JPH10313819A - Sweet food - Google Patents

Sweet food

Info

Publication number
JPH10313819A
JPH10313819A JP9124162A JP12416297A JPH10313819A JP H10313819 A JPH10313819 A JP H10313819A JP 9124162 A JP9124162 A JP 9124162A JP 12416297 A JP12416297 A JP 12416297A JP H10313819 A JPH10313819 A JP H10313819A
Authority
JP
Japan
Prior art keywords
derivative
sweetness
sweet food
menthyl
sweetener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9124162A
Other languages
Japanese (ja)
Other versions
JP3869071B2 (en
Inventor
Masanobu Yoshiya
正信 吉屋
Masahiro Shimoizumi
雅宥 下泉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SANEI GEN F F I Inc
San Ei Gen FFI Inc
Original Assignee
SANEI GEN F F I Inc
San Ei Gen FFI Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SANEI GEN F F I Inc, San Ei Gen FFI Inc filed Critical SANEI GEN F F I Inc
Priority to JP12416297A priority Critical patent/JP3869071B2/en
Publication of JPH10313819A publication Critical patent/JPH10313819A/en
Application granted granted Critical
Publication of JP3869071B2 publication Critical patent/JP3869071B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Tea And Coffee (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Seasonings (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a sweet food having a plain aftertaste free from bitterness and astringency after eating and long remaining thick sweetness, by including a sweetener having a high degree of sweetness and a specific amount of a p-menthane skeleton-containing derivative. SOLUTION: This sweet food contains (A) a sweetener having a high degree of sweetness and (B) a p-menthane skeleton-containing derivative, preferably 1-menthyl-3-hydroxybutyrate, 1-menthyl acetate, 1-menthyl lactate, 3-1- menthyloxy-1,2-propanediol in an added amount equal to or smaller than a threshold value.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、甘味食品に関する
ものであり、詳細には、食した後に苦味や渋味が少な
く、後引きのくどい甘味が感じられず、さっぱりとした
後味を有する高甘味度甘味料を用いた甘味食品に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sweet food product, and more particularly, to a high-sweetness product having little bitterness or astringency after eating, not having an intense aftertaste, and a refreshing aftertaste. The present invention relates to a sweet food using a degree sweetener.

【0002】[0002]

【従来の技術】従来から、食品や歯磨き剤等の口腔に含
ませるものの甘味料として砂糖の数十倍以上の甘味を持
つ高甘味度甘味料が用いられている。しかし、高甘味度
甘味料をこれら食品等に添加した場合、口にした後に高
甘味度甘味料由来のくどい甘味が残り、後味が悪くなる
という問題があった。
2. Description of the Related Art Conventionally, a high-intensity sweetener having a sweetness several tens times or more that of sugar has been used as a sweetener to be contained in the oral cavity such as foods and dentifrices. However, when a high-intensity sweetener is added to these foods or the like, there is a problem that a severe sweetness derived from the high-intensity sweetener remains in the mouth and the aftertaste deteriorates.

【0003】その改善策として、特開昭56−6581
3号公報には、アンモニア化グリチルリジンとメントー
ルとからなる着香料が記載されており、甘味値を抑制す
ることなく、不快な甘草様後味を押さえるとされてい
る。しかし、アンモニア化グリチルリジンの甘草味を押
さえるためにアンモニア化グリチルリジンの重量に基づ
いて約60〜70%のメントールを含有するため、メン
トールそのものの清涼感によりマスキングし、不快な後
味を感じられなくするものであった。
[0003] As a remedy, Japanese Patent Application Laid-Open No. 56-6581
No. 3 discloses a flavoring agent composed of ammoniated glycyrrhizin and menthol, which suppresses an unpleasant licorice-like aftertaste without suppressing the sweetness value. However, in order to suppress the licorice taste of ammoniated glycyrrhizin, menthol is contained in an amount of about 60 to 70% based on the weight of ammoniated glycyrrhizin, so that the menthol itself is masked by the refreshing sensation to prevent unpleasant aftertaste. Met.

【0004】[0004]

【発明が解決しようとする課題】本発明は、かかる事情
に鑑みて開発されたものであり、食した後に高甘味度甘
味料由来のくどい甘味が残らず、さっぱりとした後味を
有する甘味食品を提供することを目的とする。
DISCLOSURE OF THE INVENTION The present invention has been developed in view of the above circumstances, and is intended to provide a sweet food having a refreshing aftertaste without leaving an intense sweetness derived from a high-intensity sweetener after eating. The purpose is to provide.

【0005】[0005]

【課題を解決するための手段】本発明者らは、上記従来
技術の問題点に鑑みて鋭意研究を重ねていたところ、偶
然にも甘味付与に高甘味度甘味料を用いた際、閾値以下
量のp−メンタン骨格を持つ誘導体から選ばれる1種又
は2種以上を含ませることにより、食した後にくどい甘
味が感じられず、さっぱりとした後味の有する甘味食品
を提供できることを見いだし、本発明を完成させるに至
った。
Means for Solving the Problems The inventors of the present invention have conducted intensive studies in view of the above-mentioned problems of the prior art, and found that when a high-intensity sweetener was accidentally used for imparting sweetness, it was lower than a threshold value. It has been found that by including one or more selected from derivatives having a p-menthane skeleton in an amount, it is possible to provide a sweet food having a refreshing aftertaste without having an intense sweet taste after eating. Was completed.

【0006】従来、食品等にメントール等のp−メンタ
ン骨格を持つ誘導体を閾値以下量添加すると、単独では
全く味には影響しないものであったが、高甘味度甘味料
と併用する際、偶然にも不快な後味を改善する効果があ
ることを発見し、本発明に至ったものである。
Conventionally, when a derivative having a p-menthane skeleton such as menthol is added to a food or the like in an amount less than a threshold value, the taste alone is not affected at all. However, when it is used in combination with a high-intensity sweetener, Have also been found to have the effect of improving unpleasant aftertaste, and have led to the present invention.

【0007】[0007]

【発明の実施の形態】本発明において甘味食品とは、主
に高甘味度甘味料により甘味を付与された食品であり、
例えば、コーヒー飲料、紅茶飲料、炭酸飲料等の清涼飲
料、ゼリー、プリン等のデザート食品、チューインガ
ム、キャンデー、錠菓、キャラメル等の菓子類、アイス
クリーム、ラクトアイス、アイスミルク、シャーベッ
ト、等の冷菓が挙げられる。
BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, a sweet food is a food to which sweetness is mainly imparted by a high-intensity sweetener,
For example, coffee drinks, tea drinks, soft drinks such as carbonated drinks, dessert foods such as jelly and pudding, sweets such as chewing gum, candy, tablet confectionery, caramel, ice cream, lacto ice, ice milk, sherbet, etc. No.

【0008】本発明において用いられる成分(a)の高
甘味度甘味料は、天然甘味料非糖質であるステビア甘味
料、グリチルリチン、ソーマチン、モネリン、アマチャ
抽出物、羅漢果抽出物、アミノ酸系甘味料であるアスパ
ルテーム、アリテーム、合成甘味料であるアセスルファ
ムK、スクラロース、ネオヘスペリジンヒドロカルコ
ン、サッカリンナトリウム等であり、これらは1種又は
2種以上を使用することができる。
The high-intensity sweetener of the component (a) used in the present invention is a natural sweetener non-saccharide, stevia sweetener, glycyrrhizin, thaumatin, monelin, amacha extract, arhat extract, amino acid sweetener Aspartame, Alitame, Acesulfame K, a synthetic sweetener, sucralose, neohesperidin hydrochalcone, sodium saccharin, etc., and one or more of these can be used.

【0009】これら高甘味度甘味料の砂糖に対する甘味
度は、砂糖を1として、ステビア甘味料200〜35
0、グリチルリチン200〜300、ソーマチン750
〜3000、モネリン3,000程度、アスパルテーム
180〜200、スクラロース400〜800、サッカ
リンナトリウム300〜500、アリテーム2000程
度、アセスルファムK130〜150、ネオヘスペリジ
ンジヒドロカルコン1500〜1800であるとされて
いる。
[0009] The degree of sweetness of these high-intensity sweeteners with respect to sugar is defined as 1 to 200% to 35% of stevia sweetener.
0, glycyrrhizin 200-300, thaumatin 750
3,000, monelin about 3,000, aspartame 180-200, sucralose 400-800, saccharin sodium 300-500, alitame about 2000, acesulfame K130-150, neohesperidin dihydrochalcone 1500-1800.

【0010】本発明において、成分(b)のp−メンタ
ン骨格を持つ誘導体は、閾値以下量の添加で成分(a)
に由来する好ましくない後味(くどい後味)を改良し、
さっぱりとした後味を付与する。このような成分(b)
のp−メンタン骨格を持つ誘導体は、化1に示す骨格を
持つ化合物であり、好ましくは、p−メンタン骨格を持
つエステル誘導体、エーテル誘導体、アルコール誘導
体、アミド誘導体及びケトン誘導体であり、例えばそれ
ぞれ、化2、化3、化4、化5、化6に示すものである
が、これに限られるものではない。
In the present invention, the derivative having a p-menthane skeleton of the component (b) may be added to the component (a) in an amount less than the threshold.
To improve the unpleasant aftertaste originating from
Gives a refreshing aftertaste. Such a component (b)
Is a compound having a skeleton shown in Chemical formula 1, and is preferably an ester derivative, an ether derivative, an alcohol derivative, an amide derivative and a ketone derivative having a p-menthane skeleton. These are shown in Chemical Formula 2, Chemical Formula 3, Chemical Formula 4, Chemical Formula 5, and Chemical Formula 6, but are not limited thereto.

【0011】[0011]

【化1】 Embedded image

【0012】[0012]

【化2】 Embedded image

【0013】[0013]

【化3】 Embedded image

【0014】[0014]

【化4】 Embedded image

【0015】[0015]

【化5】 Embedded image

【0016】[0016]

【化6】 Embedded image

【0017】成分(b)は、特に、p−メンタン骨格を
持つ誘導体の中でも、l−メンチル−3−ヒドロキシブ
チレート、l−メンチルアセテート、l−メンチルラク
テート、3−l−メンチルオキシ−1,2−プロパンジ
オールから選ばれる1種又は2種以上が好ましい。
The component (b) is, among the derivatives having a p-menthane skeleton, particularly l-menthyl-3-hydroxybutyrate, l-menthyl acetate, l-menthyl lactate, 3-l-menthyloxy-1, One or more selected from 2-propanediol is preferred.

【0018】本発明で閾値とは、味を感じるに必要な最
低の濃度であり、年齢20才代の男女10人の官能評価
により、5人以上が味を感じるようになる最低濃度の値
をいう。本発明において、成分(b)の食品への添加量
は、成分(b)が少なすぎるとそのマスキング効果が充
分でなく、多すぎると成分(b)のメントール本来の清
涼感のある味がでてしまうので、最終食品中において、
成分(b)の閾値を超えない量で適宜調節すればよく、
特に制限はない。例えば、甘味食品が飲料の場合、最終
食品中に含まれる成分(b)は0.015〜10ppmで
あることが好ましい。なお、閾値はl−メンチルアセテ
ート3ppm、d−メンチルアセテート25ppm、l−メン
トン0.3〜0.6ppm、l−イソメントール30ppm、
d−ネオイソメントール70ppm等であり成分によって
ばらつきがあるので、閾値を超えない範囲で適宜調節す
る。
In the present invention, the threshold is the minimum concentration required to feel the taste. The sensory evaluation of 10 males and females in their 20s is the minimum concentration at which five or more people can taste. Say. In the present invention, if the amount of the component (b) added to the food is too small, the masking effect of the component (b) is not sufficient, and if it is too large, the refreshing taste inherent to the menthol of the component (b) is produced. In the final food,
What is necessary is just to adjust suitably with the quantity which does not exceed the threshold value of a component (b),
There is no particular limitation. For example, when the sweet food is a beverage, the component (b) contained in the final food is preferably 0.015 to 10 ppm. In addition, threshold values are 1-menthyl acetate 3ppm, d-menthyl acetate 25ppm, l-menthone 0.3-0.6ppm, l-isomenthol 30ppm,
d-Neoisomenthol is 70 ppm or the like and varies depending on the components. Therefore, the content is appropriately adjusted within a range not exceeding the threshold value.

【0019】本発明に係る甘味食品は、成分(a)及び
(b)が結果的に含まれていればよく、成分(a)及び
(b)は、あらかじめ製剤化して食品に添加してもよい
し、食品中に別々に添加してもよい。
The sweet food according to the present invention only needs to contain the components (a) and (b) as a result. The components (a) and (b) can be prepared in advance and added to the food. Or may be added separately to the food.

【0020】[0020]

【実施例】以下、本発明の内容及び本発明の効果を以下
の実施例、比較例等を用いて具体的に説明するが、本発
明はこれらに何ら限定されるものではない。なお、官能
評価を行うパネラーは、年齢20才代の男女5人ずつ計
10名で行った。
EXAMPLES Hereinafter, the contents of the present invention and the effects of the present invention will be specifically described with reference to the following Examples and Comparative Examples, but the present invention is not limited thereto. In addition, panelists who perform a sensory evaluation were performed by a total of 10 persons each of 5 men and women in their 20s.

【0021】実施例1 高甘味度甘味料糖液の調製 下記処方に示す組成で常法に従い高甘味度甘味料糖液実
施例1を調製した。また、下記処方のうち5を含まない
比較例1を調製し、比較官能評価を行った。各試料温度
は20℃であった。結果を表1に記す。
Example 1 Preparation of high-sweetness sweetener sugar solution High-sweetness sweetener sugar solution Example 1 was prepared according to a conventional method with the composition shown below. In addition, Comparative Example 1 not including the following formulation 5 was prepared and subjected to comparative sensory evaluation. Each sample temperature was 20 ° C. The results are shown in Table 1.

【0022】 処方 重量部 1.マルチトールシロップ 2.4 2.果糖 0.9 3.ソーマチン 0.0003 4.酵素処理ステビア 0.05 5.l−メンチルアセテート 0.0001 ───────────────────────── 清水にて全量を100重量部とする。Formulation Parts by Weight 1. Maltitol syrup 2.4 2. Fructose 0.93. Thomatin 0.0003 4. 4. Enzyme-treated stevia 0.05 l-Mentyl acetate 0.0001 に て Make the total amount 100 parts by weight with Shimizu.

【0023】[0023]

【表1】 [Table 1]

【0024】表1の結果から、実施例1の高甘味度甘味
料糖液は、くどい後味はなく良好であった。それに対し
て、比較例1の高甘味度甘味料糖液はくどい後味がかな
り認められた。
From the results shown in Table 1, the sugar solution of the high-intensity sweetener of Example 1 was excellent with no terrible aftertaste. On the other hand, the sugar solution of the high-intensity sweetener of Comparative Example 1 had a considerable aftertaste.

【0025】 実施例2 シュガーレスコーヒー飲料の調製 処方 重量部 1.10%コーヒー抽出液 52 2.牛乳 7.5 3.生クリーム(乳脂45%) 3 4.還元デンプン加水分解物 5.7 5.乳化剤 0.1 6.ソーマチン 0.000001 7.ステビア抽出物 0.007 8.コーヒー香料 0.1 9.l−メンチルラクテート 0.0003 ───────────────────────── 清水にて全量を100重量部とする。 上記処方で得られたコーヒー溶液を容器に充填し、12
1℃20分間殺菌してコーヒー飲料を調製した。得られ
たコーヒー飲料は、飲用した後も後味はすっきりとして
おり、いやな後味はなかった。
Example 2 Preparation of Sugarless Coffee Beverage Formulation Parts by Weight 1.10% Coffee Extract 52 2 Milk 7.5 3. Fresh cream (45% milk fat) 3 4. Reduced starch hydrolyzate 5.7 5. Emulsifier 0.1 6. Thaumatin 0.000001 7. Stevia extract 0.007 8. Coffee flavor 0.19. l-Mentyl lactate 0.0003 に て Make the total amount to 100 parts by weight with Shimizu. A container is filled with the coffee solution obtained by the above formulation, and 12
A paste was sterilized at 1 ° C. for 20 minutes to prepare a coffee beverage. The obtained coffee beverage had a clean aftertaste even after drinking, and had no unpleasant aftertaste.

【0026】 実施例3 ローカロリー紅茶飲料の調製 処方 重量部 1.紅茶抽出物 30 2.グリチルリチン 0.001 3.スクラロース 0.0025 4.マルチトール 3 5.L-アスコルビン酸ナトリウム 0.07 6.紅茶香料 0.15 7.l−メンチルアセテート 0.00005 8.l−メンチルー3ーヒドロキシブチレート 0.0002 ────────────────────────────── 清水にて全量を100重量部とする。 上記処方で得られた紅茶溶液を容器に充填し、121℃
10分間殺菌して、紅茶飲料を調製した。得られた紅茶
飲料は、飲用した後も後味はくどくなくさっぱりとして
いた。
Example 3 Preparation of Low Calorie Black Tea Beverage Formulation Parts by Weight Black tea extract 30 2. Glycyrrhizin 0.001 3. Sucralose 0.0025 4. Maltitol 3 5. 5. L-sodium ascorbate 0.07 Black tea flavor 0.15 7. 7. l-menthyl acetate 0.00005 l-menthyl-3-hydroxybutyrate 0.0002 と 100 parts by weight in Shimizu I do. Fill the container with the black tea solution obtained by the above formula,
The paste was sterilized for 10 minutes to prepare a black tea beverage. The resulting black tea beverage had a refreshing aftertaste after drinking.

【0027】 実施例4 炭酸飲料の調製 処方 重量部 1.マルチトールシロップ 8 2.アスパルテーム 0.01 3.ポリデキストロースシロップ 6.3 5.白桃1/5濃縮果汁 0.7 6.クエン酸(結晶) 0.1 8.赤色色素 0.02 9.フルーツ香料 0.2 10.3−l−メンチルオキシー1,2−プロパンジオール 0.00005 ─────────────────────────────────── 清水を加え60重量部としてシロップを調製する。 上記処方のシロップ6重量部に対し炭酸水4部を加えて
炭酸飲料を調製した。得られた炭酸飲料は、飲用後の後
味はくどい甘味もなくさっぱりとしていた。
Example 4 Preparation of Carbonated Beverage Formulation Parts by Weight Maltitol syrup 8 2. Aspartame 0.01 3. Polydextrose syrup 6.3 5. 5. White peach 1/5 concentrated fruit juice 0.7 7. citric acid (crystal) 0.1 Red pigment 0.02 9. Fruit flavor 0.2 10.3-l-menthyloxy-1,2-propanediol 0.00005 ────────────────────────────を Add syrup to make up 60 parts by weight of syrup. Carbonated water was prepared by adding 4 parts of carbonated water to 6 parts by weight of the syrup having the above formulation. The resulting carbonated beverage had a refreshing aftertaste with no intense sweetness.

【0028】 実施例5 ストロベリーゼリーの調製 処方 重量部 1.エリスリトール 10 2.ガラクトオリゴ糖 8 3.ポリデキストロース 7 4.ゲル化剤 0.8 5.クエン酸(結晶) 0.18 6.1/5イチゴ濃縮透明果汁 2 7.アスパルテーム 0.024 8.赤色色素 0.07 9.フルーツ香料 0.3 10.l−メンチルラクテート 0.0001 ───────────────────────────── 清水にて全量を100重量部とする。 上記処方のゼリー液を80℃で10分間攪拌溶解して容
器に充填後、85℃30分間殺菌し、水冷して、ストロ
ベリーゼリーを調製した。得られたストロベリーゼリー
は、食した後も後味はさっぱりとしていた。
Example 5 Preparation of Strawberry Jelly Formulation Parts by Weight Erythritol 10 2. Galactooligosaccharide 8 3. Polydextrose 7 4. Gelling agent 0.85. Citric acid (crystal) 0.18 6.1 / 5 Strawberry concentrated clear juice 2 7. 7. Aspartame 0.024 Red pigment 0.07 9. Fruit flavor 0.3 10. l-Mentyl lactate 0.0001 に て Make the total amount 100 parts by weight with Shimizu. The jelly solution of the above formulation was stirred and dissolved at 80 ° C. for 10 minutes, filled in a container, sterilized at 85 ° C. for 30 minutes, and cooled with water to prepare a strawberry jelly. The resulting strawberry jelly had a refreshing aftertaste after eating.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI A23L 2/00 A23L 2/00 T 2/60 C ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI A23L 2/00 A23L 2/00 T 2/60 C

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】以下の成分(a)及び(b) (a)高甘味度甘味料 (b)p−メンタン骨格を持つ誘導体から選ばれる1種
又は2種以上 を含有する食品であって、かつ、(b)の成分の添加量
が食品において閾値以下量であることを特徴とすること
を特徴とする甘味食品。
A food containing one or more of the following components (a) and (b): (a) a high-intensity sweetener; (b) a derivative having a p-menthane skeleton; A sweet food characterized in that the amount of the component (b) added is less than or equal to a threshold in the food.
【請求項2】成分(b)が、p−メンタン骨格を持つエ
ステル誘導体、エーテル誘導体、アルコール誘導体、ア
ミド誘導体及びケトン誘導体である請求項1記載の甘味
食品。
2. The sweet food according to claim 1, wherein the component (b) is an ester derivative, ether derivative, alcohol derivative, amide derivative or ketone derivative having a p-menthane skeleton.
【請求項3】成分(b)が、l−メンチル−3−ヒドロ
キシブチレート、l−メンチルアセテート、l−メンチ
ルラクテート、3−l−メンチルオキシ−1,2−プロ
パンジオールから選ばれる1種又は2種以上である請求
項1記載の甘味食品。
3. The composition according to claim 1, wherein the component (b) is at least one member selected from the group consisting of l-menthyl-3-hydroxybutyrate, l-menthyl acetate, l-menthyl lactate, and 3-l-menthyloxy-1,2-propanediol. The sweet food according to claim 1, wherein the sweet food is at least two kinds.
JP12416297A 1997-05-14 1997-05-14 Sweet food Expired - Lifetime JP3869071B2 (en)

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