JPH11193020A - Paper container that can be retort pasteurized - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a paper container which can be used in a microwave oven and can be retort pasteurized. SOLUTION: A paper container is comprised of a container body 10 composed of an opening 11 comprising a laminated sheet mainly formed from paper layers, a body part 12, and a bottom part 13, and a tape-shaped laminated film 20 to cover the opposite inner and outer edges of a body 12 of the container body 10, both the edges being bonded together. An opening periphery member 31 located on the outer periphery of the opening of the body 10 so as to be thermally bonded to the outer periphery and a bottom annular member 34 located along the bottom incurled inner wall of the body 10 so as to be thermally bonded to the bottom inner wall are provided by an insert injection molding to inject molten polypropylene into a die, into which the container body 10 is inserted beforehand.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a paper container capable of retort sterilization, and more particularly to a cup-shaped paper container capable of being reheated by a microwave oven.

[0002]

2. Description of the Related Art Paper containers which can be subjected to a retort sterilization treatment are disclosed, for example, in JP-A-57-46734 and JP-A-5-46734.
Many inventions and ideas have been disclosed, including the inventions disclosed in JP-A-8-52033 and JP-A-58-20638.

[0003] The invention disclosed in Japanese Patent Application Laid-Open No. 57-46734 discloses a synthetic resin or paper mainly composed of a thermoplastic resin excluding a high-density polyethylene resin and having a melting point of 115 ° C or higher as both outer layers. The both ends of the laminated sheet made of aluminum foil are rolled and subjected to waterproofing and welded to form a cylindrical body, and the upper and lower openings of the obtained cylindrical body are formed with the synthetic resin in the laminated sheet. A container closed with a lid made of aluminum foil whose inner surface is coated with the same kind of synthetic resin, wherein the laminated sheet is a packaging container having a laminated structure in which aluminum foil is disposed on both sides of paper. Things.

Further, the invention disclosed in Japanese Patent Application Laid-Open No. 58-52033 discloses a method in which both ends corresponding to a body seal portion of a fan-shaped or rectangular blank sheet made of a paper material subjected to a water-resistant treatment on both sides are opposite to each other over a certain width. The upper and lower parts of the body cylinder formed by folding both sides of the blank sheet so as to form a cylinder and bonding both ends at the surface having the pair of folded pieces obtained above, This is a completely water-resistant paper container sealed with a lid and a bottom plate so that the paper end surface is not exposed.

Further, in the invention disclosed in Japanese Patent Application Laid-Open No. 58-20638, the resin layer forming the inner layer and the intermediate layer made of paperboard and the like are integrally bonded, and the resin layer forming the outer layer and the intermediate layer are integrally bonded. Alternatively, the resin is bonded to each other at the upper edge of the container, the layers are degassed, and a multilayer container is formed in which an intermediate layer is sandwiched between resin layers on both sides.

[0006] However, these inventions have a problem that they are not suitable for microwave ovens because they use a lot of aluminum foil, and there remains a problem in the disposal property because they use a lot of synthetic resins.

[0007]

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems relating to a paper container capable of performing a retort sterilization treatment, and provides a paper container capable of performing a retort sterilization treatment suitable for a microwave oven. The purpose is to do.

[0008]

Means for Solving the Problems A first invention of the present invention is:
A cup-shaped container body provided with an opening made of a laminated sheet mainly composed of a paper layer, a body portion, and a bottom portion, and both inner and outer edges formed at a bonded portion of the body portion of the container body for covering the edges. A tape-shaped laminated film, and a paper container composed of: an opening peripheral member which is positioned so as to cover the outer peripheral edge of the opening of the container main body at the end face and is heat-sealed; and And a bottom incurred annular member to be heat-sealed, and a retort sterilizable paper characterized by being provided by an insert injection molding method of injecting a hot-melted polypropylene resin into a mold in which the container body is previously inserted and arranged. Container.

In a second aspect based on the first aspect, the laminated sheet comprises a CPP film,
It is a retort sterilizable paper container which is a laminated sheet having at least a four-layer configuration in which a cup base paper, a barrier layer, and a CPP film are laminated in this order.

In a third aspect of the present invention, in the first and second aspects, the CPP film located outside the container of the CPP film constituting the laminated sheet is a block type or random type CPP film, The CPP film located on the side that comes into contact with the contents is a block-type CPP film that is a paper container that can be subjected to retort sterilization.

Further, a fourth invention is the film according to the first, second and third inventions, wherein the barrier layer constituting the laminated sheet is a film in which an inorganic compound vapor-deposited thin film is formed.
This is a retort sterilizable paper container that is either a film on which a metal compound deposited thin film is formed or a barrier plastic film.

Further, a fifth invention is directed to the first, second, and third aspects.
In the third and fourth inventions, there is provided a paper container which can be subjected to a retort sterilization process, wherein the cup base paper constituting the laminated sheet is a cup base paper in which a coating layer made of diatomaceous earth is applied to the base paper surface at a rate of 12 to 18 g / m ^2. is there.

Still further, a sixth invention is directed to the first, second, and third aspects.
In the third, fourth and fifth inventions, the retort sterilizable paper container wherein the tape-shaped laminated film is a laminated film having at least three layers laminated in the order of a CPP film, a barrier layer, and a CPP film. . It is.

[0014] Furthermore, a seventh invention is directed to the first, second, and third aspects.
In the third, fourth, fifth and sixth inventions, the barrier layer constituting the tape-shaped laminated film is a film formed with an inorganic compound vapor-deposited thin film, a film formed with a metal compound vapor-deposited thin film, or a barrier plastic film. A paper container that can be subjected to a retort sterilization treatment.

Further, the eighth invention is characterized in that the first, second,
In the third, fourth, fifth, sixth and seventh inventions, the polypropylene resin used for the insert injection molding method, wherein the polypropylene resin used for the opening peripheral member and the bottom annular member has an MFR of 8 to 30. This is a paper container that can be subjected to a retort sterilization process, which is a block type polypropylene resin.

[0016]

As described above, according to the present invention, the end surface of the laminated sheet exposed to the outside after the paper container is formed is covered with a tape-shaped laminated film, and the outer periphery of the opening and the wall surface of the bottom incurred portion are made of synthetic resin such as polypropylene resin. Because it is covered, retort sterilization treatment is possible.

The laminated sheet may be a CPP film, a cup base paper, a film formed with an inorganic compound vapor-deposited thin film, a film formed with a metal compound vapor-deposited thin film, or a barrier plastic film, or a CPP film. A barrier layer composed of any one of a polypropylene film, a film formed with an inorganic compound vapor-deposited thin film, a film formed with a metal compound vapor-deposited thin film, or a barrier plastic film, and a polypropylene film Are suitable for a microwave oven.

[0018]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below with reference to examples, but the present invention is not limited to the following examples unless it exceeds the gist. As shown in FIGS. 1 and 3, a paper container capable of performing the retort sterilization process of the present invention is a cup-shaped container body (10) having an opening (11), a body (12), and a bottom (13). And the bonding part of the body of the container body (14)
From the tape-like laminated film (20) for covering both the inner and outer edges (15, 16) generated in the container, the opening peripheral member (31) covering the main part of the container body, and the bottom incurred annular member (34). And a covering member (30).

As shown in FIG. 2, the laminated sheet constituting the body and bottom of the container body is composed of a CPP film (2), a cup base paper (3), a barrier layer (4), and a CP from the outside of the container.
A laminated sheet (1) having at least a four-layer structure in which a P film (5) is laminated in this order.

The cup base paper (3) is a substrate of the laminated sheet, the basis weight 280g / m ² ~320g / m ² about what can be preferably used. In addition, use a cup base paper coated with a diatomaceous earth coat layer (3a) on the surface, because it has excellent pattern reproducibility when printing on paper and is a measure to prevent the appearance of yellowing due to the heat of the paper. Is preferred. The coating amount of the coat layer is preferably from 12 to 18 g / m ² .

The barrier layer (4) provided inside the cup base paper is made of a plastic film such as a polyethylene terephthalate (PET) film, a biaxially stretched nylon (ONy) film, a biaxially stretched polypropylene (OPP) film, or the like. 400 thin films of aluminum etc.
A vapor deposition film deposited by a method such as a vacuum deposition method can be preferably used, but an ethylene vinyl alcohol copolymer resin (EVOH) film may be used.

The CPP film (2) used on the outside of the cup base paper has heat resistance of 120 ° C. or more, and
A block-type or random-type CPP film that does not require a significant change in molding conditions in a conventional cup molding machine when molding a cup can be preferably used, and a film having a thickness of 30 to 70 μm can be suitably used.

The innermost layer of the laminated sheet (1), the CPP film (5) provided on the side in contact with the contents, has a low extraction amount of low molecular weight substances. Therefore, the contents are retort sterilized or hot-filled. However, it is necessary to use a block-type CPP film because it has a very small effect on taste and has excellent impact resistance during distribution.

In order to further reduce the occurrence of pinholes during cup molding, a layer of a PET film (not shown) may be provided between the CPP film (2) and the cup base paper (3). The thickness of the PET film is preferably about 9 to 16 μm.

When a printed portion is provided on the laminated sheet (1), it is generally provided on the coat layer (3a) of the cup base paper (3). It may be provided on either of the front and back surfaces of the PET film, or may be provided on the coat layer.

The lamination of the cup base paper (3) and each of the above layers is as follows.
The laminated sheet (1) can be prepared by laminating in an appropriate order by a commonly used known laminating method, for example, a dry lamination method using a two-component polyester adhesive.

Separately, when one end face and the other end face of the body member blank, which is the body part of the container body, are bonded to each other, both end faces that go outside and inside are covered. CPP film (21) as shown in FIG. 3,
The tape-shaped laminated film (2) is formed by sequentially laminating the barrier layer (22) and the CPP film (23).
0) is prepared.

The barrier layer (22) is made of a PET film,
ONy film, OPP film and other plastic films are coated with thin films of silicon oxide, aluminum oxide, etc.
A deposited film deposited by a method such as vacuum deposition can be preferably used, but an EVOH film may be used.

C provided on both sides of the barrier layer (22)
The PP films (21, 23) may be any of a homo type, a random type and a block type.

The CPP film (21) and the barrier layer (2)
2) and barrier layer (22) and CPP film (2
The bonding in 3) can be performed by a commonly used known laminating method, for example, a dry lamination method using a two-component polyester adhesive, and the tape-shaped laminated film (20) can be easily formed. Can be made.

The tape-shaped laminated film (20) can be heat-sealed to both ends of the body blank serving as the body (12) of the container body by any of a heat sealing method, an impulse sealing method and an ultrasonic sealing method. Depending on the method. Further, the fusion processing is preferably performed in a blank state before forming the cup.

The molding of the paper container can be performed, for example, as follows. First, in order to form a cup-shaped container body (10) from the laminated sheet (1), a body member blank serving as a body portion (12) of the container body and a bottom member roll serving as a bottom portion (13) of the container body are formed. Make it. Then, when the container body of the body member blank is assembled to the body, both inner and outer end surfaces generated at the bonded portion of the body are shown in the tape-shaped laminated film (20), for example, as shown in FIG. Cover in such a state.

The body member blank and the bottom member roll, each of which is covered with the tape-shaped laminated film at a required position, are set in a paper cup forming machine. First, the body member blank is bent into a cylindrical shape so that the CPP film (5) becomes the inner surface, and one end surface of the body member blank covered with the tape-like laminated film and the other end covered with the tape-like laminated film. And the lamination part (1
A cylindrical body (12) having 4) is manufactured.

Next, the outer surface of the outer peripheral edge of the substantially circular bottom member punched out from the bottom member roll and having the outer peripheral edge rising downward is joined to the lower inner surface of the cylindrical body (12) by heating. Further, the lower edge of the body member is bent inward so as to cover the outer peripheral portion, and is press-bonded to the inner surface of the outer peripheral edge of the bottom member by a knurl (not shown) to form a paper container (5).
0) is performed (see FIG. 4). At this time, the inner surface of the body member and the inner surface of the bottom member are completely fused, and the inner layer C
It is important that the resin is sufficiently buried in the adhesive surface between the body member and the bottom member due to the melting of the PP film, so that when the contents are filled, the moisture or oil content of the contents is reduced to the end surface of the bottom member. No longer penetrates

The outer periphery of the opening of the paper container (50) and the inner wall of the bottom incurd are coated with a polypropylene resin by insert injection molding so that the end surface of the laminated sheet is not exposed.

The procedure of the insert injection molding method is as follows, for example.
As shown in FIG. 5, first, a paper container (50) is inserted into the core mold (61) from the opening (11), and the paper container (5) is inserted.
0) A cavity mold (62) is mounted from above. Next, the outer periphery of the opening of the paper container is covered with molten polypropylene resin as an opening peripheral member (31) from one open gate injection opening (68T) through the sprue (66) and the runner (67). . The inner wall of the bottom incurd of the paper container is covered with the bottom incurred annular member (34) from the other open gate outlet (68B) through which the runner (69) passes. In this way, a paper container that can be subjected to the retort sterilization process is manufactured.

The polypropylene resin used at this time is a block type polypropylene resin having excellent impact resistance and a small amount of low molecular weight components eluted for an opening peripheral member.
MFR is 8 to 30 g / 10 min. Is preferably used. The polypropylene resin used for the bottom incurred annular member may be any of a homo type, a random type and a block type.

[0038]

EXAMPLES Examples of the present invention will be described below more specifically. Example 1 A laminated sheet (1) constituting a container body, a tape-shaped laminated film (20) for covering an exposed end face of the container body obtained by molding the laminated sheet, and an opening of the container body were sealed. The lid member to be formed was produced by a dry lamination method using a polyester resin-based two-component reactive adhesive with the following configuration.

Layer structure of laminated sheet (1), [outside of container]
CPP film (50 μm thickness) (2) / PET film (9 μm thickness) (6) / coat layer (coating amount: 15 g /
m ² ) (3a) / cup base paper (basis weight; 295 g / m ² )
(3) / PET film (12 μm thick), aluminum oxide deposited thin film (400 °) (4) / CPP film (5
0 μm thickness) (5) [Inside of container]

Layer structure of the tape-shaped laminated film (20),
CPP film (30 μm thickness) (21) / PET film (12 μm thickness), aluminum oxide deposited thin film (400
Å) (22) / CPP film (30 μm thick) (23)

Layer structure of lid member, [outside of container] PET film (12 μm thick), aluminum oxide deposited thin film (40
0Å) / ONy film (14 μm thickness) / CPP film (70 μm thickness) [inside of container]

The CPP film used for the laminated sheet (1) is a CPP film having the following constitution and physical properties. That is, propylene-ethylene block copolymer, melting point: 160 ° C., density: 0.90 g / cm ³ , MF
R: 8 g / 10 min. ··· Ethylene content: 2.5w
t%, ethylene-butene copolymer (amorphous resin) is added to impart impact resistance.

The moisture content of the cup base paper is 5.0%.

From the laminated sheet, a cup-shaped container body (1
In order to form (0), a body member blank serving as the body (12) of the container body and a bottom member roll serving as the bottom (13) of the container body were produced. Then, as shown in FIG. 4B, the tape-shaped laminated film (20) having a width of 10 mm is impulse-sealed as shown in FIG. Was coated.

A cylindrical cup-shaped container was formed by using a body member blank in which the exposed portion of the paper end surface was covered with a tape-shaped laminated film and a bottom member roll. As a heating method, a method of locally heating and pressing the CPP film on the outside of the welded portion was adopted in order to prevent the generation of blisters due to vaporization of moisture in the cup base paper of the laminated sheet. (Detailed molding methods are described in paragraphs 0033 and 0034)

A polypropylene resin melted by heat was injected onto the inner wall portion of the incurl at the bottom of the paper container (50) thus produced to cover the annular member (34) at the bottom. Next, the opening outer peripheral member (31) was coated on the outer peripheral edge of the opening of the container body by injecting a hot-melt polypropylene resin, thereby producing a paper container capable of performing a retort sterilization process without any exposure of the paper end surface. .

The above-described injection molding method employs insert molding dies (61, 62) and sprues (66), runners (67, 69), and open gate injection ports (68T, 68B) as shown in FIG. ).
The polypropylene resin used for injection molding had the following configuration and physical properties. That is, ethylene-propylene block copolymer, melting point: 160 °
C, density: 0.90 g / cm ³ , MFR: 14 g /
10 min.

<Comparative Example 1> A paper container produced by the same material and molding method as in Example 1 except that the end surface of the body member constituting the body portion (12) is not covered with the tape-like laminated film (20). (Detailed description is omitted)

<Comparative Example 2> A paper container produced by the same material and molding method as in Example 1 except that a 9 μm-thick aluminum foil was used as a barrier layer constituting a laminated sheet.
(Detailed description is omitted)

<Reference Example 1> A plastic container having the same shape as that of Example 1 (the structure is polypropylene resin (PP) / EVO)
H / PP was prepared.

The suitability for retort and the suitability for a microwave oven were evaluated by conducting experiments on three types of paper containers and one type of plastic container having the same shape as described above in accordance with the methods described below.

<Experiment 1> Suitability of retort (1) After filling the above four kinds of containers with water and sealing with a lid member, retort sterilization of an aerated system using a device manufactured by Hisaka Seisakusho under the following two conditions. The processing was performed, and the state of the shape change of the container was observed. Table 1 shows the results. Condition 1 ‥‥ Initial temperature; 80 ° C., temperature rising condition; 120 ° C. reached 15 minutes Holding condition: 30 minutes, cooling time; 30 minutes Condition 2 ‥‥ Initial temperature; 80 ° C., temperature rising condition; 130 ° C. Achieved 15 minutes Holding condition: 30 minutes, cooling time: 30 minutes In Table 1, ○ indicates that the container has no shape change such as deformation, and × indicates that the bonded portion of the trunk is peeled off by water from the paper end surface. Indicates that the container has been torn.

<Experiment 2> Suitability of retort (2) The three types of containers of Example 1, Comparative Example 2 and Reference Example 1 were filled with the following oxygen barrier detecting material as contents and sealed with a lid member. Retort sterilization was performed under two conditions, and the presence or absence of oxygen barrier properties was observed. Table 1 shows the results. Oxygen barrier detection material も の A mixture of sucrose fatty acid ester, agar powder, sodium hydroxide, methylene blue, and D-glucose dissolved in hot water. Evaluation method of barrier properties こ と Methylene blue develops a blue color when exposed to oxygen. In Table 1, 透過 indicates that the content liquid does not develop a blue color and has an oxygen barrier property, and X indicates that the content liquid entirely develops a blue color.
Indicates that the oxygen barrier property has deteriorated, and-indicates that the experiment has not been performed.

<Experiment 3> Suitability for microwave oven For the three types of containers of Example 1, Comparative Example 2, and Reference Example 1, heating by a microwave oven was performed under the following conditions after the retort sterilization treatment, and the suitability for the microwave oven was observed and evaluated. did. Table 2 shows the results. The microwave oven has a rated voltage of 10
A commonly used one having 0 V and a rated frequency of 60 Hz was used. In Table 2, ○ indicates a state in which reheating by a microwave oven was successfully performed, and X indicates a state in which reheating by a microwave oven could not be performed.

[0055]

[Table 1]

[0056]

[Table 2]

From Tables 1 and 2, it can be seen that the paper container of the present invention in which the paper end surface is completely covered has not only the suitability for retort sterilization but also the microwave oven suitability after retort sterilization (Example 1). It can be seen that, when the paper container not covered with the paper end face is subjected to the retort sterilization treatment, water penetrates from the paper end face, causing deformation of the container and being unusable (Comparative Example 1). Further, it can be seen that the paper container using the aluminum foil for the barrier layer of the laminated sheet has retort sterilization suitability but not microwave oven suitability (Comparative Example 2). Further, the plastic container having the PP / EVOH / PP constitution does not change its shape due to the retort sterilization treatment. Although it has microwave oven suitability, it can be seen that there is a problem in gas barrier properties after the retort sterilization treatment (Reference Example 1). .

[0058]

As described above, since the paper container of the present invention is a container mainly composed of paper, it has excellent display properties and printability, and does not require a secondary container such as a plastic container.
Generation of garbage can be suppressed. Because it is a paper container, it has excellent incineration. Further, since retort sterilization treatment is possible, it can be used as a water-resistant container instead of a plastic bottle around water.

[Brief description of the drawings]

FIG. 1 is an explanatory view showing an embodiment of a retort sterilizable paper container of the present invention as viewed from the inside in a longitudinal section.

FIG. 2 is an explanatory cross-sectional view showing one embodiment of a laminated sheet used for the paper container of the present invention.

FIG. 3 is an explanatory sectional view showing one embodiment of a tape-shaped laminated film used for the paper container of the present invention.

FIG. 4 is an explanatory view of a container body used in the present invention;
(A) is a front explanatory view in which a part of the container body is cut out,
(B) is an enlarged plan explanatory view of a portion A.

FIG. 5 is an explanatory view showing one example of an insert injection molding method.

[Explanation of symbols]

 1 Laminated sheet 2, 5, 21, 23 CPP film 3 Cup base paper 3a Coat layer 4 Barrier layer 6 PET film 10 Container body 11 Opening 12 Body 13 {Bottom part 14} Laminated part 15, 16} Edge part 20 {Tape-like laminated film 22} Barrier layer 30} Covering member 31 {Opening peripheral member 34} Bottom bottom incurred ring member 50} ‥ Paper container 61 ‥‥ Core mold 62 ‥‥ Cavity mold 66 ‥‥ Sprue 67,69 ‥‥ Runner 68T, 68B ‥‥ Open gate injection port

Continued on the front page (51) Int.Cl. ⁶ Identification code FI B32B 9/00 B32B 9/00 A 27/00 27/00 H 27/10 27/10 27/32 27/32 Z B65D 3/22 B65D 3 / 22 B 81/34 81/34 U

Claims (8)

[Claims] 1. A cup-shaped container body having an opening made of a laminated sheet mainly composed of a paper layer, a body and a bottom, and both inner and outer edges formed at a bonding portion of the body of the container. A tape-shaped laminated film for covering the outer peripheral edge of the opening of the container main body, which is positioned so as to cover the outer peripheral edge, and an inner peripheral wall of the bottom incur of the container main body. And a bottom incurred annular member which is positioned along the portion and which is heat-sealed is provided by an insert injection molding method for injecting hot-melted polypropylene resin into a mold in which the container body is inserted and arranged in advance. Paper container that can be sterilized. 2. The laminated sheet according to claim 1, wherein the laminated sheet has at least a four-layer structure in which an unstretched polypropylene (CPP) film, a cup base paper, a barrier layer, and an unstretched polypropylene (CPP) film are laminated in this order from the outside of the container. The paper container capable of being subjected to a retort sterilization treatment according to claim 1. 3. The CPP film located on the outside of the container of the CPP film constituting the laminated sheet is a block type or a random type CPP film, and the CPP film located on the side in contact with the contents is a block type CPP film. 2. The film according to claim 1, which is a film.
Or a paper container capable of being subjected to a retort sterilization treatment according to item 2. 4. The laminate sheet according to claim 1, wherein the barrier layer comprises:
The retort sterilizable paper container according to claim 1, 2 or 3, which is any one of a film on which an inorganic compound deposited thin film is formed, a film on which a metal compound deposited thin film is formed, and a barrier plastic film. 5. The cup base paper constituting the laminated sheet,
A diatomaceous earth coat layer on the base paper surface is 12 to 18 g / m
² coated, characterized in that a cup base paper has claim 1, 2, 3 or 4 retorting possible paper container according. 6. The tape-shaped laminated film according to claim 1, wherein the laminated film is composed of at least three layers laminated in the order of a CPP film, a barrier layer and a CPP film. Or a paper container capable of being subjected to a retort sterilization treatment. 7. The barrier layer constituting the tape-shaped laminated film is one of a film on which an inorganic compound vapor-deposited thin film is formed, a film on which a metal compound vapor-deposited thin film is formed, and a barrier plastic film. The paper container according to claim 1, 2, 3, 4, 5, or 6, which can be subjected to a retort sterilization treatment. 8. A polypropylene resin used for the insert injection molding method, wherein the polypropylene resin used for the opening peripheral member and the bottom annular member is a block type polypropylene resin having an MFR of 8 to 30. The retort sterilizable paper container according to claim 1, 2, 3, 4, 5, 6, or 7.