JPH11150344A - Hybrid ic module and manufacture thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hybrid IC module of a structure, wherein the dielectric constant of a fiber for forming woven fabrics or unwoven fabrics, which are a substrate constituent material, is low and the thermal expansion coefficient of the fiber is equal with that of a good conductivity film formation metal or is lower than that of the formation metal, and a method of manufacturing the module. SOLUTION: Woven fabrics or unwoven fabrics 12, which are formed of a low-thermal expansion polytetrafluoroethylene film 11, are impregnated with a synthetic resin 13 and at the same time, the resin 13 is made to solidify to form a substrate 2 and thereafter, with an electric circuit 3 formed on the surface of the substrate 2, various electronic components are mounted on the surface of the circuit 3.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a hybrid IC.
The present invention relates to a module and a method for manufacturing the same, and more particularly to a hybrid IC module for high-speed transmission of electric signals and high-speed arithmetic processing, and a method for manufacturing the same.

[0002]

2. Description of the Related Art As a conventional circuit board, a synthetic resin is impregnated into a woven or non-woven fabric formed of glass fiber, a woven or non-woven fabric formed of aramid resin fiber, and the like.
One in which a substrate is formed by solidifying the synthetic resin and an electric circuit is formed on the surface of the substrate is used.

As a method of forming an electric circuit on a substrate, there are the following methods.

A good conductive film is formed on one side of a substrate,
After forming a photosensitive polymer film on the surface of the good conductive film, the polymer film is masked with a mask formed so that only a portion corresponding to an electric circuit pattern transmits light. At the same time as irradiating light, the polymer film in the light-irradiated portion is cross-linked and cured, and thereafter, the polymer film in the portion not irradiated with light is removed using a chemical solution, and further, the polymer film is further removed. A method of forming an electric circuit on a substrate surface by etching away the exposed portion of the good conductive film.

[0005] A good conductive film is formed on one side of the substrate,
After forming a photosensitive polymer film on the surface of the good conductive film, the polymer film is masked with a mask formed so that only the portion corresponding to the electric circuit pattern does not transmit light, and the mask is applied to the mask. While irradiating the light, the polymer chain of the polymer coating in the light-irradiated portion is cut and broken, and thereafter, the polymer coating in the light-irradiated portion is removed using a chemical solution, and further, the polymer is removed. A method of forming an electric circuit on a substrate surface by etching away a portion where a good conductive film is exposed by removing the film.

A good conductive film is formed on both sides of the substrate,
After forming a through hole in the substrate and forming a good conductive film on the inner surface of the through hole, or forming an electric circuit on both surfaces of the substrate using the above method, and forming a good conductive film on the inner surface of the through hole. A method of electrically connecting electric circuits on both sides of a board.

Here, a synthetic resin is impregnated into a woven or nonwoven fabric made of glass fiber, a woven or nonwoven fabric made of aramid resin fiber, and the like, instead of a substrate made of synthetic resin alone, and the synthetic resin is solidified. The reason why the following substrate is used is as follows.

(A) The thermal expansion coefficient of the synthetic resin is 5.0 to 5.0.
8.0 × 10 ⁻⁵ K ⁻¹ , a substrate forming a good conductive film of an electric circuit having a coefficient of thermal expansion of 1.5 to 2.0 × 10 ⁻⁵ K ⁻¹ , and a substrate made of a synthetic resin alone In this case, the difference in the thermal expansion coefficient between the two becomes large, so that the good conductive film forming the electric circuit is damaged by expansion and contraction based on the thermal history applied to the substrate.

(B) A substrate made of a synthetic resin alone has too low rigidity, so that the substrate is likely to be deformed when an external force is applied, and in some cases, an electric circuit may be damaged.

In recent years, when an integrated circuit or the like such as an IC is mounted on a main substrate, the integrated circuit or the like such as an IC is first mounted on a module and hybridized instead of directly on the main substrate.
A method of attaching a C module to a main board is adopted. This hybrid IC module is designed for high-density mounting and high functionality in order to reduce the size and performance of the system.

With the recent development of electronic arithmetic technology and information processing technology, it has been required to further improve the high-speed transmission performance of electric signals and the high-speed arithmetic processing performance. The dielectric constant of the substrate has been reduced.

[0012]

However, the permittivity of the woven or non-woven fabric constituting the substrate is 4.5 to 5.8 when glass fiber is used, and 3.5 when aramid resin fiber is used. Even when using a synthetic resin having a low dielectric constant,
The dielectric constant of a composite substrate of a woven or non-woven fabric and a synthetic resin has a limit, which has been an obstacle to the development of electronic computing technology and information processing technology.

[0013] Further, even in a substrate in which a woven or nonwoven fabric made of glass fiber (2.7 to 5.6 × 10 ^-5 K ^-1 ) having a relatively small coefficient of thermal expansion and a synthetic resin are combined, an electric circuit is also required. Coefficient of thermal expansion of metal forming a good conductive film of
2.0 × 10 ⁻⁵ K ⁻¹ ).

Therefore, the present invention solves the above-mentioned problems, and has a low dielectric constant of a fiber for forming a woven or nonwoven fabric which is a constituent material of a substrate, and has a good thermal expansion coefficient of the fiber to form a conductive film. Hybrid I equal to or less than metal
An object of the present invention is to provide a C module and a method of manufacturing the same.

[0015]

Means for Solving the Problems In order to solve the above-mentioned problems, the invention according to claim 1 impregnates a synthetic resin into a woven or non-woven fabric formed of low thermal expansion polytetrafluoroethylene fibers, and uses the synthetic resin for the impregnation. After solidification to form a substrate, an electric circuit is formed on the surface of the substrate,
Various electronic components are mounted on the surface of the electric circuit.

According to a second aspect of the present invention, there is provided a hybrid IC module comprising an electric circuit formed on a surface of a substrate, various electronic components mounted on the surface of the electric circuit, and being mounted on a surface of the main substrate. The substrate is a composite of a woven or non-woven fabric made of low thermal expansion polytetrafluoroethylene fiber and a synthetic resin.

According to a third aspect of the present invention, there is provided the hybrid IC according to the second aspect, wherein a coefficient of thermal expansion in a length direction of the low thermal expansion polytetrafluoroethylene fiber is smaller than a coefficient of thermal expansion of a metal forming the electric circuit. Module.

According to a fourth aspect of the present invention, the low thermal expansion polytetrafluoroethylene fiber has a coefficient of thermal expansion of 20 in the longitudinal direction.
4. The hybrid IC module according to claim 2, wherein the temperature is from 0 to 250 ° C. and the tensile breaking strength of the low thermal expansion polytetrafluoroethylene fiber is 0.5 GPa or more. 5.

According to a fifth aspect of the present invention, there is provided the hybrid IC module according to the second aspect, wherein the synthetic resin is a fluorine-based synthetic resin.

According to the above construction, a synthetic resin is impregnated into a woven or non-woven fabric formed of low thermal expansion polytetrafluoroethylene fibers, and the synthetic resin is solidified to form a substrate. In addition to forming an electric circuit on the surface of the electric circuit and mounting various electronic components on the surface of the electric circuit, the fiber for forming a woven or non-woven fabric which is a component of the substrate has a low dielectric constant and a thermal expansion of the fiber. A hybrid IC module having a rate equal to or less than that of the metal forming the good conductive film can be obtained.

[0021]

Embodiments of the present invention will be described below.

As a result of extensive studies, the present inventors have found that as a fibrous material for forming a woven or non-woven fabric constituting a substrate, the dielectric constant is as low as 2.1 and the thermal expansion in the fiber length direction. It has been found that low-thermal-expansion polytetrafluoroethylene (hereinafter referred to as low-thermal-expansion PTFE) having a lower coefficient of thermal expansion than the metal forming the electric circuit is used.

FIG. 1 is a perspective view of a hybrid IC module of the present invention, and FIG. 2 is an enlarged view of a cross section of a substrate in the hybrid IC module of the present invention. Here, FIG.
FIG. 2B is an enlarged view of a main part of FIG.

As shown in FIGS. 1 and 2, the hybrid IC module 1 of the present invention is obtained by combining a laminate of a woven fabric (or nonwoven fabric) 12 made of PTFE fibers 11 with low thermal expansion and a synthetic resin 13. An electric circuit 3 composed of a highly conductive film (metal film forming an electric circuit) 15 on the surface of a substrate (hereinafter referred to as a hybrid integrated circuit substrate) 2
Is formed, and various electronic components (ICs) are formed on the surface of the electric circuit 3.
Chip 5, electrolytic capacitor 6, connector 7, etc.), and a main substrate (not shown) via lead portion 4 formed in hybrid IC module 1.
That can be attached to the surface of

Next, the manufacturing method of the present invention will be described.

First, a PTFE (polytetrafluoroethylene) -based synthetic resin is subjected to paste extrusion to form a PTFE.
Form a polymer monofilament.

After the monofilament is heat-treated at a temperature equal to or higher than the melting point, the monofilament is subjected to a stretching process so that the molecular chains are oriented in the longitudinal direction and the coefficient of thermal expansion in the longitudinal direction is a metal that forms an electric circuit. The low thermal expansion PTFE fiber 11 having a smaller coefficient of thermal expansion is formed.

A woven (or non-woven) fabric 12 is formed using the low thermal expansion PTFE fiber 11. Thereafter, the laminate of the woven fabric (or non-woven fabric) 12 is impregnated with the synthetic resin 13 and the synthetic resin 13 is solidified to form the hybrid integrated circuit board 2.

An electric circuit 3 is formed on the surface of the hybrid integrated circuit board 2 by using the above-mentioned methods (1) to (6), and various electronic components are mounted on the surface of the electric circuit 3 to produce the hybrid IC module 1. .

The coefficient of thermal expansion in the longitudinal direction of the low thermal expansion PTFE fiber 11 is 1.5 × 10 ⁻⁶ K ⁻¹ or less, preferably 0 or less, which is smaller than the coefficient of thermal expansion of the metal forming the good conductive film 15. The low thermal expansion PTFE fiber 11 has a tensile strength at break of 0.5 GPa or more from the viewpoint of the rigidity of the hybrid integrated circuit board.

The fiber diameter of the low thermal expansion PTFE fiber 11 is not particularly limited, but is preferably 100 μm or less.

The synthetic resin 13 impregnated into the woven fabric 12 (or non-woven fabric) is not particularly limited, but a fluorine-based synthetic resin having a low dielectric constant is preferable.
FE, fluorinated ethylene-hexafluoropropylene copolymer, fluorinated acrylic resin, fluorinated epoxy resin, etc., and in particular, fluorinated epoxy having a good impregnation property to a woven or nonwoven fabric as a substrate constituent material Resins are preferred.

Here, the fact that the coefficient of thermal expansion of the low-thermal-expansion PTFE fiber 11 is 0 or less means that thermal contraction occurs at a high temperature. However, the woven fabric 12 (or The synthetic resin 13 is impregnated and solidified in the nonwoven fabric).

For this reason, the synthetic resin 13 has a low thermal expansion PT
The resistance of shrinkage of the FE fiber 11 occurs, and the hybrid integrated circuit board 2 does not shrink even at a high temperature. Also,
There is no possibility that the hybrid integrated circuit board 2 and the electric circuit 3 formed on the surface of the hybrid integrated circuit board 2 are separated. Furthermore, since the tensile break strength of the low thermal expansion PTFE fiber 11 is 0.5 GPa or more, the low thermal expansion
Even if the FE fiber 11 receives shrinkage resistance (tensile force) due to the synthetic resin 13, there is no possibility of breaking.

That is, according to the hybrid IC module of the present invention, since the low thermal expansion PTFE fiber is used as the forming fiber of the woven or nonwoven fabric constituting the substrate, it has a low dielectric constant and its thermal expansion. A hybrid integrated circuit substrate having a rate equal to or less than that of the metal forming the good conductive film can be obtained.

Since the low-thermal-expansion PTFE fiber 11 is more expensive than glass fiber or the like, it is preferably applied only to the hybrid integrated circuit board 2 of the hybrid IC module 1 from the viewpoint of manufacturing cost. When priority is given to improving the high-speed signal transmission performance and the high-speed arithmetic processing performance, it goes without saying that the present invention may be applied to a main board on which the hybrid IC module 1 is mounted.

[0037]

EXAMPLE An example of manufacturing a low thermal expansion PTFE fiber for forming a woven or nonwoven fabric as a constituent material of a hybrid integrated circuit board will be described.

PT as a raw material of low thermal expansion PTFE fiber
The fine powder of the FE polymer has an inherent tackiness, so that it is likely to form a powder mass by receiving the force of vibration and its own weight during transportation and storage. If powder lumps are present in the fine powder, the handleability of the fine powder deteriorates, and uniform impregnation with an extrusion aid becomes difficult.

When any force is applied to mechanically loosen the powder mass, the fine powder is easily fiberized by the shearing force at this time and adversely affects extrusion molding. It is very important to make the fine powder grains as small as possible and to reduce the tackiness of the fine powder as much as possible before adding the auxiliary agent.

For this reason, it is necessary to pass fine powder of PTFE polymer through a 4 or 8 mesh sieve. The weighing of the fine powder of the PTFE polymer is desirably performed in a room adjusted to a room temperature transition temperature of PTFE (about 19 ° C.) or less.

The blended material of the PTFE polymer fine powder and the extrusion aid after the weighing of the sieve is put into a dry-mouthed wide-mouth bottle with a sufficient capacity. At this time, in order to improve the mixing property of the compounding material in the next step, the amount of the compounding material to be charged into the bottle is set to about １ ／ to ／ of the bottle volume.

Immediately after the introduction of the compounding material, an airtight seal is attached to the bottle mouth to prevent the volatilization of the extrusion aid,
Shake the bottle lightly to disperse the extrusion aid. Thereafter, the bottle is placed on a rotating base and the bottle is rotated at an appropriate speed to mix and disperse the PTFE polymer fine powder and the extrusion aid.

Thereafter, the extrusion aid is allowed to sufficiently penetrate into the secondary particles of the fine powder, and is left at room temperature until the surface of the primary particles of the fine powder becomes wet with the extrusion aid. Thereafter, the mixed material is sieved with an appropriate mesh size to remove lumps generated by mixing.

The mixture is charged into a cylinder of a preform apparatus, and is compressed to form a billet. At this time, 1 to 10 kgf / cm ² (about 9.8 × 10
^With a compression force of ^{4 to} 9.8 × 10 ⁵ Pa), holding for several minutes is required.

After forming the billet, the billet is subjected to paste extrusion to form a monofilament. At this time, since a billet formed by compressing fine powder of PTFE polymer wetted with an extrusion aid is used, paste extruding of the billet is easy, and a monofilament can be easily formed. PTF
The temperature condition of the paste extrusion of the fine powder of the E polymer is preferably in the range of 40 to 60 ° C.

Here, an important factor in paste extrusion is a reduction ratio expressed by a ratio of a cross-sectional area of a cylinder of an extruder to a cross-sectional area of a die, and is an important factor in ordinary paste extrusion. This is particularly important when fiberizing low thermal expansion PTFE. That is, the essence of low thermal expansion of PTFE fiber is
The polymer molecules constituting the synthetic resin are extended to the extent possible in terms of the bond angle between the atoms constituting the main chain and the angle of rotation with respect to each bond, and the ultimately extended molecular chain is extended in the longitudinal direction of the fiber. It is up to the arrangement.

Next, PTFE was added to this monofilament.
Temperature (360-390) higher than the melting point of
C) and sintering is performed.

The monofilament after sintering is stretched at a temperature equal to or higher than the melting point and at a draw ratio of about 40 to 100 times, and then immediately subjected to a quenching treatment, whereby the molecular chains are oriented in the longitudinal direction to obtain a low thermal expansion property. Make PTFE fibers.

This low-thermal-expansion PTFE fiber is cut into an appropriate length, and the coefficient of thermal expansion in the length direction of the fiber is measured. The coefficient of thermal expansion is determined by using TMA (thermomechanical analysis) and measuring the rate of change in fiber length at each temperature based on the fiber length at normal temperature (20 ° C.).

FIG. 3 shows the relationship between the temperature and the thermal expansion of the low thermal expansion polytetrafluoroethylene fiber. In the figure, the horizontal axis indicates temperature (° C.), and the vertical axis indicates the amount of change in length (%).

As shown in FIG. 3, in the temperature range from room temperature to 270 ° C., the coefficient of thermal expansion of the low thermal expansion PTFE fiber is always negative, and at 250 ° C., 3 to 4% as compared with that at room temperature. It is shrunk, and has an average coefficient of thermal expansion at -250 × 250 ° C. of −1.5 × 10 ⁻⁴ K ⁻¹ .

[0052]

In summary, according to the present invention, low-expansion polytetrafluoroethylene fibers are used as the forming fibers of the woven or non-woven fabric constituting the substrate, so that the fibers have a low dielectric constant and a high thermal expansion. It is possible to obtain a hybrid integrated circuit board whose efficiency is equal to or less than that of the metal forming the good conductive film, and thus has an excellent effect of improving the performance of the hybrid IC module.

[Brief description of the drawings]

FIG. 1 is a perspective view of a hybrid IC module according to the present invention.

FIG. 2 is an enlarged view of a cross section of a substrate in the hybrid IC module of the present invention.

FIG. 3 is a diagram showing the relationship between the temperature and the thermal expansion of a low thermal expansion polytetrafluoroethylene fiber.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Hybrid IC module 2 Hybrid integrated circuit board (substrate) 3 Electric circuit 11 Low thermal expansion polytetrafluoroethylene fiber 12 Woven cloth (woven cloth or nonwoven cloth) 13 Synthetic resin 15 Good conductive film (metal film forming electric circuit) )

Claims (5)

[Claims] 1. A woven or non-woven fabric formed of low thermal expansion polytetrafluoroethylene fibers is impregnated with a synthetic resin, and the synthetic resin is solidified to form a substrate, and then an electric circuit is formed on the surface of the substrate. And mounting various electronic components on the surface of the electric circuit. 2. A hybrid IC module in which an electric circuit is formed on a surface of a substrate, various electronic components are mounted on the surface of the electric circuit, and the substrate is mounted on a surface of a main substrate. Hybrid I characterized by combining a woven or non-woven fabric made of conductive polytetrafluoroethylene fibers with a synthetic resin
C module. 3. The hybrid IC module according to claim 2, wherein a coefficient of thermal expansion of the low thermal expansion polytetrafluoroethylene fiber in a length direction is smaller than a coefficient of thermal expansion of a metal forming the electric circuit. 4. The thermal expansion coefficient of the low thermal expansion polytetrafluoroethylene fiber in the longitudinal direction is 0 or less in a temperature range of 20 to 250 ° C., and the low thermal expansion polytetrafluoroethylene fiber has a tensile fracture. The hybrid IC according to claim 2 or 3, wherein the strength is 0.5 GPa or more.
module. 5. The hybrid IC module according to claim 2, wherein said synthetic resin is a fluorine-based synthetic resin.