JPH11292116A - Retort-sterilizable paper container lid - Google Patents
Retort-sterilizable paper container lidInfo
- Publication number
- JPH11292116A JPH11292116A JP10097944A JP9794498A JPH11292116A JP H11292116 A JPH11292116 A JP H11292116A JP 10097944 A JP10097944 A JP 10097944A JP 9794498 A JP9794498 A JP 9794498A JP H11292116 A JPH11292116 A JP H11292116A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- paper container
- lid
- film
- lid material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 claims abstract description 87
- 239000011347 resin Substances 0.000 claims abstract description 87
- 230000002093 peripheral effect Effects 0.000 claims abstract description 29
- 238000001746 injection moulding Methods 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 70
- 239000000123 paper Substances 0.000 claims description 69
- 239000004743 Polypropylene Substances 0.000 claims description 65
- 229920001155 polypropylene Polymers 0.000 claims description 65
- 239000010408 film Substances 0.000 claims description 64
- 230000001954 sterilising effect Effects 0.000 claims description 30
- 238000004659 sterilization and disinfection Methods 0.000 claims description 30
- 239000010410 layer Substances 0.000 claims description 28
- 230000004888 barrier function Effects 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 18
- 230000008018 melting Effects 0.000 claims description 18
- 239000010409 thin film Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011087 paperboard Substances 0.000 claims description 10
- -1 polypropylene Polymers 0.000 claims description 10
- 229920001684 low density polyethylene Polymers 0.000 claims description 9
- 239000004702 low-density polyethylene Substances 0.000 claims description 9
- 238000007789 sealing Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 229920005992 thermoplastic resin Polymers 0.000 claims description 7
- WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 claims description 6
- 229920006026 co-polymeric resin Polymers 0.000 claims description 6
- 239000002356 single layer Substances 0.000 claims description 5
- 239000005909 Kieselgur Substances 0.000 claims description 4
- 150000002484 inorganic compounds Chemical class 0.000 claims description 3
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 150000002736 metal compounds Chemical class 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- 239000012153 distilled water Substances 0.000 description 9
- 239000011888 foil Substances 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 229920002799 BoPET Polymers 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 229910052814 silicon oxide Inorganic materials 0.000 description 6
- 229920003002 synthetic resin Polymers 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 239000000057 synthetic resin Substances 0.000 description 5
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000012943 hotmelt Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 2
- 101100160821 Bacillus subtilis (strain 168) yxdJ gene Proteins 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004823 Reactive adhesive Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000009820 dry lamination Methods 0.000 description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000003303 reheating Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229920006127 amorphous resin Polymers 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229920005676 ethylene-propylene block copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920006284 nylon film Polymers 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Injection Moulding Of Plastics Or The Like (AREA)
- Package Specialized In Special Use (AREA)
- Packages (AREA)
- Closures For Containers (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、ホット充填後の容
器内の減圧に耐え得るレトルト殺菌処理可能な紙容器用
の蓋材に関し、特には、電子レンジによる再加熱が可能
でレトルト殺菌処理可能なカップ状をした紙容器に用い
る蓋材に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cover material for a paper container which can withstand reduced pressure in a container after hot filling and which can be subjected to a retort sterilization process, and more particularly to a retort sterilization process which can be reheated by a microwave oven. The present invention relates to a lid material used for a paper container having a cup shape.
【0002】[0002]
【従来の技術】レトルト殺菌処理可能な紙容器として
は、例えば、特開昭57−46734号公報、特開昭5
8−52033号公報、特開昭58−20638号公報
等に開示された発明をはじめとして多数の発明、考案が
開示されている。2. Description of the Related Art Paper containers which can be subjected to a retort sterilization treatment are disclosed, for example, in JP-A-57-46734 and JP-A-5-46734.
Many inventions and ideas have been disclosed, including the inventions disclosed in JP-A-8-52033 and JP-A-58-20638.
【0003】特開昭57−46734号公報に開示され
た発明は、高密度ポリエチレン樹脂を除く熱可塑性樹脂
が主体であって、融点が115°C以上の樹脂を両外層
とした合成樹脂、紙およびアルミ箔からなる積層シート
を丸めて重ね合せた両側端部に防水処理を施すとともに
溶着して筒体を形成し、得られた筒体の上下両開口部
を、前記積層シートにおける合成樹脂と同種の合成樹脂
で内面を被覆したアルミ箔からなる蓋材で閉蓋してなる
容器であって、前記積層シートが紙の両側面にアルミ箔
を配した積層構造とされた包装用容器としたものであ
る。[0003] The invention disclosed in Japanese Patent Application Laid-Open No. 57-46734 discloses a synthetic resin or paper mainly composed of a thermoplastic resin excluding a high-density polyethylene resin and having a melting point of 115 ° C or higher as both outer layers. The both ends of the laminated sheet made of aluminum foil are rolled and subjected to waterproofing and welded to form a cylindrical body, and the upper and lower openings of the obtained cylindrical body are formed with the synthetic resin in the laminated sheet. A container closed with a lid made of aluminum foil whose inner surface is coated with the same kind of synthetic resin, wherein the laminated sheet is a packaging container having a laminated structure in which aluminum foil is disposed on both sides of paper. Things.
【0004】また特開昭58−52033号公報に開示
された発明は、両面耐水処理をした紙質原反からなる扇
形又は方形ブランクシートの胴シール部に相当する両端
部をある幅にわたって互いに逆面へと折返し且つブラン
クシート全体を筒体を形成するように折曲げて前記で得
られた一対の折返し片を有する面で両端部を貼合してな
る胴部筒体の上下部を、その上下紙端面が露出しないよ
うに蓋体および底板でシールしてなる完全耐水性紙質容
器としたものである。Further, the invention disclosed in Japanese Patent Application Laid-Open No. 58-52033 discloses a method in which both ends corresponding to a body seal portion of a fan-shaped or rectangular blank sheet made of a paper material subjected to a water-resistant treatment on both sides are opposite to each other over a certain width. The upper and lower parts of the body cylinder formed by folding both sides of the blank sheet so as to form a cylinder and bonding both ends at the surface having the pair of folded pieces obtained above, This is a completely water-resistant paper container sealed with a lid and a bottom plate so that the paper end surface is not exposed.
【0005】さらに特開昭58−20638号公報に開
示された発明は、内層を形成する樹脂層と板紙等からな
る中間層が一体接着され、外層を形成する樹脂層と中間
層とが一体接着もしくは容器上縁での樹脂同士の接着が
なされ、各層間は脱気され、中間層が両側の樹脂層に挟
まれている多層容器としたものである。Further, in the invention disclosed in Japanese Patent Application Laid-Open No. 58-20638, the resin layer forming the inner layer and the intermediate layer made of paperboard and the like are integrally bonded, and the resin layer forming the outer layer and the intermediate layer are integrally bonded. Alternatively, the resin is bonded to each other at the upper edge of the container, the layers are degassed, and a multilayer container is formed in which an intermediate layer is sandwiched between resin layers on both sides.
【0006】しかしながらこれらの発明は、いずれもア
ルミニウム箔を多用しているため電子レンジ適性が無
い、合成樹脂を多用しているため廃棄性に問題が残る、
等の問題を有していた。[0006] However, these inventions are not suitable for microwave ovens because they all use aluminum foil, and there is still a problem in disposability because they use a lot of synthetic resins.
And so on.
【0007】[0007]
【発明が解決しようとする課題】そこで発明者等は、ア
ルミニウム箔を使用せず、合成樹脂使用量も少ない電子
レンジ適性を有するレトルト殺菌処理可能な紙容器を開
発し、特願平10−4724号他として出願した。本発
明はこれらのレトルト殺菌処理可能な紙容器に適用する
ための蓋材を提供することを目的とする。Accordingly, the present inventors have developed a retort sterilizable paper container which does not use aluminum foil and has a small amount of synthetic resin and which is suitable for a microwave oven. No. and others. An object of the present invention is to provide a lid material to be applied to these paper containers that can be subjected to a retort sterilization treatment.
【0008】[0008]
【課題を解決するための手段】上記目的を達成するため
に、先ず、請求項1に記載の発明では、開口部周縁が外
側にカールし、その上下層が互いに偏平に熱圧着された
口縁部を有するレトルト殺菌可能なカップ状紙容器の開
口部を密封する蓋材であって、該蓋材が、天板と、天板
の周縁に立設された、カップ状紙容器の胴部内壁に密着
可能な周壁と、周壁の上縁に外方に向けて天板と平行に
設けられたシールフランジと、からなる落とし込み蓋材
部と、落とし込み蓋材部の全体を覆い天板との間に空間
部を形成させる蓋材シート部と、蓋材シート部周縁の端
面を含む三方向を覆う断面コの字状の端面被覆部材と、
から成り、シールフランジと端面被覆部材と端面被覆部
材で被覆された蓋材シート部周縁とが互いに熱融着さ
れ、カップ状紙容器の口縁部に熱融着可能に載置される
蓋材であって、該端面被覆部材は、蓋材シート部を前も
って挿入配置した金型内に熱溶融したポリプロピレン樹
脂を射出するインサート射出成形法により設けたことを
特徴とするレトルト殺菌処理可能な紙容器用蓋材であ
る。In order to achieve the above object, according to the first aspect of the present invention, the opening edge is curled outward, and the upper and lower layers are flatly thermocompression-bonded to each other. A lid material for sealing an opening of a retort-sterilizable cup-shaped paper container having a portion, the lid material being a top plate, and a torso inner wall of the cup-shaped paper container standing upright on a peripheral edge of the top plate. Between a top wall that covers the whole of the dropping cover part, and a top cover that covers the whole of the dropping cover part, and a peripheral wall that can be in close contact with the ceiling wall, and a seal flange that is provided on the upper edge of the peripheral wall outward and parallel to the top plate. A lid material sheet portion that forms a space portion, and an end surface covering member having a U-shaped cross section that covers three directions including an end surface of the lid material sheet portion peripheral edge,
And a lid material that is heat-fused with the seal flange, the end surface covering member, and the lid material sheet peripheral edge covered with the end surface covering member, and that is placed on the edge of the cup-shaped paper container so as to be heat-fusible. The end face covering member is provided by an insert injection molding method for injecting a hot-melted polypropylene resin into a mold in which a lid material sheet is inserted and arranged in advance, wherein the paper container is capable of being subjected to a retort sterilization process. It is a cover material.
【0009】また、請求項2に記載の発明では、前記端
面被覆部材の周縁に、蓋材を紙容器開口部に被せた際、
部分的に口縁部より外方に突出した開封取手部が形成さ
れていることを特徴とするレトルト殺菌処理可能な紙容
器用蓋材である。Further, according to the invention described in claim 2, when a cover material is put on the opening of the paper container around the peripheral edge of the end face covering member,
A cover material for a paper container which can be subjected to a retort sterilization process, wherein an opening handle portion protruding partly outward from an edge portion is formed.
【0010】また、請求項3に記載の発明では、前記蓋
材シート部は、容器外側よりポリプロピレン(PP)フ
ィルム、板紙、バリヤー性フィルム、PPフィルムの順
序で積層される少なくとも4層構成からなる積層シート
であることを特徴とするレトルト殺菌処理可能な紙容器
用蓋材である。According to the third aspect of the present invention, the cover sheet portion has at least a four-layer structure in which a polypropylene (PP) film, a paperboard, a barrier film, and a PP film are laminated in this order from the outside of the container. It is a lid material for a paper container which can be subjected to a retort sterilization treatment, which is a laminated sheet.
【0011】ここで特に、上記の蓋材シート部の内外面
に使用するPPフィルムは、融点が150°C以上のP
P樹脂を製膜して得られる。In particular, the PP film used for the inner and outer surfaces of the above-mentioned cover sheet has a melting point of 150 ° C. or more.
It is obtained by forming a P resin into a film.
【0012】また、請求項5に記載の発明では、前記蓋
材シート部を構成するバリヤー性フィルムが、無機化合
物蒸着薄膜を形成したフィルム、金属化合物蒸着薄膜を
形成したフィルム、またはバリヤー性プラスチックフィ
ルムのいずれかである。Further, in the invention according to claim 5, the barrier film constituting the cover sheet portion is a film on which an inorganic compound vapor-deposited thin film is formed, a film on which a metal compound vapor-deposited thin film is formed, or a barrier plastic film. Is one of
【0013】また、請求項6に記載の発明では、前記蓋
材シート部を構成する板紙が、板紙表面に珪藻土からな
るコート層が10〜18g/m2 塗布されている板紙で
ある。In the invention according to claim 6, the paperboard constituting the cover sheet portion is a paperboard having a diatomaceous earth coat layer applied to the paperboard surface in an amount of 10 to 18 g / m 2 .
【0014】また、請求項7に記載の発明では、前記落
とし込み蓋材部は、少なくとも蓋材シート部との接合面
にPP樹脂を用いた単層または2層以上の熱可塑性樹脂
フィルムからなり、かつ、使用する全ての熱可塑性樹脂
フィルムの融点が140°C以上である。Further, in the invention according to claim 7, the drop-in lid member portion is made of a single-layer or two or more-layer thermoplastic resin film using PP resin at least on a joint surface with the lid member sheet portion, Further, the melting points of all the thermoplastic resin films used are 140 ° C. or higher.
【0015】また、請求項8に記載の発明では、前記イ
ンサート射出成形法に用いるPP樹脂であって、端面被
覆部材に使用するPP樹脂は、PP樹脂とLDPE樹脂
またはPP樹脂とエチレン−ブテン共重合体樹脂をそれ
ぞれブレンドした樹脂である。Further, in the invention according to claim 8, the PP resin used for the insert injection molding method, wherein the PP resin used for the end face covering member is a PP resin and an LDPE resin or a PP resin and an ethylene-butene copolymer. It is a resin blended with a polymer resin.
【0016】ここで特に、上記のPP樹脂とLDPE樹
脂またはPP樹脂とエチレン−ブテン共重合体樹脂との
ブレンド比率は、それぞれ100/10〜100/30
である。In particular, the blend ratio of the PP resin and the LDPE resin or the PP resin and the ethylene-butene copolymer resin is 100/10 to 100/30, respectively.
It is.
【0017】[0017]
【作用】上記のように本発明によれば、蓋材が、天板
と、天板の周縁に立設された、カップ状紙容器の胴部内
壁に密着可能な周壁と、周壁の上縁に外方に向けて天板
と平行に設けられたシールフランジと、からなる落とし
込み蓋材部と、落とし込み蓋材部の全体を覆い天板との
間に空間部を形成させる蓋材シート部と、蓋材シート部
周縁の端面を含む三方向を覆う断面コの字状の端面被覆
部材と、から成り、シールフランジと端面被覆部材と端
面被覆部材で被覆された蓋材シート部周縁とが互いに熱
融着された蓋材であるので、ホット充填後冷却しても容
器内の減圧状態を空間部で吸収し、容器本体の変形を防
ぐことができる。As described above, according to the present invention, the lid is provided with a top plate, a peripheral wall erected on the periphery of the top plate, which can be in close contact with the inner wall of the body of the cup-shaped paper container, and an upper edge of the peripheral wall. A sealing flange provided outwardly in parallel with the top plate, a dropping lid material portion, and a lid material sheet portion that covers the entire dropping lid material portion and forms a space between the top plate and , An end covering member having a U-shaped cross section that covers three directions including the end surface of the lid material sheet peripheral edge, and the seal flange, the end surface covering member, and the lid material sheet peripheral edge covered with the end surface covering member are mutually separated. Since the lid material is heat-sealed, even if it is cooled after hot filling, the depressurized state in the container is absorbed in the space, and deformation of the container body can be prevented.
【0018】また、前記端面被覆部材の周縁に、蓋材を
紙容器開口部に被せた際、部分的に口縁部より外方に突
出した開封取手部が形成されているので、紙容器を開封
する際は開封取手部より容易に開封可能である。[0018] Further, when the lid material is placed over the opening of the paper container at the peripheral edge of the end surface covering member, an opening handle portion which is partially protruded outward from the edge of the paper container is formed. When opening, the opening can be easily opened from the opening handle portion.
【0019】また、端面被覆部材に使用するPP樹脂が
PP樹脂とLDPE樹脂またはPP樹脂とエチレン−ブ
テン共重合体樹脂とのブレンド樹脂であり、落とし込み
蓋材部の容器外側に使用するフィルムが140°C以上
の融点を有するPP樹脂からなるフィルムであり、蓋材
シート部の容器外側に使用するフィルムが150°C以
上の融点を有するPP系樹脂を製膜して得られるフィル
ムであるので、開封時に蓋材が容器本体から適度の剥離
強度をもって剥離する。Further, the PP resin used for the end face covering member is a blend resin of PP resin and LDPE resin or PP resin and ethylene-butene copolymer resin. It is a film made of a PP resin having a melting point of at least ° C, and the film used on the outer side of the container of the lid sheet portion is a film obtained by forming a PP-based resin having a melting point of at least 150 ° C. At the time of opening, the lid material peels from the container body with an appropriate peel strength.
【0020】さらに、蓋材シート部を構成するバリヤー
性フィルムが、無機化合物蒸着薄膜を形成したフィル
ム、金属化合物蒸着薄膜を形成したフィルム、またはバ
リヤー性プラスチックフィルムのいずれかで構成されて
いるので、内容物の保護性が良好であると共に電子レン
ジ適性を有する。Further, since the barrier film constituting the cover sheet portion is formed of any one of a film formed with an inorganic compound vapor-deposited thin film, a film formed with a metal compound vapor-deposited thin film, and a barrier plastic film, It has good protection of the contents and is suitable for microwave ovens.
【0021】さらにまた、蓋材シート部の容器外側に使
用するPPフィルムは、融点が150°C以上のポリプ
ロピレン系樹脂であり、落とし込み蓋材部は、融点が1
40°C以上のPP樹脂であり、端面被覆部材は、PP
樹脂とLDPE樹脂またはPP樹脂とエチレン−ブテン
共重合体樹脂とをブレンドした樹脂を使用しているの
で、レトルト殺菌処理適性を有する。Further, the PP film used on the outside of the container of the cover sheet portion is a polypropylene resin having a melting point of 150 ° C. or higher, and the melting point of the dropping cover portion is 1 point.
40 ° C. or higher PP resin, and the end face covering member is made of PP resin.
Since a resin blended with a resin and an LDPE resin or a PP resin and an ethylene-butene copolymer resin is used, it is suitable for a retort sterilization treatment.
【0022】[0022]
【発明の実施の形態】以下実施例により本発明を詳細に
説明するが、本発明はその要旨を越えぬ限り下記実施例
に限定されない。本発明のレトルト殺菌処理可能な紙容
器用蓋材は、例えば、図1(a)、(b)および図2に
示すように、天板23と、天板の周縁に立設されたカッ
プ状紙容器の胴部11内壁に密着可能な周壁22と、周
壁の上縁に外方に向けて天板と平行に設けられたシール
フランジ21と、からなる落とし込み蓋材部24と、落
とし込み蓋材部の全体を覆い天板との間に空間部26を
形成させる蓋材シート部25と、蓋材シート部周縁の端
面を含む三方向を覆う断面コの字状の端面被覆部材30
と、から構成されている。BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below with reference to examples, but the present invention is not limited to the following examples unless it exceeds the gist. As shown in FIGS. 1 (a), 1 (b) and 2, the lid material for a paper container which can be subjected to the retort sterilization treatment of the present invention is, for example, a top plate 23 and a cup-shaped upright provided on the periphery of the top plate. A drop lid member 24 comprising a peripheral wall 22 which can be in close contact with the inner wall of the body 11 of the paper container, and a seal flange 21 provided on the upper edge of the peripheral wall outwardly in parallel with the top plate; Cover sheet portion 25 that covers the entire portion and forms a space portion 26 with the top plate, and an end surface covering member 30 having a U-shaped cross section that covers three directions including an end surface of the peripheral portion of the cover sheet portion.
And is composed of
【0023】蓋材シート部25は、容器外側よりPPフ
ィルム、板紙、バリヤー性フィルム、PPフィルムの順
序で積層される少なくとも4層構成からなる積層シート
から構成されている。The cover material sheet portion 25 is composed of a laminated sheet having at least a four-layer structure in which a PP film, a paperboard, a barrier film, and a PP film are laminated in this order from the outside of the container.
【0024】そして、蓋材シート部25の内外層に使用
するPPフィルムを構成するPP樹脂は、ポリプロピレ
ン樹脂系で融点が150°C以上であれば、ランダムタ
イプ、ブロックタイプ、ホモタイプいずれのタイプの樹
脂であってもレトルト殺菌処理時の耐熱性をクリヤーす
るので使用可能である。The PP resin constituting the PP film used for the inner and outer layers of the cover material sheet portion 25 may be any of a random type, a block type and a homo type if the melting point is 150 ° C. or higher. Even resins can be used because they clear heat resistance during retort sterilization.
【0025】蓋材シート部25を構成するバリヤー性フ
ィルムは、ポリエチレンテレフタレート(PET)フィ
ルム、ポリエチレンナフタレート(PEN)フィルム、
二軸延伸ナイロン(ONy)フィルム等の基材フィルム
に、酸化珪素、酸化アルミニウム等の薄膜を400Å程
度真空蒸着法などの方法により蒸着した蒸着フィルムが
好ましく使用できるが、上記基材フィルムに塩化ビニリ
デン(PVDC)樹脂を塗布したフィルムを用いても良
い。The barrier film constituting the cover sheet portion 25 is a polyethylene terephthalate (PET) film, a polyethylene naphthalate (PEN) film,
A vapor-deposited film obtained by vapor-depositing a thin film of silicon oxide, aluminum oxide or the like on a substrate film such as a biaxially stretched nylon (ONy) film by a vacuum vapor deposition method of about 400 ° can be preferably used. A film coated with (PVDC) resin may be used.
【0026】蓋材シート部25を構成する板紙は蓋材シ
ート部の基材であり、坪量100〜320g/m2 程度
のカップ原紙、アイボリー、両面カード等が好ましく使
用でき、印刷適性を付与するために珪藻土層を10〜1
8g/m2 程度設けたものが良い。The paperboard constituting the cover sheet section 25 is a base material of the cover sheet section, and cup base paper having a basis weight of about 100 to 320 g / m 2 , ivory, double-sided card, or the like can be preferably used to impart printability. 10-1 diatomaceous earth layer
What provided about 8 g / m < 2 > is good.
【0027】蓋材シート部25を構成するフィルムの中
に衝撃性を緩和させる目的でナイロンフィルムを介在さ
せても良い。A nylon film may be interposed in the film constituting the cover material sheet portion 25 for the purpose of reducing impact.
【0028】各フィルムとシートの積層は、公知の、例
えば、二液反応型ポリエステル接着剤等を用いたドライ
ラミネーション法により行うことが好ましい。The lamination of each film and sheet is preferably performed by a known dry lamination method using, for example, a two-component polyester adhesive.
【0029】端面被覆部材30は、蓋材シート部25周
縁の端面を含む三方向を覆う断面コの字状の環状のPP
樹脂成形部材である。The end-face covering member 30 is an annular PP having a U-shaped cross section that covers three directions including the end face of the peripheral edge of the lid sheet portion 25.
It is a resin molded member.
【0030】端面被覆部材30の蓋材シート部25周縁
への被覆は、蓋材シート部25を前もって挿入配置した
金型内に熱溶融したPP樹脂を射出するインサート射出
成形法により行う。The peripheral surface of the cover sheet portion 25 of the end surface covering member 30 is coated by an insert injection molding method in which hot melted PP resin is injected into a mold in which the cover sheet portion 25 is inserted and arranged in advance.
【0031】そして端面被覆部材30に使用するPP樹
脂は、PP樹脂とLDPE樹脂またはPP樹脂とエチレ
ン−ブテン共重合体樹脂をそれぞれブレンドした樹脂が
好ましく使用でき、そのブレンド比率は、それぞれ10
0/10〜100/30の範囲が好ましい。ブレンド比
率を100/10〜100/30の範囲に規定すること
により端面被覆部材と口縁部の界面で凝集破壊が起き、
一般的にイージーピール性と呼ばれる易剥離現象が生じ
る。As the PP resin used for the end surface covering member 30, a resin obtained by blending a PP resin and an LDPE resin or a resin obtained by blending a PP resin and an ethylene-butene copolymer resin can be preferably used.
The range of 0/10 to 100/30 is preferred. By defining the blend ratio in the range of 100/10 to 100/30, cohesive failure occurs at the interface between the end face covering member and the rim,
An easy peeling phenomenon generally called easy peeling occurs.
【0032】端面被覆部材30の周縁に、蓋材を紙容器
開口部に被せた際、部分的に口縁部より外方に突出した
開封取手部29を設けておくと、紙容器を開封する際、
開封がより容易になる。When a cover material is placed over the opening of the paper container around the edge of the end face covering member 30, an opening handle portion 29 that partially projects outward from the edge of the paper container is provided to open the paper container. When
Opening is easier.
【0033】落とし込み蓋材部24は、少なくとも蓋材
シート部25との接合面にPP樹脂を用いた単層構成ま
たは2層構成以上の熱可塑性フィルムから成っており、
使用する樹脂の融点は全て140°C以上であること
が、レトルト殺菌処理時の耐熱性をクリヤーするために
も必要な条件となる。The drop-in lid part 24 is made of a thermoplastic film having a single-layer structure or a two-layer structure or more using PP resin at least on the joint surface with the lid material sheet part 25.
It is a necessary condition that the melting point of all the resins used is 140 ° C. or higher in order to clear the heat resistance during the retort sterilization treatment.
【0034】落とし込み蓋材部24の層構成中に、バリ
ヤー性樹脂層を設けても良く、エチレンビニルアルコー
ル共重合樹脂(EVOH)、塩化ビニリデン樹脂(PV
DC)等が好適な樹脂として例示できる。[0034] A barrier resin layer may be provided in the layer structure of the drop-in lid member portion 24, and an ethylene vinyl alcohol copolymer resin (EVOH), a vinylidene chloride resin (PV
DC) etc. can be illustrated as a suitable resin.
【0035】落とし込み蓋材部24を形成する熱可塑性
樹脂フィルムの総厚みは150μm以上であることが望
ましく、圧空成形法または真空成形法により作製され
る。It is desirable that the total thickness of the thermoplastic resin film forming the drop-in lid member portion 24 is 150 μm or more, and it is manufactured by a pressure forming method or a vacuum forming method.
【0036】落とし込み蓋材部24の絞り量(高低段
差)は紙容器の口径寸法と内容物の充填容量に依存し、
シールフランジ21と天板23との間の高低差は空間部
26のヘッドスペースが10cc以下になるように設計
する。The squeezing amount (height difference) of the drop-in lid member 24 depends on the diameter of the paper container and the filling capacity of the contents.
The height difference between the seal flange 21 and the top plate 23 is designed so that the head space of the space 26 is 10 cc or less.
【0037】最後に、周縁が端面被覆部材30で被覆さ
れた蓋材シート部25を、天板23との間に空間部26
が形成されるように落とし込み蓋材部24の上に被せ、
端面被覆部材30とシールフランジ21とを超音波シー
ル法などのシール方法により熱融着して、本発明のレト
ルト殺菌処理可能な紙容器用蓋材が作製できた。落とし
込み蓋材部24と端面被覆部材が被覆された蓋材シート
部25とは、ほぼ同一径になるように設計しておくと外
観の綺麗な蓋材に仕上がる。Finally, the cover sheet portion 25 whose peripheral edge is covered with the end surface covering member 30 is placed between the top plate 23 and the space portion 26.
Is formed so as to cover the cover member portion 24 so that
The end face covering member 30 and the seal flange 21 were heat-sealed by a sealing method such as an ultrasonic sealing method, whereby a lid material for a paper container capable of being subjected to the retort sterilization treatment of the present invention was produced. If the drop-in lid part 24 and the lid part sheet part 25 covered with the end surface covering member are designed to have substantially the same diameter, a lid with a beautiful appearance is finished.
【0038】[0038]
【実施例】以下に本発明の実施例をさらに具体的に説明
する。 〈実施例1〉先ず、落とし込み蓋材部24を構成する熱
可塑性樹脂フィルムとして200μm厚のPP単層シー
トを作製した。EXAMPLES Examples of the present invention will be described below more specifically. <Example 1> First, a PP single-layer sheet having a thickness of 200 µm was prepared as a thermoplastic resin film constituting the drop-in lid member 24.
【0039】使用したPP樹脂は、エチレン−プロピレ
ンランダムブロック共重合体で、・融点 151°C、
・密度 0.91g/cm2 の物性を有する樹脂を使用
した。そして、得られた単層シートを真空成型し落とし
込み蓋材部24とした。The PP resin used was an ethylene-propylene random block copolymer having a melting point of 151 ° C.
-A resin having physical properties of a density of 0.91 g / cm 2 was used. Then, the obtained single-layer sheet was vacuum molded and dropped into a lid member 24.
【0040】真空成型の絞り量(高低段差)は、後記す
るカップ状紙容器の口径:58.7mm、内部高さ:8
5.6mm、内容量:200ml(蒸留水)を考慮し
て、ヘッドスペースが10mmになるように落とし込み
蓋材部24のシールフランジ21と天板23との高低差
を8mmに設定した。The squeezing amount (level difference) of the vacuum molding is as follows: diameter of cup-shaped paper container: 58.7 mm, internal height: 8
In consideration of 5.6 mm and the internal capacity: 200 ml (distilled water), the head space was reduced to 10 mm, and the height difference between the sealing flange 21 of the lid member 24 and the top plate 23 was set to 8 mm.
【0041】次に、蓋材シート部25を構成する積層シ
ートをポリエステル樹脂系二液反応型接着剤を用いたド
ライラミネーション法により下記する構成で作製した。Next, a laminated sheet constituting the lid material sheet portion 25 was produced by a dry lamination method using a polyester resin-based two-component reactive adhesive in the following configuration.
【0042】〔容器外側〕CPPフィルム(プロピレン
−エチレンブロック共重合体タイプ、融点:160°
C、30μm厚)/アイボリー(160g/m2 )、珪
藻土の塗布量;15g/m2 /PETフィルム(12μ
m厚)、酸化珪素蒸着薄膜(400Å)/CPPフィル
ム(プロピレン−エチレンブロック共重合体タイプ、融
点:160°C、30μm厚)〔容器内側〕[Outside of Container] CPP film (propylene-ethylene block copolymer type, melting point: 160 °)
C, 30 μm thickness) / ivory (160 g / m 2 ), diatomaceous earth coating amount; 15 g / m 2 / PET film (12 μm)
m thickness), silicon oxide vapor deposited thin film (400 °) / CPP film (propylene-ethylene block copolymer type, melting point: 160 ° C, 30 µm thickness) [inside of container]
【0043】次いで、この積層シートを所定の寸法にカ
ットして蓋材シート部25とし、蓋材シート部周縁の端
面を含む三方向に、断面形状がコの字状のプラスチック
成形品を嵌め込むように被覆し端面被覆部材30とし
た。Next, the laminated sheet is cut into a predetermined size to form a lid material sheet portion 25, and plastic molded products having a U-shaped cross section are fitted in three directions including the end surface of the peripheral edge of the lid material sheet portion. Thus, the end face covering member 30 was formed.
【0044】端面被覆部材30の蓋材シート部25への
取り付けは次のようにして行った。すなわち、蓋材シー
ト部25をインサート成形の金型内にセットし、ゲート
より熱溶融したPP樹脂を射出する方法で蓋材シート部
25の周縁に端面被覆部材30を形成させた。The attachment of the end surface covering member 30 to the cover sheet portion 25 was performed as follows. That is, the cover sheet portion 25 was set in an insert molding die, and the end surface covering member 30 was formed on the periphery of the cover material sheet portion 25 by a method of injecting hot melt PP resin from a gate.
【0045】この際用いたPP樹脂はPP樹脂とLDP
E樹脂とのブレンド樹脂であり、配合比はPP樹脂/L
DPE樹脂=100/30である。また、PP樹脂とL
DPE樹脂の物性値は下記の通りである。 ・PP樹脂:ブロック重合体、MFR=30g/mi
n.、融点=161°C ・LDPE樹脂:MFR=25g/min.、融点=1
20°CThe PP resin used at this time was PP resin and LDP
It is a blend resin with E resin, and the compounding ratio is PP resin / L
DPE resin = 100/30. In addition, PP resin and L
The physical property values of the DPE resin are as follows.・ PP resin: block polymer, MFR = 30 g / mi
n. , Melting point = 161 ° C. LDPE resin: MFR = 25 g / min. , Melting point = 1
20 ° C
【0046】最後に、周縁が端面被覆部材30で被覆さ
れた蓋材シート部25を天板23との間に空間部26が
形成されるように落とし込み蓋材部24の上に被せ、端
面被覆部材30と落とし込み蓋材部のシールフランジ2
1とを超音波シール法により熱融着して本発明のレトル
ト殺菌処理可能な紙容器用蓋材20を作製した。Lastly, the cover material sheet portion 25 whose peripheral edge is covered with the end surface covering member 30 is dropped so as to form a space 26 between the top plate 23 and the lid material sheet portion 25, and is placed on the cover material portion 24. Seal flange 2 of member 30 and drop-in lid material
1 was thermally fused by an ultrasonic sealing method to produce a paper container lid material 20 of the present invention which can be subjected to the retort sterilization treatment.
【0047】別に、この蓋材に適合するカップ状紙容器
として、つぎの構成からなる筒状のカップ紙容器を作製
した。Separately, a cylindrical cup paper container having the following structure was manufactured as a cup-shaped paper container suitable for the lid material.
【0048】先ず、容器本体を構成する積層シートおよ
び積層シートを成形して得られる容器本体の端面露出箇
所を被覆するためのテープ状積層フィルムをポリエステ
ル樹脂系二液反応型接着剤を用いたドライラミネーショ
ン法により下記する構成で作製した。First, a laminated sheet constituting the container body and a tape-shaped laminated film for covering the exposed end face of the container body obtained by molding the laminated sheet were dried using a polyester resin-based two-component reactive adhesive. It was produced by the lamination method in the following configuration.
【0049】積層シートの層構成、〔容器外側〕CPP
フィルム(50μm厚)/PETフィルム(9μm厚)
/コート層(塗布量;15g/m2 )/カップ原紙(坪
量;295g/m2 )/PETフィルム(12μm
厚),酸化珪素蒸着薄膜(400Å)/CPPフィルム
(50μm厚)〔容器内側〕Layer structure of laminated sheet, [outside container] CPP
Film (50 μm thickness) / PET film (9 μm thickness)
/ Coat layer (coating amount: 15 g / m 2 ) / cup base paper (basis weight: 295 g / m 2 ) / PET film (12 μm
Thickness), Silicon oxide vapor deposited thin film (400mm) / CPP film (50μm thickness) [inside of container]
【0050】テープ状積層フィルムの層構成、CPPフ
ィルム(30μm厚)/PETフィルム(12μm
厚),酸化珪素蒸着薄膜(400Å)/CPPフィルム
(30μm厚)Layer structure of tape-shaped laminated film, CPP film (30 μm thick) / PET film (12 μm
Thickness), Silicon oxide vapor deposited thin film (400mm) / CPP film (30μm thickness)
【0051】積層シートおよびテープ状積層フィルムに
用いるCPPフィルムは、下記構成、物性からなるCP
Pフィルムで、蓋材成形部に用いるPP樹脂と同系統の
PP樹脂を製膜したものである。すなわち、プロピレン
−エチレンブロック共重合体、・融点;160°C、・
密度;0.90g/cm3 、・MFR;8g/10mi
n.・エチレン含有率;2.5wt%、・耐衝撃性付与
のため、エチレン−ブテン共重合体(非晶性樹脂)を添
加している。The CPP film used for the laminated sheet and the tape-shaped laminated film has the following composition and physical properties:
It is a P film formed of the same type of PP resin as the PP resin used for the lid material molding section. That is, propylene-ethylene block copolymer, melting point: 160 ° C.,
Density: 0.90 g / cm 3 , MFR: 8 g / 10 mi
n. -Ethylene content: 2.5 wt%-Ethylene-butene copolymer (amorphous resin) is added to impart impact resistance.
【0052】また、カップ原紙の水分率は5.0%であ
る。The moisture content of the cup base paper is 5.0%.
【0053】積層シートより、カップ状の容器を成形す
るため、容器の胴部11となる胴部材ブランクと、底部
13となる底部材ロールを作製した。そして、胴部材ブ
ランクの成形時に貼り合わせ部となる両端面露出部すべ
てにわたり幅10mmのテープ状積層フィルム14をイ
ンパルスシールし、紙端面露出部を被覆した。In order to form a cup-shaped container from the laminated sheet, a body member blank serving as the body 11 of the container and a bottom member roll serving as the bottom 13 were prepared. Then, the tape-shaped laminated film 14 having a width of 10 mm was impulse-sealed over all exposed portions on both end surfaces to be bonded portions when the trunk member blank was formed, thereby covering the exposed portions on the paper end surface.
【0054】この紙端面露出部をテープ状積層フィルム
で被覆した胴部材ブランクと、底部材ロールとを用いて
一般的に使用されている紙カップ成形機により外側にカ
ールした口縁部12を有する筒状のカップ状紙容器10
を成形した。加熱方式は積層シートのカップ原紙内水分
の気化に伴うブリスターの発生を防止するため、溶着部
外側のCPPフィルムを局所的に加熱圧着する方式を採
用した。なお、このカップ状紙容器の寸法は、口径:5
8.7mm、カップ内部高さ:85.6mmである。A cylinder having an edge portion 12 curled outward by a generally used paper cup molding machine using a body member blank in which the exposed portion of the paper end surface is covered with a tape-like laminated film and a bottom member roll. Cup-shaped paper container 10
Was molded. As a heating method, a method of locally heating and pressing the CPP film on the outside of the welded portion was adopted in order to prevent the generation of blisters due to vaporization of moisture in the cup base paper of the laminated sheet. The dimensions of the cup-shaped paper container are as follows:
8.7 mm, cup internal height: 85.6 mm.
【0055】また、このカップ状紙容器は、成形後、口
縁部を上下から加熱圧着して偏平に押しつぶしておく。After the molding of the cup-shaped paper container, the edge is heated and pressed from above and below to flatten and crush it.
【0056】作製した紙容器の底部のインカール内壁部
に、熱溶融したPP樹脂を射出し底部インカール環状部
材15を、また、口縁部には、外側面および下面を覆う
口縁周縁部材16を熱溶融したPP樹脂で被覆して、紙
端面の露出が全くないレトルト殺菌処理可能な紙容器を
作製した(図3参照)。容器へのPP樹脂の被覆は、容
器を前もって挿入配置した金型内に熱溶融したPP樹脂
を射出するインサート射出成形法により行った。A hot-melt PP resin is injected into the inner wall portion of the incurd at the bottom of the manufactured paper container, and the bottom incurred annular member 15 is injected into the inker. A paper container coated with hot-melt PP resin and capable of being subjected to retort sterilization treatment without any exposure of the paper end surface was produced (see FIG. 3). The container was coated with the PP resin by an insert injection molding method in which the hot-melted PP resin was injected into a mold in which the container was previously inserted and arranged.
【0057】この際用いたPP樹脂は下記する構成、物
性からなるものであった。すなわち、エチレン−プロピ
レンブロック共重合体、・融点;160°C、・密度;
0.90g/cm3 、・MFR;14g/10min.The PP resin used at this time had the following constitution and physical properties. That is, ethylene-propylene block copolymer, melting point: 160 ° C., density:
0.90 g / cm 3 , MFR: 14 g / 10 min.
【0058】こうして作製した上記紙容器に65°Cの
蒸留水を200ml充填し、開口部に同じく作製した蓋
材を被せて、容器本体の口縁周縁部材と蓋材フィルム部
とを超音波シール法により熱融着して紙容器を密封し実
施例1とした(図2参照)。The paper container thus prepared was filled with 200 ml of distilled water at 65 ° C., and the opening was covered with the same lid, and the peripheral edge member of the container body and the lid material film were ultrasonically sealed. The paper container was hermetically sealed by heat fusion according to the method described in Example 1 (see FIG. 2).
【0059】〈比較例1〉実施例1の蓋材から落とし込
み蓋材部を除いたものを、蓋材として使用した以外は実
施例1と同じ構成で、紙容器に65°Cの蒸留水を20
0ml充填し密封して比較例1の密封紙容器とした(詳
細な説明は省略する。実施例1と比較して落とし込み蓋
材部がなくなっている)。<Comparative Example 1> The same structure as in Example 1 was used except that the lid material of Example 1 except for the drop-in lid material was used as the lid material. Distilled water at 65 ° C was placed in a paper container. 20
The container was filled with 0 ml and sealed to obtain a sealed paper container of Comparative Example 1 (detailed description is omitted. The drop-off lid member is eliminated as compared with Example 1).
【0060】〈比較例2〉紙容器を構成する積層シート
のバリヤー層として酸化珪素の薄膜を蒸着したPETフ
ィルムの代わりに9μm厚のアルミニウム箔を使用した
以外は、実施例1と同じ構成、形状の紙容器と蓋材を使
用し、紙容器に65°Cの蒸留水を200ml充填し密
封して比較例2の密封紙容器とした(詳細な説明は省略
する)。Comparative Example 2 The same configuration and shape as in Example 1 except that a 9 μm-thick aluminum foil was used instead of a PET film on which a silicon oxide thin film was deposited as a barrier layer of a laminated sheet constituting a paper container. The container was filled with 200 ml of distilled water at 65 ° C. and sealed to obtain a sealed container of Comparative Example 2 (detailed description is omitted).
【0061】〈比較例3〉実施例1の蓋材の代わりに、
〔容器外側〕ONyフィルム(16μm厚)/PETフ
ィルム(12μm厚),酸化珪素蒸着薄膜(400Å)
/イージーピールPPフィルム(50μm厚)〔容器内
側〕構成からなる積層フィルムを用いた以外は実施例1
と同じ構成、形状の紙容器を使用し、紙容器に65°C
の蒸留水を200ml充填し密封して比較例2の密封紙
容器とした(詳細な説明は省略する)。<Comparative Example 3> Instead of the lid material of Example 1,
[Outside of container] ONy film (16 μm thickness) / PET film (12 μm thickness), evaporated silicon oxide thin film (400 mm)
Example 1 except that a laminated film having a structure of / Easy peel PP film (50 μm thick) [inside of container] was used.
Use a paper container of the same configuration and shape as in
Was filled and sealed to obtain a sealed paper container of Comparative Example 2 (detailed description is omitted).
【0062】〈参考例1〉容器として、実施例1と同形
状のプラスチック容器(構成はPP樹脂/エチレンビニ
ルアルコール共重合樹脂(EVOH)/PP樹脂)を使
用し、蓋材として、比較例3で使用した蓋材を使用し、
容器に65°Cの蒸留水を200ml充填し密封して参
考例1の密封容器とした(詳細な説明は省略する)。Reference Example 1 As a container, a plastic container having the same shape as in Example 1 (constitution was made of PP resin / ethylene vinyl alcohol copolymer resin (EVOH) / PP resin) was used. Use the lid material used in
The container was filled with 200 ml of 65 ° C. distilled water and sealed to obtain a sealed container of Reference Example 1 (detailed description is omitted).
【0063】以上、65°Cの蒸留水を200ml充填
し密封した4種類の紙容器と1種類のプラスチック容器
について、ホット充填後の容器変形とレトルト適性、電
子レンジ適性を以下に述べる方法に従って実験し評価し
評価した。As described above, container deformation, retort suitability, and microwave oven suitability after hot filling were tested for four types of paper containers and one type of plastic container filled with 200 ml of 65 ° C. distilled water according to the methods described below. And evaluated.
【0064】〈実験1〉ホット充填後の容器変形 65°Cの蒸留水を200ml充填し密封した実施例
1、比較例1、2、3、参考例1の5種類の容器を室温
(23°C)まで放冷した時の容器本体の変形の有無を
目視により観察した。その結果を表1に示す。表1中、
○は容器本体に変形等の形状変化がないことを示し、×
は容器本体が凹んで変形したことを示す。<Experiment 1> Deformation of container after hot filling Five containers of Example 1, Comparative Examples 1, 2, 3 and Reference Example 1, which were filled with 200 ml of distilled water at 65 ° C. and sealed, were placed at room temperature (23 ° C.). The presence or absence of deformation of the container body when allowed to cool to C) was visually observed. Table 1 shows the results. In Table 1,
○ indicates that there is no shape change such as deformation in the container body, and ×
Indicates that the container body was dented and deformed.
【0065】〈実験2〉レトルト適性(1) 室温まで下がった蒸留水200mlを充填した実施例
1、比較例2、参考例1の3種類の容器を、下記2条件
で株式会社日阪製作所製の装置を用い、含気方式のレト
ルト殺菌処理を行い、レトルト殺菌後の容器の変形の有
無を目視により観察した。その結果を表2に示す。表2
中、○は容器本体、蓋材の双方に変形等の形状変化がな
いことを示し、×は蓋材が凹んで変形したことを示す。 条件1‥‥初期温度;80°C、昇温条件;120°C 到達15分 保持条件;30分間、冷却時間;30分間 条件2‥‥初期温度;80°C、昇温条件;130°C 到達15分 保持条件;30分間、冷却時間;30分間<Experiment 2> Suitability of retort (1) Three containers of Example 1, Comparative Example 2 and Reference Example 1 filled with 200 ml of distilled water lowered to room temperature were manufactured by HISAKA CORPORATION under the following two conditions. Using the apparatus described in (1), an air-containing retort sterilization treatment was performed, and the presence or absence of deformation of the container after the retort sterilization was visually observed. Table 2 shows the results. Table 2
Among them, ○ indicates that there is no shape change such as deformation in both the container body and the lid member, and X indicates that the lid member was dented and deformed. Condition 1 ‥‥ Initial temperature; 80 ° C., temperature rising condition; 120 ° C. reached 15 minutes Holding condition: 30 minutes, cooling time; 30 minutes Condition 2 ‥‥ Initial temperature; 80 ° C., temperature rising condition; 130 ° C. Arrival 15 minutes Holding condition: 30 minutes, cooling time: 30 minutes
【0066】〈実験3〉レトルト適性(2) 実施例1、比較例2、参考例1の3種類の容器に、蒸留
水200mlの代わりに下記する酸素バリヤー検知材料
を内容物として充填し、上記2条件でレトルト殺菌処理
を行い酸素バリヤー性の有無を目視観察した。その結果
を表2に示す。 酸素バリヤー検知材料‥‥ショ糖脂肪酸エステル、寒天
粉末、水酸化ナトリウム、メチレンブルー、Dグルコー
スの混合体を熱水中で溶解したもの バリヤー性の評価方法‥‥メチレンブルーが酸素に触れ
ると青く発色することを利用し、酸素透過の程度を色相
にて評価する 表2中、○は内容液が青色に発色せず酸素バリヤー性が
有ることを示し、×は内容液全体が青色に発色して、酸
素バリヤー性が劣化していることを示す。<Experiment 3> Suitability of retort (2) The three types of containers of Example 1, Comparative Example 2, and Reference Example 1 were filled with the following oxygen barrier detecting material as a content instead of 200 ml of distilled water. A retort sterilization treatment was performed under two conditions, and the presence or absence of oxygen barrier properties was visually observed. Table 2 shows the results. Oxygen barrier detection material も の A mixture of sucrose fatty acid ester, agar powder, sodium hydroxide, methylene blue, and D-glucose dissolved in hot water. Evaluation method of barrier properties こ と Methylene blue develops a blue color when exposed to oxygen. In Table 2, ○ indicates that the content liquid does not develop blue and has oxygen barrier properties, and × indicates that the entire content liquid develops blue and oxygen Indicates that the barrier properties have deteriorated.
【0067】〈実験4〉電子レンジ適性 実験2で用いたレトルト殺菌処理後の3種類の容器を定
格電圧100V、定格周波数60Hzの一般的に用いら
れている電子レンジに下記する条件でセットし、電子レ
ンジ適性を目視により観察、評価した。その結果を表3
に示す。 電子レンジ加熱条件‥‥加熱時間 3分間 表3中、○は電子レンジによる再加熱が問題なく出来た
状態を示し、×は電子レンジによる再加熱が出来なかっ
た状態を示す。<Experiment 4> Suitability of microwave oven The three types of containers after the retort sterilization treatment used in Experiment 2 were set in a generally used microwave oven having a rated voltage of 100 V and a rated frequency of 60 Hz under the following conditions. The suitability for microwave oven was visually observed and evaluated. Table 3 shows the results.
Shown in Microwave oven heating condition ‥‥ Heating time 3 minutes In Table 3, ○ indicates a state where reheating by a microwave oven was successfully performed, and X indicates a state where reheating by a microwave oven was not performed.
【0068】[0068]
【表1】 [Table 1]
【0069】[0069]
【表2】 [Table 2]
【0070】[0070]
【表3】 [Table 3]
【0071】表1、2、3から考察すると、ヘッドスペ
ースが10ccになるようにシールフランジと天板との
高低差を8mmに設定した落とし込み蓋材部を設けた蓋
材を用いた容器は、ホット充填が可能であり、ガスバリ
ヤー性に優れている上レトルト殺菌適性と共にレトルト
殺菌後の電子レンジ適性をも有することがわかる(実施
例1)。Considering from Tables 1, 2 and 3, a container using a lid member provided with a drop-in lid member portion in which the height difference between the seal flange and the top plate is set to 8 mm so that the head space is 10 cc is as follows. It can be seen that hot filling is possible, the gas barrier property is excellent, and in addition to the retort sterilization suitability, it also has the microwave oven suitability after retort sterilization (Example 1).
【0072】[0072]
【発明の効果】本発明の紙容器用蓋材は、紙化率が高
く、廃棄性に優れている。容器の減圧状態を吸収するた
め、容器の変形が防げ、容器の外観を損なうことがな
い。The lid material for paper containers of the present invention has a high paper conversion rate and is excellent in disposability. Since the reduced pressure state of the container is absorbed, deformation of the container can be prevented, and the appearance of the container is not impaired.
【0073】また、容器内側に使用するPPフィルム
は、エチレン系オレフィン樹脂とPP樹脂の比率によ
り、接着強度を調整したブレンド樹脂で作製されている
ため、開封するとき、熱融着している蓋を容器から適宜
の接着強度をもって剥離し易い。Further, since the PP film used inside the container is made of a blended resin whose adhesive strength is adjusted by the ratio of the ethylene-based olefin resin and the PP resin, the heat-sealed lid is used when opening the container. From the container with an appropriate adhesive strength.
【0074】バリヤー性フィルムを使用しているので、
内容物保護性を有すると共に、アルミニウム箔等の金属
箔を使用していないので、レトルト殺菌処理適性のほか
に電子レンジ適性を有する。Since a barrier film is used,
Since it has content protection properties and does not use metal foil such as aluminum foil, it has microwave oven suitability as well as retort sterilization suitability.
【図1】(a)は本発明の蓋材の一実施例を示す平面説
明図であり、(b)はA−A’線断面説明図である。FIG. 1A is an explanatory plan view showing an embodiment of a lid member according to the present invention, and FIG. 1B is an explanatory sectional view taken along line AA ′.
【図2】実施例1の蓋材を紙容器に載置して密封シール
した状態を示す断面説明図である。FIG. 2 is an explanatory cross-sectional view showing a state in which the lid member of Example 1 is placed on a paper container and hermetically sealed.
【図3】実施例1で使用したレトルト殺菌処理可能な紙
容器の断面説明図である。FIG. 3 is an explanatory sectional view of a paper container capable of being subjected to a retort sterilization treatment used in Example 1.
10‥‥カップ状紙容器 11‥‥胴部 12‥‥口縁部 13‥‥底部 14‥‥テープ状積層フィルム 15‥‥底部インカール環状部材 16‥‥口縁周縁部材 20‥‥蓋材 21‥‥シールフランジ 22‥‥周壁 23‥‥天板 24‥‥落とし込み蓋材部 25‥‥蓋材フィルム部 26‥‥空間部 29‥‥開封取手部 30‥‥端面被覆部材 10 cup-shaped paper container 11 trunk 12 mouth edge 13 bottom 14 tape-shaped laminated film 15 bottom incurred annular member 16 edge margin member 20 lid 21 {Seal flange 22} Peripheral wall 23} Top plate 24} Drop-down lid part 25} Lid part film part 26} Space part 29} Opening handle part 30} End face covering member
フロントページの続き (51)Int.Cl.6 識別記号 FI B65D 81/34 B65D 81/34 U Continued on the front page (51) Int.Cl. 6 Identification code FI B65D 81/34 B65D 81/34 U
Claims (9)
が互いに偏平に熱圧着された口縁部を有するレトルト殺
菌可能なカップ状紙容器の開口部を密封する蓋材であっ
て、該蓋材が、天板と、天板の周縁に立設された、カッ
プ状紙容器の胴部内壁に密着可能な周壁と、周壁の上縁
に外方に向けて天板と平行に設けられたシールフランジ
と、からなる落とし込み蓋材部と、落とし込み蓋材部の
全体を覆い天板との間に空間部を形成させる蓋材シート
部と、蓋材シート部周縁の端面を含む三方向を覆う断面
コの字状の端面被覆部材と、から成り、シールフランジ
と端面被覆部材と端面被覆部材で被覆された蓋材シート
部周縁とが互いに熱融着され、カップ状紙容器の口縁部
に熱融着可能に載置される蓋材であって、該端面被覆部
材は、蓋材シート部を前もって挿入配置した金型内に熱
溶融したポリプロピレン樹脂を射出するインサート射出
成形法により設けたことを特徴とするレトルト殺菌処理
可能な紙容器用蓋材。1. A lid material for sealing an opening of a retort-sterilizable cup-shaped paper container having an opening part whose outer periphery curls outward and whose upper and lower layers are flatly thermocompression-bonded to each other, The lid member is provided with a top plate, a peripheral wall erected on the peripheral edge of the top plate, which can be in close contact with the inner wall of the body of the cup-shaped paper container, and provided on the upper edge of the peripheral wall outward in parallel with the top plate. Three-dimensional including a dropping lid material portion, a dropping lid material portion, a lid material sheet portion that covers the entire dropping lid material portion and forms a space between the top plate, and an end surface of the lid material sheet portion peripheral edge. A sealing flange, an end covering member, and a lid material sheet peripheral portion covered with the end covering member are thermally fused to each other, and the edge of the cup-shaped paper container is formed. A lid material that can be thermally fused to the part, wherein the end surface covering member is a lid material sheet. Previously inserted and arranged the retort sterilization can be paper container lid, characterized in that provided by insert injection molding method of injecting a hot molten polypropylene resin in the mold.
開口部に被せた際、部分的に口縁部より外方に突出した
開封取手部が形成されていることを特徴とする請求項1
記載のレトルト殺菌処理可能な紙容器用蓋材。2. An opening handle portion is formed on a peripheral edge of the end surface covering member so as to partially protrude outward from an edge portion when a lid material is put on a paper container opening. Claim 1
A cover material for a paper container which can be subjected to the retort sterilization treatment according to the above.
ロピレン(PP)フィルム、板紙、バリヤー性フィル
ム、PPフィルムの順序で積層される少なくとも4層構
成からなる積層シートであることを特徴とする請求項1
または2記載のレトルト殺菌処理可能な紙容器用蓋材。3. The lid sheet section is a laminated sheet having at least a four-layer structure in which a polypropylene (PP) film, a paperboard, a barrier film, and a PP film are laminated in this order from the outside of the container. Claim 1
Or a cover material for a paper container which can be subjected to a retort sterilization treatment according to item 2.
フィルムは、融点が150°C以上のPP系樹脂を製膜
して得られることを特徴とする請求項1、2または3記
載のレトルト殺菌処理可能な紙容器用蓋材。4. A PP used on the inner and outer surfaces of the cover sheet portion.
The retort sterilizable paper container lid according to claim 1, wherein the film is obtained by forming a PP resin having a melting point of 150 ° C or more.
ィルムが、無機化合物蒸着薄膜を形成したフィルム、金
属化合物蒸着薄膜を形成したフィルム、またはバリヤー
性プラスチックフィルムのいずれかであることを特徴と
する請求項1、2、3または4記載のレトルト殺菌処理
可能な紙容器用蓋材。5. A method according to claim 1, wherein the barrier film constituting the cover sheet portion is any one of a film formed with an inorganic compound vapor-deposited thin film, a film formed with a metal compound vapor-deposited thin film, and a barrier plastic film. The lid material for a paper container capable of being subjected to a retort sterilization treatment according to claim 1, 2, 3, or 4.
表面に珪藻土からなるコート層が10〜18g/m2 塗
布されている板紙であることを特徴とする請求項1、
2、3、4または5記載のレトルト殺菌処理可能な紙容
器用蓋材。6. The paperboard constituting the lid material sheet portion, wherein the paperboard surface is coated with a diatomaceous earth coat layer of 10 to 18 g / m 2 .
6. A lid material for a paper container which can be subjected to a retort sterilization treatment according to 2, 3, 4 or 5.
シート部との接合面にPP樹脂を用いた単層構成または
2層構成以上の熱可塑性樹脂フィルムからなり、かつ、
使用する全ての熱可塑性樹脂フィルムの融点が140°
C以上であることを特徴とする請求項1、2、3、4、
5または6記載のレトルト殺菌処理可能な紙容器用蓋
材。7. The dropping cover part is made of a thermoplastic resin film having a single-layer structure or a two-layer structure or more using PP resin at least on a joint surface with the cover material sheet part, and
The melting point of all thermoplastic resin films used is 140 °
C, or more, 1, 2, 3, 4,
7. A lid material for a paper container which can be subjected to a retort sterilization treatment according to 5 or 6.
脂であって、端面被覆部材に使用するPP樹脂は、PP
樹脂と低密度ポリエチレン(LDPE)樹脂またはPP
樹脂とエチレン−ブテン共重合体樹脂をそれぞれブレン
ドした樹脂であることを特徴とする請求項1、2、3、
4、5、6または7記載のレトルト殺菌処理可能な紙容
器用蓋材。8. The PP resin used for the insert injection molding method, wherein the PP resin used for the end face covering member is PP resin.
Resin and low density polyethylene (LDPE) resin or PP
A resin blended with a resin and an ethylene-butene copolymer resin, respectively.
4. A lid material for a paper container which can be subjected to a retort sterilization treatment according to 4, 5, 6 or 7.
脂とエチレン−ブテン共重合体樹脂とのブレンド比率
は、それぞれ100/10〜100/30であることを
特徴とする請求項1、2、3、4、5、6、7または8
記載のレトルト殺菌処理可能な紙容器用蓋材。9. The blend ratio of the PP resin and the LDPE resin or the PP resin and the ethylene-butene copolymer resin is 100/10 to 100/30, respectively. 4, 5, 6, 7, or 8
A cover material for a paper container which can be subjected to the retort sterilization treatment according to the above.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10097944A JPH11292116A (en) | 1998-04-09 | 1998-04-09 | Retort-sterilizable paper container lid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10097944A JPH11292116A (en) | 1998-04-09 | 1998-04-09 | Retort-sterilizable paper container lid |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH11292116A true JPH11292116A (en) | 1999-10-26 |
Family
ID=14205791
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10097944A Pending JPH11292116A (en) | 1998-04-09 | 1998-04-09 | Retort-sterilizable paper container lid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH11292116A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100805799B1 (en) | 2005-09-01 | 2008-02-21 | 권석웅 | Container lid with paper cover surface and apparatus for manufacturing same |
WO2008071838A1 (en) | 2006-12-12 | 2008-06-19 | Stora Enso Oyj | A cover of a package, a method for manufacturing the same and a package sealed with a cover and a method for sealing a package |
CN110844308A (en) * | 2019-12-19 | 2020-02-28 | 瑞安市贝斯特机械有限公司 | Anti-leakage paper cover |
-
1998
- 1998-04-09 JP JP10097944A patent/JPH11292116A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100805799B1 (en) | 2005-09-01 | 2008-02-21 | 권석웅 | Container lid with paper cover surface and apparatus for manufacturing same |
WO2008071838A1 (en) | 2006-12-12 | 2008-06-19 | Stora Enso Oyj | A cover of a package, a method for manufacturing the same and a package sealed with a cover and a method for sealing a package |
EP2097334A1 (en) * | 2006-12-12 | 2009-09-09 | Stora Enso Oyj | A cover of a package, a method for manufacturing the same and a package sealed with a cover and a method for sealing a package |
EP2097334A4 (en) * | 2006-12-12 | 2012-07-04 | Stora Enso Oyj | A cover of a package, a method for manufacturing the same and a package sealed with a cover and a method for sealing a package |
US8701922B2 (en) | 2006-12-12 | 2014-04-22 | Stora Enso Oyj | Cover of a package, a method for manufacturing the same and a package sealed with a cover and a method for sealing a package |
CN110844308A (en) * | 2019-12-19 | 2020-02-28 | 瑞安市贝斯特机械有限公司 | Anti-leakage paper cover |
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