JPH11172359A - Screw made of high strength aluminum alloy and its production - Google Patents

Screw made of high strength aluminum alloy and its production

Info

Publication number
JPH11172359A
JPH11172359A JP9341780A JP34178097A JPH11172359A JP H11172359 A JPH11172359 A JP H11172359A JP 9341780 A JP9341780 A JP 9341780A JP 34178097 A JP34178097 A JP 34178097A JP H11172359 A JPH11172359 A JP H11172359A
Authority
JP
Japan
Prior art keywords
screw
strength
aluminum alloy
wire
subjected
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9341780A
Other languages
Japanese (ja)
Other versions
JP3939414B2 (en
Inventor
Tomiharu Okita
富晴 沖田
Akira Hideno
晃 秀野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Furukawa Electric Co Ltd
Original Assignee
Furukawa Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Furukawa Electric Co Ltd filed Critical Furukawa Electric Co Ltd
Priority to JP34178097A priority Critical patent/JP3939414B2/en
Publication of JPH11172359A publication Critical patent/JPH11172359A/en
Application granted granted Critical
Publication of JP3939414B2 publication Critical patent/JP3939414B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21KMAKING FORGED OR PRESSED METAL PRODUCTS, e.g. HORSE-SHOES, RIVETS, BOLTS OR WHEELS
    • B21K1/00Making machine elements
    • B21K1/44Making machine elements bolts, studs, or the like
    • B21K1/46Making machine elements bolts, studs, or the like with heads
    • B21K1/463Making machine elements bolts, studs, or the like with heads with recessed heads

Abstract

PROBLEM TO BE SOLVED: To produce a screw (bolt) made of an aluminum alloy in which the length of crystal grains in the longitudinal direction is regulated to <=100 μm, tensile strength regulated to <=350 N/mm<2> , proof stress is regulated to <=300 N/mm<2> , elongation is regulated to >=6%, and torsional strength is regulated to the value higher than that of AL3 (A6061-T6) by >=10%. SOLUTION: An aluminum alloy contg., by weight, 0.5 to 1.5% Mg, 0.5 to 1.5% Si, 0.5 to l.5% Cu, 0.2 to 0.5% Mn, 0.005 to 0.l% Ti, 0.001 to 0.05% B and 0.05 to 0.25% Zr, and the balance aluminum with inevitable impurities is melted to cast, the obtd. ingot is subjected to homogenizing treatment and is next worked into an wire element 1 for a screw by an extrusion method, a reduction method or a rolling method while annealing is suitably executed, the working ratio after final annealing in this wire element for a screw is regulated to >=40%, then, the wire element for a screw is annealed at a prescribed temp. and is formed into a screw 7, and this screw formed body is subjected to solution treatment, is thereafter rapidly cooled and is then subjected to artificial age hardening treatment.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、高強度の6000
系アルミニウム合金製ねじおよびその製造方法に関す
る。
TECHNICAL FIELD The present invention relates to a high-strength 6000
The present invention relates to a system-based aluminum alloy screw and a method for manufacturing the same.

【0002】[0002]

【従来の技術】アルミニウム合金製構造物の組立てに用
いる鋼製ねじ(ボルトを含む、以下ねじで代表する)
は、強度的には問題ないが、腐食環境では電食が起きる
ためZnまたはNiをめっきして用いられる。しかしめ
っきが剥がれたり或いは腐食環境が特に悪いときは電食
を防止することができない。鋼製のねじについてはJI
S−B−1051-1991 「鋼製ボルト・小ねじの機械的
性質」で規格されている。ステンレス製ねじはアルミニ
ウム合金と相性が良く電食し難いので、A6063合金
の窓用サッシを始めとする多くのアルミニウム合金製構
造物に用いられている。ステンレス製ねじについてはJ
IS−B−1054-1985 「ステンレス鋼製耐食ねじ部
品の機械的性質」で規格されている。
2. Description of the Related Art Steel screws used for assembling aluminum alloy structures (including bolts, hereinafter represented by screws)
Although there is no problem in strength, it is used by plating Zn or Ni because electrolytic corrosion occurs in a corrosive environment. However, when the plating is peeled off or the corrosive environment is particularly bad, electrolytic corrosion cannot be prevented. JI for steel screws
SB - 1051-1991 Standardized in "Mechanical Properties of Steel Bolts and Machine Screws". Stainless steel screws are compatible with aluminum alloys and are not easily eroded, so they are used in many aluminum alloy structures such as A6063 alloy window sashes. J for stainless steel screws
IS-B-1054 -1985 Standardized in "Mechanical properties of stainless steel corrosion-resistant screw parts".

【0003】ところで、近年、地球資源の有効活用、省
エネルギー、環境の清浄化等の観点から、材料のリサイ
クルが強く叫ばれている。アルミニウムは、原料のボー
キサイトを精錬し地金にするには莫大な電気エネルギー
を要するが、アルミニウムは低融点のためアルミスクラ
ップの再溶解にはそれほどエネルギーを要さずリサイク
ル効果が大きい。しかし、アルミニウム合金製構造物の
スクラップは、そのまま再溶解すると鋼製またはステン
レス製ねじが溶解するため、得られるアルミニウム合金
の純度が低下する。ねじを外して再溶解するのは手間を
要しリサイクル効果が半減する。
[0003] In recent years, there has been a strong demand for material recycling from the viewpoints of effective use of earth resources, energy saving, and environmental cleanup. Aluminum requires an enormous amount of electrical energy to refine the raw material bauxite into bullion, but since aluminum has a low melting point, re-melting aluminum scrap does not require much energy and has a large recycling effect. However, if the scrap of the aluminum alloy structure is redissolved as it is, the steel or stainless steel screw is melted, and the purity of the obtained aluminum alloy is reduced. Removing the screws and re-melting is time-consuming and reduces the recycling effect by half.

【0004】前記再溶解による純度低下の問題はアルミ
ニウム合金製ねじを用いることにより解決でき、現にア
ルミニウム合金製ねじは市販されている。リサイクルの
点からは、例えば、A6063合金製窓用サッシには、
同じ6000系合金のねじを使用することが望ましい。
アルミニウム合金製ねじについてはJIS−B−105
-1989 「非鉄金属製ねじ部品の機械的性質」で規格さ
れている。
[0004] The problem of the decrease in purity due to the re-melting can be solved by using aluminum alloy screws, and aluminum alloy screws are currently commercially available. In terms of recycling, for example, A6063 alloy window sashes
It is desirable to use screws of the same 6000 series alloy.
JIS-B-105 for aluminum alloy screws
7-1989 Standardized in "Mechanical properties of non-ferrous metal screw parts".

【0005】一方、自動車産業では省エネルギーや環境
清浄化に対して努力が続けられ、その最も有力な対策
は、車体をアルミ化して軽くすることに落ち着きつつあ
る。アルミ車体の構造は、プレス加工板に強度メンバー
を兼用させた従来のモノコック式から、骨となる形材に
ボディーを載せるスペースフレーム式が検討されてい
る。前記形材には高強度で押出性にも優れるJIS−A
6000系合金が採用される公算が高い。形材とボディ
の接合には、従来の抵抗スポット溶接に代わって信頼性
が高く省エネ的なねじを用いた機械的接合が大々的に採
用される見通しである。アルミ車体の自動車にもリサイ
クル性が要求され、そこには当然アルミ合金製ねじが使
用され、その合金には形材と同じ6000系合金が望ま
しい。
On the other hand, in the automobile industry, efforts are being made to save energy and clean the environment, and the most influential measure is to reduce the weight of the vehicle body to aluminum to make it lighter. Regarding the structure of the aluminum body, a space frame type in which the body is mounted on a shape member serving as a bone is being studied from a conventional monocoque type in which a strength member is also used as a pressed plate. JIS-A which has high strength and excellent extrudability
It is likely that a 6000 series alloy will be used. It is expected that mechanical joints using reliable and energy-saving screws will be used extensively to replace the conventional resistance spot welding for joining sections and bodies. Recyclability is also required for automobiles having an aluminum body, and naturally aluminum alloy screws are used, and the alloy is desirably the same 6000 series alloy as the profile.

【0006】ところで、JIS−B−1057
-1989 「非鉄金属製ねじ部品の機械的性質」には、アル
ミニウム合金製ねじとして、AL1(A5052)、A
L2(A5056)、AL3(A6061)、AL4
(A2024)、AL5(7N01)、AL6(A70
75)の6種類が規格化されている。ねじ(ボルトを含
む)の規格を表1に示す。
Incidentally, JIS-B-1057
-1989 "Mechanical properties of non-ferrous metal threaded parts" includes AL1 (A5052), A1
L2 (A5056), AL3 (A6061), AL4
(A2024), AL5 (7N01), AL6 (A70
75) are standardized. Table 1 shows the specifications of screws (including bolts).

【0007】[0007]

【表1】 (注)M4のねじり強さ、単位:N・M。ねじり強さは各ねじ径ごとに規定 されている。[Table 1] (Note) Torsion strength of M4, unit: NM. The torsional strength is specified for each screw diameter.

【0008】次に、前記ねじの従来の製造工程を示す。 (1)AL1(A5052)……鋳造→均質化処理→押出→抽伸→素線→ →H16材→切削加工→完成 →O材→ヘッダー加工、ねじ転造加工(H16)→完成 (2)AL2(A5056)……鋳造→均質化処理→押出→抽伸→素線→ →H16材→切削加工→完成 →O材→ヘッダー加工、ねじ転造加工(H16)→完成 (3)AL3(A6061)……鋳造→均質化処理→押出→抽伸→素線→ →T6処理→切削加工→完成 →O材→ヘッダー加工、ねじ転造加工→T6処理→完成 (4)AL4(A2024)……鋳造→均質化処理→押出→抽伸→素線→ →T4処理→切削加工→完成 →O材→ヘッダー加工、ねじ転造加工→T4処理→完成 (5)AL5(A7N01)……鋳造→均質化処理→押出→抽伸→素線→ →T6処理→切削加工→完成 →O材→ヘッダー加工、ねじ転造加工→T6処理→完成 (6)AL6(A7075)……鋳造→均質化処理→押出→抽伸→素線→ →T6処理→切削加工→完成 →O材→ヘッダー加工、ねじ転造加工→T6処理→完成Next, a conventional manufacturing process of the screw will be described. (1) AL1 (A5052) ... Casting → homogenization → extrusion → drawing → strand → → H16 material → cutting → completed → O material → header processing, thread rolling (H16) → completed (2) AL2 (A5056) …… Casting → homogenization processing → extrusion → drawing → element wire →→ H16 material → cutting → completed → O material → header processing, thread rolling (H16) → completed (3) AL3 (A6061)… … Casting → Homogenization → Extrusion → Drawing → Wire → → T6 processing → Cutting → Finishing → O material → Header processing, thread rolling → T6 processing → Completed (4) AL4 (A2024) …… Casting → Homogeneous Processing → Extrusion → Drawing → Wire → → T4 processing → Cutting → Completed → O material → Header processing, thread rolling → T4 processing → Completed (5) AL5 (A7N01) …… Casting → Homogenization processing → Extrusion → Drawing → Element wire →→ T6 processing → Cutting → Completion → O material → Header Work, thread rolling → T6 processing → completion (6) AL6 (A7075) …… Casting → homogenization processing → extrusion → drawing → wire → → T6 processing → cutting → completion → O material → header processing, screw rolling Manufacturing → T6 treatment → Completion

【0009】[0009]

【発明が解決しようとする課題】前記工程で作製した従
来のねじを窓用サッシや自動車に用いる場合の問題点は
次の通りである。 (1)AL1(A5052)は6000系合金ではないの
でリサイクル性に劣る。切削加工材は強度が低く(30
0N/mm2 以下)、加工コストが高い。ヘッダー加工
・ねじ転造加工材は強度が低い(300N/mm2
下)。 (2)AL2(5056)は6000系でないのでリサイ
クル性に劣る。切削加工材はコストが高い。ヘッダー加
工・ねじ転造加工材は加工性が悪いので加工中に割れ易
い。 (3)AL3(A6061)については、切削加工材は加
工コストが高い。ヘッダー加工・ねじ転造加工材は加工
性が悪く加工中に割れ易い。 (4)AL4(A2024)は6000系でないのでリサ
イクル性に劣る。また腐食し易い。切削加工材は加工コ
ストが高い。ヘッダー加工・ねじ転造加工材は加工性が
悪く加工中に割れ易い。 (5)AL5(A7N01)は6000系でないのでリサ
イクル性に劣る。また腐食し易い。切削加工材は加工コ
ストが高い。ヘッダー加工・ねじ転造加工材は加工性が
悪く加工中に割れ易い。 (6)AL6(A7075)は6000系でないのでリサ
イクル性に劣る。また腐食し易い。切削加工材は加工コ
ストが高い。ヘッダー加工・ねじ転造加工材は加工性が
悪く加工中に割れ易い。
Problems when the conventional screw produced in the above process is used for a window sash or an automobile are as follows. (1) Since AL1 (A5052) is not a 6000 series alloy, it has poor recyclability. The cutting material has low strength (30
0 N / mm 2 or less), and the processing cost is high. Header processed and thread rolled materials have low strength (300 N / mm 2 or less). (2) AL2 (5056) is inferior in recyclability because it is not 6000 type. Cutting materials are expensive. Since the header processed and thread rolled materials have poor workability, they are easily broken during processing. (3) With regard to AL3 (A6061), the processing cost of the cutting material is high. Header processed and thread rolled materials have poor workability and are easily cracked during processing. (4) AL4 (A2024) is inferior in recyclability because it is not 6000 type. Moreover, it is easily corroded. Cutting materials have high processing costs. Header processed and thread rolled materials have poor workability and are easily cracked during processing. (5) Since AL5 (A7N01) is not a 6000 series, it has poor recyclability. Moreover, it is easily corroded. Cutting materials have high processing costs. Header processed and thread rolled materials have poor workability and are easily cracked during processing. (6) AL6 (A7075) is inferior in recyclability because it is not 6000 type. Moreover, it is easily corroded. Cutting materials have high processing costs. Header processed and thread rolled materials have poor workability and are easily cracked during processing.

【0010】前記ねじ規格の中に6000系合金を求め
るとAL3がある。AL3(A6061−T6)は、引
張強さ320N/mm2 、耐力250N/mm2 、伸び
7%、ねじり強さ(M4)1.4N・mが規格値であ
る。自動車の組立構造に用いられるねじには、引張強さ
350N/mm2 以上、耐力300N/mm2 以上、伸
び6%以上が要求され、ねじり強さは従来のボルト・ナ
ット式からタッピングねじ式に移行する傾向が見られる
ためAL3の規格値の10%以上高い値が望まれてい
る。さらに、錆びないこと、低コストなことも望まれ
る。本発明は、引張強さ350N/mm2 以上、耐力3
00N/mm2 以上、伸び6%以上、ねじり強さがAL
3規格値の10%以上高く、自動車の組立構造に十分耐
える機械的性質を有し、しかも錆び難く、低コストの高
強度アルミニウム合金製ねじの提供を目的とする。
[0010] When a 6000 series alloy is required in the thread standard, there is AL3. AL3 (A6061-T6), the tensile strength of 320N / mm 2, yield strength 250 N / mm 2, elongation of 7%, the torsional strength (M4) 1.4N · m is standard value. Screws used in the assembly structure of automobiles are required to have a tensile strength of 350 N / mm 2 or more, a proof stress of 300 N / mm 2 or more, and an elongation of 6% or more. The torsional strength is changed from the conventional bolt and nut type to tapping screw type. Since there is a tendency to shift, a value higher than the standard value of AL3 by 10% or more is desired. Furthermore, it is also desired that they do not rust and that they are low in cost. The present invention has a tensile strength of 350 N / mm 2 or more and a proof stress of 3
00N / mm 2 or more, elongation 6% or more, torsional strength is AL
(3) It is an object of the present invention to provide a low-cost, high-strength aluminum alloy screw which is 10% or more of the standard value, has mechanical properties enough to withstand the assembly structure of an automobile, is hardly rusted, and is low in cost.

【0011】[0011]

【課題を解決するための手段】請求項1記載の発明は、
Mg:0.5〜1.5wt%、Si:0.5〜1.5wt
%、Cu:0.5〜1.5wt%、Mn:0.2〜0.5
wt%、Ti:0.005〜0.1wt%、B:0.001
〜0.05wt%、Zr:0.05〜0.25wt%を含有
し、残部アルミニウムおよび不可避不純物からなること
を特徴とする高強度アルミニウム合金製ねじである。
According to the first aspect of the present invention,
Mg: 0.5 to 1.5 wt%, Si: 0.5 to 1.5 wt%
%, Cu: 0.5 to 1.5 wt%, Mn: 0.2 to 0.5
wt%, Ti: 0.005 to 0.1 wt%, B: 0.001
It is a high-strength aluminum alloy screw containing -0.05 wt% and Zr: 0.05-0.25 wt%, the balance being aluminum and unavoidable impurities.

【0012】請求項2記載の発明は、Mg:0.5〜
1.5wt%、Si:0.5〜1.5wt%、Cu:0.5
〜1.5wt%、Mn:0.2〜0.5wt%、Ti:0.
005〜0.1wt%、B:0.001〜0.05wt%、
Zr:0.05〜0.25wt%を含有し、かつ、Sc、
希土類元素、Vのうち少なくとも1種を含み、それぞれ
を単独で添加する場合は、Sc:0.05〜1wt%、希
土類元素:0.05〜1wt%、V:0.05〜0.5wt
%とし、2種類以上を同時に添加する場合は、それぞれ
の添加量の総和が0.05〜0.7wt%とし、残部アル
ミニウムおよび不可避不純物からなることを特徴とする
高強度アルミニウム合金製ねじである。
The invention according to claim 2 is characterized in that Mg: 0.5 to
1.5 wt%, Si: 0.5 to 1.5 wt%, Cu: 0.5
-1.5 wt%, Mn: 0.2-0.5 wt%, Ti: 0.
005 to 0.1 wt%, B: 0.001 to 0.05 wt%,
Zr: contains 0.05 to 0.25 wt%, and contains Sc,
When at least one of the rare earth element and V is contained and each is added alone, Sc: 0.05 to 1 wt%, rare earth element: 0.05 to 1 wt%, V: 0.05 to 0.5 wt%
%, And when two or more kinds are added simultaneously, the total amount of the respective additions is 0.05 to 0.7 wt%, and the balance is aluminum and unavoidable impurities. .

【0013】請求項3記載の発明は、Mg:0.5〜
1.5wt%、Si:0.5〜1.5wt%、Cu:0.5
〜1.5wt%、Mn:0.2〜0.5wt%、Ti:0.
005〜0.1wt%、B:0.001〜0.05wt%、
Zr:0.05〜0.25wt%を含有し、残部アルミニ
ウムおよび不可避不純物からなるアルミニウム合金を溶
解、鋳造し、得られる鋳塊を均質化処理し、次いで、適
宜焼鈍を入れながら、押出法、抽伸法、または圧延法の
いずれかによりねじ用素線に加工し、このねじ用素線の
最終焼鈍後の加工率を40%以上とし、次いでこのねじ
用素線を所定温度で焼鈍したのち、前記素線をねじに成
形し、このねじ成形体を溶体化処理後急冷し、次いで人
工時効硬化処理を行って、長手方向の結晶粒長さを20
0μm以下、引張強さを350N/mm2 以上、耐力を
300N/mm2 以上、伸びを6%以上、ねじり強さを
JIS−B−1057-1989 のAL3(A6061−T
6)のねじ強さより10%以上高い値にすることを特徴
とする高強度アルミニウム合金製ねじの製造方法であ
る。
The invention according to claim 3 is characterized in that Mg: 0.5 to
1.5 wt%, Si: 0.5 to 1.5 wt%, Cu: 0.5
-1.5 wt%, Mn: 0.2-0.5 wt%, Ti: 0.
005 to 0.1 wt%, B: 0.001 to 0.05 wt%,
An aluminum alloy containing 0.05 to 0.25 wt% of Zr, the balance being aluminum and unavoidable impurities is melted and cast, and the obtained ingot is homogenized. After being processed into a thread for a screw by either a drawing method or a rolling method, the working rate after final annealing of the thread for a screw is set to 40% or more, and then the wire for a screw is annealed at a predetermined temperature, The wire is formed into a screw, the screw formed body is solution-treated, rapidly cooled, and then subjected to artificial age hardening to reduce the length of crystal grains in the longitudinal direction to 20 mm.
0 μm or less, tensile strength of 350 N / mm 2 or more, proof strength of 300 N / mm 2 or more, elongation of 6% or more, and torsional strength of AL3 (A6061-T) of JIS-B- 1057-1989.
A method for manufacturing a high-strength aluminum alloy screw, characterized in that the screw strength is set to a value 10% or more higher than the screw strength of 6).

【0014】請求項4記載の発明は、Mg:0.5〜
1.5wt%、Si:0.5〜1.5wt%、Cu:0.5
〜1.5wt%、Mn:0.2〜0.5wt%、Ti:0.
005〜0.1wt%、B:0.001〜0.05wt%、
Zr:0.05〜0.25wt%を含有し、かつ、Sc、
希土類元素、Vのうち少なくとも1種を含み、それぞれ
を単独で添加する場合は、Sc:0.05〜1wt%、希
土類元素:0.05〜1wt%、V:0.05〜0.5wt
%とし、2種類以上を同時に添加する場合は、それぞれ
の添加量の総和が0.05〜0.7wt%とし、残部アル
ミニウムおよび不可避不純物からなるアルミニウム合金
を溶解、鋳造し、得られる鋳塊を均質化処理し、次い
で、適宜焼鈍を入れながら、押出法、抽伸法、または圧
延法のいずれかによりねじ用素線に加工し、このねじ用
素線の最終焼鈍後の加工率を40%以上とし、次いでこ
のねじ用素線を所定温度で焼鈍したのち、前記素線をね
じに成形し、このねじ成形体を溶体化処理後急冷し、次
いで人工時効硬化処理を行って、長手方向の結晶粒長さ
を200μm以下、引張強さを350N/mm2 以上、
耐力を300N/mm2 以上、伸びを6%以上、ねじり
強さをJIS−B−1057-1989 のAL3(A606
1−T6)のねじ強さより10%以上高い値にすること
を特徴とする高強度アルミニウム合金製ねじの製造方法
である。
The invention according to claim 4 is characterized in that Mg: 0.5 to
1.5 wt%, Si: 0.5 to 1.5 wt%, Cu: 0.5
-1.5 wt%, Mn: 0.2-0.5 wt%, Ti: 0.
005 to 0.1 wt%, B: 0.001 to 0.05 wt%,
Zr: contains 0.05 to 0.25 wt%, and contains Sc,
When at least one of the rare earth element and V is contained and each is added alone, Sc: 0.05 to 1 wt%, rare earth element: 0.05 to 1 wt%, V: 0.05 to 0.5 wt%
%, And when two or more kinds are added at the same time, the total of the respective addition amounts is 0.05 to 0.7 wt%, and the aluminum alloy consisting of the remaining aluminum and unavoidable impurities is melted and cast, and the obtained ingot is cast. Homogenization treatment and then, while appropriately annealing, are processed into a thread for screw by any one of extrusion method, drawing method, or rolling method, and the working rate of the screw wire after final annealing is 40% or more. Then, after annealing the element wire for a screw at a predetermined temperature, the element wire is formed into a screw, the screw formed body is subjected to a solution treatment, quenched, and then subjected to an artificial age hardening treatment to obtain a longitudinal crystal. The grain length is 200 μm or less, the tensile strength is 350 N / mm 2 or more,
Strength of 300N / mm 2 or more, elongation of 6% or more, the torsional strength of the JIS-B-1057 -1989 AL3 ( A606
1-T6) A method for producing a high-strength aluminum alloy screw, wherein the screw strength is set to a value higher than the screw strength by 10% or more.

【0015】[0015]

【発明の実施の形態】本発明において、MgとSiは本
発明ねじの主要構成元素で、強度向上に寄与する。Mg
とSiが共存するときは、焼入れおよび人工時効硬化処
理によってMg2 Siが析出して強度が向上する。本発
明において、Mgを0.5〜1.5wt%、Siを0.5
〜1.5wt%にそれぞれ規定する理由は、いずれが0.
5wt%未満でもその強度が十分向上せず、またいずれが
1.5wt%を超えても引張特性、ねじり強さ、ヘッダー
加工性、および転造加工性が低下するためである。
BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, Mg and Si are the main constituent elements of the screw of the present invention and contribute to the improvement of strength. Mg
When Si and Si coexist, Mg 2 Si is precipitated by quenching and artificial age hardening, and the strength is improved. In the present invention, 0.5 to 1.5 wt% of Mg, 0.5
The reason for specifying each in the range of .about.1.5 wt% is 0.1.
If the amount is less than 5% by weight, the strength is not sufficiently improved, and if the amount exceeds 1.5% by weight, tensile properties, torsional strength, header workability, and rolling workability are reduced.

【0016】Cuは、Mg、Siと共に強度向上に寄与
する。その含有量を0.5〜1.5wt%に規定する理由
は、0.5%未満ではその効果が十分に得られず、1.
5wt%を超えると、引張特性、ねじり強さ、ヘッダー加
工性、転造加工性、耐蝕性が低下するためである。
Cu contributes to strength improvement together with Mg and Si. The reason for defining the content to be 0.5 to 1.5 wt% is that if the content is less than 0.5%, the effect cannot be sufficiently obtained.
If the content exceeds 5% by weight, the tensile properties, torsional strength, header workability, rolling workability, and corrosion resistance decrease.

【0017】Mnは一部マトリックスに固溶して強度向
上に寄与する。また不純物として含有されるAl−Fe
系化合物と結合してAl−Fe−Mn系のロッド状化合
物を形成しヘッダー加工性および転造加工性の向上に寄
与する。さらにMnはMg2Siの析出を促進する。M
nは0.2wt%未満ではその効果が十分に得られず、
1.5wt%を超えると巨大な介在物が生成して、引張特
性、ねじり強さ、ヘッダー加工性、および転造加工性が
低下する。従ってMnは0.2〜0.5wt%含有させ
る。
Mn partially forms a solid solution in the matrix and contributes to improvement in strength. Al-Fe contained as impurities
The Al-Fe-Mn-based rod-like compound is formed by combining with the base compound, and contributes to the improvement of the header workability and the rolling workability. Further, Mn promotes the precipitation of Mg 2 Si. M
If n is less than 0.2 wt%, the effect cannot be sufficiently obtained.
If it exceeds 1.5 wt%, huge inclusions are formed, and the tensile properties, torsional strength, header workability, and rolling workability decrease. Therefore, Mn is contained in an amount of 0.2 to 0.5% by weight.

【0018】Tiまたは/およびBは鋳造割れ性を改善
し、またヘッダー加工性および転造加工性を向上させ
る。Tiが0.005wt%未満、或いはBが0.001
wt%未満ではその効果が十分に得られず、Tiが0.1
wt%を超え、或いはBが0.05wt%を超えると粗大な
介在物が生成して引張特性、ねじり強さ、ヘッダー加工
性、および転造加工性が低下する。従って、Tiは0.
005〜0.1wt%、Bは0.001〜0.05wt%含
有させる。
[0018] Ti and / or B improves cast cracking properties, and also improves header workability and roll workability. Ti is less than 0.005 wt% or B is 0.001
If the content is less than 0.1 wt%, the effect cannot be sufficiently obtained.
If the content of B exceeds 0.05% by weight or B exceeds 0.05% by weight, coarse inclusions are formed and the tensile properties, torsional strength, header workability, and rolling workability decrease. Therefore, Ti is set to 0.
005 to 0.1 wt%, and B is 0.001 to 0.05 wt%.

【0019】Zrは熱処理時の結晶粒の粗大化を防止
し、特にヘッダー加工性および転造加工性を向上させ
る。Zrの含有量は、0.05wt%未満ではその効果が
十分に得られず、0.25wt%を超えると粗大な介在物
が生成して、引張特性、ねじり強さ、ヘッダー加工性、
および転造加工性が低下する。
Zr prevents coarsening of crystal grains during heat treatment, and particularly enhances header workability and roll workability. If the content of Zr is less than 0.05 wt%, the effect cannot be sufficiently obtained, and if it exceeds 0.25 wt%, coarse inclusions are formed, and tensile properties, torsional strength, header workability,
And rolling workability falls.

【0020】Sc、希土類元素、Vは、いずれも結晶組
織の微細化を助長し、また引張強さ、ねじり強さ、ヘッ
ダー加工性、転造加工性を改善する。Sc、希土類元
素、Vを単独で用いる場合は、それぞれ、0.05wt%
未満ではその効果が十分に得られず、Sc、希土類元素
の含有量が1wt%を超えると、またVの含有量が0.5
wt%を超えると粗大介在物が生成し、引張特性、ねじり
強さ、ヘッダー加工性、および転造加工性が低下する。
Sc、希土類元素、Vのうちの2以上を含有させる場合
は、各含有量(wt%)の和が0.05wt%未満ではその
効果が十分に得られず、Sc、希土類元素、Vの含有量
の和が0.7wt%を超えると粗大介在物が生成して、引
張特性、ねじり強さ、ヘッダー加工性、および転造加工
性が低下する。
Sc, rare earth elements, and V all contribute to the refinement of the crystal structure, and also improve the tensile strength, torsional strength, header workability, and roll workability. When Sc, a rare earth element, and V are used alone, 0.05 wt%
If the content is less than 1 wt%, the content of V is 0.5% or less.
If the content exceeds wt%, coarse inclusions are formed, and the tensile properties, torsional strength, header workability, and rolling workability decrease.
When two or more of Sc, rare earth element, and V are contained, the effect cannot be sufficiently obtained if the sum of the respective contents (wt%) is less than 0.05 wt%. If the sum of the amounts exceeds 0.7 wt%, coarse inclusions are formed, and the tensile properties, torsional strength, header workability, and rolling workability decrease.

【0021】希土類元素としては、La、Ce、Pr、
Nd、Sm等のうち1種又は2種以上用いることがで
き、これらのうちいずれか1種の含有量、あるいは2種
以上の合計の含有量が0.05〜1wt%の範囲であれば
良い。前記諸元素のうちの2種以上を含む合金として、
例えば、Ce、Laを主成分とするミッシュメタル(通
常、Ce45〜50wt%、La20〜40wt%、残部そ
の他の希土類元素(Pr、Nd、Sm等)と不可避不純
物からなる)がある。前記の各希土類元素やミッシュメ
タルは、いずれも同等の効果を示すが、価格的には、ミ
ッシュメタルの方が希土類元素単体より安く有利であ
る。
As rare earth elements, La, Ce, Pr,
One or more of Nd, Sm and the like can be used, and the content of any one of them or the total content of two or more thereof may be in the range of 0.05 to 1 wt%. . As an alloy containing two or more of the above elements,
For example, there is a misch metal containing Ce and La as main components (usually, 45 to 50% by weight of Ce, 20 to 40% by weight of La, and a balance of other rare earth elements (Pr, Nd, Sm, etc.) and inevitable impurities). Each of the above-mentioned rare earth elements and misch metals has the same effect, but in terms of price, misch metal is more inexpensive than rare earth elements alone.

【0022】本発明では、前記合金を、常法により、溶
解、鋳造し、得られる鋳塊に均質化処理を施したのち、
押出、抽伸、または圧延のいずれかの方法により、焼鈍
を入れながら、ねじ用素線に加工する。本発明におい
て、ねじ用素線の最終焼鈍後の加工率を40%以上にす
る理由は、加工率が40%未満では、その後の焼鈍で、
Zrが添加されているとは言え、結晶粒が粗大化し、ヘ
ッダー加工性および転造加工性が低下し、ねじ加工中に
割れ等の欠陥が発生し易くなるためである。ねじ用素線
の最終焼鈍後の加工度を40%以上にすると、Zrとの
相乗効果でその後の焼鈍でも結晶粒が粗大化せず、結晶
粒は微細なままで、ねじのヘッダー加工および転造加工
中に割れ等の欠陥が発生せず、加工が容易に行われる。
In the present invention, the alloy is melted and cast by a conventional method, and the obtained ingot is subjected to a homogenization treatment.
By extrusion, drawing, or rolling, the wire is processed into a screw wire while annealing. In the present invention, the reason why the working rate after the final annealing of the thread for a screw is 40% or more is that if the working rate is less than 40%, the subsequent annealing is performed.
Although Zr is added, the crystal grains become coarse, header workability and rolling workability are reduced, and defects such as cracks are easily generated during screw working. When the working degree after the final annealing of the screw wire is set to 40% or more, the crystal grains do not become coarse even in the subsequent annealing due to the synergistic effect with Zr, and the crystal grains remain fine, and the header processing and rolling of the screw are performed. Defects such as cracks do not occur during fabrication, and the fabrication is facilitated.

【0023】ねじ用素線は、ねじ加工などがし易くなる
ように焼鈍したのち、ヘッダー加工および転造加工によ
りねじ形状に加工される。次いで焼入れ、人工時効硬化
処理を施して強度を高めてねじが完成する。このような
工程で加工することにより、ねじの長手方向の結晶粒の
平均長さが200μm以下に押さえられる。また引張強
さを350N/mm2 以上、耐力を300N/mm2
上、伸びを6%以上、ねじり強さをJIS−B−105
-1 989 のAL3(A6061−T6)の10%以上高
い値にすることができる。本発明で、ねじの長手方向の
結晶粒の平均長さを200μm以下に押さえる理由は、
200μmを超えると靱性が低下し、ねじの締め付け時
に割れたりするためである。前記結晶粒の平均長さは1
00μm以下が特に望ましい。
The thread for a screw is annealed so as to facilitate threading and the like, and then processed into a screw shape by header processing and rolling. Next, quenching and artificial age hardening are performed to increase the strength and complete the screw. By processing in such a process, the average length of the crystal grains in the longitudinal direction of the screw is suppressed to 200 μm or less. Further, the tensile strength is 350 N / mm 2 or more, the proof stress is 300 N / mm 2 or more, the elongation is 6% or more, and the torsional strength is JIS-B-105.
The value can be increased by 10% or more than that of AL3 (A6061-T6) of 7 −1 989 . In the present invention, the reason for suppressing the average length of crystal grains in the longitudinal direction of the screw to 200 μm or less,
If the thickness exceeds 200 μm, the toughness is reduced and the screw is cracked when tightened. The average length of the crystal grains is 1
It is particularly desirable that the thickness be 00 μm or less.

【0024】[0024]

【実施例】(実施例1)表2のNo.1〜27に示す本発明組
成のアルミニウム合金を半連続鋳造法で219mmφの
ビレットに鋳造し、得られた鋳塊を長さ300mmに切
断し、これを540℃で4時間均質化処理し、次いで4
70℃で熱間押出して9mmφの線材とし、この線材を
表4に示す製造工程Aにより3.46mmφの素線に加
工した。次いでこの素線1を切断機2で所定長さに切断
し(図1イ)、これをヘッダー加工機3により頭部4を
形成し(図1ロ)、ねじ転造加工機5によりねじ部6を
形成し(図1ハ、ニ)た。次に540℃で1時間加熱後
水焼き入れしたのち、180℃で8時間人工時効硬化処
理を行ってM4のねじを製造した。M4ねじ7の寸法を
図2に示す。なお、加工性の悪いものは、前記頭部形成
時に、頭部の付け根や十字溝部に割れが発生し、前記転
造加工時に、ねじ部に割れが発生した。
EXAMPLES (Example 1) Aluminum alloys of the present invention compositions shown in Nos. 1 to 27 in Table 2 were cast into billets of 219 mmφ by a semi-continuous casting method, and the obtained ingot was cut into a length of 300 mm. This was homogenized at 540 ° C. for 4 hours.
The wire was hot-extruded at 70 ° C. to obtain a wire having a diameter of 9 mm, and this wire was processed into a strand having a diameter of 3.46 mm by a manufacturing process A shown in Table 4. Next, the strand 1 is cut into a predetermined length by a cutting machine 2 (FIG. 1A), and a head 4 is formed by a header processing machine 3 (FIG. 1B). 6 was formed (FIG. 1C, D). Next, after heating at 540 ° C. for 1 hour and then water quenching, an artificial age hardening treatment was performed at 180 ° C. for 8 hours to produce M4 screws. The dimensions of the M4 screw 7 are shown in FIG. In the case of poor workability, cracks occurred at the base of the head and the cross-groove during the formation of the head, and cracks occurred at the thread during the rolling process.

【0025】(比較例1)表3の No.28〜49に示す本発
明組成以外のアルミニウム合金を半連続鋳造法で219
mmφのビレットに鋳造し、得られた鋳塊を長さ300
mmに切断し、これを540℃で4時間均質化処理し、
次いで470℃で熱間押出して9mmφの線材とし、こ
の線材を表4に示す製造工程Bにより3.46mmφの
素線とし、この素線を実施例1と同じように加工してM
4のねじを製造した。
(Comparative Example 1) Aluminum alloys other than the compositions of the present invention shown in Nos.
into a billet with a diameter of 300 mm.
mm, and homogenized at 540 ° C. for 4 hours.
Next, the material was hot-extruded at 470 ° C. to obtain a wire having a diameter of 9 mm. The wire was formed into a strand having a diameter of 3.46 mm by the manufacturing process B shown in Table 4.
No. 4 screws were manufactured.

【0026】(従来例1)表3の No.50〜54に示す従来
合金(A6061、A5052、A5056、A202
4、A7N01)を半連続鋳造法で219mmφのビレ
ットに鋳造し、得られた鋳塊を比較例1と同じように加
工してM4のねじを製造した。
(Conventional example 1) Conventional alloys (A6061, A5052, A5056, A202) shown in No. 50 to No. 54 of Table 3
4, A7N01) was cast into a 219 mmφ billet by a semi-continuous casting method, and the obtained ingot was processed in the same manner as in Comparative Example 1 to produce an M4 screw.

【0027】得られた各々のねじについて、ねじ加工性
(ヘッダー加工性、ねじ転造性)を調べた。また引張試
験、ねじり試験、長手方向の断面のミクロ組織観察、腐
食試験を行った。結果を表4〜7に示す。試験、観察方
法、或いは良、不良の判定基準を下記に示す。 (1)ヘッダー加工性:ヘッダー加工が問題なくできたもの…良(○)。 ヘッダー加工中割れたもの…………不良(×)。 (2)転造加工性:M4のねじ加工が問題なくできたもの……良(○)。 M4のねじ転造中に割れたもの…………不良(×)。 (3)引張特性:図3に示すように、M4ねじ7を上チャック8と下チャック9 で挟んで引張試験した。 引張強さが350N/mm2 以上のもの………良(○)。 引張強さが350N/mm2 未満のもの……不良(×)。 耐力が300N/mm2 以上のものを…………良(○)。 耐力が300N/mm2 未満のものを………不良(×)。 伸びが6%以上のもの……………………………良(○)。 伸びが6%未満のもの…………………………不良(×)。 (4)ねじり強さ:図4に示すように、M4ねじ7を固
定治具10にハンドル11を回してしっかり固定したの
ち、M4ねじ7をトルクメーター12に取付けたプラス
ドライバー13で破断するまで回し、破断時のトルク値
(ねじり強さ)を求めた。ねじり強さの基準値はAL3
の規格値1.4N・mより10%以上高い1.54N・
mとした。 ねじり強さが1.54N・m以上のもの………良(○)。 ねじり強さが1.54N・m未満のもの……不良(×)。 (5)結晶粒長さの測定:図5(イ)、(ロ)に示すよ
うに、M4ねじ7を縦に切断し、その断面を研磨したの
ち、エッチングして、金属顕微鏡で14の部分を観察
し、各結晶粒の長手方向の長さ15を50個の結晶粒に
ついて測定した。 平均値が200μm以下のもの…………………良(○)。 平均値が200μmを超えたもの……………不良(×)。 (6)腐食試験方法:図6に示すように、M4ねじ7と
同じ材質のナット16でA6063合金板(3×100
×100mm)17を締めつけて試験体とし、これをス
テンレス製の槽18中の5%食塩水19中に浸漬した。
前記試験体は絶縁性のベークライト台20上に配置し
た。1000時間経過後、試験体を取出し腐食状況を調
べた。 耐食性がA6061製ボルトと同等のもの………………良(○)。 耐食性がA6061製ボルトより劣るもの……………不良(×)。
With respect to each of the obtained screws, thread workability (header workability, screw rollability) was examined. Further, a tensile test, a torsion test, a microstructure observation of a cross section in a longitudinal direction, and a corrosion test were performed. The results are shown in Tables 4 to 7. The test, observation method, or criteria for good or bad are shown below. (1) Header processability: header process was performed without any problem ... good (○). Cracked during header processing ..... Defective (x). (2) Rolling workability: M4 screw processing was performed without any problem ... good (O). Cracked during M4 thread rolling ..... Poor (x). (3) Tensile properties: As shown in FIG. 3, a tensile test was performed with an M4 screw 7 sandwiched between an upper chuck 8 and a lower chuck 9. Those having a tensile strength of 350 N / mm 2 or more: good (○). Those having a tensile strength of less than 350 N / mm 2 ... poor (x). Those with a proof stress of 300 N / mm 2 or more: good (○). Those with a proof stress of less than 300 N / mm 2 ... poor (x). Those with an elongation of 6% or more: good (O). Those with an elongation of less than 6%: poor (x). (4) Torsion strength: As shown in FIG. 4, after turning the handle 11 to the fixing jig 10 and firmly fixing the M4 screw 7, until the M4 screw 7 is broken by the plus screwdriver 13 attached to the torque meter 12. It was turned to determine the torque value (torsional strength) at break. The reference value for torsional strength is AL3
1.54N ・ 10% or more higher than the standard value of 1.4N ・ m
m. Good in torsional strength of 1.54 N · m or more. Those with a torsional strength of less than 1.54 N · m: defective (x). (5) Measurement of crystal grain length: As shown in FIGS. 5 (a) and 5 (b), the M4 screw 7 is cut vertically, its cross section is polished, then etched, and a metal microscope section 14 is used. Was observed, and the length 15 in the longitudinal direction of each crystal grain was measured for 50 crystal grains. Those having an average value of 200 μm or less: good (○). Those with an average value exceeding 200 μm: poor (×). (6) Corrosion test method: As shown in FIG. 6, an A6063 alloy plate (3 × 100
(× 100 mm) 17 was tightened to obtain a test body, which was immersed in a 5% saline solution 19 in a stainless steel tank 18.
The specimen was placed on an insulating bakelite table 20. After a lapse of 1000 hours, the test specimen was taken out and the state of corrosion was examined. Corrosion resistance equivalent to bolts made of A6061 .......... Good (O). Inferior to A6061 bolts in corrosion resistance .......... Poor (x).

【0028】[0028]

【表2】 [Table 2]

【0029】[0029]

【表3】 [Table 3]

【0030】[0030]

【表4】 [Table 4]

【0031】[0031]

【表5】 [Table 5]

【0032】[0032]

【表6】 [Table 6]

【0033】[0033]

【表7】 [Table 7]

【0034】[0034]

【表8】 [Table 8]

【0035】[0035]

【表9】 [Table 9]

【0036】[0036]

【表10】 [Table 10]

【0037】[0037]

【表11】 [Table 11]

【0038】表5〜11より明らかなように、本発明例
のNo.1〜54(表5〜8)はいずれも、加工性、ねじの引
張試験、ねじり試験、ミクロ組織、腐食試験において良
好な特性を示し、総合的に、従来例の No.77〜86(表1
1) より優れるものであった。また製造工程(表4)
については、ねじの引張試験、ねじり試験、ミクロ組織
に関し、Aの方がBより良好な特性を示した。これに対
し、比較例の No.55〜76(表9、10)は、合金組成が
本発明組成外のため、いずれかの特性が不良となり、総
合評価に劣るものとなった。
As is clear from Tables 5 to 11, all of Examples Nos. 1 to 54 (Tables 5 to 8) of the present invention are excellent in workability, screw tensile test, torsion test, microstructure and corrosion test. No.77-86 (Table 1)
1) It was better. Manufacturing process (Table 4)
With regard to, A exhibited better properties than B with respect to the tensile test, the torsion test, and the microstructure of the screw. On the other hand, in Comparative Examples Nos. 55 to 76 (Tables 9 and 10), since the alloy composition was not the composition of the present invention, one of the characteristics was poor and the overall evaluation was poor.

【0039】(実施例2)表2のNo.1〜27に示す本発明
組成のアルミニウム合金を半連続鋳造法で219mmφ
のビレットに鋳造し、得られた鋳塊を長さ300mmに
切断し、これを540℃で4時間均質化処理し、次いで
470℃で熱間押出して10mmφの線材とし、この線
材を表9に示す製造工程Cにより7.1mmφの素線に
加工した。次にこの素線21を切断機2で所定長さに切
断し(図7イ)、これを丸頭→6角頭の2段階でヘッダ
ー加工して頭部24を形成し(図7ロ、ハ)、ねじ転造
加工機によりねじ部26を形成し(図7ニ)、次いで5
40℃で1時間加熱後水焼入れしたのち、180℃で8
時間人工時効硬化処理を行ってM8ボルト27を製造し
た。M8ボルト27の寸法を図8に示す。なお、加工性
の悪いものは、頭部形成時に、頭部の付け根や十字溝部
に割れが発生し、転造加工時に、ねじ部に割れが発生し
た。
Example 2 An aluminum alloy having the composition of the present invention shown in Nos. 1 to 27 of Table 2 was 219 mmφ by a semi-continuous casting method.
And the resulting ingot was cut into a length of 300 mm, homogenized at 540 ° C. for 4 hours, and then hot extruded at 470 ° C. to obtain a 10 mmφ wire. It was processed into a 7.1 mmφ element wire by the manufacturing process C shown below. Next, the strand 21 is cut into a predetermined length by the cutting machine 2 (FIG. 7A), and this is subjected to header processing in two stages of round head → hexagonal head to form a head 24 (FIG. 7B, C) A thread portion 26 is formed by a thread rolling machine (FIG. 7D).
After heating at 40 ° C for 1 hour and water quenching,
An M8 bolt 27 was manufactured by performing an artificial age hardening treatment for a time. The dimensions of the M8 bolt 27 are shown in FIG. In the case of poor workability, cracks occurred at the base of the head and the cross groove at the time of forming the head, and cracks occurred at the thread during the rolling process.

【0040】(比較例2)表3の No.28〜49に示す本発
明組成以外のアルミニウム合金を半連続鋳造法で219
mmφのビレットに鋳造し、得られた鋳塊を長さ300
mmに切断し、これを540℃で4時間均質化処理し、
次いで470℃で熱間押出して10mmφの線材とし、
この線材を表9に示す製造工程Dにより7.1mmφの
素線とし、この素線を実施例2と同じように加工してM
8のボルトを製造した。
Comparative Example 2 Aluminum alloys other than the compositions of the present invention shown in Nos.
into a billet with a diameter of 300 mm.
mm, and homogenized at 540 ° C. for 4 hours.
Next, it is hot-extruded at 470 ° C. to form a 10 mmφ wire,
This wire was made into a 7.1 mmφ wire by the manufacturing process D shown in Table 9, and this wire was processed in the same manner as in Example 2 to obtain
Eight bolts were manufactured.

【0041】(従来例2)表3の No.50〜54に示す従来
合金(A6061、A5052、A5056、A202
4、A7N01)を半連続鋳造法で219mmφのビレ
ットに鋳造し、得られた鋳塊を比較例2と同じように加
工してM8のボルトを製造した。
(Conventional example 2) Conventional alloys (A6061, A5052, A5056, A202) shown in No. 50 to No. 54 of Table 3
4, A7N01) was cast into a 219 mmφ billet by a semi-continuous casting method, and the obtained ingot was worked in the same manner as in Comparative Example 2 to produce an M8 bolt.

【0042】得られた各々のねじについて、ねじ加工性
(ヘッダー加工性、ねじ転造性)を調べた。またねじの
引張試験、長手方向の断面のミクロ組織観察、腐食試験
を実施例1と同じ方法により行った。結果を表10〜1
5に示す。
For each of the obtained screws, thread workability (header workability, thread rolling property) was examined. Further, a tensile test, observation of a microstructure of a cross section in a longitudinal direction, and a corrosion test of the screw were performed in the same manner as in Example 1. Table 10-1
It is shown in FIG.

【0043】[0043]

【表12】 [Table 12]

【0044】[0044]

【表13】 [Table 13]

【0045】[0045]

【表14】 [Table 14]

【0046】[0046]

【表15】 [Table 15]

【0047】[0047]

【表16】 [Table 16]

【0048】[0048]

【表17】 [Table 17]

【0049】[0049]

【表18】 [Table 18]

【0050】表12〜18より明らかなように、本発明
例の No.87〜140(表12〜15) はいずれも加工性、ねじの
引張試験、ミクロ組織、腐食試験において良好な特性を
示し、総合的に従来例のNo.163〜167(表18) より優れる
ものであった。また製造工程(表9)については、ねじ
の引張試験、ねじり試験、ミクロ組織に関し、Cの方が
Dより良好な特性を示した。これに対し、比較例のNo.1
41〜162(表16〜17) は、合金組成が本発明組成外のた
め、いずれかの特性が不良となり、総合評価に劣るもの
となった。
As is clear from Tables 12 to 18, all of Nos. 87 to 140 (Tables 12 to 15) of the present invention show good properties in workability, screw tensile test, microstructure and corrosion test. Overall, it was better than Nos. 163 to 167 of the conventional example (Table 18). In the production process (Table 9), C exhibited better characteristics than D in the tensile test, torsion test, and microstructure of the screw. In contrast, No. 1 of the comparative example
For 41 to 162 (Tables 16 to 17), since the alloy composition was out of the composition of the present invention, one of the properties was poor and the overall evaluation was poor.

【0051】以上、アルミニウム合金製ねじ(ボルトを
含む)について説明したが、本発明は、ナット類に適用
しても同様の効果が得られ、本発明のねじ(ボルトを含
む)と組み合わせて用いることにより、より大きい効果
が得られる。
Although the description has been given of the aluminum alloy screws (including bolts), the same effects can be obtained by applying the present invention to nuts, and the present invention is used in combination with the screws (including bolts) of the present invention. Thereby, a larger effect can be obtained.

【0052】[0052]

【発明の効果】以上に述べたように、本発明の高強度ア
ルミニウム合金製ねじ(ボルトを含む)は、引張強さが
350N/mm2 以上、耐力が300N/mm2 以上、
伸びが6%以上、ねじり強さがJIS−B−1057
-1989 のAL3(A6061−T6)の10%以上、長
手方法の平均結晶粒長さが200μm以下のもので、ア
ルミニウム合金製構造物を接合するためのねじ・ボルト
として十分な引張特性、ねじり強さ、および耐応力腐食
割れ性を有し、安定した高い継手強度が得られる。また
ヘッダー加工性、ねじ転造加工性にも優れ加工が容易で
ある。また本発明のねじは6000系合金なので、例え
ば、サッシ、自動車などの6000系合金製構造物の接
合に用いたとき、スクラップの再溶解で純度の低下が少
なく、リサイクル性に優れるものである。さらに、本発
明のねじは、製造条件を一部規定した通常の製造方法に
より容易に製造することができる。依って、工業上顕著
な効果を奏する。
As described above, the high-strength aluminum alloy screws (including bolts) of the present invention have a tensile strength of 350 N / mm 2 or more and a proof stress of 300 N / mm 2 or more.
Elongation of 6% or more, torsional strength of JIS-B-1057
10% or more of AL3 (A6061-T6) of -1989 , average grain length of 200 μm or less in longitudinal method, sufficient tensile properties and torsional strength as screws and bolts for joining aluminum alloy structures In addition, it has stress corrosion cracking resistance and stable high joint strength can be obtained. It also has excellent header workability and thread rolling workability and is easy to work. Further, since the screw of the present invention is a 6000 series alloy, for example, when used for joining a 6000 series alloy structure such as a sash or an automobile, the scrap is less likely to decrease in purity due to re-melting of the scrap and has excellent recyclability. Further, the screw of the present invention can be easily manufactured by a normal manufacturing method in which manufacturing conditions are partially defined. Therefore, an industrially remarkable effect is achieved.

【図面の簡単な説明】[Brief description of the drawings]

【図1】(イ)〜(ニ)は、M4ねじの成形加工説明図
である。
BRIEF DESCRIPTION OF THE DRAWINGS FIGS. 1A to 1D are explanatory views of a forming process of an M4 screw.

【図2】M4のねじの寸法説明図である。FIG. 2 is an explanatory diagram of dimensions of an M4 screw.

【図3】ねじの引張試験の模式図である。FIG. 3 is a schematic diagram of a tensile test of a screw.

【図4】ねじり試験機の斜視図である。FIG. 4 is a perspective view of a torsion tester.

【図5】(イ)は結晶粒長さ測定用試験片、(ロ)は結
晶粒長さの測定方法の説明図である。
5A is a diagram illustrating a test piece for measuring a crystal grain length, and FIG. 5B is an explanatory view of a method for measuring a crystal grain length.

【図6】腐食試験方法の説明図である。FIG. 6 is an explanatory diagram of a corrosion test method.

【図7】(イ)〜(ニ)は、M8ボルトの成形加工説明
図である。
FIGS. 7A to 7D are explanatory diagrams illustrating forming of an M8 bolt.

【図8】M8ボルトの寸法説明図である。FIG. 8 is an explanatory diagram of dimensions of an M8 bolt.

【符号の説明】[Explanation of symbols]

1 M4ねじ用素線 2 切断機 3 ヘッダー加工機 4 M4ねじの頭部 5 ねじ転造加工機 6 M4ねじのねじ部 7 M4ねじ 8 上チャック 9 下チャック 10 固定治具 11 ハンドル 12 トルクメーター 13 プラスドライバー 14 M4ねじの結晶粒長さ測定箇所 15 結晶粒の長さ 16 ナット 17 A6063合金板 18 ステンレス製の槽 19 食塩水 20 ベークライト台 21 M8ボルト用素線 24 M8ボルトの頭部 26 M8ボルトのねじ部 27 M8ボルト DESCRIPTION OF SYMBOLS 1 Wire for M4 screw 2 Cutting machine 3 Header processing machine 4 Head of M4 screw 5 Screw rolling machine 6 Thread part of M4 screw 7 M4 screw 8 Upper chuck 9 Lower chuck 10 Fixing jig 11 Handle 12 Torque meter 13 Phillips screwdriver 14 M4 screw crystal grain length measuring point 15 crystal grain length 16 nut 17 A6063 alloy plate 18 stainless steel tank 19 saline solution 20 bakelite table 21 M8 bolt strand 24 M8 bolt head 26 M8 bolt Thread part 27 M8 bolt

フロントページの続き (51)Int.Cl.6 識別記号 FI C22F 1/00 630 C22F 1/00 630A 631 631A 685 685Z 694 694A Continuation of the front page (51) Int.Cl. 6 identification code FI C22F 1/00 630 C22F 1/00 630A 631 631A 685 685Z 694 694A

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 Mg:0.5〜1.5wt%、Si:0.
5〜1.5wt%、Cu:0.5〜1.5wt%、Mn:
0.2〜0.5wt%、Ti:0.005〜0.1wt%、
B:0.001〜0.05wt%、Zr:0.05〜0.
25wt%を含有し、残部アルミニウムおよび不可避不純
物からなることを特徴とする高強度アルミニウム合金製
ねじ。
1. Mg: 0.5-1.5 wt%, Si: 0.1.
5 to 1.5 wt%, Cu: 0.5 to 1.5 wt%, Mn:
0.2-0.5 wt%, Ti: 0.005-0.1 wt%,
B: 0.001 to 0.05 wt%, Zr: 0.05 to 0.
A high-strength aluminum alloy screw containing 25 wt%, the balance being aluminum and unavoidable impurities.
【請求項2】 Mg:0.5〜1.5wt%、Si:0.
5〜1.5wt%、Cu:0.5〜1.5wt%、Mn:
0.2〜0.5wt%、Ti:0.005〜0.1wt%、
B:0.001〜0.05wt%、Zr:0.05〜0.
25wt%を含有し、かつ、Sc、希土類元素、Vのうち
少なくとも1種を含み、それぞれを単独で添加する場合
は、Sc:0.05〜1wt%、希土類元素:0.05〜
1wt%、V:0.05〜0.5wt%とし、2種類以上を
同時に添加する場合は、それぞれの添加量の総和が0.
05〜0.7wt%とし、残部アルミニウムおよび不可避
不純物からなることを特徴とする高強度アルミニウム合
金製ねじ。
2. Mg: 0.5-1.5 wt%, Si: 0.
5 to 1.5 wt%, Cu: 0.5 to 1.5 wt%, Mn:
0.2-0.5 wt%, Ti: 0.005-0.1 wt%,
B: 0.001 to 0.05 wt%, Zr: 0.05 to 0.
25 wt% and at least one of Sc, rare earth element, and V, when each is added alone, Sc: 0.05-1 wt%, rare earth element: 0.05-
1 wt%, V: 0.05 to 0.5 wt%, and when two or more kinds are added at the same time, the total amount of each addition is 0.1%.
A high-strength aluminum alloy screw, characterized in that the amount is from 0.5 to 0.7 wt% and the balance is aluminum and unavoidable impurities.
【請求項3】 Mg:0.5〜1.5wt%、Si:0.
5〜1.5wt%、Cu:0.5〜1.5wt%、Mn:
0.2〜0.5wt%、Ti:0.005〜0.1wt%、
B:0.001〜0.05wt%、Zr:0.05〜0.
25wt%を含有し、残部アルミニウムおよび不可避不純
物からなるアルミニウム合金を溶解、鋳造し、得られる
鋳塊を均質化処理し、次いで、適宜焼鈍を入れながら、
押出法、抽伸法、または圧延法のいずれかによりねじ用
素線に加工し、このねじ用素線の最終焼鈍後の加工率を
40%以上とし、次いでこのねじ用素線を所定温度で焼
鈍したのち、前記素線をねじに成形し、このねじ成形体
を溶体化処理後急冷し、次いで人工時効硬化処理を行っ
て、長手方向の結晶粒長さを200μm以下、引張強さ
を350N/mm2 以上、耐力を300N/mm2
上、伸びを6%以上、ねじり強さをJIS−B−105
-1989 のAL3(A6061−T6)のねじ強さより
10%以上高い値にすることを特徴とする高強度アルミ
ニウム合金製ねじの製造方法。
3. Mg: 0.5-1.5 wt%, Si: 0.
5 to 1.5 wt%, Cu: 0.5 to 1.5 wt%, Mn:
0.2-0.5 wt%, Ti: 0.005-0.1 wt%,
B: 0.001 to 0.05 wt%, Zr: 0.05 to 0.
An aluminum alloy containing 25 wt%, the balance being aluminum and unavoidable impurities is melted and cast, and the obtained ingot is homogenized, and then, while appropriately annealing,
The screw wire is processed by any one of the extrusion method, the drawing method, and the rolling method, the working rate of the screw wire after the final annealing is set to 40% or more, and then the screw wire is annealed at a predetermined temperature. After that, the wire is formed into a screw, the screw formed body is subjected to a solution treatment, quenched, and then subjected to an artificial aging hardening treatment to have a crystal grain length in the longitudinal direction of 200 μm or less and a tensile strength of 350 N / mm 2 or more, proof stress of 300 N / mm 2 or more, elongation of 6% or more, and torsional strength of JIS-B-105.
High intensity manufacturing method of an aluminum alloy screw, characterized by a high value of 10% or more than the screw strength of 7 -1989 of AL3 (A6061-T6).
【請求項4】 Mg:0.5〜1.5wt%、Si:0.
5〜1.5wt%、Cu:0.5〜1.5wt%、Mn:
0.2〜0.5wt%、Ti:0.005〜0.1wt%、
B:0.001〜0.05wt%、Zr:0.05〜0.
25wt%を含有し、かつ、Sc、希土類元素、Vのうち
少なくとも1種を含み、それぞれを単独で添加する場合
は、Sc:0.05〜1wt%、希土類元素:0.05〜
1wt%、V:0.05〜0.5wt%とし、2種類以上を
同時に添加する場合は、それぞれの添加量の総和が0.
05〜0.7wt%とし、残部アルミニウムおよび不可避
不純物からなるアルミニウム合金を溶解、鋳造し、得ら
れる鋳塊を均質化処理し、次いで、適宜焼鈍を入れなが
ら、押出法、抽伸法、または圧延法のいずれかによりね
じ用素線に加工し、このねじ用素線の最終焼鈍後の加工
率を40%以上とし、次いでこのねじ用素線を所定温度
で焼鈍したのち、前記素線をねじに成形し、このねじ成
形体を溶体化処理後急冷し、次いで人工時効硬化処理を
行って、長手方向の結晶粒長さを200μm以下、引張
強さを350N/mm2 以上、耐力を300N/mm2
以上、伸びを6%以上、ねじり強さをJIS−B−10
57-1 989 のAL3(A6061−T6)のねじ強さよ
り10%以上高い値にすることを特徴とする高強度アル
ミニウム合金製ねじの製造方法。
4. Mg: 0.5-1.5 wt%, Si: 0.
5 to 1.5 wt%, Cu: 0.5 to 1.5 wt%, Mn:
0.2-0.5 wt%, Ti: 0.005-0.1 wt%,
B: 0.001 to 0.05 wt%, Zr: 0.05 to 0.
25 wt% and at least one of Sc, rare earth element, and V, when each is added alone, Sc: 0.05-1 wt%, rare earth element: 0.05-
1 wt%, V: 0.05 to 0.5 wt%, and when two or more kinds are added at the same time, the total amount of each addition is 0.1%.
An aluminum alloy consisting of aluminum and unavoidable impurities is melted and cast, and the obtained ingot is homogenized, and then subjected to extrusion, drawing, or rolling while appropriately annealing. After the final annealing of the screw wire is made 40% or more, and then the screw wire is annealed at a predetermined temperature, and then the wire is turned into a screw. The screw formed body is subjected to solution treatment, then quenched, and then subjected to an artificial age hardening treatment to have a crystal grain length in the longitudinal direction of 200 μm or less, a tensile strength of 350 N / mm 2 or more, and a proof stress of 300 N / mm 2. Two
The elongation is 6% or more, and the torsional strength is JIS-B-10.
57 -1 989 AL3 high intensity method of manufacturing an aluminum alloy screw, characterized by a high value of 10% or more than the screw strength of (A6061-T6).
JP34178097A 1997-12-12 1997-12-12 High-strength aluminum alloy screw and manufacturing method thereof Expired - Fee Related JP3939414B2 (en)

Priority Applications (1)

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Publication Number Publication Date
JPH11172359A true JPH11172359A (en) 1999-06-29
JP3939414B2 JP3939414B2 (en) 2007-07-04

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ID=18348710

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JP2010236665A (en) * 2009-03-31 2010-10-21 Nippon Light Metal Co Ltd Method for manufacturing high-tensile aluminum alloy bolt
JP2010025348A (en) * 2009-11-02 2010-02-04 Sanwa Packing Kogyo Co Ltd Joining member
EP2548983A4 (en) * 2010-03-15 2014-08-20 Nissan Motor Aluminium alloy and high-strength bolt made from aluminium alloy
JP2011219838A (en) * 2010-04-13 2011-11-04 Motoki Saito Method of manufacturing aluminum alloy product
WO2012063900A1 (en) 2010-11-10 2012-05-18 株式会社トープラ Process for manufacture of fastening component made from aluminum-based alloy, and fastening component made from aluminum-based alloy
US9534282B2 (en) 2010-11-10 2017-01-03 Topura Co., Ltd. Method for manufacturing aluminum based alloy-made fastening part and aluminum based alloy-made fastening part
JP2013104123A (en) * 2011-11-16 2013-05-30 Sumitomo Electric Ind Ltd Aluminum alloy wire for bolt, the bolt and methods for manufacturing the same
JP2013234389A (en) * 2013-07-24 2013-11-21 Sumitomo Electric Ind Ltd Aluminum alloy wire for bolt, bolt and methods of manufacturing the same
WO2015146406A1 (en) * 2014-03-24 2015-10-01 ニッタ株式会社 Pipe joint
WO2018049585A1 (en) * 2016-09-14 2018-03-22 银邦金属复合材料股份有限公司 Aluminum alloy composite strip for internal threaded heat exchange tube, and manufacturing method therefor
EP3556875A1 (en) * 2018-04-18 2019-10-23 Newfrey LLC Fastener made of aluminium alloy comprising scandium
WO2019201994A1 (en) 2018-04-18 2019-10-24 Newfrey Llc Fastener made of aluminium alloy comprising scandium
CN111989414A (en) * 2018-04-18 2020-11-24 纽弗雷公司 Fastener made of scandium-containing aluminum alloy
JP2021522406A (en) * 2018-04-18 2021-08-30 ニューフレイ リミテッド ライアビリティ カンパニー Fasteners made of aluminum alloy containing scandium
CN112853169A (en) * 2021-01-05 2021-05-28 中国第一汽车股份有限公司 High-strength aluminum alloy bolt and manufacturing method thereof
CN114086091A (en) * 2021-11-02 2022-02-25 西北工业大学 Method for improving strength, plasticity and wear resistance of A356 alloy
CN114086091B (en) * 2021-11-02 2022-05-13 西北工业大学 Method for improving strength, plasticity and wear resistance of A356 alloy
CN114752824A (en) * 2022-06-02 2022-07-15 山东南山铝业股份有限公司 Rapid extrusion aluminum alloy profile with low rare earth content and preparation process thereof

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