JPH1046688A - Environment maintaining method in under floor of building - Google Patents

Environment maintaining method in under floor of building

Info

Publication number
JPH1046688A
JPH1046688A JP22466396A JP22466396A JPH1046688A JP H1046688 A JPH1046688 A JP H1046688A JP 22466396 A JP22466396 A JP 22466396A JP 22466396 A JP22466396 A JP 22466396A JP H1046688 A JPH1046688 A JP H1046688A
Authority
JP
Japan
Prior art keywords
building
moisture
film
floor
inorganic porous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22466396A
Other languages
Japanese (ja)
Inventor
Shigeo Yoshida
繁夫 吉田
Midori Ishihara
緑 石原
Hiroshi Horiie
大士 堀家
Kazuki Matsushita
量己 松下
Satoru Nagai
了 永井
Katsuhiro Tanaka
勝浩 田中
Yoshinaga Katsusawa
善永 勝沢
Takanobu Saito
隆信 斎藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KEMIHORUTSU KK
OOSHIKA SHINKO KK
National House Industrial Co Ltd
Takasago Industry Co Ltd
Okura Industrial Co Ltd
Original Assignee
KEMIHORUTSU KK
OOSHIKA SHINKO KK
National House Industrial Co Ltd
Takasago Industry Co Ltd
Okura Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KEMIHORUTSU KK, OOSHIKA SHINKO KK, National House Industrial Co Ltd, Takasago Industry Co Ltd, Okura Industrial Co Ltd filed Critical KEMIHORUTSU KK
Priority to JP22466396A priority Critical patent/JPH1046688A/en
Publication of JPH1046688A publication Critical patent/JPH1046688A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To maintain environment in under floor of a building in a good condition and to provide technology capable of maintaining specially the enclosed under floor of the building in a good condition. SOLUTION: In the underfloor soil surface of a building, a film having moisture permeability of 1,000g/m<2> .24hrs-20,000g/m<2> .24hrs and/or nonwoven fabric is laid, and a mixture of inorganic porous fine grain body of 20-100Å with average narrow hole radius and 20-200m<2> /gr with specific surface area and fine grain coal of 1.5-100Å with average narrow hole radius and 50-600m<2> /gr with specific surface area are so laid on the film and/or nonwoven fabric that the mutual mixed ratio reaches 20-80wt.%. By the constitution, the environment under the floor of the building is maintained in a good condition, specially the enclosed under floor of the building is maintained in a good condition, moisture in the under floor can be adjusted in a proper state, and the underfloor environment can be held in a favorable state. Moisture absorption and moisture release of hygroscopic moisture are kept in good balance, steam quantity in the enclosed under floor space can be maintained in a constant state, and it can be useful for preventing organic substance in underfloor soil from being rotted.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、建築物床下の環境
維持工法に関し、特に、密閉された建築物の床下の環境
を良好な状態に保持することができる技術に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for maintaining an environment under a floor of a building, and more particularly to a technique capable of maintaining an environment under the floor of a closed building in a favorable state.

【0002】[0002]

【従来の技術】建築物、特に、木造家屋は、微生物によ
る劣化を受け易い。例えば、木材腐朽菌等により、木材
が分解され、シロアリにより木材が食害され、木材表面
にカビ類が繁殖する。シロアリ等による被害は、暗所や
通風の少ない湿度の高いところが主に受け易い。床下
は、通風も悪く、湿度が高く、シロアリやカビ等が繁殖
するのに住み良い場所となっている。近年、建築材料や
建築工法の変化により、建築物の密閉性が、以前と比較
して高くなっており、木材腐朽や蟻害の原因となる高湿
状態に保たれていることが多い。特に、密閉された床下
は、その環境が建築物にとって好ましくない状態に陥り
易い。木材の保存の為に、建築物、特に、木造家屋に、
防腐、防虫、防蟻処理を施すことが行なわれており、従
来から各種の方法が試みられている。例えば、床下土壌
に白蟻防除の目的で土壌処理剤(液状薬剤)を散布した
り、土台に、CCA処理(クロム、銅、ヒ素化合物系木
材防腐剤による処理、JIS K 1554−197
5)した木材土台を使用したりしている。しかしなが
ら、床下土壌に液状薬剤を散布することは土壌を汚染
し、当該薬剤が流出する危険も合わせ持つ処理方法であ
る。また、CCA処理された木材は、使用時には有効で
あるが、廃棄する際に多くの問題点が指摘されており、
自然環境保護の観点から、好ましい処理方法ではない。
床下では、土壌面から多量の水分(湿気)が上昇してく
る。当該水分(湿気)を遮断し、シロアリ等の被害から
守る為に、所謂防蟻防湿シートやフィルムを、床下土壌
面に敷設するという方法も行なわれているが(実開昭6
2−52605号公報、特開平5−98717号公
報)、こうしたシートやフィルムを敷設する方法では、
湿度の高い日には、シートやフィルムの上面に結露がし
ばしば見られる等の欠点があり、また、カビも生え易
く、さらに、当該シートやフィルム単独使用では、その
破れや継ぎ目から白蟻などの害虫が出入りする等の欠点
がある。アスファルト乳剤に薬剤を添加混合してなる乳
剤を散布し、土壌面に乾燥皮膜を形成するということも
行われているが(特開昭56−115705公報、特開
昭60−19834号公報)、この方法では、その乾燥
皮膜形成に時間がかかったり、皮膜の乾燥時に、応力に
より皮膜が破れる等の欠点がある。ところで、床下で
は、土壌面から多量の水分(湿気)が上昇してくる一方
で、外気から水分(湿気)が床下に入ってくる。こうし
た場合、当該湿分を充分に吸収し、家屋上部に上昇させ
ないようにする必要がある一方で、この吸湿が一方的に
行なわれ吸湿した水分をなかなか放出しないと、吸湿と
放湿というバランスの採れた湿度の調節をとることが難
しくなり、前記のような結露が発生し、カビも生え易く
なってくる。上記カビの発生は、床下をかび臭くさせ
る。元々、家屋床下では、通風も悪く異臭が発生し易
く、建築物の密閉性が益々家屋床下に各種臭い(異臭)
を停滞させ易くしている。特開平1−295948号公
報には、防腐防虫防蟻薬剤を活性炭に吸着せしめてなる
組成物を家屋床下土壌面に散布する防除法が記載されて
いるが、活性炭のみでは吸湿性能は高いが、放湿性能に
欠けるため、調湿性能に難点があったりする。また、特
開昭50−99870号公報には、殺虫性化合物及び防
水性を有する有機物質の混合物を多孔性鉱物質粒状物に
吸着させて得られる殺虫性組成物を、家屋床下の地表面
に撒布する家屋床下害虫の防除法が記載されているが、
床下害虫の防除を目的とし、脱臭効果面などにおいて性
能が不足し、また、上記した調湿性能にも難点がある。
従って、従来例では、床下環境を良好に保つ為に、各種
の方法が試みられているが、何れも一長一短があり、上
記した性能面等においてバランスの採れた方法はないの
が現状である。
BACKGROUND OF THE INVENTION Buildings, especially wooden houses, are susceptible to microbial degradation. For example, wood is decomposed by wood rot fungi and the like, the wood is damaged by termites, and molds propagate on the wood surface. Damage by termites and the like is mainly susceptible to dark places and places with low ventilation and high humidity. The underfloor has poor ventilation and high humidity, making it a livable place for termites and mold to breed. In recent years, due to changes in building materials and construction methods, the hermeticity of buildings has been higher than before, and they are often kept in a high humidity state that causes wood decay and ant damage. In particular, under a closed floor, the environment tends to fall into an unfavorable state for a building. For the preservation of wood, in buildings, especially wooden houses,
Antiseptic, insect repellent, and termite treatments have been performed, and various methods have been tried in the past. For example, a soil treatment agent (liquid agent) is sprayed on the underfloor soil for the purpose of termite control, or the base is treated with CCA (chromium, copper, arsenic compound-based wood preservative, JIS K 1554-197).
5) The used wood base is used. However, spraying a liquid drug onto the underfloor soil is a treatment method that contaminates the soil and also has a risk of the drug flowing out. Wood treated with CCA is effective at the time of use, but many problems have been pointed out when discarding it.
From the viewpoint of protection of the natural environment, this is not a preferable treatment method.
Under the floor, a large amount of moisture (humidity) rises from the soil surface. In order to cut off the moisture (humidity) and protect it from damage by termites and the like, a method of laying a so-called termite-proof moisture-proof sheet or film on the soil surface under the floor has been used (see, for example, Jpn.
2-52605, JP-A-5-98717), such a method of laying a sheet or a film,
On humid days, there are drawbacks such as dew condensation often seen on the upper surface of the sheet or film, and mold tends to grow.In addition, when the sheet or film is used alone, pests such as termites break from the seam or seams. There are drawbacks such as entry and exit. It has also been practiced to form a dry film on the soil surface by spraying an emulsion obtained by adding and mixing a drug to an asphalt emulsion (JP-A-56-115705 and JP-A-60-19834). This method has drawbacks such as a long time required to form the dried film and a breakage of the film due to stress when the film is dried. By the way, under the floor, while a large amount of moisture (humidity) rises from the soil surface, moisture (humidity) from the outside air enters under the floor. In such a case, it is necessary to absorb the moisture sufficiently so as not to rise to the upper part of the house. On the other hand, if this moisture absorption is performed unilaterally and the absorbed moisture is not easily released, the balance between moisture absorption and moisture release is required. It is difficult to control the humidity taken, and the above-mentioned dew condensation occurs, and mold tends to grow. The occurrence of the above mold makes the underfloor musty. Originally, under the floor of the house, ventilation is poor and off-flavors are apt to be generated, and the hermeticity of the building is increasing.
Makes it easy to stagnate. Japanese Patent Application Laid-Open No. 1-295948 describes a control method in which a composition obtained by adsorbing a preservative, insect repellent and repellent agent on activated carbon is sprayed on the soil surface under the floor of a house. Due to lack of moisture release performance, there is a difficulty in humidity control performance. Japanese Patent Application Laid-Open No. 50-99870 discloses an insecticidal composition obtained by adsorbing a mixture of an insecticidal compound and a waterproof organic substance onto porous mineral particulates, and applying the composition to a ground surface under a house floor. Although the method of controlling house floor pests to be sprayed is described,
For the purpose of controlling pests under the floor, the performance is insufficient in terms of deodorizing effect and the like, and the above-mentioned humidity control performance also has disadvantages.
Therefore, in the conventional example, various methods have been tried in order to maintain a good underfloor environment, but all have their advantages and disadvantages, and at present there is no method that balances the above-mentioned performance aspects.

【0003】[0003]

【発明が解決しようとする課題】本発明の目的は、建築
物床下の環境を良好な状態に維持し、特に、密閉された
建築物の床下を良好な状態に保持することができる技術
を提供することにある。本発明の前記ならびにそのほか
の目的と新規な特徴は、本明細書の記述からあきらかに
なるであろう。
SUMMARY OF THE INVENTION An object of the present invention is to provide a technique capable of maintaining the environment under the floor of a building in a good state, and in particular, capable of maintaining the environment under the floor of a closed building in a good state. Is to do. The above and other objects and novel features of the present invention will become apparent from the description of the present specification.

【0004】[0004]

【課題を解決するための手段】本発明は、建築物の床下
土壌面に透湿度が1000g/m2・24hrs〜20
000g/m2・24hrsのフイルムおよび/または
不織布(以下、フイルム類という場合もある)を敷設
し、当該フイルム類上に粉粒炭を除く無機多孔質粉粒体
と粉粒炭との混合物を敷設することを特徴とする建築物
床下の環境維持工法に係り、好ましい実施態様として、
無機多孔質粉粒体の平均細孔半径が20〜100Å、比
表面積が20〜200m2/grであること、粉粒炭の
平均細孔半径が1.5〜100Å、比表面積が50〜6
00m2/grであること、無機多孔質粉粒体と粉粒炭
の相互の混合割合が、20〜80重量%であること、無
機多孔質粉粒体および粉粒炭が、その50%以上がJI
S Z8801で規定する19mmの篩を通過し、0.
3mmの篩上にとどまる粉砕粒であること、また、無機
多孔質粉粒体と粉粒炭とフイルム類の少なくとも一以上
に防腐、防虫、防蟻処理を施したことを特徴とするもの
である。
SUMMARY OF THE INVENTION According to the present invention, a moisture permeability of 1000 g / m < 2 >.
2,000 g / m 2 · 24 hrs of film and / or non-woven fabric (hereinafter sometimes referred to as films) is laid, and a mixture of the inorganic porous powder and the powdered coal except the powdered coal is placed on the film. Concerning the environmental maintenance method under the floor of the building characterized by laying, as a preferred embodiment,
The average pore radius of the inorganic porous powder is 20 to 100 °, the specific surface area is 20 to 200 m 2 / gr, the average pore radius of the pulverized coal is 1.5 to 100 °, and the specific surface area is 50 to 6
00 m 2 / gr, the mixing ratio of the inorganic porous powder and the particulate coal to each other is 20 to 80% by weight, and the inorganic porous powder and the particulate coal are at least 50% Is JI
S Pass through a 19 mm sieve specified in Z8801;
It is characterized by being crushed particles that remain on a 3 mm sieve, and that at least one of inorganic porous particles, powdered charcoal, and films has been subjected to antiseptic, insect repellent, and termite-proof treatment. .

【0005】本発明によれば、床下において、その土壌
面に適当な透湿度を有するフイルム類を敷設する。そし
て、当該フイルム類上に、無機多孔質粉粒体と粉粒炭と
の混合物をさらに敷設する。当該無機多孔質粉粒体と粉
粒炭との混合物によれば、吸湿性能が高いだけでなく、
適宜湿分を放湿して、床下における湿度を適宜の状態に
調節でき、カビの発生を防止し、白蟻等の有害昆虫等の
侵入および繁殖を阻止し、また、床下に発生する異臭の
除去効果が高く、床下の環境を好適に保全することがで
きる。当該フイルム類は、適当な透湿度を有し、水蒸気
は透過させるが、水は遮断するので、当該フイルム類を
土壌面上に敷設し、当該フイルム類を介して無機多孔質
粉粒体と粉粒炭との混合物を敷設すれば、土壌側からの
水を遮断できるので、当該混合物が水により飽和状態に
なり、能力が低下してくることを防止できる。また、そ
の際に、水蒸気は透過させるので、上記湿分の吸湿と放
湿とのバランスにも寄与し、密閉された床下空間の水蒸
気量をコンスタントな状態に保持できる。特に、地下水
が高いような場合に有効である。また、当該フイルム類
を介して無機多孔質粉粒体と粉粒炭との混合物を敷設す
れば、当該無機多孔質粉粒体と粉粒炭との混合物を単独
で敷設する場合の飛散を防止できる。さらに、当該フイ
ルム類の敷設により、当該フイルム類上の無機多孔質粉
粒体と粉粒炭との混合物が湿り、湿った混合物が直接床
下土壌面に接することによる影響を回避でき、例えば、
有機物のくされ防止に役立たせることができる。
According to the present invention, under the floor, a film having appropriate moisture permeability is laid on the soil surface. Then, a mixture of the inorganic porous powder and the particulate coal is further laid on the film. According to the mixture of the inorganic porous powder and the particulate coal, not only has high moisture absorption performance,
By releasing moisture appropriately, the humidity under the floor can be adjusted to an appropriate state, preventing the occurrence of mold, preventing the invasion and propagation of harmful insects such as termites, and removing the unpleasant odor generated under the floor The effect is high, and the environment under the floor can be suitably preserved. The films have an appropriate moisture permeability and allow water vapor to permeate but block water, so the films are laid on the soil surface, and the inorganic porous powder and the powder are interposed via the films. If a mixture with granular coal is laid, water from the soil side can be blocked, so that the mixture can be prevented from being saturated with water and having a reduced capacity. Further, at this time, since the water vapor is permeated, it also contributes to the balance between the moisture absorption and the moisture release, and the amount of water vapor in the closed underfloor space can be kept constant. It is especially effective when the groundwater is high. In addition, if a mixture of the inorganic porous powder and the granular coal is laid through the film, scattering when the mixture of the inorganic porous powder and the granular coal is laid alone is prevented. it can. Further, by laying the films, the mixture of the inorganic porous granular material and the granular coal on the films becomes wet, and the influence of the wet mixture directly contacting the underfloor soil surface can be avoided.
It can be useful for preventing organic matter from being broken.

【0006】本発明で使用される建築物の床下土壌面に
敷設するフイルム類は、その透湿度が1000g/m2
・24hrs〜20000g/m2・24hrsの範囲
にあることが必要である。当該透湿度は、40℃、相対
湿度差が90%の条件下における透湿度である。当該フ
イルム類の透湿度が1000g/m2・24hrs未満
では、水および水蒸気の透過を遮断するので、当初はカ
ビの発生を抑え、結露も抑えることができるが、その後
に、湿度の上昇により、カビが発生し、結露してくる。
また、仮に、無機多孔質粉粒体と粉粒炭との混合物を敷
設した場合、当該混合物による湿分の吸湿と放湿とのバ
ランスに寄与できず、結露し、水がフイルム類上に停滞
し、カビ臭を抑えることができなくなる。一方、200
00g/m2・24hrsを超えるときには、水や水蒸
気の透過が進み過ぎ、無機多孔質粉粒体と粉粒炭との混
合物が早めに飽和状態に達し易く、その能力低下も早ま
る。当該フイルム類の例としては、上記透湿度を満たす
ものであれば特に制限はなく、ポリエチレン、エチレン
−酢酸ビニル共重合体、ポリプロピレン等のポリオレフ
イン系樹脂フイルム、ポリアミド樹脂、ポリエステル樹
脂、ポリ塩化ビニル樹脂、ポリビニルアルコール、アセ
チルセルロース、ポリウレタン樹脂等の合成樹脂フイル
ムや不織布またはそれらの組み合わせが挙げられる。合
成樹脂フイルムは通常合成樹脂に無機質充填材を添加し
て製膜した後、延伸加工して製造するのが一般的であ
り、無機質充填材の添加量や延伸倍率を変えることによ
って透湿度を自由に調節することができる。
The film laid on the soil surface under the floor of the building used in the present invention has a moisture permeability of 1000 g / m 2.
It is necessary to be in the range of 24 hrs to 20,000 g / m 2 · 24 hrs. The moisture permeability is a moisture permeability under the condition of 40 ° C. and a relative humidity difference of 90%. When the moisture permeability of the film is less than 1000 g / m 2 · 24 hrs, the permeation of water and water vapor is blocked, so that the generation of mold and the dew condensation can be suppressed at first, but thereafter, due to the rise in humidity, Mold develops and forms dew.
Also, if a mixture of inorganic porous powder and granulated coal is laid, it cannot contribute to the balance between moisture absorption and desorption of moisture due to the mixture, causing dew condensation and water stagnation on the film. And the mold odor cannot be suppressed. On the other hand, 200
When it exceeds 00 g / m 2 · 24 hrs, the permeation of water and water vapor proceeds too much, and the mixture of the inorganic porous powder and the powdered coal tends to reach a saturated state sooner, and the capacity of the mixture is quickened. Examples of the films are not particularly limited as long as the film satisfies the above-mentioned moisture permeability, and polyethylene, ethylene-vinyl acetate copolymer, polyolefin resin film such as polypropylene, polyamide resin, polyester resin, polyvinyl chloride resin. And synthetic resin films such as polyvinyl alcohol, acetylcellulose, and polyurethane resins, nonwoven fabrics, and combinations thereof. Generally, a synthetic resin film is formed by adding an inorganic filler to a synthetic resin, forming a film, and then stretching the film.The moisture permeability can be freely adjusted by changing the amount of the inorganic filler and the stretching ratio. Can be adjusted.

【0007】本発明で使用される無機多孔質粉粒体と
は、天然土壌を粉砕する、あるいは、天然岩石を粉砕す
る等無機系物質を多孔質の粉体と粒体とが混じり合った
ものとしたものをいい、当該無機多孔質粉粒体として
は、各種のものが使用できるが、代表的には、珪藻土の
天然土壌を粉砕したものを使用することが好ましい。当
該珪藻土の天然土壌を粉砕したものは、特に、吸湿、放
湿性能に優れ、中でも、その平均細孔半径が20〜10
0Å好ましくは20〜60Åで、比表面積が20〜20
0m2/grのものが、本発明のバランスの採れた環境
保全対策を施すという目的上、良好である。当該無機多
孔質粉粒体の50%(重量基準)以上は、JIS Z8
801で規定する19mmの篩を通過し、0.3mmの
篩上にとどまる粉砕粒であることが好ましい。0.3m
m未満では、風等により飛散したりして環境を悪化させ
る虞れがある。また、粉粒炭と混合したときに、粉体と
粒体がそれぞれに分離し、バランスの採れた環境保全対
策を施すことが難しくなる。一方、19mmを超える
と、土壌面に少量で均一に敷設することが難しくなり、
バランスの採れた環境保全対策を施すことが難しくな
る。特に好ましいのは、当該無機多孔質粉粒体の50%
(重量基準)以上が、JIS Z8801で規定する8
mmの篩を通過し、1.5mmの篩上にとどまる粉砕粒
であり、粉砕粒の直径が1.5mmを超えると、白アリ
が粉砕粒を持ち上げられず、より一層当該効果を助長す
る。
[0007] The inorganic porous powder used in the present invention is a mixture of a porous powder and granules of an inorganic material such as crushing natural soil or crushing natural rock. As the inorganic porous powder, various types can be used, but typically, a diatomaceous earth obtained by pulverizing natural soil is preferably used. Pulverized natural soil of the diatomaceous earth is particularly excellent in moisture absorption and moisture release performance, among which the average pore radius is 20 to 10
0 °, preferably 20-60 °, and a specific surface area of 20-20
The one with 0 m 2 / gr is good for the purpose of taking the balanced environmental preservation measures of the present invention. More than 50% (by weight) of the inorganic porous powder is JIS Z8
It is preferable that the crushed particles pass through a 19 mm sieve specified in 801 and remain on a 0.3 mm sieve. 0.3m
If it is less than m, it may be scattered by wind or the like to deteriorate the environment. In addition, when mixed with pulverized coal, the powder and the granular material are separated from each other, making it difficult to take balanced environmental conservation measures. On the other hand, when it exceeds 19 mm, it is difficult to lay a small amount uniformly on the soil surface,
It will be difficult to take balanced environmental conservation measures. Particularly preferred is 50% of the inorganic porous powder.
(Weight basis) 8 specified by JIS Z8801
The crushed particles pass through a 1.5-mm sieve and remain on the 1.5-mm sieve. When the diameter of the crushed particles exceeds 1.5 mm, termites cannot lift the crushed particles, further promoting the effect.

【0008】本発明で使用される粉粒炭とは、炭化され
た粉末状あるいは粒状物質またはこれら粉末状物質と粒
状物質とが混じり合ったものをいい、例えば、木材や椰
子の実の殻等の植物を炭化することにより、あるいは、
汚泥や産業廃棄物等を焼成することにより得られる。当
該粉粒炭は、上記のように、粉末形態のものでも粒状の
ものでも棒状のもの等でも良いが、好ましくは粒径(直
径)0.3〜19mmの粒状粉粒炭がよい。粒径が0.
3mm未満では、無機多孔質粉粒体と混合するときに飛
散したり、無機多孔質粉粒体と混合したときに、粉粒炭
と無機多孔質粉粒体とが分離し、バランスの採れた環境
保全対策を施すことが難しくなり、また、防腐、防虫、
防蟻処理を施すときに、当該薬剤が定着し難い。一方、
19mmを超えると、吸湿、脱臭効果は良くても、床下
に均一に敷設することが困難でかつ大量に使用しないと
バランスの採れた環境保全対策を施すことが難しくな
る。粉粒炭は、その平均細孔半径が1.5〜100Å
で、比表面積が50〜600m2/gr、好ましくは、
その平均細孔半径が10〜50Åで、比表面積が100
〜300m2/grであることが、粉粒炭と無機多孔質
粉粒体とを混合し、バランスの採れた環境保全対策を施
す上で好ましい。
The granular coal used in the present invention refers to carbonized powdery or granular substances or a mixture of these powdery substances and particulate substances, such as wood and coconut shells. By carbonizing the plant, or
It is obtained by firing sludge and industrial waste. As described above, the granular coal may be in the form of powder, granular, or rod-like, but preferably granular coal having a particle size (diameter) of 0.3 to 19 mm. Particle size is 0.
If it is less than 3 mm, the particles are scattered when mixed with the inorganic porous particles, or when mixed with the inorganic porous particles, the powdered coal and the inorganic porous particles are separated and balanced. It is difficult to take environmental preservation measures.
When performing termite control, the drug is difficult to settle. on the other hand,
If it exceeds 19 mm, it is difficult to lay it evenly under the floor, even if the effect of absorbing and deodorizing is good, and it is difficult to take balanced environmental conservation measures unless it is used in large quantities. Pulverized coal has an average pore radius of 1.5 to 100 °.
And the specific surface area is 50 to 600 m 2 / gr, preferably
Its average pore radius is 10-50 ° and its specific surface area is 100
It is preferably from 300 to 300 m 2 / gr in order to mix the fine-grained coal with the inorganic porous fine powder and to take a balanced environmental preservation measure.

【0009】粉粒炭は、吸着、脱臭効果は良いが、放湿
性能が劣り、吸湿した水分をなかなか放出しない欠点が
あるが、無機多孔質粉粒体との混合により、吸湿性能に
も優れ、又放湿性能にも優れ、バランスの採れた環境保
全対策を施すことができるようになる。しかも、無機多
孔質粉粒体単独では、脱臭効果について臭気の選択性が
あり、良く吸着する物質と吸着しにくい物質があるが、
粉粒炭との混合により、当該臭気の選択性が少なくな
り、バランスの採れた環境保全対策を施すことができる
ようになる。こうしたバランスの採れた環境保全対策を
施すには、両物質を適切な混合割合で混合することが重
要となり、無機多孔質粉粒体に対し粉粒炭が多過ぎたり
すると、吸湿した水分をなかなか放出せず、放湿性との
バランスがとれなくなったり、粉粒炭に対し無機多孔質
粉粒体が多過ぎたりすると、脱臭性能とのバランスがと
れなくなったりする。こうした観点から、本発明におけ
る無機多孔質粉粒体と粉粒炭との混合物における粉粒炭
の混合割合は、20〜80重量%であることが好まし
い。粉粒炭の混合割合が80重量%を越えるときには、
吸湿した水分をなかなか放出せず、吸放湿性能の欠如を
きたし、床下が結露し易い。粉粒炭の混合割合が20重
量%未満では、脱臭、地球に対するマイナスイオン効果
が低く、人間に対して健康的な環境を維持することが難
しくなる。
[0009] Pulverized coal has good adsorption and deodorizing effects, but has poor moisture release performance and has a drawback that it does not readily release absorbed moisture, but also has excellent moisture absorption performance when mixed with inorganic porous powder. In addition, it has excellent moisture release performance, and can take balanced environmental preservation measures. Moreover, the inorganic porous powder alone has odor selectivity with respect to the deodorizing effect, and there are substances that adsorb well and substances that do not easily adsorb.
By mixing with pulverized coal, the selectivity of the odor is reduced, and balanced environmental conservation measures can be taken. In order to take such balanced environmental preservation measures, it is important to mix both substances in an appropriate mixing ratio.If there is too much fine coal in the inorganic porous powder, it is difficult to remove the moisture absorbed. If the powder is not released and the balance with the moisture release property cannot be obtained, or if the amount of the inorganic porous powder is too large relative to the powdered coal, the balance with the deodorizing performance cannot be obtained. From such a viewpoint, the mixing ratio of the granular coal in the mixture of the inorganic porous granular material and the granular coal in the present invention is preferably 20 to 80% by weight. When the mixing ratio of pulverized coal exceeds 80% by weight,
It does not readily release the absorbed moisture, resulting in a lack of moisture absorption and desorption performance, and is easily condensed under the floor. If the mixing ratio of the pulverized coal is less than 20% by weight, deodorization and negative ion effects on the earth are low, and it is difficult to maintain a healthy environment for humans.

【0010】本発明では上記無機多孔質粉粒体と粉粒炭
およびフイルム類の少なくともいずれか一つ以上に防
腐、防虫、防蟻処理を施すとよい。当該防腐、防虫、防
蟻処理には各種の防腐防虫防蟻剤(以下、単に、薬剤と
いうこともある)を使用することが出来る。ここに例示
すると、有機リン系化合物、ピレスロイド系化合物、ピ
レスロイド様化合物、クロロニコチル系化合物、カーバ
メイト系化合物、有機塩素系化合物、トリプロピルイソ
シアヌレート、イミダクロプリド、ほう素化合物、ナフ
テン酸金属塩、アルキルアンモニウム化合物、有機よう
素化合物、フェノール類、8−オキシキノリノール銅、
クロルフェノール及びブロムフェノール類、クロルナフ
タリン類、キシラザン類、その他化合物等がある。これ
らの薬剤は、そのものにあった形態に製剤され用いられ
る。本発明における上記無機多孔質粉粒体、粉粒炭の防
腐、防虫、防蟻処理においては、木酢液の吸着処理を施
すことも可能である。木酢液は、木材を乾留することに
より得ることができる。木材を乾留することにより得ら
れる液体生成物を静置すると2層に分離するが、その上
層の酢酸を多く含む層が木酢液である。原料としての木
材の樹種には、広葉樹や針葉樹が使用される。廃材を使
用することもできる。木酢液は、適宜水により希釈して
使用することができる。木酢液は、その生産の際に、有
害物質や低沸点のカルボニル化合物等を包含する。ま
た、木タールの一部やメタノール、ホルムアルデヒド等
が含まれる。精製木酢液(純正木酢液)を使用すること
が好ましい。木酢液は、その有効成分としての酢酸を高
濃度に例えば73%近く含む。pHが、3以下とかなり
酸性が高いものになっている。上記のように、防腐、防
虫、防蟻処理を施す場合、その薬剤の無機多孔質粉粒体
や粉粒炭やフイルム類に対する処理量(付着量)が多過
ぎる時には、かえって、居住環境を悪化させる場合もあ
るので、10wt%以下に留めておくことが好ましい。
In the present invention, it is preferred that at least one of the above-mentioned inorganic porous powder, powdered charcoal, and films is subjected to antiseptic, insect repellent and termite control treatments. Various preservatives, insect repellents, and termiticides (hereinafter sometimes simply referred to as chemicals) can be used for the preservation, insect repellent and termite repellent treatments. When exemplified here, an organic phosphorus compound, a pyrethroid compound, a pyrethroid-like compound, a chloronicotyl compound, a carbamate compound, an organic chlorine compound, tripropyl isocyanurate, imidacloprid, a boron compound, a metal salt of naphthenic acid, an alkyl ammonium compound , Organic iodine compounds, phenols, 8-oxyquinolinol copper,
Chlorphenol and bromophenols, chlornaphthalenes, xylazanes, other compounds, and the like. These drugs are formulated and used in a form suitable for the drug itself. In the preservation, insect repellent, and termite repellent treatment of the inorganic porous powder and the particulate coal in the present invention, a wood vinegar liquid adsorption treatment can be performed. The wood vinegar can be obtained by carbonizing wood. When the liquid product obtained by carbonizing wood is allowed to stand, it separates into two layers. The upper layer containing acetic acid is wood vinegar. Hardwoods and conifers are used as wood species as raw materials. Waste material can also be used. The wood vinegar can be appropriately diluted with water for use. The wood vinegar solution contains harmful substances and low-boiling carbonyl compounds during its production. It also contains a part of wood tar, methanol, formaldehyde and the like. It is preferable to use a purified wood vinegar solution (pure wood vinegar solution). The wood vinegar solution contains acetic acid as an active ingredient in a high concentration, for example, near 73%. The pH is quite high, being 3 or less. As described above, when the preservative, insect repellent, and termite treatments are applied, if the treatment amount (adhesion amount) of the agent to inorganic porous powders, powdered charcoal, and films is excessive, the living environment is rather deteriorated. In some cases, the content is preferably set to 10 wt% or less.

【0011】[0011]

【発明の実施の形態】BEST MODE FOR CARRYING OUT THE INVENTION

【0012】[0012]

【実施例】次に、本発明の実施例を示す。尚、フイルム
の透湿度は、以下の測定法に準拠して行なった。 フイルムの透湿度:40℃、相対湿度差が90%の条件
で厚さ0.1mm,面積1m2のフイルムを24時間で
通過する水蒸気量のg数[単位;g/m2・24hr
s]で示す。
Next, examples of the present invention will be described. The moisture permeability of the film was measured according to the following measurement method. Moisture permeability of the film: The number of grams of water vapor passing through a film having a thickness of 0.1 mm and an area of 1 m 2 in 24 hours under the conditions of 40 ° C. and a relative humidity difference of 90% [unit: g / m 2 · 24 hr]
s].

【0013】参考例1.透湿度が、各々2000g/m
2・24hrs、6000g/m2・24hrsおよび1
2000g/m2・24hrsのフイルムを用い、PE
T(ポリエチレンテレフタレート)製容器(高さ45m
m、開口部直径100mm、低面部直径80mmの円形
容器)に、代用土壌(園芸用培養土:バーミキュライ
ト:腐葉土:水=8:1:1:1.5)を約100cc
入れ、土壌面にスギ木片(20x20x10mm)を置
き、開口部を前記フイルムで覆った。内部の木片等の変
化の観察と容器全体の重量変化を観察した。その結果を
表1に示す。
Reference Example 1 2000 g / m each moisture permeability
2 · 24hrs, 6000g / m 2 · 24hrs and 1
Using a film of 2000 g / m 2 · 24 hrs, PE
T (Polyethylene terephthalate) container (45m high)
m, a circular container having an opening diameter of 100 mm and a low side diameter of 80 mm), about 100 cc of substitute soil (horticultural culture soil: vermiculite: humus: water = 8: 1: 1: 1.5)
Then, a piece of cedar wood (20 × 20 × 10 mm) was placed on the soil surface, and the opening was covered with the film. Observation of changes in internal wood chips and the like and changes in the weight of the entire container were observed. Table 1 shows the results.

【0014】比較参考例1.透湿度が10g/m2・2
4hrsのフイルムを用いた他は、参考例1と同様にし
て、容器内部の木片等の変化の観察と容器全体の重量変
化を観察した。その結果を表1に示す。
Comparative Reference Example 1. Moisture permeability of 10g / m 2 · 2
Except that a 4 hrs film was used, the observation of changes in the wood chips inside the container and the change in weight of the entire container were observed in the same manner as in Reference Example 1. Table 1 shows the results.

【0015】[0015]

【表1】 [Table 1]

【0016】実施例1.980x1880x2700m
mのプレハブ小屋を建て、床下高さを450mmにして
床下空間を造り、土壌面に透湿度が6000g/m2
24hrsのフイルムを敷き、その上に、平均細孔半径
が20〜40Å、比表面積が190〜200m2/gr
の珪藻土(稚内層珪質頁岩)と平均細孔半径が5〜20
Å、比表面積が500〜600m2/grの粉粒炭
((これら珪藻土および粉粒炭は、共にJIS Z88
01 8mmの篩を通過し、JIS Z8801 2m
mの篩上に残った粉粒体を50wt%以上含む。)と
を、50:50の割合で配合した混合物を敷設し、床下
空間を密閉状態にした後、スギ木片(100x100x
5mm)を吊るし、毎日200ccの水分を加湿器によ
り与え、床下空間の結露と黴の発生状況および木片の含
水率と状態を観察した。その結果を表2に示す。
Embodiment 1.980 × 1880 × 2700 m
built a prefabricated hut of m, build the underfloor space and under the floor height to 450mm, moisture permeability to the soil surface is 6000g / m 2 ·
A 24 hrs film is laid, and the average pore radius is 20 to 40 ° and the specific surface area is 190 to 200 m 2 / gr.
Diatomaceous earth (wakkanai siliceous shale) and average pore radius of 5-20
粉, pulverized coal having a specific surface area of 500 to 600 m 2 / gr ((Diatomaceous earth and pulverized coal are both JIS Z88
018 through a 8mm sieve, JIS Z8801 2m
m containing 50 wt% or more of the powdery particles remaining on the sieve. ) And a mixture of 50:50 was laid, and the underfloor space was sealed.
5 mm) was hung, and 200 cc of water was given by a humidifier every day. The dew condensation in the underfloor space, the occurrence of mold, and the moisture content and condition of the wood chips were observed. Table 2 shows the results.

【0017】実施例2.透湿度が12000g/m2
24hrsのフイルムを用いた他は、実施例1と同様に
して、床下空間の結露と黴の発生状況および木片の含水
率と状態を観察した。その結果を表2に示す。
Embodiment 2 FIG. Moisture permeability 12000g / m 2
Except that a 24 hrs film was used, the dew condensation in the underfloor space and the occurrence of mold and the moisture content and state of the wood chips were observed in the same manner as in Example 1. Table 2 shows the results.

【0018】実施例3 珪藻土に、クロルピリホスの薬剤有効成分が1.0%
(wt,以下同じ)含有されるように、当該薬剤を吸着
させた他は、実施例1と同様にして、床下空間の結露と
黴の発生状況および木片の含水率と状態を観察した。そ
の結果を表2に示す。
Example 3 Diatomaceous earth contains 1.0% of an active pharmaceutical ingredient of chlorpyrifos.
In the same manner as in Example 1 except that the drug was adsorbed so as to be contained (wt, the same applies hereinafter), the dew condensation in the underfloor space, the occurrence of mold, and the moisture content and state of the wood chips were observed. Table 2 shows the results.

【0019】比較例1.土壌面に透湿度が6000g/
2・24hrsのフイルムを敷いただけの状態にした
他は、実施例1と同様にして、床下空間の結露と黴の発
生状況および木片の含水率と状態を観察した。その結果
を表3に示す。
Comparative Example 1 6000g / moisture permeability on the soil surface
except that the state of the just laid the film of m 2 · 24hrs, the same procedure as in Example 1, were observed moisture content and the state of occurrence and wood pieces of condensation and mold underfloor space. Table 3 shows the results.

【0020】比較例2.透湿度が600g/m2・24
hrsのフイルムを用いた他は、実施例1と同様にし
て、床下空間の結露と黴の発生状況および木片の含水率
と状態を観察した。その結果を表3に示す。
Comparative Example 2 Moisture permeability of 600g / m 2 · 24
Except that the hrs film was used, the same conditions as in Example 1 were used to observe the dew condensation in the underfloor space, the occurrence of mold, and the water content and state of the wood chips. Table 3 shows the results.

【0021】比較例3.透湿度が23000g/m2
24hrsのフイルムを用いた他は、実施例1と同様に
して、床下空間の結露と黴の発生状況および木片の含水
率と状態を観察した。その結果を表3に示す。
Comparative Example 3 The moisture permeability is 23000 g / m 2.
Except that a 24 hrs film was used, the dew condensation in the underfloor space and the occurrence of mold and the moisture content and state of the wood chips were observed in the same manner as in Example 1. Table 3 shows the results.

【0022】[0022]

【表2】 [Table 2]

【0023】[0023]

【表3】 [Table 3]

【0024】参考例2.クロルピリホスの薬剤有効成分
が1.0%(wt,以下同じ)含有されるように、当該
薬剤を吸着させた珪藻土(稚内層珪質頁岩)と、平均細
孔半径が20〜40Å、比表面積が190〜200m2
/grの珪藻土(稚内層珪質頁岩)と、平均細孔半径が
20〜35Å、比表面積が200m2/grの粉粒炭と
を、15:65:20の割合で配合した混合物を調製し
た。尚、これら粉粒炭と珪藻土とは、両者共にJIS
Z8801 19mmの篩を通過し、JIS Z880
1 0.3mmの篩上に残った粉粒体を50wt%以上
含んでいた。このように配合された混合物を(社)日本
木材保存協会規格第17号「防蟻剤処理非木材系製品の
室内防蟻効力試験方法及び性能基準」に基づいて、忌避
性能試験、白蟻貫通防止試験を行った。また、(社)日
本木材保存協会規格第11号「塗付・吹付け・浸漬処理
用木材防蟻剤の防蟻効力試験方法(1)室内試験方法」
に準じて、接触試験を行った。更に、吸湿・放湿性能試
験を次のようにして行なった。すなわち、シャーレ(9
0mm¢×20mmH)にブレンド品を30grとり、
精秤して、底部に30℃の温水150mlを入れたデシ
ケーター(内径180mm×180mmH)に入れ、4
0℃の恒温器に7日間放置し、経過後サンプルをすばや
く測定して吸湿量を計算した。その後、室温に3日間放
置してサンプル重量を測定し、放湿量を求めた。更に
又、脱臭効果の測定のため次の試験を行った。即ち、右
上端部に突出したガス入口を有するテトラバッグと左上
端部に突出したガス入口を有するテトラバッグとをゴム
管で接続した検知管(北川式検知管、全体容量10リッ
ター)の一方のテトラバッグ側に、測定液を入れ気化さ
せ、空気を入れて下記のようにガス初期濃度を調整し、
他方のテトラバッグ側に試料(各試料共10g/1試
料)を入れて、ゴム管で接続した一方のテトラバッグ側
から他方のテトラバッグ側にガスを移行させ、当該試料
に吸収されたガスの吸収量(%)を測定した。 ガス初期濃度: アンモニアガス 1000 p.p.m 酢酸ガス 1000 p.p.m ピリジン 200 p.p.m メルカプタン 10 p.p.m トリメチルブタン 10 p.p.m 硫化水素 1000 p.p.m 試験結果を表4〜表6および表8〜表9に示す。
Reference Example 2 Diatomaceous earth (Waknai layer siliceous shale) to which the drug is adsorbed so that the drug active ingredient of chlorpyrifos is contained at 1.0% (wt, the same applies hereinafter), the average pore radius is 20 to 40 mm, and the specific surface area is 190-200m 2
/ Gr. Diatomaceous earth (Wakkanai siliceous shale) and a granular coal having an average pore radius of 20 to 35 ° and a specific surface area of 200 m 2 / gr were prepared at a ratio of 15:65:20. . In addition, these powdered coal and diatomaceous earth are both JIS.
Z8801 After passing through a 19 mm sieve, JIS Z880
The powder contained 50 wt% or more of the particles remaining on the 10.3 mm sieve. The mixture thus blended is tested for repellency and termite penetration based on the Japanese Wood Preservation Association Standard No. 17 "Method and Performance Standard for Indoor Termite Control of Non-wood Products Treated with Termites". The test was performed. Also, Japan Wood Preservation Association Standard No. 11 "Testing method for termite-controlling effectiveness of wood termiticides for coating, spraying and dipping (1) Laboratory test method"
A contact test was conducted according to Further, a moisture absorption / desorption performance test was performed as follows. That is, the petri dish (9
0mm ¢ × 20mmH), take 30gr of the blended product,
Weigh precisely, put it in a desiccator (inner diameter 180 mm × 180 mmH) containing 150 ml of 30 ° C. hot water at the bottom,
The sample was allowed to stand in a thermostat at 0 ° C. for 7 days. After the elapse, the sample was quickly measured to calculate the moisture absorption. Thereafter, the sample was allowed to stand at room temperature for 3 days, the weight of the sample was measured, and the amount of released moisture was determined. Further, the following test was performed to measure the deodorizing effect. That is, one of a detection tube (Kitakawa type detection tube, total capacity of 10 liters) in which a tetrabag having a gas inlet projecting at the upper right end and a tetrabag having a gas inlet projecting at the upper left end are connected by a rubber tube. On the tetra bag side, put the measurement liquid and vaporize, put air and adjust the gas initial concentration as follows,
A sample (10 g / 1 sample for each sample) was placed in the other tetrabag, and gas was transferred from one tetrabag connected to the rubber tube to the other tetrabag, and the gas absorbed by the sample was removed. The amount of absorption (%) was measured. Gas initial concentration: ammonia gas 1000 p. p. acetic acid gas 1000 p. p. m pyridine 200 p. p. m mercaptan 10 p. p. m trimethylbutane 10 p. p. m hydrogen sulfide 1000 p. p. m The test results are shown in Tables 4 to 6 and 8 to 9.

【0025】参考例3 パーメスリンの薬剤有効成分が0.2%含有されるよう
に、当該薬剤を平均細孔半径が50〜80Å、比表面積
が90m2/grの珪藻土(稚内層珪質頁岩)に吸着さ
せた物と、平均細孔半径が20〜35Å、比表面積が1
80m2/grの珪藻土と、平均細孔半径が60〜80
Å、比表面積が50〜100m2/grの粉粒炭(これ
ら各珪藻土および粉粒炭は、共にJIS Z8801
8mmの篩を通過し、JIS Z8801 1.5mm
の篩上に残った粉粒体を50wt%以上含む。)とを、
5:65:30の割合で配合した混合物を用いた他は、
参考例2と同様にした。試験結果を表4〜表6および表
8〜表9に示す。
Reference Example 3 Diatomaceous earth (wakkanai siliceous shale) having an average pore radius of 50 to 80 ° and a specific surface area of 90 m 2 / gr so that the active ingredient of permethrin is contained at 0.2%. With an average pore radius of 20 to 35 ° and a specific surface area of 1
80 m 2 / gr diatomaceous earth having an average pore radius of 60 to 80
Å, pulverized coal having a specific surface area of 50 to 100 m 2 / gr (these diatomaceous earth and pulverized coal are both JIS Z8801)
8mm sieve, JIS Z8801 1.5mm
Contains 50 wt% or more of the powdery particles remaining on the sieve. ) And
Except for using a mixture blended at a ratio of 5:65:30,
Same as Reference Example 2. The test results are shown in Tables 4 to 6 and 8 to 9.

【0026】参考例4 平均細孔半径が20〜40Å、比表面積が190〜20
0m2/grの珪藻土(稚内層珪質頁岩)と平均細孔半
径が5〜20Å、比表面積が500〜600m2/gr
の粉粒炭((これら珪藻土および粉粒炭は、共にJIS
Z88018mmの篩を通過し、JIS Z8801
2mmの篩上に残った粉粒体を50wt%以上含
む。)とを、50:50の割合で配合した混合物を用い
た他は、実施例1と同様にした。試験結果を表4〜表6
および表8〜表9に示す。
Reference Example 4 The average pore radius is 20-40 ° and the specific surface area is 190-20.
0 m 2 / gr diatomaceous earth (wakkanai siliceous shale), average pore radius of 5 to 20 °, specific surface area of 500 to 600 m 2 / gr
Coal ((These diatomaceous earth and coal are both JIS
Z88018mm sieve, JIS Z8801
The powder contains 50 wt% or more of the particles remaining on the 2 mm sieve. ) Was used in the same manner as in Example 1 except that a mixture in which 50:50 was used was used. Table 4 to Table 6 show the test results.
And Tables 8 and 9.

【0027】参考例5 平均細孔半径が70Å、比表面積が100m2/grの
珪藻土(稚内層珪質頁岩)と平均細孔半径が35〜60
Å、比表面積が300m2/grの粉粒炭((これら珪
藻土および粉粒炭は、共にJIS Z8801 8mm
の篩を通過し、JIS Z8801 0.5mmの篩上
に残った粉粒体を50wt%以上含む。)とを、20:
80の割合で配合した混合物を、片面通気性があり、片
面は薬剤有効成分として1.0%のクロルピリホスが含
有されている合成樹脂の袋に入れた他は、参考例2と同
様にした。試験結果を表4〜表6および表8〜表9に示
す。
Reference Example 5 Diatomaceous earth (wakkanai siliceous shale) having an average pore radius of 70 ° and a specific surface area of 100 m 2 / gr, and an average pore radius of 35-60.
粉, pulverized coal having a specific surface area of 300 m 2 / gr ((both diatomaceous earth and pulverized coal are JIS Z88018 mm
Containing 50 wt% or more of the powdery granules that passed through the sieve of No. JIS Z8801 and remained on a 0.5 mm sieve. ) And 20:
The same procedure as in Reference Example 2 was carried out except that the mixture blended at a ratio of 80 was air-permeable on one side, and one side was placed in a bag of a synthetic resin containing 1.0% of chlorpyrifos as an active ingredient. The test results are shown in Tables 4 to 6 and 8 to 9.

【0028】参考例6 ビフェントリンの薬剤有効成分が0.05%含有される
ように、当該薬剤を平均細孔半径が30〜50Å、比表
面積が500m2/grの粉粒炭に吸着させた物と、平
均細孔半径が50Å、比表面積が60m2/grの珪藻
土(稚内層珪質頁岩)とを(両者共にJIS Z880
1 8mmの篩を通過し、JIS Z8801 1mm
の篩上に残った粉粒体を50wt%以上含む。)、7
0:30の割合で配合した混合物を用いた他は、実施例
1と同様にした。試験結果を表4〜表6および表8〜表
9に示す。
Reference Example 6 A substance obtained by adsorbing bifenthrin on pulverized coal having an average pore radius of 30 to 50 ° and a specific surface area of 500 m 2 / gr so that the active ingredient of bifenthrin is contained at 0.05%. And a diatomaceous earth (wakkanai siliceous shale) having an average pore radius of 50 ° and a specific surface area of 60 m 2 / gr (both are JIS Z880).
After passing through a 18 mm sieve, JIS Z8801 1 mm
Contains 50 wt% or more of the powdery particles remaining on the sieve. ), 7
The procedure was the same as in Example 1, except that a mixture blended at a ratio of 0:30 was used. The test results are shown in Tables 4 to 6 and 8 to 9.

【0029】比較参考例2 薬剤無処理の細孔半径10〜20nmのヤシガラ活性炭
(JIS Z88018mmの篩を通過し、JIS Z
8801 2mmの篩上に残った粉粒炭を50wt%以
上含む)を単独で用いた他は、参考例2と同様にした。
試験結果を表4〜表5および表7〜表9に示す。
Comparative Reference Example 2 Untreated chemical coconut shell activated carbon having a pore radius of 10 to 20 nm (JIS Z88018 mm passed through a sieve,
The same operation as in Reference Example 2 was carried out, except that the powdered coal remaining on the 88012 mm sieve was 50 wt% or more.
The test results are shown in Tables 4 to 5 and 7 to 9.

【0030】比較参考例3 薬剤無処理の平均細孔半径10〜15nmのセピオライ
ト(JIS Z8801 8mmの篩を通過し、JIS
Z8801 2mmの篩上に残った粉粒体を50wt
%以上含む。)を単独で用いた他は、参考例2と同様に
した。試験結果を表4〜表5および表7〜表9に示す。
Comparative Reference Example 3 A non-drug treated sepiolite having an average pore radius of 10 to 15 nm (JIS Z88018 passed through a 8 mm sieve, and passed through a JIS sieve).
50% by weight of the powder and granules remaining on the Z8801 2mm sieve
% Or more. ) Was used alone, except that) was used alone. The test results are shown in Tables 4 to 5 and 7 to 9.

【0031】比較参考例4 薬剤無処理ののパルプスラッジを焼成して得られた活性
炭(JIS Z8801 8mmの篩を通過し、JIS
Z8801 2mmの篩上に残った粉粒炭を50wt
%以上含む)を単独で用いた他は、参考例2と同様にし
た。試験結果を表4〜表5および表7〜表9に示す。
COMPARATIVE REFERENCE EXAMPLE 4 Activated carbon obtained by calcining pulp sludge without treatment (JIS Z8801; passed through an 8 mm sieve;
50% of the powdered coal remaining on the Z8801 2mm sieve
% Or more) was used alone, except that Reference Example 2 was used. The test results are shown in Tables 4 to 5 and 7 to 9.

【0032】[0032]

【表4】 [Table 4]

【0033】[0033]

【表5】 [Table 5]

【0034】[0034]

【表6】 [Table 6]

【0035】[0035]

【表7】 [Table 7]

【0036】[0036]

【表8】 [Table 8]

【0037】[0037]

【表9】 [Table 9]

【0038】以上本発明者によってなされた発明を実施
例にもとずき具体的に説明したが、本発明は上記実施例
に限定されるものではなく、その要旨を逸脱しない範囲
で種々変更可能であることはいうまでもない。
Although the invention made by the inventor has been specifically described based on the embodiments, the present invention is not limited to the above-described embodiments, and can be variously modified without departing from the gist thereof. Needless to say,

【0039】[0039]

【発明の効果】本願において開示される発明のうち代表
的なものによって得られる効果を簡単に説明すれば、下
記のとおりである。すなわち、本発明によれば、吸湿性
能が高いだけでなく、適宜湿分を放湿して、床下におけ
る湿度を適宜の状態に調節でき、カビの発生を防止し、
白蟻等の有害昆虫等の侵入および繁殖を阻止し、また、
床下に発生する異臭の除去効果が高く、床下の環境を好
適に保全することができる。また、フイルム類上の混合
物の能力低下を防止し、湿分の吸湿と放湿とのバランス
をとり、床下が高湿度状態に陥ることを防止し、密閉さ
れた床下空間の水蒸気量をコンスタントな状態に保持で
きる。さらに、床下土壌の有機物のくされ防止に役立た
せることができる。
The effects obtained by the representative ones of the inventions disclosed in the present application will be briefly described as follows. That is, according to the present invention, not only the moisture absorption performance is high, but also by appropriately releasing moisture, the humidity under the floor can be adjusted to an appropriate state, preventing the occurrence of mold,
Prevent invasion and reproduction of harmful insects such as termites,
The effect of removing off-flavors generated under the floor is high, and the environment under the floor can be suitably preserved. It also prevents the capacity of the mixture on the film from deteriorating, balances the absorption and release of moisture, prevents the underfloor from falling into a high-humidity state, and constantly reduces the amount of water vapor in the closed underfloor space. Can be kept in a state. Further, it can be used to prevent the organic matter in the underfloor soil from being broken down.

───────────────────────────────────────────────────── フロントページの続き (71)出願人 392012397 ケミホルツ株式会社 京都府久世郡久御山町大字佐山小字新開地 194−1 (72)発明者 吉田 繁夫 大阪府豊中市新千里西町1丁目1番4号 ナショナル住宅産業株式会社内 (72)発明者 石原 緑 大阪府豊中市新千里西町1丁目1番4号 ナショナル住宅産業株式会社内 (72)発明者 堀家 大士 大阪府豊中市新千里西町1丁目1番4号 ナショナル住宅産業株式会社内 (72)発明者 松下 量己 大阪府豊中市新千里西町1丁目1番4号 ナショナル住宅産業株式会社内 (72)発明者 永井 了 岐阜県土岐市駄知町2321番地の2 高砂工 業株式会社内 (72)発明者 田中 勝浩 香川県丸亀市中津町1515番地 大倉工業株 式会社内 (72)発明者 勝沢 善永 東京都板橋区板橋4丁目13番1号 大鹿振 興株式会社内 (72)発明者 斎藤 隆信 京都府久世郡久御山町大字佐山小字新開地 194−1 ケミホルツ株式会社内 ──────────────────────────────────────────────────続 き Continuation of the front page (71) Applicant 392012397 Kemiholtz Co., Ltd. 194-1, Kamiyama-cho, Kuse-gun, Kyoto, Japan Newly opened Sayama small-sized area 194-1 (72) Inventor Shigeo Yoshida 1-1-4 Shinsenri Nishimachi, Toyonaka-shi, Osaka National Inside the Housing Industry Co., Ltd. (72) Inventor Midori Ishihara 1-1-4 Shinsenri-Nishimachi, Toyonaka City, Osaka Prefecture Inside the National Housing Industry Co., Ltd. No. 4 Inside the National Housing Industry Co., Ltd. (72) Inventor Kazumi Matsushita 1-4-1, Shinsenri Nishimachi, Toyonaka City, Osaka Prefecture Inside the National Housing Industry Co., Ltd. (2) Inventor Katsuhiro Tanaka 1515 Nakatsucho, Marugame City, Kagawa Prefecture Okura Industry Co., Ltd. The inner (72) inventor Katsusawa YoshiHisashi Itabashi-ku, Tokyo Itabashi 4-chome 13th No. 1 Oshika vibration Xing within Co., Ltd. (72) inventor Takanobu Saito Kyoto Prefecture Kuse District Kumiyama Oaza Sayama Sublocality new frontier 194-1 Kemihorutsu within Co., Ltd.

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 建築物の床下土壌面に透湿度が1000
g/m2・24hrs〜20000g/m2・24hrs
のフイルムおよび/または不織布を敷設し、当該フイル
ムおよび/または不織布上に粉粒炭を除く無機多孔質粉
粒体と粉粒炭との混合物を敷設することを特徴とする建
築物床下の環境維持工法。
1. A structure having a moisture permeability of 1000 under the floor of a building.
g / m 2 · 24hrs~20000g / m 2 · 24hrs
Characterized by laying a film and / or non-woven fabric of the present invention, and laying a mixture of inorganic porous granules other than granulated coal and granulated coal on the film and / or non-woven fabric. Construction method.
【請求項2】 無機多孔質粉粒体の平均細孔半径が20
〜100Å、比表面積が20〜200m2/grである
ことを特徴とする、請求項1に記載の建築物床下の環境
維持工法。
2. The inorganic porous powder has an average pore radius of 20.
2. The method for maintaining an environment under a building floor according to claim 1, wherein the specific surface area is 20 to 200 m 2 / gr.
【請求項3】 粉粒炭の平均細孔半径が1.5〜100
Å、比表面積が50〜600m2/grであることを特
徴とする、請求項1に記載の建築物床下の環境維持工
法。
3. The pulverized coal has an average pore radius of 1.5 to 100.
The method for maintaining an environment under a building floor according to claim 1, wherein the specific surface area is 50 to 600 m 2 / gr.
【請求項4】 無機多孔質粉粒体と粉粒炭の相互の混合
割合が、20〜80重量%であることを特徴とする、請
求項1、2または3に記載の建築物床下の環境維持工
法。
4. The under-floor environment of a building according to claim 1, wherein the mixing ratio of the inorganic porous powder and the powdered coal is 20 to 80% by weight. Maintenance method.
【請求項5】 無機多孔質粉粒体および粉粒炭が、その
50%以上がJISZ8801で規定する19mmの篩
を通過し、0.3mmの篩上にとどまる粉砕粒であるこ
とを特徴とする、請求項1、2、3または4に記載の建
築物床下の環境維持工法。
5. The method according to claim 1, wherein 50% or more of the inorganic porous powder and the granular coal are pulverized particles that pass through a 19 mm sieve specified in JISZ8801 and remain on a 0.3 mm sieve. The method for maintaining an environment under a building floor according to claim 1, 2, 3, or 4.
【請求項6】 無機多孔質粉粒体と粉粒炭とフイルムお
よび/または不織布の少なくとも一以上に防腐、防虫、
防蟻処理を施したことを特徴とする、請求項1、2、
3、4または5に記載の建築物床下の環境維持工法。
6. An antiseptic, insect repellent, at least one of inorganic porous powder, powdered charcoal, film and / or non-woven fabric.
The termite-proof treatment has been performed, The claim 1, 2,
The method for maintaining an environment under a building floor according to 3, 4, or 5.
JP22466396A 1996-08-08 1996-08-08 Environment maintaining method in under floor of building Pending JPH1046688A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22466396A JPH1046688A (en) 1996-08-08 1996-08-08 Environment maintaining method in under floor of building

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22466396A JPH1046688A (en) 1996-08-08 1996-08-08 Environment maintaining method in under floor of building

Publications (1)

Publication Number Publication Date
JPH1046688A true JPH1046688A (en) 1998-02-17

Family

ID=16817268

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22466396A Pending JPH1046688A (en) 1996-08-08 1996-08-08 Environment maintaining method in under floor of building

Country Status (1)

Country Link
JP (1) JPH1046688A (en)

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