JPH1028995A - Treatment of waste water - Google Patents
Treatment of waste waterInfo
- Publication number
- JPH1028995A JPH1028995A JP8185979A JP18597996A JPH1028995A JP H1028995 A JPH1028995 A JP H1028995A JP 8185979 A JP8185979 A JP 8185979A JP 18597996 A JP18597996 A JP 18597996A JP H1028995 A JPH1028995 A JP H1028995A
- Authority
- JP
- Japan
- Prior art keywords
- wastewater
- solid
- treatment
- liquid separation
- treatment step
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、排水処理方法、特
に排煙脱硫排水、生活系排水等の排水中に含まれる成分
のうち、特に有機物及び窒素化合物を処理する排水の処
理方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for treating wastewater, and more particularly to a method for treating wastewater for treating organic matter and nitrogen compounds among components contained in wastewater such as flue gas desulfurization wastewater and domestic wastewater.
【0002】[0002]
【従来の技術】有機物及び窒素化合物を含む排水の高度
処理法としては、生物学的硝化脱窒法によって窒素成分
の大部分を除去した後、この生物処理水に凝集剤を添加
して凝集処理し、次いでこの凝集処理水を膜分離する方
法が従来より知られている。2. Description of the Related Art As an advanced treatment method of wastewater containing organic substances and nitrogen compounds, most of nitrogen components are removed by a biological nitrification denitrification method, and then a coagulant is added to the biological treatment water to carry out coagulation treatment. Then, a method of membrane-separating the coagulated water has been conventionally known.
【0003】これを図4によって説明すると、前記した
成分を含む排水を生物処理装置(生物学的硝化脱窒処理
装置)41に導き、好気性微生物を用いた生物化学的酸
化によって排水中の窒素化合物を硝酸根または亜硝酸根
に変化させ、さらに嫌気性微生物を用いた生物化学的還
元によってこの硝酸根または亜硝酸根を窒素ガスに変化
させ、窒素化合物及び有機物の大部分を分解する。Referring to FIG. 4, wastewater containing the above-mentioned components is led to a biological treatment device (biological nitrification and denitrification treatment device) 41, and nitrogen in the wastewater is subjected to biochemical oxidation using aerobic microorganisms. The compound is changed to nitrate or nitrite, and the nitrate or nitrite is changed to nitrogen gas by biochemical reduction using an anaerobic microorganism, thereby decomposing most of nitrogen compounds and organic substances.
【0004】この生物処理水52は、排水貯槽42を経
由して凝集沈殿装置43に導き、凝集剤C 53として
塩化第2鉄、硝酸第2鉄等の第2鉄塩、塩化アルミニウ
ム、硝酸アルミニウム、PAC(ポリ塩化アルミニウ
ム)等のアルミニウム塩にみられる無機凝集剤を添加
し、水酸化ナトリウム、水酸化カルシウム等のpH調整
剤54でpH6〜8に調整した後、有機高分子凝集剤等
を添加することによって排水中の懸濁物とともに粗大な
フロックを形成し沈殿する。[0004] The biologically treated water 52 is led to a coagulation and sedimentation device 43 via a drainage storage tank 42, and as a coagulant C 53, ferric salts such as ferric chloride and ferric nitrate, aluminum chloride and aluminum nitrate , An inorganic coagulant found in aluminum salts such as PAC (polyaluminum chloride) is added, and the pH is adjusted to 6 to 8 with a pH adjuster 54 such as sodium hydroxide and calcium hydroxide. The addition forms coarse flocs with the suspension in the wastewater and precipitates.
【0005】沈殿した凝集沈殿汚泥56は濃縮装置44
で濃縮し、さらに脱水装置45で脱水後、脱水ケーキ5
7として排出する。またその際発生した脱離液58は前
記排水貯槽42に返送して循環処理される。凝集沈殿装
置43における凝集沈殿後の上澄水55はろ過装置46
に導かれ、液中に残存する懸濁粒子や微細粒子が除去さ
れる。[0005] The settled coagulated sediment sludge 56 is condensed by the concentration device 44.
And then dehydrated in a dehydrator 45, and then dehydrated cake 5
Discharge as 7. Further, the desorbed liquid 58 generated at that time is returned to the drainage storage tank 42 to be circulated. The supernatant water 55 after coagulation and sedimentation in the coagulation and sedimentation device 43 is
To remove suspended particles and fine particles remaining in the liquid.
【0006】ろ過装置46より排出された分離液59は
RO(逆浸透)脱塩装置47に導き、逆浸透膜によって
液中に溶存する塩類を除去する。そして同膜を透過した
透過水は脱塩処理水60として再利用に供するか、もし
くは放流する。The separated liquid 59 discharged from the filtration device 46 is guided to an RO (reverse osmosis) desalination device 47, and salts dissolved in the liquid are removed by a reverse osmosis membrane. Then, the permeated water that has passed through the membrane is reused or discharged as desalted water 60.
【0007】また、RO脱塩処理によって発生した濃縮
水61中には、排水中より除去された濃厚な有機物や窒
素化合物が含有し、そのままでは放流できないため活性
炭等を充填した吸着装置48を通過させてこれらの成分
を除去した後、吸着処理水62として放流する。[0007] The concentrated water 61 generated by the RO desalination process contains concentrated organic substances and nitrogen compounds removed from the wastewater and cannot be discharged as it is, so it passes through the adsorption device 48 filled with activated carbon or the like. After removing these components, the water is discharged as adsorption treated water 62.
【0008】[0008]
【発明が解決しようとする課題】しかしながら、前記し
た従来技術には次のような問題点があった。However, the above-mentioned prior art has the following problems.
【0009】(1)排水の全量を高度処理するため、特
に凝集沈殿後の工程となるろ過装置46及びRO脱塩装
置47において各々大規模の設備を必要とする。(1) In order to treat the entire amount of the wastewater to a high degree, large-scale equipment is required for each of the filtration device 46 and the RO desalination device 47 which are the processes after the coagulation and sedimentation.
【0010】(2)ろ過装置46に流入する多量の汚泥
によって装置への負荷が大きくなり易く、メインテナン
スに手間がかかる。(2) A large amount of sludge flowing into the filtration device 46 tends to increase the load on the device, and maintenance is troublesome.
【0011】(3)RO脱塩処理装置47より排出され
る濃縮水61を処理するための、新たな活性炭等の吸着
装置48を別途設置する必要がある。しかも、濃縮水6
1が多量で且つ塩濃度が高いため大型の吸着装置48を
必要とする。(3) It is necessary to separately install a new activated carbon adsorption device 48 for treating the concentrated water 61 discharged from the RO desalination treatment device 47. Moreover, the concentrated water 6
1 has a large amount and a high salt concentration, so that a large-sized adsorption device 48 is required.
【0012】このように従来技術では設備が大型化する
傾向があり、このため設備費用及び運転、管理費用が高
額となり、また広大な設置面積が必要であった。As described above, the conventional technology tends to increase the size of the equipment, which increases the equipment cost, operation and management costs, and requires a large installation area.
【0013】本発明は、設備を小型化して設置面積と設
備費用を低減すると共に、運転と管理費用を節減可能と
した排水中の有機物及び窒素化合物を処理する排水処理
方法を提供することを課題としている。An object of the present invention is to provide a wastewater treatment method for treating organic matter and nitrogen compounds in wastewater, which makes it possible to reduce the installation area and equipment cost by reducing the size of the equipment and to reduce the operation and management costs. And
【0014】[0014]
【課題を解決するための手段】本発明は、前記した課題
を解消するため次の排水処理方法を提供する。SUMMARY OF THE INVENTION The present invention provides the following wastewater treatment method for solving the above-mentioned problems.
【0015】有機物または窒素化合物を含有する排水の
処理方法において、該排水を生物学的処理して窒素化合
物及び有機物を分解する生物処理工程、同生物処理工程
から得られた生物処理水の一部を凝集沈殿処理する凝集
沈殿処理工程、前記生物処理工程から得られた生物処理
水の残部を固液分離する固液分離工程、及び同固液分離
工程に引き続き脱塩処理する脱塩処理工程の各工程より
なり、同脱塩処理工程から排出される濃縮水を前記生物
処理工程に返送して未処理の排水と混合し、濃縮水中に
残存する有機物及び窒素化合物を前記生物処理工程にお
いて分解処理する。In a method for treating wastewater containing an organic substance or a nitrogen compound, a biological treatment step of biologically treating the wastewater to decompose a nitrogen compound and an organic substance, and a part of biologically treated water obtained from the biological treatment step Coagulation sedimentation process, coagulation sedimentation process, solid-liquid separation process of solid-liquid separation of the remaining biologically treated water obtained from the biological treatment process, and desalination process subsequent to the solid-liquid separation process The concentrated water discharged from the desalting step is returned to the biological treatment step and mixed with untreated wastewater, and the organic substances and nitrogen compounds remaining in the concentrated water are decomposed in the biological treatment step. I do.
【0016】本発明によるこの排水処理方法では、前記
したように処理すべき排水のうち再利用を行う水量分に
対してのみ脱塩処理を含む高度処理を施し、放流する排
水に対しては凝集沈殿処理等の放流に必要な処理を施す
にとどめるので、再利用水を得るのに必要なMF(精密
ろ過)膜またはUF(限外ろ過)膜を使った固液分離装
置やRO(逆浸透)脱塩装置の各々を小型化することが
できる。In this wastewater treatment method according to the present invention, as described above, advanced treatment including desalination treatment is performed only on the amount of water to be reused among wastewater to be treated, and wastewater discharged is aggregated. Since only treatment required for discharge such as settling treatment is performed, a solid-liquid separation device using an MF (microfiltration) membrane or a UF (ultrafiltration) membrane and RO (reverse osmosis) necessary for obtaining reused water ) Each of the desalination devices can be downsized.
【0017】また、本発明による排水処理方法では、R
O脱塩処理によって発生する濃縮水を最前段工程である
生物処理工程に返送して処理するため、従来の排水処理
方法で必要としていた吸着装置等の処理設備を必要とし
ない。このようにして、本発明の排水処理方法によれ
ば、設備を小型化したり省略でき、設備費と運転費用を
大きく節減できる。In the wastewater treatment method according to the present invention, R
Since the concentrated water generated by the O desalination treatment is returned to the biological treatment step, which is the first step, for treatment, the treatment equipment such as an adsorption device required in the conventional wastewater treatment method is not required. Thus, according to the wastewater treatment method of the present invention, the equipment can be reduced in size or omitted, and the equipment cost and operation cost can be greatly reduced.
【0018】本発明による排水処理方法では、前記した
工程に加え、固液分離工程より排出される濃縮汚泥と、
生物処理水を凝集処理して得た凝集液とを混合し、その
混合液の一部を固液分離工程へ循環して再度固液分離す
るとともに、その混合液の残部を前記凝集沈殿処理工程
から排出される汚泥と混合し、濃縮、脱水処理するのが
望ましい。In the wastewater treatment method according to the present invention, in addition to the above-described steps, the concentrated sludge discharged from the solid-liquid separation step includes:
The biologically treated water is mixed with the coagulation liquid obtained by coagulation treatment, a part of the mixed liquid is circulated to the solid-liquid separation step to perform solid-liquid separation again, and the remainder of the mixed liquid is subjected to the coagulation sedimentation step. It is desirable to mix with sludge discharged from, and concentrate and dewater.
【0019】このように固液分離工程から排出される濃
縮汚泥と、凝集沈殿処理工程から排出される汚泥とを混
合してまとめて処理すると大がかりな設備を必要とせ
ず、またメインテナンスの手間も省ける。As described above, when the concentrated sludge discharged from the solid-liquid separation step and the sludge discharged from the coagulation sedimentation step are mixed and treated collectively, no large-scale equipment is required, and the maintenance work can be omitted. .
【0020】更にまた、本発明の排水処理方法では、前
記した固液分離工程から排出される濃縮汚泥を生物処理
水と混合した後、前記凝集沈殿処理工程へ導いて凝集沈
殿処理するようにするのが望ましい。Further, in the wastewater treatment method of the present invention, after the concentrated sludge discharged from the solid-liquid separation step is mixed with biologically treated water, the mixture is led to the coagulation / sedimentation step to perform the coagulation / sedimentation treatment. It is desirable.
【0021】このように固液分離工程から排出される濃
縮汚泥を生物処理水と混合すると濃縮汚泥中の懸濁粒子
を核として粗大なフロックを形成させることができ、凝
集沈殿工程における沈降分離性を向上させることができ
る。When the concentrated sludge discharged from the solid-liquid separation step is mixed with the biologically treated water, coarse flocs can be formed with the suspended particles in the concentrated sludge as nuclei, and the sedimentation and sedimentation in the coagulation sedimentation step Can be improved.
【0022】また、本発明は、前記した課題を解決する
ため、有機物または窒素化合物を含有する排水を生物学
的処理して窒素化合物及び有機物を分解した後浮遊物を
沈殿分離する生物処理工程、同生物処理工程から得られ
た生物処理水を固液分離する固液分離工程、及び同固液
分離工程に引き続き脱塩処理する脱塩処理工程の各工程
よりなり、同脱塩処理工程から排出される濃縮水を前記
生物処理工程に返送して未処理の排水と混合し、濃縮水
中に残存する有機物及び窒素化合物を前記生物処理工程
において分解処理する排水の処理方法を提供する。In order to solve the above-mentioned problems, the present invention provides a biological treatment step of subjecting wastewater containing an organic substance or a nitrogen compound to biological treatment to decompose the nitrogen compound and the organic substance, and then sedimenting and separating the suspended matter. It consists of a solid-liquid separation step for solid-liquid separation of biologically treated water obtained from the biological treatment step, and a desalination treatment step for desalination processing following the solid-liquid separation step, and is discharged from the desalination processing step. The present invention provides a method for treating wastewater in which concentrated water is returned to the biological treatment step and mixed with untreated wastewater, and organic substances and nitrogen compounds remaining in the concentrated water are decomposed in the biological treatment step.
【0023】このように脱塩処理工程で生ずる濃縮水を
最前部の生物処理工程へ返送して処理すると、吸着装置
等の処理設備を別途設ける必要がなく、設備を小型化も
しくは省略できるため、設備費用及び運転費用を大幅に
節減するとともに、設置面積を縮小することができて有
利である。この排水処理方法では生物処理水の全量を脱
塩処理するので排水量に対し再利用する水量の割合が多
い場合に適用できる。When the concentrated water generated in the desalination process is returned to the biological treatment process at the forefront for treatment, there is no need to separately provide a treatment facility such as an adsorption device, and the facility can be reduced in size or omitted. Advantageously, the facility and operating costs can be significantly reduced and the footprint can be reduced. In this wastewater treatment method, the entire amount of biologically treated water is desalted, so that it can be applied to the case where the ratio of the amount of water reused to the amount of wastewater is large.
【0024】以上説明した本発明の排水処理方法におけ
る生物処理工程として生物学的硝化脱窒素処理を採用で
き、また、凝集沈殿処理工程では高速凝集沈殿処理を採
用してよい。In the wastewater treatment method of the present invention described above, a biological nitrification denitrification treatment can be employed as the biological treatment step, and a high-speed coagulation / sedimentation treatment may be employed in the coagulation / sedimentation treatment step.
【0025】また、前記した本発明の排水処理方法で
は、その固液分離工程が精密ろ過処理又は限外ろ過処理
を含み、また、脱塩処理工程が逆浸透処理を含むものと
することができる。In the wastewater treatment method of the present invention described above, the solid-liquid separation step may include a microfiltration treatment or an ultrafiltration treatment, and the desalination treatment step may include a reverse osmosis treatment.
【0026】[0026]
【発明の実施の形態】次に、本発明の排水処理方法を図
1ないし図3に示した実施の形態に基づいて具体的に説
明する。そのうち図1に示す実施の第1形態と図2に示
す実施の第2形態では、排水を前段の工程で生物処理し
て排水中の有機物や窒素化合物を除去した後、該生物処
理水を後段の工程で2系統に分岐し、その一方は凝集沈
殿処理工程で凝集処理して規制値以下の水質として放流
するとともに、他方は脱塩処理工程で脱塩処理して再利
用する。Next, a wastewater treatment method according to the present invention will be described in detail with reference to the embodiments shown in FIGS. In the first embodiment shown in FIG. 1 and the second embodiment shown in FIG. 2, the wastewater is biologically treated in a previous step to remove organic substances and nitrogen compounds in the wastewater, and then the biologically treated water is placed in a subsequent step. In this step, the system is branched into two systems, one of which is subjected to coagulation treatment in the coagulation sedimentation treatment step and discharged as water quality below the regulation value, and the other is subjected to desalination treatment in the desalination treatment step for reuse.
【0027】このように目的に応じて平行処理すること
により、例えば生活用雑用水や工業用水もしくは純水用
原料水等として必要分だけ高度処理することができ、排
水全量を過分に処理する無駄を省くことができる。As described above, by performing the parallel treatment according to the purpose, for example, it is possible to perform an advanced treatment only for a necessary amount as domestic water for industrial use, raw water for industrial water or pure water, etc. Can be omitted.
【0028】一方、図3に示す実施の第3形態では、排
水を前記のように生物処理した後、生物処理水の全量を
脱塩処理するもので、排水量に対し再利用に要する水量
の割合が多い場合に適用する。On the other hand, in the third embodiment shown in FIG. 3, after the wastewater is biologically treated as described above, the entire amount of the biologically treated water is subjected to desalination treatment. Applies when there are many.
【0029】(実施の第1形態)先ず、図1により実施
の第1形態について説明する。発電所排水や総合排水
等、有機物、窒素化合物等を含む排水21を生物処理装
置(生物学的硝化脱窒処理装置)1に導入する。生物処
理装置1は、従来技術の項で述べたと同様の公知のもの
でよく、硝化槽1a、脱窒槽1b、酸化槽1c、沈殿槽
1d等で構成される。硝化槽1aでは、排水中の窒素化
合物が好気性微生物の作用で酸化され、アンモニア性窒
素の状態を経て次の化学式1に示すとおり亜硝酸根や硝
酸根に変化する。(First Embodiment) First, a first embodiment will be described with reference to FIG. Wastewater 21 containing organic matter, nitrogen compounds, and the like, such as power plant wastewater and general wastewater, is introduced into a biological treatment device (biological nitrification and denitrification treatment device) 1. The biological treatment apparatus 1 may be a known apparatus similar to that described in the section of the related art, and includes a nitrification tank 1a, a denitrification tank 1b, an oxidation tank 1c, a sedimentation tank 1d, and the like. In the nitrification tank 1a, nitrogen compounds in the wastewater are oxidized by the action of the aerobic microorganisms, and change into nitrite and nitrate as shown in the following chemical formula 1 through the state of ammonia nitrogen.
【0030】[0030]
【化1】 Embedded image
【0031】脱窒槽1bでは、硝化槽1aで生成した亜
硝酸根や硝酸根が嫌気性微生物の作用で還元され、次の
化学式2に示すとおり酸化窒素ガス(N2 O)あるいは
窒素ガス(N2 )となって大気中に放散する。この過程
で、嫌気性微生物すなわち脱窒素菌には、栄養源として
メタノールを添加する。この生物学的硝化脱窒処理によ
って窒素化合物と有機物の大部分が分解する。In the denitrification tank 1b, nitrite and nitrate generated in the nitrification tank 1a are reduced by the action of an anaerobic microorganism, and as shown in the following chemical formula 2, nitrogen oxide gas (N 2 O) or nitrogen gas (N 2 ) Dissipate into the atmosphere. In this process, anaerobic microorganisms, that is, denitrifying bacteria, are added with methanol as a nutrient source. This biological nitrification and denitrification degrades most of the nitrogen compounds and organic matter.
【0032】[0032]
【化2】 Embedded image
【0033】次に酸化槽1cでは、排水中に含まれる有
機物の未処理分と脱窒素菌に栄養源として通常添加され
るメタノール等の有機物が、好気性微生物の作用で酸化
されて炭酸ガス(CO2 )と水(H2 O)に分解する。
こうして有機物及び窒素化合物を除去した後の硝化脱窒
処理水は沈殿槽1dに移されて処理に寄与した生物体等
からなる懸濁物質(SS)分を沈殿処理して除去する。Next, in the oxidation tank 1c, untreated organic matter contained in the wastewater and organic matter such as methanol, which is usually added as a nutrient to denitrifying bacteria, are oxidized by the action of aerobic microorganisms to produce carbon dioxide gas ( (CO 2 ) and water (H 2 O).
The nitrification-denitrification-treated water from which organic substances and nitrogen compounds have been removed in this way is transferred to a sedimentation tank 1d to remove suspended substances (SS) composed of living organisms and the like that have contributed to the treatment by precipitation treatment.
【0034】その後、生物処理水22は中継槽3を経由
して一部を凝集沈殿処理工程に、残部を脱塩処理工程に
分岐させて導く。両工程への配分割合は各装置の処理能
力と、必要とする回収水量等によって決められ、例えば
3/4を放流し1/4を回収し再利用するようにする。
なお中継槽3は、前記排水貯槽2と兼用させてもよく、
その場合は省略することができる。Thereafter, a part of the biologically treated water 22 is led to the coagulation / sedimentation treatment step via the relay tank 3, and the remaining part is led to the desalination treatment step. The distribution ratio to both processes is determined by the processing capacity of each device and the required amount of recovered water, and, for example, 3/4 is discharged, 1/4 is recovered and reused.
In addition, the relay tank 3 may be used also as the drainage storage tank 2,
In that case, it can be omitted.
【0035】前記生物処理水22の分岐した一方を凝集
沈殿装置4に導入し、凝集剤A 23を添加、混合す
る。なお凝集剤A 23は、凝集沈澱装置4へ流入する
直前の管路内または同装置4内の生物処理液22に添加
すればよい。One of the branches of the biologically treated water 22 is introduced into the coagulation sedimentation apparatus 4, and the coagulant A23 is added and mixed. The coagulant A 23 may be added to the biological treatment liquid 22 in the pipe just before flowing into the coagulation / sedimentation apparatus 4 or in the same apparatus 4.
【0036】凝集剤A 23としては塩化第2鉄、硫酸
第2鉄等の第2鉄塩や、塩化アルミニウム、硫酸バン
土、PAC等アルミニウム塩にみられる無機凝集剤、な
らびに有機高分子凝集剤の中から適宜1種または複数種
選択する。凝集剤A 23を添加後、水酸化ナトリウ
ム、水酸化カルシウム等のpH調整剤24でpH6〜8
に調整することによって液中の懸濁物とともに粗大なフ
ロックを形成する。Examples of the flocculant A23 include ferric salts such as ferric chloride and ferric sulfate; inorganic flocculants found in aluminum salts such as aluminum chloride, bansulfate and PAC; and organic polymer flocculants. One or more types are appropriately selected from the above. After adding the flocculant A23, the pH is adjusted to 6 to 8 with a pH adjuster 24 such as sodium hydroxide and calcium hydroxide.
To form coarse flocs with the suspension in the liquid.
【0037】なお、凝集沈殿装置4として、通常の凝集
沈殿装置に代えて高速凝集沈殿装置(造粒沈殿装置)を
採用してもよい。その場合、通常のフロックと比べてさ
らに沈降性のよいペレットを形成し、例えばフロックの
場合はLV=0.8m/h 程度であるのに対してペレット
の場合はLV=8〜15m/h 程度となる。As the coagulating sedimentation device 4, a high-speed coagulating sedimentation device (granulation sedimentation device) may be used instead of a normal coagulation sedimentation device. In this case, pellets having better sedimentation properties are formed as compared with ordinary flocks. For example, LV = about 0.8 m / h for flocs, whereas LV = about 8 to 15 m / h for pellets. Becomes
【0038】凝集沈殿装置4で得られた上澄水25は、
必要により砂ろ過等のろ過装置5で微量の懸濁物を除去
した後処理水26として放流する。また凝集沈殿装置4
の底部に沈降した凝集沈殿汚泥(フロックまたはペレッ
ト)27は、濃縮装置6で濃縮し、さらに脱水装置7で
脱水した後脱水ケーキ28として系外に排出する。The supernatant water 25 obtained in the coagulating sedimentation apparatus 4 is
If necessary, a trace amount of suspended matter is removed by a filtration device 5 such as sand filtration, and then discharged as treated water 26. Coagulation sedimentation device 4
The coagulated sediment (floc or pellet) 27 settled at the bottom of is concentrated by the concentrator 6, further dewatered by the dehydrator 7, and then discharged out of the system as a dewatered cake 28.
【0039】なお、凝集沈殿汚泥27がペレットの状態
の場合、通常のフロックと比べて濃縮、脱水性が良好と
なり、含水率の低いケーキが得られる。濃縮装置6で分
離した分離水は前記排水貯槽2に返送して循環処理す
る。When the coagulated sediment sludge 27 is in the form of pellets, the concentration and dewatering properties are improved as compared with ordinary flocs, and a cake having a low water content is obtained. The separated water separated by the concentrating device 6 is returned to the drainage storage tank 2 and circulated.
【0040】前記生物処理水22のうち、分岐した他方
を凝集装置8に導入し、凝集剤B30として塩化第2
鉄、硫酸第2鉄等の第2鉄塩や、塩化アルミニウム、硫
酸バン土、PAC等アルミニウム塩にみられる無機凝集
剤の中から適宜1種または複数種選択し添加、混合した
後、水酸化ナトリウム、水酸化カルシウム等のpH調整
剤24でpH6〜8に調整することによって液中の懸濁
物とともにフロックを形成する。The other of the biologically treated water 22 is introduced into the coagulation device 8 and is converted into a coagulant B30.
One or a plurality of inorganic coagulants are selected from ferric salts such as iron and ferric sulfate, aluminum chloride, bansulfate, and aluminum salts such as PAC. By adjusting the pH to 6 to 8 with a pH adjuster 24 such as sodium or calcium hydroxide, a floc is formed together with the suspension in the liquid.
【0041】ここで有機高分子凝集剤を添加すると、後
段に設置されたMF(精密ろ過)膜またはUF(限外ろ
過)膜を使用した固液分離装置10、ならびにRO膜を
使用した脱塩装置12の各々膜に有する細孔を閉塞する
等障害になるので添加すべきではない。When the organic polymer flocculant is added here, the solid-liquid separator 10 using a MF (microfiltration) membrane or a UF (ultrafiltration) membrane installed in the subsequent stage, and the desalination using an RO membrane It should not be added because it will obstruct the pores in each membrane of the device 12 and so on.
【0042】フロックを形成した凝集液31は循環槽9
へ導入し、後段の固液分離装置10から返送される濃縮
汚泥33と混合して固液分離装置10との間を循環する
ことによって汚泥が高濃度の状態となり、逐次新たなフ
ロックが成長していく。The floc-formed flocculant 31 is supplied to the circulation tank 9.
To the concentrated sludge 33 returned from the subsequent solid-liquid separation device 10 and circulated between the solid-liquid separation device 10 and the sludge is brought into a high concentration state, and new flocs grow sequentially. To go.
【0043】汚泥濃度がある一定以上となった場合、例
えば10000mg/リットルとなったような場合はその一部
を槽外に抜出して前記濃縮装置6へ移送し、凝集沈殿装
置4から排出される凝集沈殿汚泥27と混合した後、前
記と同様に濃縮した後脱水する。When the sludge concentration exceeds a certain level, for example, when the sludge concentration reaches 10,000 mg / liter, a part of the sludge is withdrawn from the tank, transferred to the concentrating device 6 and discharged from the coagulating sedimentation device 4. After being mixed with the coagulated sedimentation sludge 27, it is concentrated and dehydrated in the same manner as described above.
【0044】前記のように循環槽9に残留する濃縮汚泥
33は固液分離装置10に循環し、MF膜またはUF膜
によってろ過される。MF膜は0.1〜10μm の孔径
を有してそれ以上の粒径の微細粒子を除去し、UF膜は
0.001〜0.1μm の孔径を有してコロイドの粒子
や高分子物質を除去する。As described above, the concentrated sludge 33 remaining in the circulation tank 9 is circulated to the solid-liquid separator 10, and is filtered by the MF membrane or the UF membrane. The MF membrane has a pore diameter of 0.1 to 10 μm and removes fine particles having a larger diameter, and the UF membrane has a pore diameter of 0.001 to 0.1 μm to remove colloid particles and polymer substances. Remove.
【0045】固液分離装置10のMF膜またはUF膜を
通過した分離液32は、中継槽11を経由して脱塩装置
12へ供給して微細粒子やコロイド粒子を除去した後、
さらにRO(逆浸透)膜によって溶存する塩類を除去す
る。The separated liquid 32 that has passed through the MF or UF membrane of the solid-liquid separator 10 is supplied to the desalter 12 via the relay tank 11 to remove fine particles and colloidal particles.
Further, dissolved salts are removed by an RO (reverse osmosis) membrane.
【0046】なお、RO膜への微生物やスケールの付着
を防止するため、必要により次亜塩素酸ナトリウム等の
塩素系酸化剤にみられるような殺菌剤やインヒビター等
を同装置へ流入する直前の管路等を通じて注入すること
がある。In order to prevent microorganisms and scale from adhering to the RO membrane, a bactericide or an inhibitor, such as that found in a chlorine-based oxidizing agent such as sodium hypochlorite, may be added to the RO membrane immediately before flowing into the apparatus. It may be injected through a pipe or the like.
【0047】脱塩装置12でRO膜を通過した透過液3
4は回収水槽13に移され、回収水35として必要個所
へ供給し再利用する。また濃縮水36は前段の工程であ
る生物処理装置1の入口へ返送し、新たに流入した排水
とともに前記と同様循環処理する。The permeated liquid 3 that has passed through the RO membrane in the desalination device 12
4 is transferred to a recovery water tank 13 and supplied to a required location as recovered water 35 for reuse. Further, the concentrated water 36 is returned to the inlet of the biological treatment apparatus 1 which is the previous step, and is circulated together with newly flowing wastewater in the same manner as described above.
【0048】(実施の第2形態)次に図2に示された実
施の第2形態について説明する。この場合も発電所排水
や総合排水等、有機物、窒素化合物等を含む排水は生物
処理装置1に導入し、微生物の作用で有機物と窒素化合
物の大部分を分解する。そして得られた生物処理水を分
岐し、前記と同様にその一部を凝集沈殿処理工程で処理
して放流するとともに、残部を脱塩処理工程で処理して
得られた回収水を再利用に供する。(Second Embodiment) Next, a second embodiment shown in FIG. 2 will be described. In this case as well, wastewater containing organic matter, nitrogen compounds, and the like, such as power plant wastewater and general wastewater, is introduced into the biological treatment apparatus 1, and most of organic matter and nitrogen compounds are decomposed by the action of microorganisms. Then, the obtained biologically treated water is branched, a part of the water is treated in the coagulation sedimentation treatment step and discharged as described above, and the remaining water obtained by treating the remaining part in the desalination treatment step is reused. Offer.
【0049】図2の工程中、図1と異なる点は、脱塩処
理工程に供給される生物処理水を、固液分離装置10で
MF膜またはUF膜で全量ろ過するものであり、図1の
循環槽9を設けることなく、固液分離装置10より排出
される濃縮汚泥33を、凝集沈殿処理工程の中継槽3に
供給し、新たな生物処理水22とともに混合処理するこ
とにある。その他の構成は図1で述べたと実質同様であ
る。The difference between the process of FIG. 2 and FIG. 1 is that the biologically treated water supplied to the desalination process is completely filtered by a solid-liquid separation device 10 through an MF membrane or a UF membrane. Without providing the circulation tank 9, the concentrated sludge 33 discharged from the solid-liquid separation device 10 is supplied to the relay tank 3 in the coagulation / sedimentation treatment step, and mixed with fresh biological treatment water 22. Other configurations are substantially the same as those described with reference to FIG.
【0050】このような構成により、生物処理水22を
凝集沈殿処理するに際して、固液分離装置10から供給
される濃縮汚泥33中の懸濁粒子を核として粗大なフロ
ックを形成させる作用があり、凝集沈殿装置4における
沈降分離性を向上させる効果がある。With such a configuration, when the biologically treated water 22 is subjected to coagulation and sedimentation treatment, it has an effect of forming coarse flocs using suspended particles in the concentrated sludge 33 supplied from the solid-liquid separator 10 as nuclei. This has the effect of improving the sedimentation and separability in the coagulation and sedimentation device 4.
【0051】(実施の第3形態)次に、実施の第3形態
を図3により説明する。発電所排水や総合排水等、有機
物、窒素化合物等を含む排水21を生物処理装置1に導
入し、微生物の作用で有機物と窒素化合物の大部分を分
解する。そして得られた生物処理水22は分岐すること
なく、その全量を脱塩処理工程で処理し回収水35を再
利用に供する。すなわち、図3に示す実施の第3形態で
は図1における凝集処理工程を省略したもので、その他
の構成は図1で述べたと実質同様である。この第3実施
形態は、排出される排水量に対して再利用を必要とする
水量の割合が多い場合に適している。Third Embodiment Next, a third embodiment will be described with reference to FIG. Wastewater 21 containing organic substances, nitrogen compounds, and the like, such as power station wastewater and general wastewater, is introduced into the biological treatment apparatus 1, and most of organic substances and nitrogen compounds are decomposed by the action of microorganisms. Then, the obtained biologically treated water 22 is processed in the desalination process without branching, and the recovered water 35 is reused. That is, in the third embodiment shown in FIG. 3, the aggregation treatment step in FIG. 1 is omitted, and other configurations are substantially the same as those described in FIG. The third embodiment is suitable when the ratio of the amount of water that needs to be reused to the amount of discharged wastewater is large.
【0052】(実施例1)A事業所より排出される総合
排水について図1に示す工程で処理実験を行った。その
際の排水(原水)ならびにそれを処理して得た凝集沈殿
処理水及び脱塩処理後の回収水の性状を表1にまとめて
示す。またその際に発生した凝集沈殿汚泥及びMF処理
汚泥の発生量を表2に示す。(Example 1) A treatment experiment was conducted on the comprehensive wastewater discharged from the A business in the process shown in FIG. The properties of the wastewater (raw water), coagulated sedimentation water obtained by treating it, and recovered water after desalination treatment are summarized in Table 1. Table 2 shows the amounts of coagulated sediment sludge and MF treated sludge generated at that time.
【0053】なお、工程中それぞれの処理条件を表3な
いし表5に示したが、本実施例では凝集沈殿処理効果を
把握するため砂ろ過処理を省略した。その結果凝集沈殿
処理水は、何れの項目も排水基準を定める総理府令の基
準値を十分満足するもので放流して問題のない値である
ことを確認した。Although the respective processing conditions during the process are shown in Tables 3 to 5, in this example, the sand filtration treatment was omitted in order to grasp the effect of the coagulation sedimentation treatment. As a result, it was confirmed that all the coagulated sedimentation treated water sufficiently satisfies the standard values of the ordinance of the Prime Minister's Ordinance that sets the drainage standards, and has a value that does not cause any problem.
【0054】また脱塩処理回収水も、溶存塩類が効果的
に除去されており、接続して例えばイオン交換処理を行
って支障のない値であることを確認した。さらにMF処
理汚泥はクロスフローにより十分に循環濃縮されている
ので発生汚泥量が少なく、凝集沈殿汚泥と混合して濃縮
した場合に濃縮槽を小型化できることが判明した。It was also confirmed that the recovered water from the desalination treatment also had dissolved salts effectively removed, and was connected to, for example, subjected to ion exchange treatment to have a value that would not cause any trouble. Furthermore, since the MF-treated sludge was sufficiently circulated and concentrated by the cross flow, the amount of generated sludge was small, and it was found that the concentration tank could be downsized when mixed with coagulated sediment sludge.
【0055】[0055]
【表1】 [Table 1]
【0056】[0056]
【表2】 [Table 2]
【0057】[0057]
【表3】 [Table 3]
【0058】[0058]
【表4】 [Table 4]
【0059】[0059]
【表5】 [Table 5]
【0060】(実施例2)実施例1と同じ排水について
図2に示す工程で処理実験を行った。その際の排水(原
水)ならびにそれを処理して得た凝集沈殿処理水及び脱
塩処理後の回収水の性状を表6にまとめて示す。なお、
工程中それぞれの処理条件は表3ないし表5に示すもの
と全く同じであるが、本実施例では凝集沈殿処理効果を
把握するため砂ろ過処理を省略した。(Example 2) The same wastewater as in Example 1 was subjected to a treatment experiment in the steps shown in FIG. Table 6 summarizes the properties of the wastewater (raw water), the coagulated sedimentation treated water obtained by treating it, and the recovered water after desalination treatment. In addition,
The treatment conditions during the process are exactly the same as those shown in Tables 3 to 5, but in this example, the sand filtration treatment was omitted in order to grasp the effect of the coagulation sedimentation treatment.
【0061】その結果、凝集沈殿処理水、脱塩処理回収
水とも実施例1とほぼ同等の値が得られた。なお凝集沈
殿処理の際、MF処理時に発生した濃縮汚泥を投入する
ことによって種晶の核として作用し凝集反応を促進する
ものとみられ、実施例1の場合と比べてやや重く沈殿し
易いフロックが得られた。As a result, substantially the same value as in Example 1 was obtained for both the coagulated sedimentation treated water and the desalted treated recovered water. During the coagulation and sedimentation treatment, it is considered that the concentrated sludge generated during the MF treatment acts as a seed crystal nucleus to promote the coagulation reaction. Obtained.
【0062】[0062]
【表6】 [Table 6]
【0063】(実施例3)実施例1と同じ排水について
図3に示す工程で処理実験を行った。その際の排水(原
水)ならびにそれを処理して得た脱塩処理後の回収水の
性状を表7にまとめて示す。なお、工程中それぞれの処
理条件は表3ないし表5に示すものと全く同じである。
その結果、脱塩処理回収水は実施例1とほぼ同等の値が
得られた。(Example 3) The same wastewater as in Example 1 was subjected to a treatment experiment in the process shown in FIG. The properties of the wastewater (raw water) and the recovered water after desalination obtained by treating it are summarized in Table 7. The processing conditions during the process are exactly the same as those shown in Tables 3 to 5.
As a result, the value of the desalinated water recovered was almost the same as that of Example 1.
【0064】[0064]
【表7】 [Table 7]
【0065】[0065]
【発明の効果】以上説明したように、本発明による排水
処理方法では、脱塩処理によって発生する濃縮水を最前
部の生物学的硝化脱窒処理工程へ返送して処理するた
め、従来の排水処理で必要としていた吸着装置等の処理
設備を別途設ける必要がなく、設備を小型化もしくは省
略できる。このため設備費用及び運転費用を大幅に節減
するとともに、設置面積を縮小することができる。As described above, in the wastewater treatment method according to the present invention, the concentrated water generated by the desalination treatment is returned to the foremost biological nitrification and denitrification treatment step for treatment. There is no need to separately provide processing equipment such as an adsorption device required for the processing, and the equipment can be reduced in size or omitted. For this reason, the equipment cost and the operating cost can be significantly reduced, and the installation area can be reduced.
【0066】また、本発明の排水処理方法において、生
物処理工程から得られた生物処理水の一部を凝集沈殿処
理する凝集沈殿処理工程に送り、生物処理工程から得ら
れた生物処理水の残部を固液分離する固液分離工程、そ
してその固液分離工程に引き続き脱塩処理する脱塩処理
工程に送って処理するようにしたものでは、排水全量の
うち、再利用を必要とする水量分のみ高度処理するた
め、特にMFまたはUFによる固液分離装置及びRO脱
塩装置の各々を小型化することができる。In the wastewater treatment method of the present invention, a part of the biologically treated water obtained from the biological treatment step is sent to the coagulation and sedimentation treatment step for coagulating and sedimentation treatment, and the remaining part of the biologically treated water obtained from the biological treatment step is removed. In a solid-liquid separation step of solid-liquid separation, and a desalination treatment step of desalination treatment subsequent to the solid-liquid separation step. Since only advanced treatment is performed, it is possible to reduce the size of each of the solid-liquid separation device and the RO desalination device using MF or UF.
【0067】また、本発明の排水処理方法において、固
液分離装置から排出される濃縮汚泥を、濃厚な状態で凝
集沈殿装置から排出される汚泥と混合してまとめて処理
するようにしたものでは、大がかりな設備を必要とせ
ず、またメインテナンスの手間が省ける。Further, in the wastewater treatment method of the present invention, the concentrated sludge discharged from the solid-liquid separation device is mixed with the sludge discharged from the coagulation sedimentation device in a concentrated state and is treated collectively. No large-scale equipment is required, and maintenance work can be omitted.
【図1】本発明の実施の第1形態における排水処理工程
説明図。FIG. 1 is an explanatory view of a wastewater treatment step according to a first embodiment of the present invention.
【図2】本発明の実施の第2形態における排水処理工程
説明図。FIG. 2 is an explanatory view of a wastewater treatment step according to a second embodiment of the present invention.
【図3】本発明の実施の第3形態における排水処理工程
説明図。FIG. 3 is an explanatory view of a wastewater treatment step according to a third embodiment of the present invention.
【図4】従来技術における排水処理工程説明図。FIG. 4 is an explanatory diagram of a wastewater treatment process in the conventional technology.
1 生物処理装置 1a 硝化槽 1b 脱窒槽 1c 酸化槽 1d 沈殿槽 2 排水貯槽 3 中継槽 4 凝集沈殿装置 5 ろ過装置 6 濃縮装置 7 脱水装置 8 凝集装置 9 循環槽 10 固液分離装置 11 中継槽 12 脱塩装置 13 回収水槽 21 排水 22 生物処理水 23 凝集剤A 24 pH調整剤 25 上澄水 26 処理水 27 凝集沈殿汚泥 28 脱水ケーキ 29 脱離液 30 凝集剤B 31 凝集液 32 分離液 33 濃縮汚泥 34 透過液 35 回収水 36 濃縮水 DESCRIPTION OF SYMBOLS 1 Biological treatment apparatus 1a Nitrification tank 1b Denitrification tank 1c Oxidation tank 1d Precipitation tank 2 Drainage storage tank 3 Relay tank 4 Coagulation sedimentation apparatus 5 Filtration apparatus 6 Concentration apparatus 7 Dehydration apparatus 8 Coagulation apparatus 9 Circulation tank 10 Solid-liquid separation apparatus 11 Relay tank 12 Desalination device 13 Recovery water tank 21 Wastewater 22 Biologically treated water 23 Coagulant A 24 pH adjuster 25 Supernatant water 26 Treated water 27 Coagulated sediment sludge 28 Dehydration cake 29 Desorbed liquid 30 Coagulant B 31 Coagulated liquid 32 Separated liquid 33 Concentrated sludge 34 Permeate 35 Collected water 36 Concentrated water
フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C02F 9/00 502 C02F 9/00 502P B01D 61/02 500 B01D 61/02 500 61/14 500 61/14 500 C02F 1/44 C02F 1/44 K 1/52 1/52 Z 3/30 3/30 Z 3/34 101 3/34 101A (72)発明者 中川 平安 神戸市兵庫区小松通五丁目1番16号 株式 会社神菱ハイテック内Continued on the front page (51) Int.Cl. 6 Identification number Reference number in the agency FI Technical display location C02F 9/00 502 C02F 9/00 502P B01D 61/02 500 B01D 61/02 500 61/14 500 61/14 500 C02F 1/44 C02F 1/44 K 1/52 1/52 Z 3/30 3/30 Z 3/34 101 3/34 101A (72) Inventor Heian Nakagawa 5-1-1, Komatsudori, Hyogo-ku, Kobe-shi Shinryo High-Tech Co., Ltd.
Claims (7)
の処理方法において、該排水を生物学的処理して窒素化
合物及び有機物を分解する生物処理工程、同生物処理工
程から得られた生物処理水の一部を凝集沈殿処理する凝
集沈殿処理工程、前記生物処理工程から得られた生物処
理水の残部を固液分離する固液分離工程、及び固液分離
工程に引き続き脱塩処理する脱塩処理工程の各工程より
なり、同脱塩処理工程から排出される濃縮水を前記生物
処理工程に返送して未処理の排水と混合し、濃縮水中に
残存する有機物及び窒素化合物を前記生物処理工程にお
いて分解処理することを特徴とする排水の処理方法。1. A method for treating wastewater containing an organic substance or a nitrogen compound, comprising: a biological treatment step of biologically treating the wastewater to decompose a nitrogen compound and an organic substance; and a biologically treated water obtained from the biological treatment step. A coagulation sedimentation step of partially coagulating and sedimentation processing, a solid-liquid separation step of solid-liquid separation of the remaining biologically treated water obtained from the biological treatment step, and a desalination treatment step of desalination subsequent to the solid-liquid separation step The concentrated water discharged from the desalting step is returned to the biological treatment step and mixed with untreated wastewater, and the organic substances and nitrogen compounds remaining in the concentrated water are decomposed in the biological treatment step. A method for treating wastewater, comprising treating.
泥と、前記生物処理水を凝集処理して得た凝集液とを混
合し、該混合液の一部を同固液分離工程へ循環するとと
もに、同混合液の残部を前記凝集沈殿処理工程から排出
される汚泥と混合し、濃縮、脱水処理することを特徴と
する請求項1に記載の排水の処理方法。2. The concentrated sludge discharged from the solid-liquid separation step is mixed with the coagulated liquid obtained by coagulating the biologically treated water, and a part of the mixed liquid is circulated to the solid-liquid separation step. The method for treating wastewater according to claim 1, wherein the remaining portion of the mixed solution is mixed with sludge discharged from the coagulation sedimentation process, and the mixture is concentrated and dehydrated.
た凝集液を固液分離し、排出される濃縮汚泥を前記生物
処理水と混合した後、前記凝集沈殿処理工程に導くこと
を特徴とする請求項1または2に記載の排水の処理方
法。3. A coagulation liquid obtained by coagulating a part of the biologically treated water is subjected to solid-liquid separation, and the concentrated sludge discharged is mixed with the biologically treated water, followed by leading to the coagulation and sedimentation treatment step. The method for treating wastewater according to claim 1 or 2, wherein:
の処理方法において、該排水を生物学的処理して窒素化
合物及び有機物を分解した後浮遊物を沈殿分離する生物
処理工程、同生物処理工程から得られた生物処理水を固
液分離する固液分離工程、及び同固液分離工程に引き続
き脱塩処理する脱塩処理工程の各工程よりなり、同脱塩
処理工程から排出される濃縮水を前記生物処理工程に返
送して未処理の排水と混合し、同濃縮水中に残存する有
機物及び窒素化合物を前記生物処理工程において分解処
理することを特徴とする排水の処理方法。4. A method for treating wastewater containing an organic substance or a nitrogen compound, comprising: a biological treatment step of biologically treating the wastewater to decompose the nitrogen compound and the organic substance; Solid-liquid separation step of solid-liquid separation of the biologically treated water obtained, and desalination treatment step of desalination treatment following the solid-liquid separation step, and the concentrated water discharged from the desalination treatment step A method for treating wastewater, comprising returning to the biological treatment step, mixing with untreated wastewater, and decomposing organic substances and nitrogen compounds remaining in the concentrated water in the biological treatment step.
処理であることを特徴とする請求項1ないし4のいづれ
か1つに記載の排水の処理方法。5. The method according to claim 1, wherein the biological treatment step is a biological nitrification and denitrification treatment.
理であることを特徴とする請求項1ないし5のいづれか
1つに記載の排水の処理方法。6. The method for treating wastewater according to claim 1, wherein the coagulation-sedimentation process is a high-speed coagulation-sedimentation process.
外ろ過処理を含み、前記脱塩処理工程が逆浸透処理を含
むことを特徴とする請求項1ないし6のいづれか1つに
記載の排水の処理方法。7. The method according to claim 1, wherein the solid-liquid separation step includes a microfiltration treatment or an ultrafiltration treatment, and the desalination treatment step includes a reverse osmosis treatment. Wastewater treatment method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8185979A JPH1028995A (en) | 1996-07-16 | 1996-07-16 | Treatment of waste water |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8185979A JPH1028995A (en) | 1996-07-16 | 1996-07-16 | Treatment of waste water |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH1028995A true JPH1028995A (en) | 1998-02-03 |
Family
ID=16180238
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8185979A Withdrawn JPH1028995A (en) | 1996-07-16 | 1996-07-16 | Treatment of waste water |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH1028995A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103420464A (en) * | 2012-05-15 | 2013-12-04 | 株式会社日立制作所 | Composite flocculant solution for water treatment, and water treatment apparatus and method using same |
CN105084526A (en) * | 2015-09-24 | 2015-11-25 | 桑德集团有限公司 | Biological rotating disc process operation method for disposing waste water in villages and towns |
US11156041B2 (en) | 2012-02-22 | 2021-10-26 | Richard Paul Posa | System and method for treating water |
-
1996
- 1996-07-16 JP JP8185979A patent/JPH1028995A/en not_active Withdrawn
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11156041B2 (en) | 2012-02-22 | 2021-10-26 | Richard Paul Posa | System and method for treating water |
US12091923B2 (en) | 2012-02-22 | 2024-09-17 | Richard Paul Posa | System and method for treating water |
CN103420464A (en) * | 2012-05-15 | 2013-12-04 | 株式会社日立制作所 | Composite flocculant solution for water treatment, and water treatment apparatus and method using same |
CN105084526A (en) * | 2015-09-24 | 2015-11-25 | 桑德集团有限公司 | Biological rotating disc process operation method for disposing waste water in villages and towns |
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