JPH10309707A - Woody molded article - Google Patents

Woody molded article

Info

Publication number
JPH10309707A
JPH10309707A JP12045997A JP12045997A JPH10309707A JP H10309707 A JPH10309707 A JP H10309707A JP 12045997 A JP12045997 A JP 12045997A JP 12045997 A JP12045997 A JP 12045997A JP H10309707 A JPH10309707 A JP H10309707A
Authority
JP
Japan
Prior art keywords
wood
lumber
molded article
weight
sectional area
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12045997A
Other languages
Japanese (ja)
Inventor
Naoya Mitsuara
直也 三荒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Plastics Inc
Original Assignee
Mitsubishi Plastics Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Plastics Inc filed Critical Mitsubishi Plastics Inc
Priority to JP12045997A priority Critical patent/JPH10309707A/en
Publication of JPH10309707A publication Critical patent/JPH10309707A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To obtain a woody effect similar to natural lumber by specifying the rate of a total cross sectional area of a woody molded article formed by coating the outer surface of lumber with a coating layer of a foamed resin composition consisting of a specific synthetic resin and wood powder. SOLUTION: The surface of lumber is coated with a coating layer made of foaming a resin composition filled with 1-100 pts.wt. wood powder in 100 pts.wt. synthetic resin, and the rate of a cross sectional area of lumber is made 40-90% with respect to the total cross section of a woody molded article. For example, 1 pts.wt. azodicarbonamide is added to a composition having 50 pts.wt. wood powder of 100 meshes or lower to 100 pts.wt. polyvinylchloride, and a coating layer is formed on the outer periphery of lumber by use of a head die having its cross section formed into a threshold. Furthermore, two stripes of a recessed groove are formed on the surface for making a woody molded article being 70% in the rate of a cross section of lumber with respect to the total cross sectional area of the woody molded article. In this manner, a woody molded article is obtained having the same strength as natural lumber and a woody effect similar to natural lumber.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、住宅における回り
縁、幅木、敷居及び家具等の化粧板、さらには車両の内
装部材等に用い、木材と合成樹脂との複合材である木質
成形品に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wooden molded product which is a composite material of wood and a synthetic resin, which is used as a decorative board such as a rim, a skirting board, a sill and furniture in a house, and an interior member of a vehicle. .

【0002】[0002]

【従来の技術及び課題】近年、合成樹脂成形品に天然木
材が有する表面特性に近い特性を付与し、住宅用造作部
材の回り縁、幅木、敷居、あるいは家具、車両内装部材
の表面を天然木材の質感に近いものにする試みがなされ
ている。天然木材の質感に近いものにする手段として
は、木材に近似した色調に着色すると共に、合成樹脂に
木粉を所定量添加し、発泡させて木質成形品を得てい
る。
2. Description of the Related Art In recent years, a synthetic resin molded article has been given characteristics close to the surface characteristics of natural wood, and the surrounding edge of a house-made member, a skirting board, a sill, furniture or a vehicle interior member has been made of natural wood. Attempts have been made to make the texture closer to that of the original. As means for making the texture close to that of natural wood, a woody article is obtained by coloring the wood in a color tone similar to that of wood, adding a predetermined amount of wood powder to synthetic resin, and foaming.

【0003】しかしながら、合成樹脂の線膨脹係数が木
材よりも大きいため、温度による伸縮が大きい。このた
め伸縮幅を考慮して設計する必要がある上、伸縮により
隙間が生じると軋み音が発生するという問題点がある。
また、敷居等住宅の床面では、合成樹脂成形品であると
剛性が木材と比較して小さく、木材と同様の設計では強
度的に使用することができないという問題点があった。
また、木材は湿度による反りが発生し、天然のため木目
模様などが不均一であり、木目の均一な高級品は高価で
入手しにくい等の問題点があった。
[0003] However, since the linear expansion coefficient of synthetic resin is larger than that of wood, expansion and contraction by temperature is large. For this reason, it is necessary to design in consideration of the expansion and contraction width, and there is a problem that a squeak sound is generated when a gap is generated by expansion and contraction.
Further, on a floor of a house such as a sill, there is a problem that rigidity of a synthetic resin molded product is lower than that of wood, so that it cannot be used with a similar design to wood in terms of strength.
In addition, there is a problem in that wood is warped due to humidity, has a non-uniform wood grain pattern due to nature, and high-quality products having a uniform wood grain are expensive and difficult to obtain.

【0004】[0004]

【課題を解決するための手段】上記課題を達成するため
に、本発明は、合成樹脂100重量部と木粉1〜100
重量部よりなる樹脂組成物を発泡させた被覆層で木材の
外面を被覆した木質成形品であって、木質成形品の全断
面積に対する木材の断面積の割合を40〜95%とした
ことを特徴とする。
In order to achieve the above-mentioned object, the present invention relates to a method for producing 100 parts by weight of synthetic resin and 1 to 100 parts of wood flour.
A wooden molded article in which the outer surface of wood is covered with a coating layer obtained by foaming a resin composition consisting of parts by weight, wherein the ratio of the cross-sectional area of the wood to the total cross-sectional area of the wooden molded article is 40 to 95%. Features.

【0005】[0005]

【発明の実施の形態】以下、本発明の実施例を詳細に説
明する。本発明において、合成樹脂としては、ポリ塩化
ビニル樹脂、ABS樹脂が挙げられる。充填する木粉の
添加量としては、合成樹脂100重量部に木粉1〜10
0重量部としてある。木粉の添加量が1重量部より少な
いと、木質感が得られず、100重量部より多く添加す
ると、樹脂溶融粘度の上昇により成形不良又は発泡の不
均一が生じ、木質感が損なわれるためである。発泡剤と
しては、アゾジカルボンアミド、ジニトロソペンタメチ
ルテラミンな度の有機発泡剤が挙げられる。これらの有
機発泡剤は合成樹脂100重量部に対し、0.5〜5重
量部添加し、発泡倍率1.5〜2.5倍とする。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described in detail. In the present invention, examples of the synthetic resin include a polyvinyl chloride resin and an ABS resin. The amount of wood flour to be filled was 1 to 10 wood flour per 100 parts by weight of synthetic resin.
0 parts by weight. If the amount of wood flour is less than 1 part by weight, a woody feeling cannot be obtained, and if it is added more than 100 parts by weight, resin melt viscosity increases, resulting in poor molding or uneven foaming, and the woody feeling is impaired. It is. Examples of the foaming agent include azodicarbonamide and dinitrosopentamethylteramine, which are organic foaming agents. These organic foaming agents are added in an amount of 0.5 to 5 parts by weight with respect to 100 parts by weight of the synthetic resin, so that the expansion ratio is 1.5 to 2.5 times.

【0006】芯材となる木材としては、集成材、ベニア
等を用い、所定寸法に切断した木材をクロスヘッドダイ
を有する押出機に供給し、クロスヘッドダイにスクリュ
ーにて合成樹脂を押出し、フォーマーで形を整え冷却
し、木材の外面に合成樹脂被覆層を形成する。木材の外
周に酢酸ビニルエマルジョン等の木工用接着剤を塗布し
ておくか、又はホットメルト接着剤層を共押出しにて成
形すると、合成樹脂と木材との接着強度を高めることが
できる。
[0006] Glued wood, veneers and the like are used as the core wood, and the wood cut to a predetermined size is supplied to an extruder having a crosshead die, and a synthetic resin is extruded with a screw through the crosshead die to form a core. And cool it down to form a synthetic resin coating on the outer surface of the wood. Applying a woodworking adhesive such as a vinyl acetate emulsion to the outer periphery of the wood, or forming a hot melt adhesive layer by co-extrusion can increase the adhesive strength between the synthetic resin and the wood.

【0007】[0007]

【実施例】【Example】

(実施例1)ポリ塩化ビニル樹脂100重量部に100
メッシュ以下の木粉50重量部を充填した組成物にアゾ
ジカルボンアミド1重量部を添加し、断面を敷居形状と
したヘッドダイを用いて、厚み33mm、幅90mm、
長さ1800mmの木材の外周面に発泡倍率1.5倍の
被覆層を形成し、木質成形品の寸法が厚み45mm、幅
98mmで、敷居凹溝として幅21mm、溝深さ3mm
の2条の凹溝を表面に形成し、木質成形品の全断面積に
対する木材の断面積の割合を70%とした木質成形品を
得た。
(Example 1) 100 parts by weight of polyvinyl chloride resin
1 part by weight of azodicarbonamide was added to a composition filled with 50 parts by weight of wood flour or less, and using a head die having a sill-shaped cross section, a thickness of 33 mm, a width of 90 mm,
A covering layer having a foaming ratio of 1.5 times is formed on the outer peripheral surface of a 1800 mm long wood, and the dimensions of the wooden molded product are 45 mm thick, 98 mm wide, 21 mm wide as a sill groove, and 3 mm deep.
Was formed on the surface to obtain a wood molded product in which the ratio of the sectional area of wood to the total sectional area of the wooden molded product was 70%.

【0008】(実施例2)ポリ塩化ビニル樹脂100重
量部に100メッシュ以下の木粉100重量部を充填し
た組成物にアゾジカルボンアミド1重量部を添加し、断
面を回り縁形状としたクロスヘッドダイを用いて、厚み
15mm、幅50mm、長さ1800mmの木材の外周
面に発泡倍率1.5倍の被覆層を形成し、木質成形品の
寸法が厚み17mm、幅55mmで、木質成形品の全断
面積に対する木材の断面積の割合を80%とした木質成
形品を得た。
(Example 2) A crosshead die having a cross-sectional shape of a periphery obtained by adding 1 part by weight of azodicarbonamide to a composition in which 100 parts by weight of polyvinyl chloride resin is filled with 100 parts by weight of wood flour of 100 mesh or less. Is used to form a coating layer having a foaming ratio of 1.5 times on the outer peripheral surface of wood having a thickness of 15 mm, a width of 50 mm and a length of 1800 mm, and the dimensions of the wooden molded product are 17 mm in thickness and 55 mm in width. A wooden molded product was obtained in which the ratio of the sectional area of the wood to the sectional area was 80%.

【0009】(実施例3)ポリ塩化ビニル樹脂100重
量部に100メッシュ以下の木粉50重量部を充填した
組成物にアゾジカルボンアミド1重量部を添加し、断面
を敷居形状としたクロスヘッドダイを用いて、表面に酢
酸ビニルエマルジョンを塗布した厚み33mm、幅90
mm、長さ1800mmの木材の外周面に発泡倍率1.
5倍の被覆層を形成し、木質成形品の寸法が厚み45m
m、幅98mmで、敷居凹溝として幅21mm、溝深さ
3mmの2条の凹溝を表面に形成し、木質成形品の全断
面積に対する木材の断面積の割合を70%とした木質成
形品を得た。
(Example 3) A crosshead die having a threshold cross section was prepared by adding 1 part by weight of azodicarbonamide to a composition in which 100 parts by weight of polyvinyl chloride resin and 50 parts by weight of wood flour having a size of 100 mesh or less were added. 33 mm thick and 90 mm wide with a vinyl acetate emulsion applied to the surface using
mm, the expansion ratio is 1.
5 times coating layer is formed, the size of the wooden molded product is 45m thick
m, 98 mm in width, 21 mm in width as a sill groove, 3 mm in depth, and 3 mm in depth, formed on the surface two grooves, and the ratio of the cross-sectional area of the wood to the total cross-sectional area of the wood-formed product was 70%. Product was obtained.

【0010】(実施例4)ポリ塩化ビニル樹脂100重
量部に100メッシュ以下の木粉50重量部を充填した
組成物にアゾジカルボンアミド1重量部を添加し、断面
を敷居形状としたクロスヘッドダイを用いて、表面に酢
酸ビニルエマルジョンを塗布した厚み37mm、幅80
mm、長さ1800mmの木材の外周面に発泡倍率1.
5倍の被覆層を形成し、木質成形品の寸法が厚み45m
m、幅98mmで、敷居凹溝として幅21mm、溝深さ
3mmの2条の凹溝を表面に形成し、木質成形品の全断
面積に対する木材の断面積の割合を70%とした木質成
形品を得た。
(Example 4) A crosshead die having a sill-shaped cross section was prepared by adding 1 part by weight of azodicarbonamide to a composition in which 100 parts by weight of polyvinyl chloride resin was filled with 50 parts by weight of wood flour of 100 mesh or less. 37 mm thick and 80 cm wide with a vinyl acetate emulsion applied to the surface using
mm, the expansion ratio is 1.
5 times coating layer is formed, the size of the wooden molded product is 45m thick
m, 98 mm in width, 21 mm in width as a sill groove, 3 mm in depth, and 3 mm in depth, formed on the surface two grooves, and the ratio of the cross-sectional area of the wood to the total cross-sectional area of the wood-formed product was 70%. Product was obtained.

【0011】(実施例5)ポリ塩化ビニル樹脂100重
量部に100メッシュ以下の木粉50重量部を充填した
組成物にアゾジカルボンアミド1重量部を添加し、断面
を敷居形状としたクロスヘッドダイを用いて、表面に酢
酸ビニルエマルジョンを塗布した厚み28mm、幅70
mm、長さ1800mmの木材の外周面に発泡倍率1.
5倍の被覆層を形成し、木質成形品の寸法が厚み45m
m、幅98mmで、敷居凹溝として幅21mm、溝深さ
3mmの2条の凹溝を表面に形成し、木質成形品の全断
面積に対する木材の断面積の割合を45%とした木質成
形品を得た。
(Example 5) A crosshead die having a sill-shaped cross section was prepared by adding 1 part by weight of azodicarbonamide to a composition in which 100 parts by weight of a polyvinyl chloride resin was filled with 50 parts by weight of wood flour of 100 mesh or less. A vinyl acetate emulsion was coated on the surface with a thickness of 28 mm and a width of 70 mm.
mm, the expansion ratio is 1.
5 times coating layer is formed, the size of the wooden molded product is 45m thick
m, 98 mm in width, 21 mm in width, 3 mm in depth as a sill groove, formed on the surface two grooves, and the ratio of the cross-sectional area of the wood to the total cross-sectional area of the wood-formed product was 45%. Product was obtained.

【0012】(比較例1)従来の木材製敷居であって、
厚み45mm、幅98mm、長さ1800mmで、敷居
凹溝として幅21mm、溝深さ3mmの2条の凹溝を表
面に形成した木材。
Comparative Example 1 A conventional wood sill,
Wood with a thickness of 45 mm, a width of 98 mm, a length of 1800 mm, and two grooves having a width of 21 mm and a depth of 3 mm formed on the surface as sill grooves.

【0013】(比較例2)ポリ塩化ビニル樹脂100重
量部に100メッシュ以下の木粉50重量部を充填した
組成物アゾジカルボンアミド1重量部を添加し、断面を
敷居形状としたクロスヘッドダイを用いて、表面に酢酸
ビニルエマルジョンを塗布した厚み40mm、幅42m
m、長さ1800mmの木材の外周面に発泡倍率1.5
倍の被覆層を形成し、木質成形品の寸法が厚み45m
m、幅98mmで、敷居凹溝として幅21mm、溝深さ
3mmの2条の凹溝を表面に形成し、木質成形品の全断
面積に対する木材の断面積の割合を39%とした木質成
形品を得た。
Comparative Example 2 1 part by weight of azodicarbonamide, which is a composition obtained by filling 50 parts by weight of wood powder of 100 mesh or less with 100 parts by weight of a polyvinyl chloride resin, was added to form a crosshead die having a threshold cross section. Using a vinyl acetate emulsion applied on the surface, thickness 40 mm, width 42 m
m, expansion ratio 1.5 on the outer peripheral surface of wood 1800 mm long
Double coating layer is formed, and the size of the wooden molded product is 45m in thickness.
m, 98 mm in width, 21 mm in width as a sill groove, 3 mm in depth, and 3 mm in depth, formed on the surface two grooves, and the ratio of the cross-sectional area of the wood to the total cross-sectional area of the wood-formed product was 39%. Product was obtained.

【0014】(比較例3)ポリ塩化ビニル樹脂100重
量部に100メッシュ以下の木粉50重量部を充填した
組成物アゾジカルボンアミド1重量部を添加し、断面を
敷居形状としたクロスヘッドダイを用いて、表面に酢酸
ビニルエマルジョンを塗布した厚み43mm、幅96m
m、長さ1800mmの木材の外周面に発泡倍率1.5
倍の被覆層を形成し、木質成形品の寸法が厚み45m
m、幅98mmで、敷居凹溝として幅21mm、溝深さ
3mmの2条の凹溝を表面に形成し、木質成形品の全断
面積に対する木材の断面積の割合を96%とした木質成
形品を得た。
Comparative Example 3 100 parts by weight of a polyvinyl chloride resin was added with 1 part by weight of an azodicarbonamide composition filled with 50 parts by weight of wood powder of 100 mesh or less, and a crosshead die having a sill-shaped cross section was prepared. Using a vinyl acetate emulsion applied to the surface, thickness 43mm, width 96m
m, expansion ratio 1.5 on the outer peripheral surface of wood 1800 mm long
Double coating layer is formed, and the size of the wooden molded product is 45m in thickness.
m, 98 mm in width, 21 mm in width as a sill groove, 3 mm in depth, 3 mm in depth, formed on the surface two grooves, and the ratio of the cross-sectional area of wood to the total cross-sectional area of the wood molded product was 96%. Product was obtained.

【0015】(比較例4)ポリ塩化ビニル樹脂100重
量部に100メッシュ以下の木粉110重量部を充填し
た組成物アゾジカルボンアミド1重量部を添加し、断面
を敷居形状としたクロスヘッドダイを用いて、表面に酢
酸ビニルエマルジョンを塗布した厚み33mm、幅90
mm、長さ1800mmの木材の外周面に発泡倍率1.
5倍の被覆層を形成し、木質成形品の寸法が厚み45m
m、幅98mmで、敷居凹溝として幅21mm、溝深さ
3mmの2条の凹溝を表面に形成し、木質成形品の全断
面積に対する木材の断面積の割合を70%とした木質成
形品を得た。
Comparative Example 4 1 part by weight of a composition, azodicarbonamide, filled with 100 parts by weight of polyvinyl chloride resin and 110 parts by weight of wood powder of 100 mesh or less was added, and a crosshead die having a sill-shaped cross section was prepared. Using a vinyl acetate emulsion applied to the surface, a thickness of 33 mm and a width of 90
mm, the expansion ratio is 1.
5 times coating layer is formed, the size of the wooden molded product is 45m thick
m, 98 mm in width, 21 mm in width as a sill groove, 3 mm in depth, and 3 mm in depth, formed on the surface two grooves, and the ratio of the cross-sectional area of the wood to the total cross-sectional area of the wood-formed product was 70%. Product was obtained.

【0016】各実施例、比較例の木質成形品を下記の測
定方法及び評価基準によって評価した結果を表1に示
す。 (1)線膨脹係数(1/℃) −20℃から60℃の温度変化に対する伸縮量(mm)
÷80(℃)÷1800(mm) <評価基準> 10×10-6以下: 良好○ 10×10-6を超える: 不良× (2)荷重たわみ(mm) スパン間隔900mmの両持ち梁で支持条件下で、中心
荷重15kgを付加したときのたわみ量 <評価基準> 30mm以下: 良好○ 30mmを超える: 不良× (3)反り(mm) 60℃における絶対乾燥条件から相対湿度90%の条件
に変化させた反りの量 <評価基準> 5mm以下: 良好○ 5mmを超える: 不良× (4)表面外観 目視による木質感 <評価基準> 5段階評価で4以上: 良好○ 5段階評価で3: やや不良△ 5段階評価で2以下: 不良×
Table 1 shows the results of evaluation of the woody molded products of the examples and comparative examples by the following measuring methods and evaluation criteria. (1) Coefficient of linear expansion (1 / ° C) Amount of expansion and contraction (mm) with respect to temperature change from -20 ° C to 60 ° C
÷ 80 (° C.) ÷ 1800 (mm) <Evaluation criteria> 10 × 10 -6 or less: good ○ Exceeding 10 × 10 -6 : bad × (2) Load deflection (mm) Supported by a double-ended beam with a span interval of 900 mm Deflection amount when a center load of 15 kg is applied under the conditions <Evaluation criteria> 30 mm or less: good ○ Exceeds 30 mm: bad × (3) Warpage (mm) From the condition of absolute drying at 60 ° C to the condition of 90% relative humidity The amount of warpage changed <Evaluation criteria> 5 mm or less: Good ○ Exceeding 5 mm: Poor × (4) Surface appearance Wood texture by visual observation <Evaluation criteria> 4 or more in 5 grade evaluation: Good ○ 3 in 5 grade evaluation: Somewhat Defective で 2 or less in 5-grade evaluation: Defective ×

【表1】 表1から、合成樹脂100重量部に木粉1〜100重量
部を充填した樹脂組成物を発泡させた被覆層で木材の外
面を被覆し、木質成形品の全断面積に対する木材の断面
積の割合を40〜95%とした木質成形品は、線膨脹係
数が10×10-6以下で、加重たわみが30mm以下で
あり、反りも5mm以下と強度面および反りにおいて良
好であるとともに、目視による木質感も5段階評価で4
以上であり、天然木材と同等の強度で、かつ木質成形品
として天然木材の質感に近いものが得られることが分か
る。
[Table 1] From Table 1, the outer surface of the wood was covered with a coating layer obtained by foaming a resin composition in which 100 parts by weight of synthetic resin was filled with 1 to 100 parts by weight of wood flour. A wood molded product having a ratio of 40 to 95% has a linear expansion coefficient of 10 × 10 −6 or less, a weight deflection of 30 mm or less, and a warpage of 5 mm or less, which is excellent in strength and warpage and is visually observed. The wood texture is 4 on a 5-point scale
As described above, it can be seen that a molded article having a strength similar to that of natural wood and close to the texture of natural wood can be obtained.

【0017】[0017]

【発明の効果】本発明によれば、住宅における回り縁や
敷居、家具等の化粧板さらには車両の内装部材等の木質
成形品を天然木材の質感に近いものにすることができる
と共に、天然木材と同等の強度で、かつ反りを小さくす
ることができる等の利点がある。
According to the present invention, it is possible to make a woody article such as a decorative panel such as a rim, a sill, furniture or the like in a house, and a wooden molded article such as an interior member of a vehicle close to the texture of natural wood. There is an advantage that the strength is the same as that and the warpage can be reduced.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 合成樹脂100重量部と木粉1〜100
重量部よりなる樹脂組成物を発泡させた被覆層で木材の
外面を被覆した木質成形品であって、木質成形品の全断
面積に対する木材の断面積の割合を40〜95%とした
ことを特徴とする木質成形品。
1. 100 parts by weight of synthetic resin and 1 to 100 wood flour
A wooden molded article in which the outer surface of wood is covered with a coating layer obtained by foaming a resin composition consisting of parts by weight, wherein the ratio of the cross-sectional area of the wood to the total cross-sectional area of the wooden molded article is 40 to 95%. Characteristic wooden molded products.
JP12045997A 1997-05-12 1997-05-12 Woody molded article Pending JPH10309707A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12045997A JPH10309707A (en) 1997-05-12 1997-05-12 Woody molded article

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12045997A JPH10309707A (en) 1997-05-12 1997-05-12 Woody molded article

Publications (1)

Publication Number Publication Date
JPH10309707A true JPH10309707A (en) 1998-11-24

Family

ID=14786704

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12045997A Pending JPH10309707A (en) 1997-05-12 1997-05-12 Woody molded article

Country Status (1)

Country Link
JP (1) JPH10309707A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100371448B1 (en) * 1999-11-29 2003-02-07 김광식 Maunfacture methode of artificial wood for tree powder
JP2010007276A (en) * 2008-06-25 2010-01-14 Panasonic Electric Works Co Ltd Floor member
KR101303531B1 (en) * 2012-04-09 2013-09-04 구명화 Manufacturing method for sled plate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100371448B1 (en) * 1999-11-29 2003-02-07 김광식 Maunfacture methode of artificial wood for tree powder
JP2010007276A (en) * 2008-06-25 2010-01-14 Panasonic Electric Works Co Ltd Floor member
KR101303531B1 (en) * 2012-04-09 2013-09-04 구명화 Manufacturing method for sled plate

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