JPH1085731A - Water treatment ceramic spherical body and water treatment device using ceramic spherical body - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a ceramic spherical body for generating an electron, also generating far infrared rays, activating and ionizing water to be treated and also provide a water treatment device using the ceramic spherical body. SOLUTION: A ceramic spherical body is formed by mixing fine powder of granite porphyry of 98-99wt.%, which is burnt at the temperature of 1,700-1,800 deg.C and then crushed into powder of particle diameters of 200-300 mesh, with a mixed metallic powder of 1-2wt.%, which is formed by mixing five kinds or more out of fine powders of iron (Fe), Manganese(Mn), titanium(Ti), calcium(Ca), magnesium(Mg), aluminum(Al), zirconium(Zr), potassium (K) and sodium (Na) of respective particle diameters of 200-300 mesh and burning a mixture at the temperature of 1,550 deg.C or above. A ceramic spherical body 50 is put into a water treatment device main body 12 having flow paths 14 and water to be treated with magnets 36 and 44 to provide a water treatment device 10.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a ceramic spherical body for treating domestic water such as drinking water, agricultural water, and industrial water, and a water treatment apparatus using the ceramic spherical body. The ceramic spherical body placed in the flowing treated water collides with the treated water to oscillate and generate electrons, generate far-infrared rays, and ionize the treated water by the action of the electrons and far-infrared rays. The present invention relates to an activatable ceramic sphere and a water treatment apparatus using the ceramic sphere.

[0002]

2. Description of the Related Art Various factors such as corrosion and mold generation due to a water supply tank type water supply in a high-rise house, generation of red rust and scale due to aging of a water pipe installed in a building, and large input of chlorine due to contamination of a water source. As a result, tap water has a bad taste, and there is a possibility that red rust, scale, mold, and bacteria may be mixed.

[0003] Under such circumstances, water purifiers using a hollow fiber membrane, activated carbon, and barley stone that can be attached to a faucet relatively easily and can filter water have become widespread.

In order to maintain the performance of these water purifiers, it is necessary to periodically replace a filter medium. For example, the maintenance of the water purifier is complicated. It is not possible to remove the generated red rust and scale. Furthermore, due to the recent growing interest in health and environmental conservation, it has been desired to make tap water more suitable for the human body and the natural environment. There is a demand for the development of a water treatment device and a water purifier that can be changed to those suitable for the natural environment.

In response to such a demand, a cylindrical ceramic case is filled with a porous ceramic that generates far-infrared rays by focusing on the water activation and ionization effects by irradiation of far-infrared rays, which is conventionally known. A water purifier for purifying tap water by introducing tap water into the cylindrical case (Japanese Patent Application Laid-Open No. Hei 8-
Focusing on the fact that the activation and ionization of water by far-infrared rays is further promoted by placing the water to be treated in a magnetic field, a permanent-infrared generator and a far-infrared ray generator such as ceramics are housed together. A water treatment device (Japanese Patent Publication No. 5-9118) which surrounds the outer periphery of the water pipe in a case where the water is passed through the water pipe surrounded by the case so as to exert far-infrared rays and magnetism on the tap water. Proposed.

[0006]

In the above-mentioned conventional water purifier and water treatment apparatus, ceramic is used as a generator of far-infrared rays, and a physical change of activating and ionizing water is also provided. In a conventional water purifier having a configuration in which a porous case is filled in a cylindrical case, and tap water is introduced into the case to bring the porous ceramic into contact with the water to be treated. Is directly in contact with the water to be treated, so that the effect of ionizing and activating the water to be treated by irradiation with far infrared rays is high. However, the porous ceramic is used for a long time because it also acts as an adsorbent for adsorbing chlorine and the like, which causes a bad smell of the water to be treated. It does not function as an adsorbent. For this reason, the maintenance for maintaining the performance of the water purifier is complicated, as in the case of the filter medium replacement of the water purifier described above, such as the need to periodically replace the porous ceramic.

[0007] Further, removing chlorine from the water to be treated weakens the bactericidal power of the water after the treatment and causes the generation and corrosion of bacteria.

Further, impurities and the like in the water to be treated are trapped in the fine pores of the porous ceramic,
The porous ceramic becomes a hotbed of bacteria and the like, and is rather unsanitary.

In addition, conventional porous ceramics that are brought into contact with the water to be treated are fragile due to a low sintering temperature, and are liable to crack or chip due to the pressure of the water to be treated which is continuously applied. Not only maintenance such as replenishment and replacement is necessary, but also cracked or chipped porous ceramic may be mixed into the treated water.

On the other hand, in a water treatment apparatus in which the outside of a water pipe is surrounded by a cover in which a far-infrared ray generator such as ceramics or a permanent magnet is disposed, the installation of the water treatment pipe is unnecessary because no special piping work is required. It is easy to use, and the far-infrared ray generators such as ceramics do not need to be replaced because they are not used as adsorbents for adsorbing chlorine and the like, and once installed, they have the advantage of requiring almost no maintenance. Things.

However, in this water treatment apparatus, the outer periphery of the water pipe is surrounded by the case containing the far-infrared ray generator and the permanent magnet. A water pipe is interposed between the water pipe and the water pipe, and there is a limit in its effect, for example, the water to be treated is not irradiated with sufficient far-infrared rays by being reflected by the water pipe. In particular, when the water pipe is a steel pipe, the lines of magnetic force extending from the permanent magnets pass through the steel part of the water pipe with high magnetic permeability, and the number of lines of magnetic force passing through the water to be treated in the water pipe is extremely large. To decrease.

The ceramic used in each of the water purifiers or water treatment devices is used as a generator of far-infrared rays and / or an adsorbent of chlorine or the like, and itself emits electrons to cover the ceramics. Although it does not promote the ionization of the treated water, the treated water can be more effectively ionized if the ceramic itself emits electrons.

Accordingly, an object of the present invention is to dispose electrons in a flowing water to be treated, whereby electrons are emitted by vibration when the water collides with the water to be treated, thereby ionizing and activating the water to be treated. , By providing a ceramic spherical body that is also a generator of far-infrared rays, promotes the phenomenon of water purification action, activation effect, reduction action, precipitation effect, water oxidation after treatment, deodorization, antibacterial, purification, Uses ceramic spheres for water treatment, which has the effect of preventing browning and the like, can prevent the occurrence of red rust and scale in water pipes, is hardly cracked and chipped, and does not require maintenance after installation, and uses the ceramic spheres It is an object of the present invention to provide an improved water treatment apparatus.

[0014]

SUMMARY OF THE INVENTION In order to achieve the above object, a ceramic spherical body for water treatment of the present invention comprises 1700 spheres.
After firing at a temperature of 温度 1800 ° C., a particle size of 200 to 300
Fine powder of barley stone crushed into mesh powder 98-99
Weight%, iron (Fe) having a particle size of 200 to 300 mesh,
Manganese (Mn), titanium (Ti), calcium (Ca), magnesium (Mg), aluminum (A
l), 1 to 2% by weight of a mixed metal powder obtained by mixing at least 5 kinds of fine powders of zirconium (Zr), potassium (K), and sodium (Na) into a spherical body at a temperature of 1550 ° C. or more It is characterized by being formed by firing or sintering. The malt stone is fired at a temperature of 1700 to 1800 ° C., cooled, and then fired again at a temperature of 1330 to 1430 ° C.
It may be crushed into 0 mesh powder.

Further, the diameter of the ceramic spherical body is:
It is 2.5 mm to 5 mm, preferably 3 to 3.5 mm.

Further, the water treatment apparatus of the present invention has an inlet 20 for the water to be treated and a supply port 32 for the treated water, and a flow path 14 communicating between the inlet 20 and the supply port 30 is formed. The permanent magnets 36 and 44 are disposed inside the water treatment apparatus main body 12, and the flow path 14 is filled with the ceramic spherical body 50 described above.

More specifically, the water treatment apparatus main body 12
Are a plurality of cylindrical tubes 16 of different diameters arranged concentrically.
The upper and lower portions (16a, 16b, 16c) are covered to form a flow path 14 of the water to be treated between the outer wall and the inner wall of each of the cylindrical tubes 16 (16a, 16b, 16c), and the respective flow paths are communicated. Thus, a flow path meandering in the water treatment device main body 12 is formed.

The flow path 14 (14a, 14b, 1)
The ceramic sphere 50 to be filled in 4c) is preferably set to 80 to 100% of the volume of the flow channel.

[0019]

BEST MODE FOR CARRYING OUT THE INVENTION

[Ceramic spheroid] The ceramic spheroid of the present invention may be a powder that is a generator of far-infrared rays, for example, a ceramic powder composed of amorphous silica, amorphous salmonosilicate, or the like. After baking the stone at a temperature of 1700 to 1800 ° C., it is crushed into a powder having a particle size of about 200 to 300 mesh to obtain fine powder of barley stone, or after the baking, cooled, and then cooled to 1330 to 1430. Baked again at a temperature of ° C., and the baked barley stone is crushed into powder having a particle size of about 200 to 300 mesh to obtain a far-infrared ceramic powder composed of fine powder of barley stone as a fine powder. Apart from infrared powder, iron (Fe), manganese (Mn), titanium (Ti) with a particle size of 200 to 300 mesh,
Five or more kinds of fine powders of calcium (Ca), magnesium (Mg), aluminum (Al), zirconium (Zr), potassium (K), and sodium (Na), for example, 52 wt% of aluminum (Al), iron ( Fe), manganese (Mn), titanium (Ti), and magnesium (Mg) are mixed at 12 wt% to form a mixed metal powder. The far-infrared ceramic powder is 98 to 99% by weight, and the mixed metal powder is 1%. A sphere having a particle size of 2.5 mm to 5 mm, which was mixed at a ratio of ２2% by weight to uniformly disperse the two and was sintered at a temperature of 1550 ° C. or more.

By manufacturing in this manner, a ceramic spherical body that can further promote the activation and ionization of the water to be treated can be obtained.

The above-mentioned ceramic spherical body is put into the water to be treated and is brought into contact with the water to be treated.
For example, the ceramic sphere is put into a container connected to a water pipe or the like and configured to discharge the tap water after circulating inside, and is arranged so as to collide with the flowing tap water.

More preferably, a water treatment apparatus main body 12 described later is used.
The ceramic sphere is filled in the flow path of the water to be formed formed therein, and the water to be processed collides with the ceramic sphere.

The filling amount of the ceramic spherical body is preferably about 80 to 100% with respect to the volume of the flow path of the water to be treated formed in the container for introducing the water to be treated or the main body of the water treatment apparatus. As described above, by filling the ceramic spheres with a margin for the volume of the container or the flow path, when the water to be treated is introduced into the flow path or the container, the ceramic spheres are pressed into the flow path by the water pressure. And the water to be treated is uniformly irradiated with far-infrared rays, and the ceramic spheres emit electrons due to the vibration of the ceramic spheres generated when the ceramic spheres collide with each other or the inner wall of the flow path. The emission of electrons exerts effects such as activation and ionization of the water to be treated, which will be described in detail later.

[Water Treatment Apparatus] An example of the water treatment apparatus 10 of the present invention is shown in FIGS. The water treatment apparatus 10 is provided with a flow path in the water treatment apparatus main body 12 in which a meandering flow path 14 communicating between an inlet 20 for introducing water to be treated and a supply port 32 for discharging treated water is formed. 14, the ceramic spherical body 50 and the permanent magnets 36 and 44 are arranged.

In one example, the flow path 14 of the water to be treated formed in the main body 12 of the water treatment apparatus is configured so that the water to be treated flows meandering up and down.
mm, 45 mm, three stainless steel cylindrical tubes 16 (16
a, 16b, 16c) are arranged concentrically in the vertical direction, cover the upper and lower openings of the three cylindrical tubes 16 (16a, 16b, 16c), and at the upper and lower ends of the side wall of the intermediate cylinder 16b. A first flow path 14a is formed between the inner wall of the outermost cylinder 16a and the outer wall of the middle cylinder 16b by piercing the lower end of the side wall of the inner cylinder 16c.
c between the outer walls of the second channel 14c and the innermost cylinder 16c.
Are formed in the hollow space in the order of the third flow path 14c.

A cylindrical inlet pipe 18 is projected from an inlet 20 provided at the lower end of the side wall of the outermost cylindrical pipe 16a of the water treatment apparatus main body 12 to the outer surface of the side wall of the outermost cylindrical pipe 16a. The water pipe (upstream side) is connected to the introduction pipe 18 via a joint such as a socket.

The upper end opening of the cylindrical tube 16 is covered with a lid 22 having a diameter of 140 mm and a supply port 32 having a diameter of 22 mm at the center fixed to the upper end of the outermost cylindrical tube 16a.

The lid 22 is made of a packing 26 made of rubber or the like.
And a flange 24 formed at a portion protruding from the outer periphery of the cylindrical tube 16a. A bolt hole is formed in the flange 24, and the cover 24 is bolted to the flange 24. The upper ends of the three cylinders are covered with a stopper or the like.

At the lower end of the main body 12 of the water treatment apparatus, a disc-shaped bottom cover 28 having the same diameter as the outer diameter of the cylindrical tube 16a is fixed to the opening of the outermost cylindrical tube 16a by welding or the like. The lower openings of the cylindrical tubes 16a, 16b, 16c are simultaneously covered. The bottom lid 28 and the three cylindrical tubes 16a, 16
Although all of b and 16c can be fixed, in the present embodiment, only the outermost cylindrical tube 16a is fixed and the other cylindrical tube 1a is fixed.
6b and 16c are only placed on the inner wall of the bottom lid 28.

In the case of such a construction, the guide body 30 for regulating the interval between the cylindrical pipes is so arranged that the three cylindrical pipes 16a, 16b, 16c are always arranged concentrically and do not shift in position. It is arranged near the upper and lower opening edges of the cylindrical tubes 16a, 16b, 16c.

A supply port 3 formed at the center of the lid 22
2 is the internal space of the innermost cylindrical tube 16c,
The treated water is in communication with the flow path 14c,
Is more exhausted. The supply port 3 is provided on the upper surface of the lid 22.
A cylindrical supply pipe 34 that communicates with the projecting pipe 2 is protruded, and the supply pipe 34 and a water pipe on the use side that communicates with a water faucet or the like can be connected via a joint such as a socket.

A permanent magnet 36 formed in a cylindrical shape is disposed at a lower portion of the lid 22 and on an inner wall at an upper end of the innermost cylindrical tube 16c. Inside the magnet 36, a hollow magnet fixture 3 whose upper end is fixed in the vicinity of the supply port 32 and which is formed wide at the bottom is provided.
8 penetrates. Then, the water to be treated that has passed through the third flow path 14 c passes through the inside of the magnet fixture 38 and is supplied to the supply port 3.
It is configured to be discharged to the outside from 2.

In FIG. 2, reference numerals 40 and 42 denote O-rings. The O-rings pass through the magnet fixture 38 together with the permanent magnets 36, and fix the cylindrical permanent magnets 36 from above and below.

Further, a permanent magnet 44 is fixed below the third flow path 14c on the inner wall surface of the bottom cover 28 which covers the lower end opening of the cylindrical tube 16, and is provided near the supply port 32. A magnetic field is formed between the magnet and the permanent magnet 36.

The water treatment apparatus main body 1 configured as described above
When water to be treated such as tap water is introduced from the inlet 20 of 2,
The introduced water to be treated is supplied to the first flow path 14 by its water pressure.
a, the liquid passes through the second flow path 14b, the third flow path 14c in order, is discharged from the supply port 32 communicating with the third flow path 14c, and flows to a water tap (not shown) or the like.

Each of the flow paths 14 (1
4a, 14b, 14c), the above-mentioned ceramic spherical body 50 is filled with a margin at a rate of 80 to 100% of the inner volume of the flow path 14 (14a, 14b, 14c). The to-be-processed water flowing in the inside 12 flows while colliding with the ceramic spherical body 50.

The ceramic spherical body 50 colliding with the water to be treated
In addition, the water emitted in the flow path 14 (14a, 14b, 14c) uniformly collides with the ceramic spherical body 50, and emits electrons by the vibration at the time of collision with the water to be treated. In addition to receiving infrared radiation, the permanent magnets 36,
By the synergistic effect with the magnetic force of 44, the molecular population (cluster) of the water to be treated is made smaller and activated,
Further, the water to be treated is ionized, and changes into water having good taste and good absorption into the human body.

Further, in the water to be treated ionized by the electrons generated from the ceramic spherical body 50, the following changes occur, and the chlorine odor of the water to be treated is removed. It decomposes ammonia (NH ₃ ) and hydrogen sulfide (H ₂ S), and prevents and eliminates the generation of red rust (Fe ₂ O ₃ ) in water supply pipes, water supply tanks, and water receiving tanks.

1. Ionization of water to be treated A part of water molecules is ionized by electrons generated by the vibration due to the collision between the ceramic spherical body 50 and the water to be treated, and hydrogen ions [H ⁺ ] and hydroxyl ions [OH ⁻ ] are formed. It is thought to disintegrate. In addition, a trace amount of oxygen [O ₂ ] in water is active oxygen [O ₂ ⁻ : superoxide anion]
And reacts with water molecules to form molecular oxide [HO ₂ ], which reacts with H ⁺ ions to generate a small amount of H ₂
O ₂ is generated.

[0040] If we can show effect by the reaction _{equation, (1) H 2 O +} e - → H + + OH - (2) O 2 + e - → O 2 - ( superoxide anions) (3) O ₂ ^{- _{+ H 2 O → OH - +}} HO 2 ( molecular oxide) and a ^{_{(4) HO 2 + 2H +}} → H + + H 2 O 2 ( hydrogen peroxide).

Further, some of the H ₂ O ₂ O ₂ decomposes as shown in the following reaction formula ^- generating a (superoxide anion).

(5) H ₂ O ₂ → HO ₂ + H ⁺ (6) HO ₂ → O ₂ ⁻ + H ⁺ Removal of chlorine odor Chlorine (Cl) reacts with H ₂ O to produce hydrogen chloride (HCl) and hypochlorous acid (HClO). Some HClO may undergo autoxidation to produce chloric acid (HClO ₃ ).

(7) Cl ₂ + H ₂ O → HCl + HClO (8) HClO + 2HClO → HClO ₃ + 2HCl By the above-mentioned action, the chlorine odor due to chlorine in the water to be treated is absorbed by the porous substance or the like. It can also be used to remove eye irritation, irritation to the eyes due to chlorine when used in pool water, and irritation to the skin when used as daily water for bathing, etc. can get.

In addition to the electron emission from the ceramic spherical body 50, the water to be treated is affected by the magnetic field due to the magnetic field formed by the permanent magnets 36 and 44 arranged in the flow path 14 in the water treatment apparatus main body 12. The water to be treated is also ionized by a synergistic effect of the magnet and the far infrared rays generated from the ceramic spherical body 50.

That is, by the action of the magnetic field formed by the permanent magnets 36 and 44, the water treatment apparatus 10 of the present invention is used.
Water molecules passing through the inside are in an excited state with an increased energy order, the outermost electrons of the water molecules are weakly connected to the nuclei, and the orbit is applied by applying light, heat, voltage, etc. from the outside. It is in a state where it becomes easy to become free electrons away.

The water molecules in the above-described state due to the influence of magnetism come into contact with the ceramic spherical body 50 which also acts as a generator of far infrared rays, thereby causing the far infrared rays emitted from the ceramic spherical bodies 50 to emit. When exposed, it is considered that the outermost electrons jump out and become free electrons, thereby ionizing and activating the water to be treated.

As described above, the ionized and activated water after the treatment is supplied from the supply port 32 provided on the upper surface of the water treatment apparatus main body 12, and is passed through the downstream water pipe communicating with the water faucet or the like. For use.

The water treated by the water treatment apparatus 10 in the course of flowing through the water pipe exerts an effect of preventing and removing red rust (Fe ₂ O ₃ ) from a drain pipe, a water supply tank, a water receiving tank and the like.

The effect is that hydrogen peroxide (H ₂ O ₂ ) generated in the water treatment apparatus of the present invention reacts with Fe ^- ions to be changed to iron oxide (FeO), and FeO is converted to red rust in the water pipe. It is considered that this occurs when red rust changes into black rust (Fe ₃ O ₄ ) little by little and comes out when it comes into contact with the surface.

Further, when the pipe is a metal pipe such as a steel pipe, a magnetite film is formed on the inner wall surface, and the magnetite film suppresses the generation of red rust and promotes the purification of tap water.

If this state is shown using a chemical formula, (9) H ₂ O ₂ + Fe ₂ ⁺ → FeO + H ₂ O (10) FeO + Fe ₂ O ₃ → Fe ₂ O ₄

Further, the water treated by the water treatment apparatus 10 of the present invention has an effect of decomposing ammonia (NH ₃ ) and hydrogen sulfide (H ₂ S) and removing an offensive odor.

This action is achieved by removing ammonia (NH ₃ ) and hydrogen sulfide (H ₂ S), which cause malodor such as toilet and sewage, from hydrogen peroxide (H ₂ ) in water treated by the water treatment apparatus 10 of the present invention. ₂ O ₂ ) is decomposed by the following formula, and it is considered that this decomposition causes a deodorizing effect.

(11) 2NE ₃ + 3H ₂ O ₂ → N ₂ ↑ + 6H ₂ O (12) H ₂ S + H ₂ O ₂ → 2H ₂ O + S By the action described above, the water treatment apparatus 10 of the present invention is used. When the treated water is used as washing water for a flush toilet, etc., an effect of deodorizing waste water can be obtained.

[Test Examples] The operations of the ceramic spherical body 50 and the water treatment apparatus 10 of the present invention described above are also clarified by the following experimental results.

1. Filled with ceramic spheroids test foregoing ceramic spheroids into a stainless steel tube, the stainless steel pipe was connected to the faucet Toei water, Ca ₂ ⁺ in over time in running water, Fe ₂ ^+, Mg ₂ ⁺ ions Was measured. Tables 1 and 2 show the results of this measurement.

[0057]

[Table 1]

[0058]

[Table 2]

From the above results, it can be seen that the use of the ceramic spheroid of the present invention makes it possible to obtain Ca ₂ ⁺ , Fe ₂ ⁺ , Mg ₂ ^{+ in} tap water.
Reduction of ions was confirmed. In particular, the decrease in Fe ₂ ^{+ in} running water measured after 90 days was remarkable.

It is evident that tap water that has passed through the ceramic spheres of the present invention has been activated by this decrease in Ca ₂ ⁺ , Fe ₂ ⁺ , and Mg ₂ ⁺ ions. Further, prolonged use Fe ₂ ⁺ reduction in tap water in the case of the ceramic spheroids of the present invention is particularly remarkable, the use of about three months the ceramic balls of the present invention, to remove rust in water pipes, Also, it can be seen that the generation of red rust can be prevented.

Further, the water to be treated in which the permanent magnet was omitted and which was in contact with the ceramic spherical body of the present invention was found to have a smaller molecular population from the results of the nuclear magnetic resonance (NMR) experiment shown in FIG. It is clear, when used as drinking water, it has good taste and absorption in the intestine, and when used as a bath, it penetrates well into the skin and warms up, promotes sweating, and when used as washing water The water is good for dirt removal.

[0062] 2. Performance Test of Water Treatment Device The water treatment device of the present invention was installed upstream of a water meter in a room of a 20-year-old apartment building, and changes in red rust in pipes that had not been cleaned for 20 years were observed. Fig. 4
(A) and FIG. 4 (B).

The water pipe used in the apartment is a steel pipe, and the test method is to provide an endoscope insertion port downstream of the water pipe to which the water treatment apparatus described in the embodiment of the present invention is attached. The inside of the straight pipe part and the joint part of the water pipe was observed with an endoscope.

Immediately after installing the water treatment apparatus of the present invention, red rust and scale are remarkably generated in both the straight pipe portion and the joint portion, and the red rust is in the form of a knob, and substantially half of the flow path in the water pipe. It was in a state where the degree was blocked.

After using the water treatment apparatus of the present invention, the endoscope was inserted again and the inside of the water pipe was observed. As a result, although red rust and scale were still observed, the size of the red rust bump was reduced to about half. It was confirmed that it was decreasing.

Further, when the water treatment apparatus of the present invention was attached and the observation was performed again with an endoscope after a lapse of 33 days,
Although red rust was still adhered, the red rust in the form of a knob was almost completely removed, and it was confirmed that the flow path of tap water had returned to the state originally possessed by the water pipe.

From the above results, it was confirmed that the use of the water treatment apparatus of the present invention was extremely effective in removing red rust in water pipes and preventing the generation of red rust.

The ceramic spheres for water treatment and the water treatment apparatus according to the present invention have been mainly described for the treatment of tap water. However, the water to be treated according to the present invention is not limited to tap water, but may be other water sources (for example, well water). And the like, and the water after treatment is suitable not only for use as domestic water but also as agricultural water, livestock raising, industrial water and the like.

[0069]

According to the structure of the present invention described above, the ceramic sphere for water treatment of the present invention has the following effects.

By contacting the treated water with the treated water, the treated water can be ionized and activated. As a result, the chlorine odor of the tap water is removed, and the water in the water pipe, the water supply tank and the water receiving tank is removed. In addition to removing red rust and suppressing generation thereof, a ceramic spherical body capable of decomposing into water capable of decomposing ammonia, hydrogen sulfide and the like, and a water treatment apparatus were provided.

The treated water has a fine water molecular cluster (cluster), is well absorbed from the skin and intestines of the human body, and when used as washing water, is treated into water with good dirt removal. The present invention has provided a ceramic spheroid and a water treatment device that can be used.

Further, since the water treatment apparatus of the present invention has a permanent magnet as a magnetic source together with the ceramic sphere,
The activation and ionization of water are further promoted, and a water treatment apparatus that can further promote the effect of the ceramic spheres can be provided.

[Brief description of the drawings]

FIG. 1 is a perspective view of a water treatment apparatus of the present invention.

FIG. 2 is a cross-sectional view of the water treatment apparatus of the present invention.

FIG. 3 is a diagram showing a spectrum resonated with a nuclear magnetic resonance apparatus of water treated with the ceramic spherical body of the present invention.

FIG. 4 is a view showing an example of installation of the water treatment apparatus of the present invention, wherein (A) shows piping before installation, and (B) shows piping after installation.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 10 Water treatment apparatus 12 Water treatment apparatus main body 14 Flow path 14a 1st flow path 14b 2nd flow path 14c 3rd flow path 16 Cylindrical tube 16a Outermost cylindrical tube 16b Middle cylindrical tube 16c Innermost cylindrical tube 18 Introduction Pipe (inlet side) 20 Inlet 22 Flange 24 Cover 26 Packing 28 Bottom lid 30 Guide 32 Supply port 34 Supply pipe (supply port side) 36 Permanent magnet (cylindrical) 38 Magnet fixture 40 O-ring 42 O-ring 44 permanent magnet 50 ceramic sphere

Claims (4)

[Claims] 1. Firing at a temperature of 1700 to 1800 ° C., and then 98 to 99% by weight of fine powder of barley stone ground to a particle size of 200 to 300 mesh; iron (Fe) and manganese having a particle size of 200 to 300 mesh (Mn), titanium (Ti), calcium (Ca),
Magnesium (Mg), aluminum (Al), zirconium (Zr), potassium (K), sodium (Na)
A water treatment ceramic sphere formed by mixing 1 to 2% by weight of a mixed metal powder obtained by mixing any five or more of the above fine powders and sintering at a temperature of 1550 ° C. or more. 2. After firing at a temperature of 1700 to 1800 ° C., cooling, and firing again at a temperature of 1330 to 1430 ° C.,
98-99% by weight of fine powder of barley stone pulverized to a particle size of 200-300 mesh, iron (Fe), manganese (Mn), titanium (Ti), calcium (Ca) having a particle size of 200-300 mesh,
Magnesium (Mg), aluminum (Al), zirconium (Zr), potassium (K), sodium (Na)
A ceramic sphere for water treatment, which is obtained by mixing 1 to 2% by weight of a mixed metal powder obtained by mixing any five or more of the above fine powders and firing at a temperature of 1550 ° C. or more. 3. A permanent magnet provided in a water treatment apparatus main body having an inlet for treated water and a supply port for treated water, wherein a flow passage for treated water communicating between the inlet and the supply port is formed. A water treatment apparatus, wherein a ceramic spherical body according to claim 1 or 2 is filled in the flow path. 4. The water treatment apparatus main body covers a plurality of concentrically arranged cylindrical pipes having different diameters, and forms a flow path of the water to be treated between an outer wall and an inner wall of each cylindrical pipe. The water treatment apparatus according to claim 3, wherein the flow paths communicate with each other to form meandering paths in the main body of the water treatment apparatus.