JPH10243777A - Composition for reinforcing dietary fiber and dietary fiber-reinforced food using the same - Google Patents
Composition for reinforcing dietary fiber and dietary fiber-reinforced food using the sameInfo
- Publication number
- JPH10243777A JPH10243777A JP9067317A JP6731797A JPH10243777A JP H10243777 A JPH10243777 A JP H10243777A JP 9067317 A JP9067317 A JP 9067317A JP 6731797 A JP6731797 A JP 6731797A JP H10243777 A JPH10243777 A JP H10243777A
- Authority
- JP
- Japan
- Prior art keywords
- starch
- dietary fiber
- food
- swelling
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
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- Coloring Foods And Improving Nutritive Qualities (AREA)
- Grain Derivatives (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Noodles (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は食品の品質に悪影響
を与えることなく、容易に食品中の食物繊維を強化せし
めることができる食物繊維強化用組成物及びそれを用い
た食物繊維強化食品に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a dietary fiber-enhancing composition which can easily enhance dietary fiber in food without adversely affecting the quality of the food, and a dietary fiber-enriched food using the same.
【0002】[0002]
【従来の技術】食物繊維はコレストロールの低下、血糖
値の上昇抑制、整腸作用、大腸ガンの予防、有害物の排
泄など種々の生理作用を有することが明らかにされてき
て、6番目の栄養素群としての位置づけを確立しつつあ
る。しかるに、通常の食事より摂取する食物繊維量は、
近年の食生活の変化に伴って減少しており、予防医学上
からも食物繊維の多い食事、即ち、食物繊維を強化した
食品が望まれていて、食物繊維を含有する多くの食品が
提案されている。例えば、ヘミセルロースの部分分解物
を含有する飲食物(特開平3−49662号)、低ペク
チン酸を配合してなる飲食物(特開平5−192108
号)、冷水可溶性食物繊維を含有してなる特定保健食品
(特開平4−335872号)、耐性澱粉を含む食品組
成物(特表平8−504583号)などである。BACKGROUND OF THE INVENTION Dietary fiber has been shown to have various physiological actions such as lowering cholesterol, suppressing an increase in blood glucose level, intestinal action, preventing colorectal cancer, and excreting harmful substances. The position as a group is being established. However, the amount of dietary fiber consumed from a normal diet is
Due to the recent changes in dietary habits, diets containing a large amount of dietary fiber have been desired from the viewpoint of preventive medicine, that is, foods reinforced with dietary fiber have been desired, and many foods containing dietary fiber have been proposed. ing. For example, foods and drinks containing hemicellulose partially decomposed products (JP-A-3-49662) and foods and drinks containing low pectic acid (JP-A-5-192108)
), Specified health foods containing cold water-soluble dietary fiber (JP-A-4-335872), and food compositions containing resistant starch (JP-A-8-504585).
【0003】特に平成8年に施行された栄養改善法の一
部改正によって、栄養表示基準が設けられて、一定量以
上の食物繊維を含有する食品について、例えば食物繊維
を3g/100g固体以上で「食物繊維含有」など、6
g/100g固体以上で「食物繊維強化」などの強調表
示ができるようになり、食物繊維を添加した食品への関
心が強くなっている。In particular, due to the partial revision of the Nutrition Improvement Act enacted in 1996, nutrition labeling standards have been established. For foods containing a certain amount of dietary fiber or more, for example, a dietary fiber of 3 g / 100 g or more is solid. 6 including "dietary fiber content"
With g / 100 g solids or more, it is possible to make a highlighting such as "dietary fiber reinforced", and the interest in foods to which dietary fiber is added has increased.
【0004】食物繊維には周知の通り水に不溶性の食物
繊維と水溶性の食物繊維がある。前者としてはセルロー
ス、小麦ふすま、アップルファイバー、さつまいもファ
イバー、キチンなどが例示される。後者は更に高粘性物
と低粘性物に大別され、高粘性物としてはペクチン、コ
ンニャクマンナン、アルギン酸、グアーガム、寒天な
ど、低粘性物としては難消化性デキストリン、ポリデキ
ストロース、グアーガム分解物などが例示される。As is well known, dietary fiber includes water-insoluble dietary fiber and water-soluble dietary fiber. Examples of the former include cellulose, wheat bran, apple fiber, sweet potato fiber, chitin and the like. The latter is further classified into high-viscosity substances and low-viscosity substances.High-viscosity substances include pectin, konjac mannan, alginic acid, guar gum, agar, etc. Is exemplified.
【0005】食品はたとえ生理機能など特殊な機能を有
していても、先ずそれぞれの食品として美味しいと感ず
るものでなければならず、外観、食感、風味など食品を
構成する要素のいずれも満足できるものであることを要
する。[0005] Even if a food has a special function such as a physiological function, it must first be tasted as each food, and all of the components constituting the food, such as appearance, texture and flavor, must be satisfied. It needs to be something that can be done.
【0006】この点に於て、水に不溶性の食物繊維はハ
ンバーグのように組織の荒い食品に用いる場合を除い
て、一般的に食品に使用すると、水に不溶性の故に、食
感的にザラツキを生じて必要量を添加するのが難しい。
水溶性の食物繊維の中で高粘性物も、その高粘性故に少
量の添加で食品の物性に与える影響が大きく、例えばコ
ンニャクのようにそれだけで作られる食品を除いて、食
物繊維源として必要量を添加することは困難である。[0006] In this regard, dietary fiber that is insoluble in water is generally textured when used in foods, unless it is used in foods with a rough tissue, such as hamburgers, because it is insoluble in water. And it is difficult to add the required amount.
Among water-soluble dietary fibers, high-viscosity substances also have a large effect on the physical properties of foods due to their high viscosity, and small amounts of them are required as a dietary fiber source, except for foods that are made by themselves, such as konjac. Is difficult to add.
【0007】一方、低粘性の水溶性食物繊維は、粘度が
殆どなくて水溶性であるため、基本的には食品に使い易
い素材で、飲料、スープなど水性の食品にはさしたる支
障なく必要量を添加することができる。しかし乍ら、固
体状の食品、特にめん類のように水中で加熱調理する食
品では、食感に影響を与えるだけでなく、加熱調理時に
熱水中に溶出して歩留が悪くなる問題があり、また、パ
ン、クッキーなどのベーカリー食品やスナック食品で
は、加熱調理時にアメ状化してボリュームの低下、食感
が硬くなる、口溶けが悪くなるなどの問題があった。On the other hand, low-viscosity water-soluble dietary fiber has almost no viscosity and is water-soluble, so it is basically an easy-to-use material for food, and the amount required is not so great for aqueous food such as drinks and soups. Can be added. However, solid foods, particularly foods cooked in water, such as noodles, have a problem that not only affects the texture, but also elutes in hot water at the time of cooking, thereby lowering the yield. In addition, bakery foods such as bread and cookies and snack foods have problems such as a reduction in volume due to candy during heating and cooking, a hard texture, and a poor melting in the mouth.
【0008】そして、これらの問題点を改善する多くの
方法が提案されている。例えば、パン類に関しては、特
定の小麦粉と界面活性剤を用いるパンの製造法(特開平
2−227020号)、微粒化セルロースを添加するパ
ン生地(特開平5−95754号)、食物繊維、酸化
剤、アミラーゼ剤、グルテン及び乳化剤を配合添加する
パン類の製造法(特開平6−70670号)、特定工程
で難消化性デキストリンを添加する技術(特開平4−5
1840号)など、クッキーなどに関しては、水との接
触で膨張する性質の食物繊維を食用油により含浸させて
用いる技術(特開昭61−115434号)、特定比率
の不溶性食物繊維と水溶性食物繊維と小麦粉、糖類、油
脂を特定割合で使用する技術(特開平3−27234
号)、食物繊維を油脂で被覆して使用する技術(特開平
8−289715号)などである。[0008] Many methods have been proposed to improve these problems. For example, as for breads, a method for producing bread using a specific flour and a surfactant (Japanese Patent Application Laid-Open No. 2-227020), a dough to which micronized cellulose is added (Japanese Patent Application Laid-Open No. 5-95754), a dietary fiber, and an oxidizing agent , A method for producing breads containing an amylase agent, gluten and an emulsifier (JP-A-6-70670), a technique of adding an indigestible dextrin in a specific step (JP-A-4-5
No. 1840), for example, a technique of using a dietary fiber which expands in contact with water by impregnating it with edible oil (Japanese Patent Application Laid-Open No. 61-115434), a specific ratio of insoluble dietary fiber and water-soluble food Technology using fibers and flour, sugars and fats and oils in specific ratios (Japanese Patent Application Laid-Open No. 3-27234)
No.), and a technique of coating and using dietary fiber with fats and oils (Japanese Patent Application Laid-Open No. 8-289715).
【0009】このように、食物繊維を添加した時に生ず
る問題点を克服する上から種々の方法が提案されてい
る。しかし、それらの方法に於ては問題点の改善が不十
分であったり、操作が煩雑になったり、風味的には好ま
しくない添加物を必要としたりして、必要な食物繊維を
容易に添加することができ、且つ、食物繊維を添加しな
いものと同等ないしはそれ以上の品質、食品としての美
味しさを有する食品が得られると言う観点に於ては、未
だ十分満足できるものには至っていない。As described above, various methods have been proposed for overcoming the problems caused when dietary fiber is added. However, in those methods, the necessary dietary fiber is easily added because the problem is insufficiently improved, the operation is complicated, or an additive that is not desirable in flavor is required. However, from the viewpoint that a food having the same or better quality and taste as food without the addition of dietary fiber can be obtained, it has not yet been sufficiently satisfactory.
【0010】[0010]
【発明が解決しようとする課題】本発明が解決しようと
する課題は、上述の食物繊維を添加した際に生ずる問題
点の解消、即ち、特に食物繊維を含有せしめた時に問題
が生じ易い麺類やベーカリー食品、スナック食品に於
て、必要な食物繊維を容易に含有せしめることができ、
しかも食物繊維を添加しないものと同等ないしはそれ以
上に良好な品質を有する食品を製造し得る食物繊維強化
用組成物及びそれを用いて食物繊維を強化した良好な品
質を有する食品の提供にある。The problem to be solved by the present invention is to solve the problems caused when the above-mentioned dietary fiber is added, that is, noodles and the like which are liable to cause a problem particularly when dietary fiber is added. In bakery foods and snack foods, necessary dietary fiber can be easily contained,
In addition, it is an object of the present invention to provide a dietary fiber reinforcing composition capable of producing a food having a quality equal to or better than that without the addition of dietary fiber, and a food having a high quality which is reinforced with dietary fiber using the composition.
【0011】[0011]
【課題を解決するための手段】本発明者らは、斯かる現
状に鑑み鋭意研究を行った結果、低粘性の水溶性食物繊
維と特定の澱粉類を特定割合の組成物とし、これを用い
て製造した食品では本発明の課題が解決されることを見
いだし、本発明を完成するに至った。Means for Solving the Problems The inventors of the present invention have conducted intensive studies in view of the above situation, and as a result, a low-viscosity water-soluble dietary fiber and a specific starch were used as a composition in a specific ratio. The present invention was found to solve the problems of the present invention in foods produced by the present invention, and the present invention was completed.
【0012】即ち、本発明は、低粘性の水溶性食物繊維
7〜50重量%と、ヒドロキシプロピル基の平均置換度
が0.02〜0.2である澱粉類50〜93重量%から
なる食物繊維強化用組成物、及びこれを食品中に6〜4
5重量%含まれるように添加してなる食物繊維強化食品
に関し、好ましくは澱粉類が膨潤度3〜15である膨潤
抑制澱粉10〜60重量%、置換度が0.05〜0.2
2のヒドロキシプロピル澱粉40〜90重量%、その他
澱粉0〜50重量%からなり、更に低粘性の水溶性食物
繊維が難消化性デキストリンである食物繊維強化用組成
物、及びこれらを用いた食品、更に好ましくは食品が麺
類、ベーカリー食品、スナック食品である。That is, the present invention relates to a food comprising 7 to 50% by weight of a low-viscosity water-soluble dietary fiber and 50 to 93% by weight of a starch having an average degree of hydroxypropyl group substitution of 0.02 to 0.2. Composition for fiber reinforcement and 6-4 in food
With respect to a dietary fiber reinforced food which is added so as to contain 5% by weight, preferably, swelling-suppressed starch in which the starch has a swelling degree of 3 to 15 is 10 to 60% by weight, and the substitution degree is 0.05 to 0.2.
2, a dietary fiber-enhancing composition comprising 40-90% by weight of hydroxypropyl starch and 0-50% by weight of other starch, wherein the low-viscosity water-soluble dietary fiber is indigestible dextrin; More preferably, the food is a noodle, a bakery food, or a snack food.
【0013】本発明に於て低粘性の水溶性食物繊維と
は、50重量%以上の食物繊維を含有し、常温水に溶解
して低粘性の溶液、概ね5重量%水溶液で20mPas
以下の粘度を示す溶液となる食物繊維素材を指称する。
具体的には、難消化性デキストリン、グアーガム加水分
解物、ライテス、ヘミセルローズ由来の物などが挙げら
れるが、この他にも低粘性、水溶性の条件を満たす食物
繊維素材は何れも包含される。In the present invention, the low-viscosity water-soluble dietary fiber refers to a low-viscosity solution containing 50% by weight or more of dietary fiber and dissolved in normal temperature water, and a 20% solution of approximately 5% by weight aqueous solution.
A dietary fiber material which becomes a solution having the following viscosity is referred to.
Specific examples include indigestible dextrin, guar gum hydrolyzate, Lytes, substances derived from hemicellulose, and the like. In addition, any low-viscosity, dietary fiber material that satisfies the water-soluble condition is also included. .
【0014】難消化性デキストリンは、澱粉を加熱分解
した後、更にアミラーゼで加水分解し、脱色、脱塩して
得た平均分子量2000前後のデキストリンで、「パイ
ンファイバー」、「ファイバーソル2」(松谷化学工業
株式会社製)の商品名で市販されていて、詳しくは”食
品新素材フォーラム”NO.3(1995、食品新素材
協議会編)に記載されている。The indigestible dextrin is a dextrin having an average molecular weight of about 2,000 obtained by subjecting starch to thermal decomposition, further hydrolyzing with amylase, decolorizing, and desalting. It is marketed under the trade name of Matsutani Chemical Industry Co., Ltd.). 3 (1995, edited by the Food New Materials Association).
【0015】グアーガム加水分解物は、「サンファイバ
ー」(太陽化学社)、「ファイバロン」(大日本製薬
社)の商品名で、ヘミセルロース由来の物は「セルエー
ス」(日本食品化工社)の商品名で市販されているし、
「ライテス」(ファイザー社)はブドー糖とソルビット
より構成される食物繊維の商品名である。これらは何れ
も詳しくは上記の”食品新素材フォーラム”に記載され
ている。これ等について、更に詳しく述べれば、以下の
通りである。The guar gum hydrolyzate is a product name of "Sun Fiber" (Taiyo Chemical) and "Fibreon" (Dainippon Pharmaceutical Co., Ltd.), and a product derived from hemicellulose is a product of "Cell Ace" (Nippon Shokuhin Kako). It is marketed by name,
"Litez" (Pfizer) is a trade name for a dietary fiber composed of budo sugar and sorbit. These are all described in detail in the above-mentioned "Food New Material Forum". These will be described in more detail below.
【0016】難消化デキストリンについては、各種の澱
粉、例えば馬鈴薯澱粉、タピオカ澱粉、コーンスター
チ、小麦粉澱粉等を130℃以上で加熱分解し、これを
アミラーゼで更に加水分解し、常法に従って、必要に応
じ脱色、脱塩して製造したものである。平均分子量は1
400〜2500好ましくは2000前後のデキストリ
ンであり、その他物性としては水溶性、低粘性、低甘味
である。As for the hardly digestible dextrin, various starches such as potato starch, tapioca starch, corn starch, wheat starch and the like are decomposed by heating at 130 ° C. or more, and further hydrolyzed with amylase, and if necessary, according to a conventional method. It is produced by decolorization and desalting. Average molecular weight is 1
Dextrin of about 400 to 2500, preferably about 2000, and other physical properties such as water solubility, low viscosity and low sweetness.
【0017】グアーガムの加水分解物はグアーガムを酵
素により加水分解したもので、その性状は通常低粘性で
冷水可溶、水溶液は中性で無色透明である。The hydrolyzate of guar gum is obtained by hydrolyzing guar gum with an enzyme, and its properties are usually low-viscosity and soluble in cold water, and the aqueous solution is neutral and colorless and transparent.
【0018】ヘミセルロース由来の物は、通常コーンの
外皮からアルカリで抽出し、精製して製造されたもの
で、平均分子量は約20万と大きいが、5%水溶液の粘
度は10cps程度と低く、水に溶けて透明な液にな
る。The substance derived from hemicellulose is usually produced by extracting and purifying from the hull of corn with alkali, and has a large average molecular weight of about 200,000. However, the viscosity of a 5% aqueous solution is as low as about 10 cps, and Dissolves into a clear liquid.
【0019】ライテスはブドウ糖とソルビトールをクエ
ン酸の存在下で液圧加熱して重合させ、精製したもので
水溶性で低粘性である。Lightes is a water-soluble and low-viscosity product obtained by polymerizing glucose and sorbitol by heating in a liquid pressure in the presence of citric acid.
【0020】これら低粘性の水溶性食物繊維の中でも、
同じ澱粉を起源にすることによるかとも思われるが、本
発明の組成物としては難消化性デキストリンが最も効果
的で好ましい。Among these low-viscosity water-soluble dietary fibers,
Although it may be due to the same starch origin, resistant dextrin is the most effective and preferred for the composition of the present invention.
【0021】本発明で使用する澱粉類は、ヒドロキシプ
ロピル基を含む澱粉、即ちヒドロキシプロピル澱粉を必
須成分とし、この他の種々の澱粉を含むか又は含まず
に、その平均置換度が0.02〜0.2であることを要
する。平均置換度は、澱粉類として用いる澱粉が含むヒ
ドロキシプロピル基の置換度(澱粉のグルコース残基当
たりのヒドロキシプロピル基のモル数で表す)の相加平
均で表わされ、単品でこの置換度を有するヒドロキシプ
ロピル澱粉であっても良いし、或はヒドロキシプロピル
基を有さない澱粉を含めた二種以上の澱粉でこの置換度
になるものでも良い。この際平均置換度が0.02未満
では本発明の効果を奏しなくなり、0.2を越えて高く
しても効果は変わらず経済的でない。The starch used in the present invention contains a starch containing a hydroxypropyl group, that is, a hydroxypropyl starch as an essential component, and has an average degree of substitution of 0.02 with or without other various starches. 0.20.2. The average degree of substitution is expressed as an arithmetic mean of the degree of substitution of hydroxypropyl groups contained in starch used as starch (expressed in moles of hydroxypropyl groups per glucose residue of starch). Hydroxypropyl starch, or two or more types of starch including starch having no hydroxypropyl group and having this substitution degree. In this case, if the average degree of substitution is less than 0.02, the effect of the present invention is not exhibited, and if it exceeds 0.2, the effect remains unchanged and is not economical.
【0022】官能基を有する加工澱粉はヒドロキシプロ
ピル澱粉の他に、アセチル基を有するアセチル化澱粉、
リン酸基のリン酸澱粉、オクテニルコハク酸基のオクテ
ニルコハク酸澱粉、コハク酸基のコハク酸澱粉など多く
あるが、本発明の目的にはヒドロキシプロピル基を有す
る澱粉のみが有効である。他の官能基を有する加工澱粉
は効果を奏しないが、効果を阻害することはないので、
上記のヒドロキシプロピル基が含まれる範囲で、これら
の加工澱粉を用いることもできる。The modified starch having a functional group is, in addition to hydroxypropyl starch, an acetylated starch having an acetyl group,
There are many types of starch such as phosphoric acid phosphate starch, octenyl succinic acid group octenyl succinic acid starch, and succinic acid group succinic acid starch. For the purpose of the present invention, only starch having a hydroxypropyl group is effective. Processed starch having other functional groups has no effect, but does not inhibit the effect,
These modified starches can also be used as long as the above-mentioned hydroxypropyl group is included.
【0023】更に好ましい澱粉類は、置換度0.05〜
0.22のヒドロキシプロピル澱粉40〜90重量%、
膨潤度3〜15の膨潤抑制澱粉10〜60%及びその他
澱粉0〜50重量%よりなるヒドロキシプロピル基の平
均置換度が0.02〜0.2である澱粉類で、このよう
な澱粉類からなる組成物を用いることにより、食物繊維
を含有せしめた食品の食感がより良くなってより好まし
い。Further preferred starches have a substitution degree of 0.05 to
40-90% by weight of 0.22 hydroxypropyl starch,
A starch having an average degree of substitution of a hydroxypropyl group consisting of 10 to 60% of a swelling-suppressed starch having a swelling degree of 3 to 15 and other starch of 0 to 50% by weight is 0.02 to 0.2. By using such a composition, the texture of food containing dietary fiber is further improved, which is more preferable.
【0024】この際のヒドロキシプロピル澱粉は、原則
として、その膨潤度は15より大きなものであり、また
その他の澱粉とは、上記ヒドロキシプロピル澱粉及び膨
潤度抑制澱粉以外の澱粉をいう。In this case, the hydroxypropyl starch in principle has a degree of swelling of greater than 15, and the other starches are starches other than the above-mentioned hydroxypropyl starch and swelling degree-suppressed starch.
【0025】澱粉類の必須成分として用いるヒドロキシ
プロピル澱粉は、常法に従って澱粉にプロピレンオキサ
イドを反応せしめて得られ、その中で置換度が0.02
以上、好ましくは0.05〜0.22のものである。こ
の置換度はプロピレンオキサイドの添加量によって調節
できる。Hydroxypropyl starch used as an essential component of starch is obtained by reacting starch with propylene oxide according to a conventional method, wherein the degree of substitution is 0.02.
As described above, it is preferably 0.05 to 0.22. This degree of substitution can be adjusted by the amount of propylene oxide added.
【0026】但し、置換度が0.2より大きく、0.0
2より小さいものは、これ単独では使用しない。However, if the degree of substitution is greater than 0.2 and 0.0
Those smaller than 2 are not used alone.
【0027】ヒドロキシプロピル澱粉を製造する際の原
料澱粉には、市販の未処理澱粉、例えば馬鈴薯澱粉、タ
ピオカ澱粉、小麦澱粉、コーンスターチ、ワキシーコー
ンスターチ、米澱粉、糯米澱粉、サゴ澱粉など何れも使
用することができる。また、ヒドロキシプロピル化処理
と他の加工処理、例えば漂白処理、酸処理、酸化剤処
理、架橋処理、α−化処理などを組み合わせたものでも
よく、要は上述の置換度を有するヒドロキシプロピル澱
粉であって、膨潤抑制澱粉として用いられるものを除い
たもの、即ち膨潤度が15を越えるものであれば良い。
尚、他の加工処理としては、従来から知られている処理
を採用すれば良い。As raw material starch for producing hydroxypropyl starch, any commercially available untreated starch such as potato starch, tapioca starch, wheat starch, corn starch, waxy corn starch, rice starch, glutinous rice starch, sago starch and the like can be used. be able to. Further, a combination of the hydroxypropylation treatment and other processing treatments, for example, a bleaching treatment, an acid treatment, an oxidizing agent treatment, a cross-linking treatment, an α-formation treatment, etc. may be used. Therefore, it is only necessary to remove those used as swelling suppressing starch, that is, those having a swelling degree of more than 15.
As the other processing, a conventionally known processing may be employed.
【0028】本発明ではヒドロキシプロピル基の平均置
換度が0.02〜0.2の澱粉類を用いる。これはヒド
ロキシプロピル澱粉のみによってこの平均置換度になる
ものも用い得るが、好ましくは膨潤度3〜15の膨潤抑
制澱粉が10〜60重量%含まれる澱粉類である。この
ような澱粉類を用いることにより、例えばクッキー、パ
ンなどではサクサが出て口溶けの良い食感になるし、麺
類では腰が強くなるなどより食感が良くなって好まし
い。In the present invention, starches having an average degree of substitution of hydroxypropyl groups of 0.02 to 0.2 are used. This may be a starch having the average degree of substitution by hydroxypropyl starch alone, but is preferably a starch containing 10 to 60% by weight of a swelling-inhibiting starch having a swelling degree of 3 to 15. By using such starches, for example, crisps and breads have a crispy appearance and have a mouth-melting texture, and noodles have a better texture than a strong waist, which is preferable.
【0029】膨潤抑制澱粉は、澱粉を水の存在下で加熱
した際に起こる膨潤が抑制された澱粉を指称し、膨潤の
程度を表す膨潤度が3〜15である膨潤抑制澱粉が好ま
しい。膨潤度がこの範囲を逸脱すると効果が減少する。
一方、膨潤度がこの範囲にある膨潤抑制澱粉は何れも使
用することができ、未処理澱粉であっても膨潤度がこの
範囲にある澱粉、例えばアミロース含量が約70重量%
ないしはそれ以上のアミロースを含有するハイアミロー
ス澱粉などは包含される。しかし、一般的には通常の澱
粉の膨潤度は上限を逸脱するので、架橋処理、湿熱処
理、乳化剤処理などにより調節するが、これらの膨潤抑
制処理の中では、架橋処理して架橋澱粉とすることが、
膨潤度の調節が容易で好ましい。The swelling-suppressed starch refers to a starch in which swelling which occurs when the starch is heated in the presence of water is suppressed, and a swelling-inhibiting starch having a degree of swelling of 3 to 15 indicating a degree of swelling is preferable. If the degree of swelling is out of this range, the effect is reduced.
On the other hand, any swelling-inhibiting starch having a swelling degree in this range can be used, and even an untreated starch having a swelling degree in this range, for example, having an amylose content of about 70% by weight.
High amylose starch containing more or more amylose is included. However, in general, the degree of swelling of ordinary starch exceeds the upper limit, and is adjusted by a crosslinking treatment, a moist heat treatment, an emulsifier treatment, and the like. That
It is preferable because the degree of swelling can be easily adjusted.
【0030】澱粉の架橋処理は、メタリン酸塩、オキシ
塩化リン、エピクロルヒドリン、アジピン酸などの常用
の架橋剤を用い、所望の膨潤度によって架橋剤の添加量
を調節しながら常法に従って澱粉を架橋することによ
り、容易に膨潤度を調節した膨潤抑制澱粉を得ることが
できる。3〜15の膨潤度にあれば、架橋処理と他の加
工処理、例えば漂白処理、α−化処理、アセチルなどの
エステル化、ヒドロキシプロピル化などのエーテル化な
どの処理を組み合わせたものであっても良い。尚、ヒド
ロキシプロピル化処理を組み合わせた場合、そのヒドロ
キシプロピル基は澱粉類としての平均置換度に算入され
る。また、架橋処理に用いる原料澱粉としては、上述の
市販の未処理澱粉の何れであっても良い。The starch is crosslinked by using a conventional crosslinking agent such as metaphosphate, phosphorus oxychloride, epichlorohydrin, adipic acid, etc., and adjusting the amount of the crosslinking agent to be added according to the desired degree of swelling. By doing so, a swelling-suppressed starch whose swelling degree is easily adjusted can be obtained. If the degree of swelling is in the range of 3 to 15, it is a combination of crosslinking treatment and other processing such as bleaching, α-treatment, esterification such as acetyl, and etherification such as hydroxypropylation. Is also good. When the hydroxypropylation treatment is combined, the hydroxypropyl group is included in the average degree of substitution as a starch. The raw starch used for the crosslinking treatment may be any of the above-mentioned commercially available untreated starches.
【0031】この際の温熱処理や乳化剤処理も、従来か
らの常法に従えば良く、例えば前者は澱粉の水分を20
〜25%程度に調整し、これを約100〜130℃で
0.5〜5時間加熱する方法を、後者は澱粉を30〜4
0%の水懸濁液とし、これに脂肪酸モノグリセライドや
蔗糖脂肪酸エステルなどの乳化剤を加えて数時間処理
後、脱水、乾燥する方法を例示できる。The heat treatment and the emulsifier treatment at this time may be carried out according to a conventional method.
2525%, and heating at about 100-130 ° C. for 0.5-5 hours.
For example, a method of preparing a 0% aqueous suspension, adding an emulsifier such as a fatty acid monoglyceride or a sucrose fatty acid ester, treating the suspension for several hours, and then dehydrating and drying the suspension can be exemplified.
【0032】尚、本発明で述べる膨潤度は次の方法に従
って測定される。即ち、乾燥物換算で試料1.0gを脱
イオン水100mlに分散し、90℃で30分間加熱後
30℃に冷却する。次いで、この糊化液を遠心分離(3
000rpm、10分間)してゲル層と上澄層に分け、
ゲル層の重量を測定してこれをAとする。重量測定した
ゲル層を乾固(105℃、恒量)し、重量を測定してこ
れをBとし、A/Bで膨潤度を表す。The degree of swelling described in the present invention is measured according to the following method. That is, 1.0 g of a sample in terms of dry matter is dispersed in 100 ml of deionized water, heated at 90 ° C. for 30 minutes, and then cooled to 30 ° C. Then, the gelatinized solution was centrifuged (3
000 rpm for 10 minutes) to separate into a gel layer and a supernatant layer,
The weight of the gel layer is measured and this is designated as A. The weight-measured gel layer was dried (105 ° C., constant weight), and the weight was measured to be B. A / B indicates the degree of swelling.
【0033】本発明で使用する澱粉類は、ヒドロキシプ
ロピル基の平均置換度が0.02〜0.2であることを
要し、好ましくは膨潤度3〜15の膨潤抑制澱粉10〜
60重量%、置換度0.05〜0.22のヒドロキシプ
ロピル澱粉40〜90重量%及びその他澱粉0〜50重
量%からなる。この平均置換度を満たす、好ましくはこ
の平均置換度及び所定量の膨潤抑制澱粉とヒドロキシプ
ロピル澱粉を含む条件を満たす限りに於て、その他の澱
粉を含むことができる。The starch used in the present invention is required to have an average degree of substitution of hydroxypropyl groups of 0.02 to 0.2, preferably a swelling-inhibiting starch having a swelling degree of 3 to 15.
It consists of 60% by weight, 40 to 90% by weight of hydroxypropyl starch having a substitution degree of 0.05 to 0.22 and 0 to 50% by weight of other starch. Other starches can be included as long as they satisfy the average degree of substitution, preferably satisfy the conditions including the average degree of substitution and a predetermined amount of swelling-inhibiting starch and hydroxypropyl starch.
【0034】その他の澱粉は、置換度0.02以上のヒ
ドロキシプロピル澱粉及び膨潤度が3〜15の膨潤抑制
澱粉以外の澱粉を指称する。従って、これらの澱粉とし
ては、馬鈴薯澱粉、タピオカ澱粉、小麦澱粉などの各種
未処理澱粉及び加工澱粉が包含される。加工澱粉として
は漂白澱粉、可溶性澱粉、油脂処理澱粉、デキストリ
ン、α−化澱粉、エーテル化澱粉、エステル化澱粉、所
定膨潤度を逸脱した架橋澱粉、湿熱処理澱粉、乳化剤処
理澱粉、エーテル化架橋澱粉、エステル化架橋澱粉など
が挙げられる。The other starches are starches other than hydroxypropyl starch having a substitution degree of 0.02 or more and swelling-inhibiting starch having a swelling degree of 3 to 15. Therefore, these starches include various untreated starches and processed starches such as potato starch, tapioca starch and wheat starch. Processed starches include bleached starch, soluble starch, fat- and oil-treated starch, dextrin, α-modified starch, etherified starch, esterified starch, crosslinked starch deviating from a predetermined degree of swelling, wet heat-treated starch, emulsifier-treated starch, and etherified crosslinked starch. And esterified cross-linked starch.
【0035】本発明の食物繊維強化用組成物は、上述の
低粘性の水溶性食物繊維7〜50重量%と澱粉類93〜
50重量%からなる。両者の比率は所望の食物繊維の添
加量及び該組成物の添加量により決められるが、低粘性
の水溶性食物繊維が7重量%より少なくなると、所望の
食物繊維を添加するためには組成物の添加量が多くなっ
て、食品の品質が劣ってくる。また、50重量%を越え
て多くなると低粘性の水溶性食物繊維のみを食品に添加
した際に生じる弊害が現れてくる。The composition for reinforcing dietary fiber of the present invention comprises 7 to 50% by weight of the low-viscosity water-soluble dietary fiber and 93 to 90% of starch.
Consists of 50% by weight. The ratio between the two is determined by the amount of the desired dietary fiber and the amount of the composition. If the low-viscosity water-soluble dietary fiber is less than 7% by weight, the composition must be added to add the desired dietary fiber. , The quality of food becomes inferior. On the other hand, if the content exceeds 50% by weight, adverse effects appear when only low-viscosity water-soluble dietary fiber is added to food.
【0036】低粘性の水溶性食物繊維をこのような組成
物にすることにより、食品の製造に際して該組成物を添
加するだけで、低粘性の水溶性食物繊維の歩留を著しく
改善、或は食品の品質に何ら悪影響を与えることなく容
易に食物繊維強化食品を得ることができる。By making a low-viscosity water-soluble dietary fiber into such a composition, the yield of the low-viscosity water-soluble dietary fiber can be remarkably improved only by adding the composition at the time of food production, or A dietary fiber-enriched food can be easily obtained without any adverse effect on the quality of the food.
【0037】本発明の食物繊維強化食品としては、本発
明の食物繊維強化用組成物が効果的に用いられる食品で
あり、特に好ましい食品としては固体状の食品であっ
て、麺類のように熱湯中で茹でられるもの、或は高温で
調理されるベーカリー食品、スナック食品などが挙げら
れる。The dietary fiber-enriched food of the present invention is a food in which the composition for dietary fiber enrichment of the present invention is effectively used, and a particularly preferred food is a solid food, such as hot water such as noodles. Boiled foods, bakery foods, and snack foods cooked at high temperatures are included.
【0038】麺類の場合、一般的には熱湯中で茹でて可
食状態にする。低粘性の水溶性食物繊維のみを麺生地に
添加した場合、茹での工程で該食物繊維は熱湯中に溶出
して歩留が著しく悪くなり、この歩留低下を加味して添
加量を多くするとグルテンの形成を阻害して製麺性の悪
化や腰の弱い麺になる問題があった。また、インスタン
ト麺では茹でる工程はないが、蒸した後熱風又はフライ
して乾燥され、その際低粘性の食物繊維が水分と共に表
面に移動、即ちマイグレイションを起こすためと思われ
るが、表面に”ぬめり”を生じてまずい食感になる。本
発明の食物繊維強化用組成物を用いることにより、これ
らの問題点が改善されて麺類としての品質を悪化するこ
となく、容易に所望の食物繊維を含有せしめた麺類を得
ることができる。In the case of noodles, they are generally boiled in boiling water to make them edible. When only the low-viscosity water-soluble dietary fiber is added to the noodle dough, the dietary fiber is eluted in boiling water during the boiling step, and the yield is significantly deteriorated. There was a problem in that the formation of gluten was inhibited and the noodle-making properties deteriorated and the noodles became weak. In addition, there is no boiling step for instant noodles, but it is steamed and then dried by hot air or fried. At that time, it is thought that the low-viscosity dietary fiber moves to the surface together with moisture, that is, causes migration. "Slimy" results in unpleasant texture. By using the composition for reinforcing dietary fiber of the present invention, these problems are improved and the noodles containing the desired dietary fiber can be easily obtained without deteriorating the quality of the noodles.
【0039】また、ベーカリー食品としてはパン、ケー
キ、クッキー、ビスケットなど、スナック食品としては
成形ポテトチップス、コーンチップス、ペレットスナッ
ク、あられなどが挙げられ、これらの製造に於ては高温
で加熱処理して全体が乾燥した状態、或は表面が乾燥し
た状態の食品になっている。低粘性の水溶性食物繊維は
その低粘性、水溶性の故に、加熱処理時マイグレイショ
ンして表面部分の濃度が高くなり、それがアメ状化して
固化すると言った現象が起こっているためではないかと
推測されるが、食感的に硬くなって口溶けが悪く、歯に
くっつき易く、体積が小さくなる問題があった。本発明
の食物繊維強化用組成物を用いることにより、これらの
問題点が解消され、品質的に優れた食物繊維強化食品を
得ることができる。Bakery foods include breads, cakes, cookies, biscuits and the like, and snack foods include molded potato chips, corn chips, pellet snacks, and arachis. The whole food is dried or the food is dried. This is not due to the fact that low-viscosity, water-soluble dietary fiber is migrated during heat treatment and its concentration on the surface becomes high due to its low viscosity and water solubility, which causes it to become candy and solidify. However, there is a problem that the texture becomes hard and the mouth dissolves poorly, sticks easily to the teeth, and reduces the volume. By using the dietary fiber-reinforced composition of the present invention, these problems can be solved and a dietary fiber-reinforced food excellent in quality can be obtained.
【0040】本発明の食物繊維強化食品は、上述の食物
繊維強化用組成物を食品中に6〜45重量%含まれるよ
うに、それぞれの食品を製造する際に従来より使用され
ている原材料に該組成物を添加し、それぞれの食品の従
来からの製造法に従って製造して得られる。その添加方
法は特に限定されることはなく、その製造方法も特に限
定されることはない。その際、必ずしも予め混合した組
成物として添加する必要はなく、最終食品中に本発明の
組成物になる比率で含まれるように、低粘性の水溶性食
物繊維と澱粉類を別々に添加することもできる。食品中
に於ける該組成物の量が6〜45重量%を逸脱すると、
食品の品質に悪影響なく所望の食物繊維を含有せしめる
のが難しくなる。The dietary fiber-enriched food of the present invention is prepared by adding the above-mentioned composition for dietary fiber enrichment to the raw materials conventionally used in the production of each food so that the food contains 6 to 45% by weight. It is obtained by adding the composition and manufacturing according to the conventional manufacturing method of each food. The addition method is not particularly limited, and the production method is not particularly limited. At that time, it is not always necessary to add the composition as a pre-mixed composition, but a low-viscosity water-soluble dietary fiber and a starch are separately added so that the composition of the present invention is contained in the final food. Can also. When the amount of the composition in the food deviates from 6 to 45% by weight,
It becomes difficult to incorporate the desired dietary fiber without adversely affecting the quality of the food.
【0041】このように本発明の食物繊維強化用組成物
を用いると、容易に食物繊維強化食品を得ることができ
る。その作用機構は明白ではないが、次のように推考さ
れる。即ち、本発明が特に効果的に適用できる食品は小
麦粉、ソバ粉、コーンフラワーなど穀粉を主原料とする
食品、或は馬鈴薯粉を主原料とするスナック食品でも澱
粉の膨潤を抑制する乳化剤が添加されて含水率の低い状
態で加熱処理されるなど、主原料に含まれる澱粉の糊化
が急激には生じない食品である。一定置換度以上のヒド
ロキシプルピル澱粉は糊化開始温度がかなり低下して、
主原料の澱粉に比べ加熱処理の初期の段階、つまり低粘
性の水溶性食物繊維が溶出、或はマイグレイションが起
こる前に澱粉粒が吸水して膨潤する。その際、該食物繊
維も水と一緒に吸着して均一に保ち、食物繊維のみを添
加した時の弊害を改善するのではないかと思われる。い
ずれにしろ、得られた食物繊維強化食品は食物繊維が強
化され、しかもそれぞれの食品として優れた品質を有す
る。By using the dietary fiber-reinforced composition of the present invention, a dietary fiber-reinforced food can be easily obtained. The mechanism of action is not clear, but is presumed as follows. That is, foods to which the present invention can be particularly effectively applied include flour, buckwheat flour, foods mainly made of flour such as corn flour, or snack foods mainly made of potato flour added with an emulsifier that suppresses swelling of starch. It is a food product in which the starch contained in the main raw material does not rapidly gelatinize, for example, is subjected to heat treatment at a low water content. Hydroxypropyl starch having a certain degree of substitution or more has a considerably lower gelatinization start temperature,
Compared to the main raw material starch, the starch granules absorb water and swell at an early stage of the heat treatment, ie, before the low-viscosity water-soluble dietary fiber elutes or before migration occurs. At that time, it is considered that the dietary fiber is also adsorbed together with water to keep the dietary fiber uniform, and that the adverse effect when only dietary fiber is added may be improved. In any case, the obtained dietary fiber reinforced food is reinforced with dietary fiber and has excellent quality as each food.
【0042】尚、本発明に於ける食物繊維としては、低
粘性の水溶性食物繊維が有効で、水に不溶性の食物繊
維、水溶性であっても高粘性の食物繊維は本発明の効果
を奏さない。しかし、これらは従来よりそれぞれの食品
の物性改良や作業性改善などの目的で使用されていて、
例えば麺類にキサンタンガムやグアーガムを添加して麺
の腰を強くする、ケーキのバッター粘度をキサンタンガ
ムの添加で調節するなどであるが、この様な使用は本発
明でも適用できる。As the dietary fiber in the present invention, a low-viscosity water-soluble dietary fiber is effective, and a water-insoluble dietary fiber and a water-soluble, high-viscosity dietary fiber can exert the effects of the present invention. I don't play. However, these are conventionally used for the purpose of improving the physical properties and workability of each food,
For example, adding xanthan gum or guar gum to noodles to strengthen the stiffness of the noodles, or adjusting the batter viscosity of the cake by adding xanthan gum, and such use can be applied to the present invention.
【0043】また、食物繊維と併せてそれ以外の生理機
能付与や栄養強化が望まれる場合、それぞれの機能を有
する成分、例えば各種オリゴ糖、多価不飽和脂肪酸、ペ
プチド類、配糖体類、ビタミン類、ポリフェノール類、
ミネラルなどを所望により添加することもできる。When it is desired to provide other physiological functions or fortification in addition to dietary fiber, components having respective functions, such as various oligosaccharides, polyunsaturated fatty acids, peptides, glycosides, Vitamins, polyphenols,
Minerals and the like can be added as desired.
【0044】次に参考例、実施例を挙げ本発明を更に詳
細に説明する。尚、参考例及び実施例で部及び%とある
は、重量部及び重量%を表す。Next, the present invention will be described in further detail with reference to Reference Examples and Examples. In Examples and Reference Examples, parts and% mean parts by weight and% by weight.
【0045】[0045]
【参考例1】水120部に硫酸ソーダ30部を溶解し、
これに馬鈴薯澱粉100部を分散させたスラリーを4点
調製し、撹拌下それぞれに3%苛性ソーダ水溶液33部
とプロピレンオキサイドを夫々1.7部、3部、6部、
12部加えて42℃で22時間反応した後、塩酸で中和
し、水洗、乾燥して試料No.1〜4のヒドロキシプロ
ピル澱粉を得た。それぞれの置換度は0.035(試料
No1)、0.061(試料No.2)、0.115
(試料No.3)、0.195(試料No.4)であっ
た。[Reference Example 1] 30 parts of sodium sulfate was dissolved in 120 parts of water,
Four parts of a slurry in which 100 parts of potato starch was dispersed were prepared, and 33 parts of a 3% aqueous solution of caustic soda and 1.7 parts, 3 parts, and 6 parts of propylene oxide were respectively added under stirring.
After adding 12 parts and reacting at 42 ° C. for 22 hours, the mixture was neutralized with hydrochloric acid, washed with water and dried to obtain a sample no. 1 to 4 hydroxypropyl starches were obtained. The respective degrees of substitution were 0.035 (sample No. 1), 0.061 (sample No. 2), and 0.115.
(Sample No. 3) and 0.195 (Sample No. 4).
【0046】[0046]
【参考例2】参考例1に於て、馬鈴薯澱粉をサゴ澱粉に
替え、プロピレンオキサイドの添加量を7部とし、更に
トリメタリン酸ソーダを0.02%加えた他は同様にし
て試料No.5のリン酸架橋ヒドロキシプロピル澱粉を
得た。その置換度は0.123、膨潤度は32.6であ
った。REFERENCE EXAMPLE 2 Sample No. 1 was prepared in the same manner as in Reference Example 1 except that potato starch was changed to sago starch, the amount of propylene oxide added was changed to 7 parts, and sodium trimetaphosphate was further added at 0.02%. Thus, a phosphoric acid-crosslinked hydroxypropyl starch No. 5 was obtained. The degree of substitution was 0.123 and the degree of swelling was 32.6.
【0047】[0047]
【参考例3】水120部に馬鈴薯澱粉100部を加えて
スラリーとし、撹拌下3%苛性ソーダ水溶液を添加して
pH8−9.5に維持しながら、室温で無水酢酸5部を
徐々に加えて4時間反応後、塩酸で中和し、水洗、乾燥
して試料No.6のアセチル化澱粉を得た。そのアセチ
ル化度(置換度)は0.051であった。Reference Example 3 A slurry was prepared by adding 100 parts of potato starch to 120 parts of water, and 5 parts of acetic anhydride was gradually added at room temperature while maintaining a pH of 8 to 9.5 by adding a 3% aqueous sodium hydroxide solution with stirring. After reacting for 4 hours, the mixture was neutralized with hydrochloric acid, washed with water, dried and dried. Thus, acetylated starch No. 6 was obtained. The acetylation degree (degree of substitution) was 0.051.
【0048】[0048]
【参考例4】水120部に硫酸ソーダ10部を溶解し、
これにタピオカ澱粉100部を分散させたスラリーを3
点調製し、これらそれぞれを撹拌下3%苛性ソーダ水溶
液を加えてpH11.1〜11.3に維持しながら、ト
リメタリン酸ソーダを夫々1.3部、0.1部、0.0
3部を加えて40℃で12時間反応した後、塩酸で中和
し、水洗、乾燥して試料No.7〜9の膨潤抑制澱粉を
得た。それぞれの膨潤度は3.5(試料No.7)、1
2.0(試料No.8)、18.2(試料No.9)で
あった。[Reference Example 4] Dissolve 10 parts of sodium sulfate in 120 parts of water,
A slurry in which 100 parts of tapioca starch was dispersed was added to 3
While maintaining the pH at 11.1-11.3 by adding a 3% aqueous sodium hydroxide solution with stirring, 1.3 parts, 0.1 parts, and 0.0 parts of sodium trimetaphosphate were prepared, respectively.
After adding 3 parts and reacting at 40 ° C. for 12 hours, the mixture was neutralized with hydrochloric acid, washed with water, and dried. 7-9 swelling-suppressed starches were obtained. Each swelling degree was 3.5 (Sample No. 7), 1
2.0 (Sample No. 8) and 18.2 (Sample No. 9).
【0049】[0049]
【参考例5】参考例4に於て、トリメタリン酸ソーダに
替えてエピクロルヒドリンを用い、その添加量を3.5
部とし、反応時間を20時間とした他は同様にして試料
No.10の膨潤抑制澱粉を得た。その膨潤度は2.6
であった。Reference Example 5 In Reference Example 4, epichlorohydrin was used in place of sodium trimetaphosphate, and the amount of addition was 3.5.
And the reaction time was set to 20 hours. Thus, 10 swelling-suppressed starches were obtained. Its swelling degree is 2.6
Met.
【0050】[0050]
【参考例6】水120部に硫酸ソーダ20部を溶解し、
これに小麦澱粉100部を加えてスラリーとし、撹拌下
3%苛性ソーダ水溶液40部、トリメタリン酸ソーダ
0.2部、プロピレンオキサイド5部を加えて41℃で
20時間反応した後、塩酸で中和し、水洗、乾燥して試
料No.11のヒドロキシプロピル基を含む膨潤抑制澱
粉を得た。その膨潤度は8.1、ヒドロキシプロピル基
の置換度は0.092であった。Reference Example 6 20 parts of sodium sulfate was dissolved in 120 parts of water,
To this, 100 parts of wheat starch is added to form a slurry, and 40 parts of a 3% aqueous sodium hydroxide solution, 0.2 parts of sodium trimetaphosphate and 5 parts of propylene oxide are added with stirring, and the mixture is reacted at 41 ° C. for 20 hours, and then neutralized with hydrochloric acid. , Washed with water, dried and dried. A swelling-suppressed starch containing 11 hydroxypropyl groups was obtained. The degree of swelling was 8.1 and the degree of substitution of hydroxypropyl group was 0.092.
【0051】[0051]
【実施例1】低粘性の水溶性食物繊維として「ファイバ
ーソル#2」(松谷化学工業社、ソル#2と略称する)
を、澱粉類として試料No.3のヒドロキシプロピル澱
粉75部と試料No.8の膨潤抑制澱粉25部の混合物
(平均置換度0.086)を用い、これらを表1の比率
(%)で混合して食物繊維を含む組成物を得た。これら
を表1に示す添加量(%)で使用して即席麺を製造し
た。Example 1 "Fibersol # 2" as a low-viscosity water-soluble dietary fiber (abbreviated as Sol # 2, Matsutani Chemical Industry Co., Ltd.)
As starches in Sample No. No. 3 hydroxypropyl starch and 75 parts of sample no. Using a mixture (average degree of substitution: 0.086) of 25 parts of the swelling-suppressing starch of No. 8 and mixing them at the ratio (%) in Table 1, a composition containing dietary fiber was obtained. These were used in the amounts (%) shown in Table 1 to produce instant noodles.
【0052】即ち、麺用小麦粉(水を除く原材料を合わ
せて100部になる量)に表1のソル#2と澱粉類を加
えて混合し、食塩1.5部、かんすい0.2部、キサン
タンガム0.2部、クチナシ色素0.04部を含む水3
2部を加えて混練し、製麺ロールで麺厚1.2mmの麺
帯とし、回転切刃(#20角)を用いて麺線を切り出
し、これを飽和水蒸気で2分間蒸煮して型詰めし、15
0℃で90秒フライしてソル#2をそれぞれ3%添加し
た即席フライ麺を得た。また、対照区はソル#2と澱粉
類の替りに未処理の馬鈴薯澱粉を10%加えて同様に製
造した。得られた即席麺を3分間調理して外観、食感を
評価し、その結果を表1に示す。尚、優劣を理解し易く
する上から、対照区を基準に外観、食感を総合的に評価
し、総合評価として次のように表した。◎:対照区に比
べやや良ないし良 ○:対照区と同等 ×:対照区に比
べやや不良ないし不良。That is, sol # 2 and starches shown in Table 1 were added to flour for noodles (a total amount of 100 parts of raw materials excluding water) and mixed, and 1.5 parts of sodium chloride, 0.2 parts of kansui, Water 3 containing xanthan gum 0.2 parts, gardenia pigment 0.04 parts
Add 2 parts and knead, make a 1.2 mm noodle band with a noodle roll, cut out noodle strings using a rotary cutting blade (# 20 square), steamed with saturated steam for 2 minutes, and packed in a mold Then 15
Fry at 0 ° C. for 90 seconds to obtain instant fried noodles to which 3% each of Sol # 2 was added. The control group was prepared in the same manner except that 10% of untreated potato starch was added in place of Sol # 2 and starches. The resulting instant noodles were cooked for 3 minutes to evaluate the appearance and texture, and the results are shown in Table 1. In addition, in order to make it easier to understand the superiority and inferiority, the appearance and the texture were comprehensively evaluated based on the control group, and the overall evaluation was expressed as follows. :: Slightly good or good compared to control group ○: Equivalent to control group ×: Slightly poor or poor compared to control group
【0053】[0053]
【表1】 [Table 1]
【0054】[0054]
【実施例2】澱粉類として試料No.8の膨潤抑制澱
粉、表2に示す試料No.のヒドロキシプロピル澱粉
(表2ではHPSと表示、但しHPSの替りに用いたア
セチル化澱粉もこの欄に示す)及びその他澱粉を表2に
示す割合(%)で用い、これら澱粉類70%と低粘性の
水溶性食物繊維としての「ファイバーソル#2」30%
を混合して食物繊維を含む組成物を得た。実施例1に於
て、これらを17%添加した他は同様にして「ファイバ
ーソル#2」を5.1%添加した即席麺を製造した。得
られた即席麺を実施例1と同様に評価して総合評価とし
て表2に示す。尚、対照区は未処理の馬鈴薯澱粉17%
添加とした。また、その他澱粉には未処理の馬鈴薯澱粉
を用いた。Example 2 Sample Nos. Were used as starches. Swelling-suppressed starch of Sample No. 8 shown in Table 2 (In Table 2, HPS is indicated as HPS; however, acetylated starch used in place of HPS is also indicated in this column) and other starches are used in the ratio (%) shown in Table 2, and these starches are as low as 70%. "Fibersol # 2" as viscous water-soluble dietary fiber 30%
Was mixed to obtain a composition containing dietary fiber. Instant noodles containing 5.1% of "Fibersol # 2" were prepared in the same manner as in Example 1, except that 17% of these were added. The instant noodles obtained were evaluated in the same manner as in Example 1 and shown in Table 2 as a comprehensive evaluation. The control was 17% untreated potato starch.
It was added. Untreated potato starch was used for other starches.
【0055】[0055]
【表2】 [Table 2]
【0056】[0056]
【実施例3】実施例2に於て、表3に示す試料No.の
膨潤抑制澱粉を20部と試料No.3のヒドロキシプロ
ピル澱粉80部(平均置換度0.092、但し試料N
o.11の場合は0.110)を澱粉類として用いた他
は実施例2と同様にして食物繊維を含む組成物を得、こ
れを同様に用いて即席麺を製造し、評価した結果を総合
評価として表3に示す。尚、未処理澱粉の中では膨潤し
難い澱粉であるコーンスターチとハイアミロースコーン
スターチ(アミロース含量約90%、表3ではハイアミ
と表示)も膨潤抑制澱粉として併せて評価した。Example 3 In Example 2, the sample No. shown in Table 3 was used. Of swelling-inhibiting starch of Sample No. 80 parts of hydroxypropyl starch (average degree of substitution: 0.092;
o. In the case of 11, a composition containing dietary fiber was obtained in the same manner as in Example 2 except that 0.110) was used as the starch, and instant noodles were produced using the same in the same manner. As shown in Table 3. Among the untreated starches, corn starch and high amylose corn starch (amylose content of about 90%, indicated as hiami in Table 3), which are hardly swellable starches, were also evaluated as swelling-inhibiting starches.
【0057】[0057]
【表3】 [Table 3]
【0058】[0058]
【実施例4】低粘性の水溶性食物繊維として表5に示す
各種を40%、澱粉類として試料No.5のヒドロキシ
プロピル澱粉50部と試料No.11の膨潤抑制澱粉5
0部の混合物(平均置換度0.109)を60%の組成
物を調製した。これらを用いて表4の処方で常法に従っ
てドウを調製し、成形、焼成してクッキーを製造した。
得られたクッキーの品質を対照区を基準に評価し、その
結果を表5に示す。EXAMPLE 4 40% of various low-viscosity water-soluble dietary fibers shown in Table 5 were used as sample materials, and starch was used as sample No. 5 as a starch. 5 and 50 parts of hydroxypropyl starch. Swelling-suppressed starch 11
A 60% composition was prepared with 0 parts of the mixture (average degree of substitution 0.109). Using these, dough was prepared according to a conventional method according to the formulation shown in Table 4, and molded and baked to produce a cookie.
The quality of the obtained cookies was evaluated based on the control group, and the results are shown in Table 5.
【0059】[0059]
【表4】クッキーの処方 [Table 4] Cookie prescription
【0060】[0060]
【表5】 (注)・1太陽化学社製、・2ファイザー社製、・3日本食品
化学社製[Table 5] (Note) ・ 1 Taiyo Chemical Co., Ltd. ・ 2 Pfizer Co., Ltd. ・ 3 Nippon Shokubai Chemical Co., Ltd.
【0061】[0061]
【実施例5】低粘性の水溶性食物繊維として「ファイバ
ーソル#2」を40%、澱粉類として試料No.3のヒ
ドロキシプロピル澱粉60部,試料No.8の膨潤抑制
澱粉20部及びその他澱粉として試料No.6のアセチ
ル化澱粉14部、市販のα−化澱粉「マツノリンM」
(松谷化学工業株式会社製)6部の混合物(ヒドロキシ
プロピル基の平均置換度0.069)60%からなる食
物繊維強化用組成物を調製した。小麦粉70部に、この
組成物30部を加えて混合し、これに食塩2部を含む食
塩水37部を添加混練し、以下常法に従って製麺ロール
及び回転切刃(No.10)を用いて生うどんを得た。
この生うどんを熱湯中で水分70%になるまで茹て茹う
どんを製造した。得られた茹うどん中の食物繊維を高速
液体クロマトグラフ法(衛新41号、平成8年5月厚生
省告示)で測定すると共に対照区と比較して食感を評価
した。尚、「ファイバーソル#2」の食物繊維含量は8
0%(水分4%、絶乾物換算繊維含量83.3%)で、
小麦粉の水分を勘案した茹でうどん中の食物繊維の理論
添加量は実施例3.22%、比較例3.20%である。
また、対照区は小麦粉100部で、比較例は小麦粉部8
8部と「ファイバーソル#2」12部で同様に茹うどん
を製造した。Example 5 "Fibersol # 2" was 40% as a low-viscosity water-soluble dietary fiber, and sample No. 1 was used as starch. No. 3 hydroxypropyl starch, 60 parts, sample no. Sample No. 8 as 20 parts of the swelling-suppressed starch of Sample No. 8 and other starches. 14 acetylated starch, commercially available α-modified starch “Matsunoline M”
A dietary fiber reinforcing composition comprising 60% of a mixture (average degree of hydroxypropyl group 0.069) of 6 parts (manufactured by Matsutani Chemical Industry Co., Ltd.) was prepared. To 70 parts of flour, 30 parts of this composition is added and mixed, and 37 parts of a saline solution containing 2 parts of sodium chloride is added and kneaded, and then using a noodle roll and a rotary cutting blade (No. 10) according to a conventional method. I got raw udon.
This raw udon was boiled in boiling water until the water content became 70% to produce a boiled noodle. The dietary fiber in the obtained boiled noodles was measured by high performance liquid chromatography (Eshin 41, notified by the Ministry of Health and Welfare in May 1996) and the texture was evaluated in comparison with the control. The fiber content of “Fibersol # 2” is 8
0% (moisture 4%, absolute dry matter fiber content 83.3%)
The theoretical amount of dietary fiber in the boiled udon in consideration of the water content of the flour is Example 3.22% and Comparative Example 3.20%.
The control group was 100 parts of flour, and the comparative example was 8 parts of flour.
8 parts and 12 parts of “Fibersol # 2” were prepared in the same manner as in the above.
【0062】[0062]
【表6】 [Table 6]
【0063】[0063]
【実施例6】低粘性の水溶性食物繊維として「ファイバ
ーソル#2」を35%、澱粉類として試料No.3のヒ
ドロキシプロピル澱粉70部と試料No.11の膨潤抑
制澱粉15部及び試料No.11をドラムドライヤーで
処理してα−化したもの15部の混合物(ヒドロキシプ
ロピル基の平均置換度0.108)65%からなる食物
繊維強化用組成物を調製した。この組成物を用いて下記
処方で、捏上温度26℃で捏混し、発酵時間を120分
とった後、50gに分割し、更にベンチタイムを10分
とり、モルダーを通して成形し、ホイロを38℃、50
分とった後、190℃で13分焼成して本発明の組成物
を約10%含有する食物繊維強化バターロールを製造し
た。得られ本発明のバターロールは、該組成物を添加せ
ずに小麦粉100部で製造した対照区と比較して、ボリ
ュウム、色調は同等で、食感はソフトで好ましい評価を
得た。Example 6 "Fibersol # 2" was 35% as a low-viscosity water-soluble dietary fiber, and sample No. 1 was used as starch. No. 3 hydroxypropyl starch and Sample No. 3 No. 11 and 15 parts of the swelling-suppressed starch of Sample No. 11; Dietary fiber No. 11 was treated with a drum dryer to form an α-protein, and a dietary fiber reinforcing composition consisting of 65% of a mixture (average degree of substitution of hydroxypropyl group: 0.108) of 65 parts was prepared. This composition was kneaded with the following formulation at a kneading temperature of 26 ° C., the fermentation time was 120 minutes, the mixture was divided into 50 g, the bench time was 10 minutes, and the mixture was molded through a moulder. ° C, 50
Then, the mixture was baked at 190 ° C. for 13 minutes to produce a dietary fiber reinforced butter roll containing about 10% of the composition of the present invention. The obtained butter roll of the present invention had the same volume and color tone as the control group prepared with 100 parts of flour without adding the composition, and had a favorable evaluation with a soft texture.
【0064】配合割合(部) 小麦粉 80 食物繊維強化用組成物 20 イースト 3 イーストフード 0.1 マーガリン 15 食塩 1.8 脂肪酸モノグリセライド 0.3 砂糖 12 脱脂粉乳 2 全卵 15 水 50Mixing ratio (parts) Flour 80 Dietary fiber reinforcing composition 20 Yeast 3 Yeast food 0.1 Margarine 15 Salt 1.8 Fatty acid monoglyceride 0.3 Sugar 12 Skim milk powder 2 Whole egg 15 Water 50
【0065】[0065]
【実施例7】低粘性の水溶性食物繊維として「ファイバ
ーソル#2」を30%、澱粉類として試料No.5のヒ
ドロキシプロピル澱粉60部と試料No.8の膨潤抑制
澱粉20部及びワキシーコーンスターチ20部の混合物
(ヒドロキシプロピル基の平均置換度0.074)70
%からなる食物繊維強化用組成物を調製した。Example 7 "Fibersol # 2" was 30% as a low-viscosity water-soluble dietary fiber, and sample No. 1 was used as starch. 5 and 60 parts of hydroxypropyl starch. Mixture of 20 parts of swelling-suppressed starch of Example 8 and 20 parts of waxy corn starch (average degree of hydroxypropyl group substitution: 0.074) 70
% Of a dietary fiber reinforcing composition was prepared.
【0066】この組成物30部をコーンフラワー220
部に加えて混合し、砂糖10部、食塩2部及び重曹1.
2部を含む水130部を加えて均一に混合する。これを
蒸煮後、圧延(1.0mm)、成型し、190℃で30
秒フライしてコーンチップを得た。対照区は澱粉類を使
用せずにコーンフラワーを250部使用し、比較例はコ
ーンフラワー241部と「ファイバーソル#2」9部を
使用して同様にコーンチップを製造した。得られたコー
ンチップを対照区を基準にして評価した。実施例は対照
区に較べて硬さは同等も、サクサク感ではやや優れてい
たのに対し、比較例は硬さが強くてサクサク感に欠け、
口溶けの点でも劣っていた。30 parts of this composition was mixed with cornflower 220
And 10 parts of sugar, 2 parts of salt and 1.
Add 130 parts of water containing 2 parts and mix uniformly. This is steamed, rolled (1.0 mm), molded, and dried at 190 ° C. for 30 minutes.
Fry for a second to obtain corn chips. The control group used 250 parts of corn flour without using starches, and the comparative example similarly manufactured corn chips using 241 parts of corn flour and 9 parts of “Fibersol # 2”. The obtained corn chips were evaluated based on the control. The examples were equivalent in hardness as compared to the control group, but slightly better in crispness, whereas the comparative examples were strong in hardness and lacked crispness,
It was also inferior in melting the mouth.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI A23L 1/18 A23L 1/18 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI A23L 1/18 A23L 1/18
Claims (8)
と、ヒドロキシプロピル基の平均置換度が0.02〜
0.2である澱粉類50〜93重量%からなることを特
徴とする食物繊維強化用組成物。1. A low-viscosity, water-soluble dietary fiber of 7 to 50% by weight.
And the average degree of substitution of the hydroxypropyl group is 0.02 to
A dietary fiber reinforcing composition comprising 50 to 93% by weight of starch having a ratio of 0.2.
粉10〜60重量%、置換度が0.05〜0.22のヒ
ドロキシプロピル澱粉40〜90重量%、その他澱粉0
〜50重量%からなる請求項1に記載の食物繊維強化用
組成物。2. A starch having a swelling degree of 3 to 15, 10 to 60% by weight of a swelling-inhibiting starch, 40 to 90% by weight of a hydroxypropyl starch having a substitution degree of 0.05 to 0.22, and other starches.
The composition for reinforcing a dietary fiber according to claim 1, which comprises about 50% by weight.
トリンである請求項1に記載の食物繊維強化用組成物。3. The composition for reinforcing a dietary fiber according to claim 1, wherein the low-viscosity water-soluble dietary fiber is an indigestible dextrin.
と、ヒドロキシプロピル基の平均置換度が0.02〜
0.2である澱粉類50〜93重量%からなる食物繊維
強化用組成物が、食品中に6〜45重量%含有されて成
ることを特徴とする食物繊維強化食品。4. A low-viscosity, water-soluble dietary fiber of 7 to 50% by weight.
And the average degree of substitution of the hydroxypropyl group is 0.02 to
A dietary fiber-enriched food, characterized in that the dietary fiber-enriched composition consisting of 50 to 93% by weight of starch, which is 0.2, is contained in the food in an amount of 6 to 45% by weight.
粉10〜60重量%、置換度が0.05〜0.22のヒ
ドロキシプロピル澱粉40〜90重量%、その他澱粉0
〜50重量%からなる請求項4に記載の食物繊維強化食
品。5. A swelling-inhibiting starch wherein the starch has a swelling degree of 3 to 15; 10 to 60% by weight; a hydroxypropyl starch having a substitution degree of 0.05 to 0.22; 40 to 90% by weight;
The dietary fiber-enriched food according to claim 4, which comprises about 50% by weight.
トリンである請求項4に記載の食物繊維強化食品。6. The dietary fiber-enriched food according to claim 4, wherein the low-viscosity water-soluble dietary fiber is an indigestible dextrin.
繊維強化食品。7. The dietary fiber-enriched food according to claim 4, wherein the food is noodles.
種である請求項4に記載の食物繊維強化食品。8. The dietary fiber-enriched food according to claim 4, wherein the food is one of a bakery food and a snack food.
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JP06731797A JP3918078B2 (en) | 1997-03-04 | 1997-03-04 | Dietary fiber-reinforced composition and dietary fiber-reinforced food using the same |
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