplastic resin. When the content of the reinforcing fiber is 5% by weight or less, a reinforcing effect such as tensile strength may not be sufficiently exhibited. On the other hand, if the content of the reinforcing fibers reaches 90% by weight or more, a sufficient reinforcing effect may not be exhibited. It is understood that the cause is that the reinforcing fibers are not sufficiently impregnated with the thermoplastic resin. [Thermoplastic resin layer] The thermoplastic resin layer is a layer formed of a thermoplastic resin having the above specific properties on the entire surface of the fiber-containing resin. The thickness of the thermoplastic resin layer is not particularly limited, but is preferably 0.1 mm or more.
A range of 1 to 1.0 mm is preferred. When the thickness of the thermoplastic resin layer is less than 0.05 mm, the welding strength of the holding portion cannot be obtained. On the other hand, when the thickness is more than 1.2 mm, the rigidity is too high, which may hinder handling. .

【0030】熱可塑性樹脂層を作製するには、例えば樹
脂を予めフィルム状に成形した後にこのフィルムを繊維
含有樹脂の表面にラミネートする方法、溶融状態の熱可
塑性樹脂を繊維含有樹脂の表面にコーティングする方法
等によって作製することができる。熱可塑性樹脂層をラ
ミネートして形成する場合には、例えば、まず熱可塑性
樹脂及び必要に応じて改質剤等とを混合して押出機に供
給して溶融混練し、これを成膜してフィルムを形成す
る。これとは別に、例えば、補強用繊維中に、溶融した
熱可塑性樹脂を含浸させて繊維含有樹脂を形成する。そ
して、この繊維含有樹脂を半溶融状態にしたままで、予
め巻き取っていたフィルムと貼り合わせてラミネートす
る。なお、繊維含有樹脂とフィルムを貼り合わす際に繊
維含有樹脂は必ずしも半溶融状態である必要はなく、繊
維含有樹脂を冷却固化させた後に接着剤を用いてフィル
ムと貼り合わせてもよい。
To form the thermoplastic resin layer, for example, a method in which the resin is formed into a film in advance and then the film is laminated on the surface of the fiber-containing resin, or the thermoplastic resin in a molten state is coated on the surface of the fiber-containing resin It can be produced by a method or the like. When the thermoplastic resin layer is formed by laminating, for example, first, a thermoplastic resin and, if necessary, a modifier and the like are mixed, supplied to an extruder, melt-kneaded, and formed into a film. Form a film. Separately, for example, a fiber-containing resin is formed by impregnating a reinforcing thermoplastic fiber with a molten thermoplastic resin. Then, while keeping the fiber-containing resin in a semi-molten state, the fiber-containing resin is laminated with a film that has been wound in advance. When the fiber-containing resin and the film are bonded together, the fiber-containing resin does not necessarily need to be in a semi-molten state, and may be bonded to the film using an adhesive after the fiber-containing resin is cooled and solidified.

【0031】また、熱可塑性樹脂層をコーティングして
形成する場合には、上記繊維含有樹脂を半溶融状態にし
たままで、この繊維含有樹脂の表面に熱可塑性樹脂を押
し出してコーティングしてもよいし、繊維含有樹脂を冷
却固化させた後に、この繊維含有樹脂表面をコーティン
グしてもよい。熱可塑性樹脂層により被覆された被覆長
尺体の厚みは、特に制限されるべきものではないが、2
mm以下が好ましい。2mmより厚い場合は、ネットと
しての剛性が高くなりすぎ、取り扱いに支障をきたす場
合があるだけでなく、長尺体の端部に形成される保持部
の作製に支障をきたす場合がある。
When the thermoplastic resin layer is formed by coating, the fiber-containing resin may be extruded and coated on the surface of the fiber-containing resin while the resin is kept in a semi-molten state. After cooling and solidifying the fiber-containing resin, the surface of the fiber-containing resin may be coated. The thickness of the coated long body covered with the thermoplastic resin layer is not particularly limited,
mm or less is preferable. If the thickness is more than 2 mm, the rigidity of the net becomes too high, which may hinder handling, as well as hinder the production of the holding portion formed at the end of the elongated body.

【0032】本発明(1)の連続繊維強化熱可塑性樹脂
製末端加工長尺体及びそれを用いたネットは、施工性、
引張り特性および寸法安定性に優れ、金属又は樹脂製の
支柱や枠に長尺体の端部に形成される輪状の保持部を差
し込むことにより、フェンスや柵等の部材として好適に
用いられる。
The continuous fiber-reinforced thermoplastic resin end-finished elongated body of the present invention (1) and the net using the same have excellent workability,
It is excellent in tensile properties and dimensional stability, and is suitably used as a member such as a fence or fence by inserting a ring-shaped holding portion formed at an end of a long body into a metal or resin support or frame.

【0033】[0033]

【実施例】次に、本発明を実施例により説明するが、本
発明はこれら実施例に限定されるものではない。また、
実施例、および比較例において用いられている用語の定
義および測定方法は以下の通りである。 ガラス繊維含有量:JIS K7052に準じ測定した。
EXAMPLES Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples. Also,
The definitions of the terms used in the examples and comparative examples and the measuring method are as follows. Glass fiber content: Measured according to JIS K7052.

【0034】MFR(メルトフローレート):JIS
K7210(荷重21.18N、加熱温度230℃)に
準じ測定した。 引張り強さ:サンプル両端部の保持部(折り返し接触部
分の溶着長さ(溶着部の長さ):40mm)に30mmφの
金属製の棒を挿入し、引張り速度 5mm/minの条件下で引
張り荷重を掛けたとき、サンプルが破断した時の荷重を
引張り強さとした。 実施例1、比較例1 改質ポリプロピレン(PP){結晶融点(Tm:示差走
査熱量測定(DSC)160℃:MFR130g/10min:無水
マレイン酸改質物}を溶融した270℃の温度の浴中に
4000本の個々のフィラメントを集束したガラスロ−ビン
グ1本を通し、浴槽の出口に設けた5mm×0.6mmのダイス
から溶融樹脂が含浸した繊維含有樹脂として引き出しニ
ップロ−ルを通して冷却固化させ線状物aを得た。線状
物aのガラス含有量は60wt%であった。更に、線状物a
を被覆用ダイスに導きPP(MFR2.0g/10分、DS
C融点160℃のPP)で線状物aの全面にほぼ均一と
なるように熱可塑性樹脂層を被覆し、冷却固化して幅7m
m,厚さ1.0mmの全面PPで被覆された線状物Aを得た。
線状物a及線状物Aの各々から上記サンプルを作成し
た。線状物aからのものを比較例1、線状物Aからのも
のを実施例1のサンプルとした。 実施例2 浴槽に導かれるガラス繊維ロービングのフィラメント本
数が2000本であること以外は実施例1と同様にして繊維
含有樹脂を形成し、次いでこれをPPにて被覆した線状
物Bを得た。得られた線状物Bのガラス繊維含有量は30
wt%、その形状は幅7mm、厚み1.0mmであった。これを上
記と同様にサンプル(実施例2)とし試験に供した。
MFR (Melt Flow Rate): JIS
It measured according to K7210 (load 21.18N, heating temperature 230 degreeC). Tensile strength: Insert a 30mmφ metal rod into the holding part at both ends of the sample (welding length of the folded contact part (welding length): 40mm), and apply a tensile load at a tensile speed of 5mm / min. , The load when the sample was broken was defined as the tensile strength. Example 1, Comparative Example 1 Modified polypropylene (PP) {crystal melting point (Tm: differential scanning calorimetry (DSC) 160 ° C: MFR 130 g / 10min: maleic anhydride modified product)} was melted in a bath at a temperature of 270 ° C.
Through a glass roving in which 4,000 individual filaments are bundled, drawn out from a 5 mm x 0.6 mm die provided at the outlet of the bathtub as a fiber-containing resin impregnated with molten resin, cooled and solidified through a nipple to obtain a linear material. a was obtained. The glass content of the linear material a was 60% by weight. Further, a linear object a
Into a die for coating, PP (MFR2.0g / 10min, DS
The entire surface of the linear object a is coated with a thermoplastic resin layer at a C melting point of 160 ° C. so as to be substantially uniform, and then cooled and solidified to a width of 7 m.
m, a linear material A having a thickness of 1.0 mm and covered with the entire surface PP was obtained.
The sample was prepared from each of the linear objects a and A. The sample from the linear object a was designated as Comparative Example 1, and the sample from the linear object A was designated as the sample of Example 1. Example 2 A fiber-containing resin was formed in the same manner as in Example 1 except that the number of filaments of the glass fiber roving led to the bath was 2000, and then a linear material B coated with PP was obtained. . The glass fiber content of the obtained linear object B is 30.
wt%, its shape was 7 mm wide and 1.0 mm thick. This was made into a sample (Example 2) in the same manner as described above, and subjected to a test.

【0035】得られた各サンプルの試験の結果を表1に
示す。
Table 1 shows the results of the tests on the obtained samples.

【0036】[0036]

【表1】 [Table 1]

【0037】表1から、熱可塑性樹脂層を有しない比較
例は、実施例に比べ引張強さが極めて劣ることが分か
る。なお、本発明は、上記の実施例に限定されるもので
なく、上記の説明から当業者が容易に類推しうる全ての
変更実施例を包含するものである。
From Table 1, it can be seen that the comparative example having no thermoplastic resin layer had extremely poor tensile strength as compared with the examples. It should be noted that the present invention is not limited to the above embodiments, but encompasses all modified embodiments that can be easily inferred by those skilled in the art from the above description.

【0038】[0038]

【発明の効果】上記の構成よりなる本発明の連続繊維強
化熱可塑性樹脂製末端加工長尺体及びそれを用いたネッ
トは、引張り特性および寸法安定性に優れ、高荷重下や
温度変化によるネットのゆるみ等が解消されるだけでな
く、現場施工性等にも優れているため工期の短縮が期待
できる。
EFFECTS OF THE INVENTION The continuous fiber-reinforced thermoplastic resin end-molded elongated body of the present invention and the net using the same, which have the above-described structure, are excellent in tensile properties and dimensional stability, and can be used under high load or temperature change. In addition to eliminating loosening, etc., it is also excellent in on-site workability, etc., so that shortening of the construction period can be expected.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の連続繊維強化熱可塑性樹脂製末端加工
長尺体の保持部の構造例を示す図である。
FIG. 1 is a view showing an example of a structure of a holding portion of a continuous fiber-reinforced thermoplastic resin end-molded long body of the present invention.

【図2】構成部材として本発明(1)の帯状長尺体を用
いて平面に格子状に重ね本発明(2)のネットを構成
し、その端部を除いた格子部を平面に対し垂直方向から
見た図である。
FIG. 2 shows a net of the present invention (2) superposed in a grid pattern on a plane using the strip-shaped elongated body of the present invention (1) as a constituent member, and a grid portion excluding its end is perpendicular to the plane. It is the figure seen from the direction.

【図3】図3は、図2のA−Aに沿った線で切断した断
面を示す図であり、(a)〜(e)の各態様を示した。
る。
FIG. 3 is a view showing a cross section cut along a line AA in FIG. 2, and shows each of the modes (a) to (e).
You.

【図4】本発明(3)の具体例を図3に準じた断面で示
した図である。
FIG. 4 is a diagram showing a specific example of the present invention (3) in a cross section according to FIG.

【図5】本発明(4)の具体的態様を(a)〜(d)に
示したもので、複数の本発明(1)の長尺体を平面に配
置し、交点を熱溶着したものを垂直方向から見た図であ
る。
5 shows specific embodiments of the present invention (4) in (a) to (d), in which a plurality of long bodies of the present invention (1) are arranged on a plane, and intersections are heat-welded. FIG. 4 is a view as viewed from a vertical direction.

【図6】本発明(1)の長尺体の幅方向の断面が矩形の
例を示したものである。
FIG. 6 shows an example in which the cross section in the width direction of the elongated body of the present invention (1) is rectangular.

【図7】引張り強さを測定する引張り試験方法を説明す
るための図である。
FIG. 7 is a diagram for explaining a tensile test method for measuring tensile strength.

【符号の説明】[Explanation of symbols]

1 保持部 2 開口部 3 溶着部 4 縦材 5 横材 6 交点 7 接触面 8a、8b、8c、8d、8e、8f 本発明(1)の
長尺体 9 補強用繊維 10 熱可塑性樹脂 11 繊維含有樹脂 12 熱可塑性樹脂層 13 被覆長尺体
DESCRIPTION OF SYMBOLS 1 Holding part 2 Opening part 3 Welding part 4 Vertical member 5 Horizontal member 6 Intersection 7 Contact surface 8a, 8b, 8c, 8d, 8e, 8f The long body of this invention (1) 9 Reinforcing fiber 10 Thermoplastic resin 11 Fiber Containing resin 12 Thermoplastic resin layer 13 Coated long body

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI B29L 28:00 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI B29L 28:00

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 連続した補強用繊維に熱可塑性樹脂を含
浸してなる繊維含有樹脂に熱可塑性樹脂層を被覆してな
る被覆長尺体であって、該被覆長尺体の両端を輪状に折
り返されてなる保持部を設けたことを特徴とする連続繊
維強化熱可塑性樹脂製末端加工長尺体。
1. A coated long body obtained by coating a thermoplastic resin layer on a fiber-containing resin obtained by impregnating a continuous reinforcing fiber with a thermoplastic resin, wherein both ends of the coated long body are formed in a ring shape. An end-processed elongated body made of a continuous fiber-reinforced thermoplastic resin, comprising a folded holding portion.
【請求項2】 前記熱可塑性樹脂層の厚みが0.1mm以上
であることを特徴とする請求項1に記載の連続繊維強化
熱可塑性樹脂製末端加工長尺体。
2. The continuous fiber-reinforced thermoplastic resin-terminated elongated body according to claim 1, wherein the thickness of the thermoplastic resin layer is 0.1 mm or more.
【請求項3】 前記被覆長尺体の厚みが2mm以下である
ことを特徴とする請求項1または2項記載の連続繊維強
化熱可塑性樹脂製末端加工長尺体。
3. A continuous fiber-reinforced thermoplastic resin-made elongated body according to claim 1, wherein the thickness of the coated elongated body is 2 mm or less.
【請求項4】 前記繊維含有樹脂中の補強用繊維含有量
が10〜80重量%であることを特徴とする請求項1〜
3の何れか1項に記載の連続繊維強化熱可塑性樹脂製末
端加工長尺体。
4. The reinforcing fiber content in the fiber-containing resin is 10 to 80% by weight.
3. The continuous fiber-reinforced thermoplastic resin-terminated elongated body according to any one of the above items 3.
【請求項5】 前記補強用繊維はガラス繊維からなるこ
とを特徴とする請求項1〜4の何れか1項に記載の連続
繊維強化熱可塑性樹脂製末端加工長尺体。
5. The continuous fiber-reinforced thermoplastic resin-terminated elongated body according to claim 1, wherein the reinforcing fiber is made of glass fiber.
【請求項6】 前記保持部の折り返し接触部分が、15mm
以上の長さで溶着されてなることを特徴とする請求項1
〜5の何れか1項に記載の連続繊維強化熱可塑性樹脂製
末端加工長尺体。
6. The folded contact portion of the holding portion has a length of 15 mm.
2. A welding method according to claim 1, wherein said welding is performed with the above length.
6. The continuous fiber-reinforced thermoplastic resin-terminated elongated body according to any one of items 1 to 5.
【請求項7】 前記繊維含有樹脂及び熱可塑性樹脂層に
用いられる樹脂がポリオレフィン樹脂またはその改質樹
脂であることを特徴とする請求項1〜6の何れか1項に
記載の連続繊維強化熱可塑性樹脂製末端加工長尺体。
7. The continuous fiber reinforced heat according to claim 1, wherein the resin used for the fiber-containing resin and the thermoplastic resin layer is a polyolefin resin or a modified resin thereof. Elongated body made of plastic resin.
【請求項8】 請求項1〜7の何れか1項に記載の連続
繊維強化熱可塑性樹脂製末端加工長尺体が2体以上格子
状に組み合わせられ且つ交点が熱溶着されてなることを
特徴とする連続繊維強化熱可塑性樹脂製ネット。
8. A continuous fiber-reinforced thermoplastic resin end-finished elongated body according to any one of claims 1 to 7, wherein two or more elongated bodies are combined in a grid and the intersections are heat-welded. A continuous fiber reinforced thermoplastic resin net.
【請求項9】 請求項1〜7の何れか1項に記載の連続
繊維強化熱可塑性樹脂製末端加工長尺体を縦材とし請求
項1〜7の何れか1項に記載の被覆長尺体またはその断
片を横材として該縦材と横材の各々の厚さ方向の面同志
を接触させて格子状に配置し該接触面を熱溶着してなる
ことを特徴とする連続繊維強化熱可塑性樹脂製ネット。
9. The coated long material according to any one of claims 1 to 7, wherein the continuous fiber-reinforced thermoplastic resin end-finished long material according to any one of claims 1 to 7 is a longitudinal member. A continuous fiber reinforced heat, wherein a body or a fragment thereof is used as a horizontal member, and the vertical members and the horizontal members are arranged in a grid by contacting surfaces in the thickness direction of the respective horizontal members, and the contact surfaces are heat-welded. Net made of plastic resin.
【請求項10】 前記縦材の両最側部に請求項1〜7の
何れか1項に記載の保持部を各々少なくとも1以上設け
たことを特徴とする請求項9記載の連続繊維強化熱可塑
性樹脂製ネット。
10. The continuous fiber reinforced heat according to claim 9, wherein at least one or more of the holding portions according to any one of claims 1 to 7 are provided on both side portions of the longitudinal member. Net made of plastic resin.
【請求項11】 請求項1〜7の何れか1項に記載の連
続繊維強化熱可塑性樹脂製末端加工長尺体が交互に2体
以上交差するように組み合わせられ且つ1以上の交点が
熱溶着されてなることを特徴とする連続繊維強化熱可塑
性樹脂製ネット。
11. A continuous fiber-reinforced thermoplastic resin end-processed elongated body according to any one of claims 1 to 7, which is combined so that two or more bodies are alternately crossed, and one or more intersections are thermally welded. A continuous fiber reinforced thermoplastic resin net characterized by being made.
【請求項12】 請求項1〜7の何れか1項に記載の保
持部は支柱や枠材に通され、フェンス乃至柵としての機
能を発揮することを特徴とする請求項8〜11の何れか
1項に記載の連続繊維強化熱可塑性樹脂製ネット。
12. The holding portion according to claim 1, wherein the holding portion is passed through a support or a frame material, and functions as a fence or a fence. The continuous fiber reinforced thermoplastic resin net according to claim 1.
JP10004953A 1998-01-13 1998-01-13 End-processed continuous member made of thermoplastic resin reinforced with continuous fiber, and net obtained therefrom Pending JPH11198238A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10004953A JPH11198238A (en) 1998-01-13 1998-01-13 End-processed continuous member made of thermoplastic resin reinforced with continuous fiber, and net obtained therefrom

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10004953A JPH11198238A (en) 1998-01-13 1998-01-13 End-processed continuous member made of thermoplastic resin reinforced with continuous fiber, and net obtained therefrom

Publications (1)

Publication Number Publication Date
JPH11198238A true JPH11198238A (en) 1999-07-27

Family

ID=11597953

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10004953A Pending JPH11198238A (en) 1998-01-13 1998-01-13 End-processed continuous member made of thermoplastic resin reinforced with continuous fiber, and net obtained therefrom

Country Status (1)

Country Link
JP (1) JPH11198238A (en)

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