JPH10237751A - Hot-melt nonwoven fabric and its production - Google Patents
Hot-melt nonwoven fabric and its productionInfo
- Publication number
- JPH10237751A JPH10237751A JP5095897A JP5095897A JPH10237751A JP H10237751 A JPH10237751 A JP H10237751A JP 5095897 A JP5095897 A JP 5095897A JP 5095897 A JP5095897 A JP 5095897A JP H10237751 A JPH10237751 A JP H10237751A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- heat
- nonwoven fabric
- fibers
- conjugate fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Multicomponent Fibers (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、潜在捲縮性複合繊
維を熱接着性繊維として使用した熱接着不織布に関する
ものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat-bondable nonwoven fabric using a latently crimpable conjugate fiber as a heat-bondable fiber.
【0002】[0002]
【従来の技術】一般に、おむつの部材やウェットティッ
シュ、ワイパー等には触感の良さと、ある程度の強力が
求められる。そのため、それらに用いられる不織布は、
レーヨン等の親水性繊維と、芯/鞘がポリエステル/ポ
リエチレン、ポリプロピレン/ポリエチレンの芯鞘型の
熱接着性複合繊維とからなる熱接着不織布であることが
多い。この不織布では、レーヨン等が不織布の触感を向
上させ、熱接着性複合繊維が不織布に強力を付与してい
る。そこで、熱接着不織布を製造する際には、柔軟性、
触感と強力を考慮して構成繊維の混合割合を決定する必
要がある。2. Description of the Related Art Generally, diaper members, wet tissues, wipers, and the like are required to have a good tactile sensation and a certain strength. Therefore, the nonwoven fabric used for them is
It is often a heat-bonded nonwoven fabric composed of a hydrophilic fiber such as rayon and a core-sheath type heat-bondable conjugate fiber of a core / sheath of polyester / polyethylene or polypropylene / polyethylene. In this nonwoven fabric, rayon or the like improves the feel of the nonwoven fabric, and the heat-adhesive conjugate fiber imparts strength to the nonwoven fabric. Therefore, when manufacturing a heat-bonded nonwoven fabric, flexibility,
It is necessary to determine the mixing ratio of the constituent fibers in consideration of the feel and strength.
【0003】[0003]
【発明が解決しようとする課題】しかし、混合割合を調
整するだけでは所望の不織布を得られない場合がある。
例えば、触感を重視して、熱接着性繊維の割合を小さく
すると、接着点の数もその分小さくなるため毛羽抜けが
生じやすくなる。また、熱接着性繊維の占める割合が小
さいと、不織布をヒートシール加工したときに十分なヒ
ートシール強力が得られないこともある。これらの場合
には熱接着性繊維の混合割合をある程度大きくしなけれ
ばならない。However, there is a case where a desired nonwoven fabric cannot be obtained only by adjusting the mixing ratio.
For example, if the ratio of the heat-adhesive fibers is reduced with emphasis on the tactile sensation, the number of bonding points is also reduced by that amount, so that fluff is likely to occur. If the proportion of the heat-adhesive fibers is small, sufficient heat sealing strength may not be obtained when the non-woven fabric is heat-sealed. In these cases, the mixing ratio of the heat-adhesive fibers must be increased to some extent.
【0004】また、上述した芯鞘型の熱接着性複合繊維
は、いずれも少量混合しただけで不織布の触感を低下さ
せるものである。[0004] In addition, the core-sheath type heat-adhesive conjugate fibers mentioned above can reduce the tactile sensation of the nonwoven fabric only by mixing a small amount.
【0005】本発明はかかる実情に鑑みてなされたもの
であり、熱接着性繊維の混合割合を大きくした場合でも
優れた柔軟性や触感を示す不織布を得ることを目的とす
るものである。The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a nonwoven fabric which exhibits excellent flexibility and touch even when the mixing ratio of the heat-adhesive fibers is increased.
【0006】[0006]
【課題を解決するための手段】本発明の熱接着不織布
は、立体捲縮が発現した潜在捲縮性複合繊維20〜50
重量%と、非熱接着性繊維80〜50重量%とからな
り、繊維同士が交絡してなる不織布であって、潜在捲縮
性複合繊維の低融点成分により繊維同士が熱接着されて
いることを特徴とする。熱接着性繊維として潜在捲縮性
複合繊維を使用することで、その混合割合を大きくした
場合でも柔軟性および触感に優れた不織布が得られる。
また繊維同士を交絡させることにより、強力の向上を図
っている。Means for Solving the Problems The heat-bonded nonwoven fabric of the present invention has a latent crimpable conjugate fiber 20 to 50 having a three-dimensional crimp.
A non-woven fabric consisting of 80% to 50% by weight of non-heat-adhesive fibers and being entangled with each other, wherein the fibers are heat-bonded by the low melting point component of the latently crimpable conjugate fiber. It is characterized by. By using a latently crimpable conjugate fiber as the heat bonding fiber, a nonwoven fabric excellent in flexibility and touch can be obtained even when the mixing ratio is increased.
In addition, the fibers are entangled to improve the strength.
【0007】この熱接着不織布は、上記繊維から構成さ
れる繊維ウェブに機械的交絡処理が施されて繊維同士が
交絡された後、繊維ウェブの面積収縮率が10%以下と
なるように熱処理が施されることにより、潜在捲縮性複
合繊維に立体捲縮が発現し、かつ低融点成分により繊維
同士が熱接着した不織布であることが望ましい。一般に
潜在捲縮性複合繊維を使用すると熱処理後の繊維ウェブ
の面積収縮率は大きくなるが、面積収縮率を低く抑える
ことで、低目付で均一な不織布を得ることができる。The heat-bonded non-woven fabric is subjected to a mechanical entanglement treatment on the fiber web composed of the above-mentioned fibers, whereby the fibers are entangled with each other, and then heat-treated so that the area shrinkage of the fiber web becomes 10% or less. It is desirable that the latent crimpable conjugate fiber be formed into a non-woven fabric in which a three-dimensional crimp is developed and the fibers are thermally bonded to each other by a low melting point component. In general, when a latently crimpable conjugate fiber is used, the area shrinkage of the fibrous web after the heat treatment becomes large, but by reducing the area shrinkage, a uniform nonwoven fabric with a low basis weight can be obtained.
【0008】前記熱接着不織布においては、潜在捲縮性
複合繊維が、自由な状態でTm −15≦T<Tm (Tm
は潜在捲縮性複合繊維の低融点成分の融点)の熱処理温
度(T℃)で加熱されたときに30個/インチ以上の立
体捲縮を発現する性質を有するものであることが望まし
い。捲縮の発現の程度が小さいと本発明が目的とする効
果が得られない。In the above-mentioned heat-bonded nonwoven fabric, the latently crimpable conjugate fiber is free from Tm−15 ≦ T <Tm (Tm
Is desirably a material which has a property of exhibiting a three-dimensional crimp of 30 pieces / inch or more when heated at a heat treatment temperature (T ° C.) of the low melting point component of the latently crimpable conjugate fiber. If the degree of crimping is small, the effect intended by the present invention cannot be obtained.
【0009】前記潜在捲縮性複合繊維は、エチレン−プ
ロピレン共重合体を第一成分、ポリプロピレンを第二成
分とし、第一成分を鞘成分、第二成分を芯成分とする偏
心型の芯鞘型複合繊維、もしくは両成分がサイドバイサ
イド型に接合された複合繊維であることが望ましい。こ
の繊維は高い捲縮能を有する。また、比較的低い温度で
熱処理することが可能である。The latently crimpable conjugate fiber is an eccentric core-sheath having an ethylene-propylene copolymer as a first component, polypropylene as a second component, a first component as a sheath component, and a second component as a core component. It is desirable that the composite fiber be a type composite fiber or a composite fiber in which both components are joined in a side-by-side type. This fiber has a high crimpability. Further, heat treatment can be performed at a relatively low temperature.
【0010】前記熱接着不織布においては、非熱接着性
繊維がレーヨン繊維であることが望ましい。レーヨン繊
維は不織布に優れた柔軟性と触感を付与する。[0010] In the heat-bonded nonwoven fabric, the non-heat-bondable fiber is desirably rayon fiber. Rayon fibers impart excellent flexibility and feel to the nonwoven.
【0011】前記熱接着不織布の好ましい製造方法は、
潜在捲縮性複合繊維20〜50重量%と、非熱接着性繊
維80〜50重量%とからなる繊維ウェブに高圧水流処
理を施して繊維同士を交絡させた後、潜在捲縮性複合繊
維の低融点成分が軟化する温度よりも高く、潜在捲縮性
複合繊維のその他の成分の融点よりも低い温度で、繊維
ウェブの熱収縮率が10%以下となるように熱処理を施
し、潜在捲縮性複合繊維に立体捲縮を発現させると同時
に低融点成分により繊維同士を熱接着させる方法であ
る。繊維ウェブの熱収縮率が10%以下となるように熱
処理を施すことで低目付で均一な不織布を得ることが可
能となり、工程管理も容易となる。以下、本発明の内容
を説明する。A preferred method for producing the heat-bonded nonwoven fabric is as follows:
After subjecting the fibrous web composed of the latently crimpable conjugate fiber 20 to 50% by weight and the non-heat-adhesive fiber 80 to 50% by weight to high-pressure water flow treatment to entangle the fibers, the latently crimpable conjugate fiber A heat treatment is performed at a temperature higher than the temperature at which the low melting point component softens and lower than the melting point of the other components of the latently crimpable conjugate fiber so that the heat shrinkage of the fiber web becomes 10% or less. This is a method in which a three-dimensional crimp is developed in the conductive conjugate fiber and the fibers are thermally bonded together with a low melting point component. By performing a heat treatment so that the thermal shrinkage of the fiber web is 10% or less, a uniform nonwoven fabric with a low basis weight can be obtained, and the process control becomes easy. Hereinafter, the contents of the present invention will be described.
【0012】[0012]
【発明の実施の形態】本発明で使用する潜在捲縮性複合
繊維とは、二以上の異なる成分からなり、繊維ウェブあ
るいは不織布にした状態で熱処理を施すと立体捲縮が発
現する繊維をいう。ここで、「立体捲縮」とは、図1〜
図3に示すように、螺旋状の捲縮のみならず、緩やかな
カーブを描いて二次元方向に屈曲しているもの、あるい
は二次元的な屈曲に三次元的な曲部が加わったもの等を
含む意であり、クリンパー等で付与される機械捲縮と区
別するために使用される語である。BEST MODE FOR CARRYING OUT THE INVENTION The latently crimpable conjugate fiber used in the present invention is a fiber composed of two or more different components and which develops a three-dimensional crimp when heat-treated in the state of a fibrous web or nonwoven fabric. . Here, the “three-dimensional crimp” refers to FIGS.
As shown in FIG. 3, not only a spiral crimp but also a two-dimensional bend with a gentle curve, or a three-dimensional bend with a two-dimensional bend And is a word used to distinguish it from a mechanical crimp given by a crimper or the like.
【0013】この潜在捲縮性複合繊維は、自由な状態で
Tm −15≦T<Tm (Tm は潜在捲縮性複合繊維の低
融点成分の融点)の熱処理温度(T℃)で加熱されたと
きに30個/インチ以上の立体捲縮を発現する性質を有
するものであることが望ましい。より好ましい潜在捲縮
性複合繊維は、30〜60個/インチの立体捲縮を発現
するものである。ここで「自由な状態で加熱する」と
は、繊維ウェブ等にした状態ではなく、繊維が束縛され
ていない状態で加熱することを意味し、Tm は繊維化す
る前の低融点成分樹脂の融点を指す。融点は、示差走査
熱量計(DSC)を用いて測定した融解ピーク温度であ
らわす。捲縮能が小さい繊維では通常の熱接着性繊維を
使用する場合と変わりなく、本発明の目的が達成されな
い。The latently crimpable conjugate fiber was heated in a free state at a heat treatment temperature (T ° C.) of Tm−15 ≦ T <Tm (Tm is the melting point of the low melting point component of the latently crimpable conjugate fiber). Sometimes it is desirable to have a property of expressing a three-dimensional crimp of 30 pieces / inch or more. A more preferable latent crimpable conjugate fiber is one that exhibits a three-dimensional crimp of 30 to 60 pieces / inch. Here, "heating in a free state" means heating in a state in which the fibers are not restrained, not in a state in which the fiber web is formed, and Tm is a melting point of the low melting point resin before fiberization. Point to. The melting point is represented by a melting peak temperature measured using a differential scanning calorimeter (DSC). A fiber having a small crimp ability is no different from the case of using a normal heat-adhesive fiber, and the object of the present invention cannot be achieved.
【0014】潜在捲縮性複合繊維は、不織布に伸縮性を
付与する目的で使用されることが多く、様々な種類のも
のが既に知られている。本発明では従来より知られてい
る潜在捲縮性複合繊維を任意に使用することができる。
但し本発明において潜在捲縮性複合繊維は熱接着性繊維
として作用するものであるから、繊維を構成する少なく
とも一成分が熱によって軟化あるいは溶融し、繊維同士
を接着させ得るものでなければならない。[0014] Latent crimpable conjugate fibers are often used for imparting elasticity to a nonwoven fabric, and various types are already known. In the present invention, a conventionally known latently crimpable conjugate fiber can be arbitrarily used.
However, in the present invention, since the latently crimpable conjugate fiber functions as a heat-adhesive fiber, at least one component constituting the fiber must be softened or melted by heat to bond the fibers.
【0015】そこで、本発明で使用する潜在捲縮性複合
繊維は、高融点成分である第一成分と、低融点成分であ
る第二成分とからなり、第一成分を芯成分、第二成分を
鞘成分とする偏心型の芯鞘型複合繊維、もしくは両成分
がサイドバイサイド型に接合された複合繊維であること
が望ましい。Therefore, the latently crimpable conjugate fiber used in the present invention comprises a first component which is a high melting point component and a second component which is a low melting point component, wherein the first component is a core component and the second component is a second component. It is preferable that the core-sheath composite fiber having an eccentric core and a composite fiber in which both components are joined in a side-by-side configuration.
【0016】第一成分と第二成分の組み合わせとして
は、エチレン−プロピレン共重合体/ポリプロピレン、
エチレン−ブテン-1−プロピレン三元共重合体/ポリプ
ロピレン、高密度ポリエチレン/ポリエチレンテレフタ
レート、高密度ポリエチレン/ポリブチレンテレフタレ
ート、ポリエチレンテレフタレート/変性ポリエステ
ル、ポリプロピレン/ポリエチレン、ポリオレフィン/
ポリアミド等を挙げることができる。As the combination of the first component and the second component, ethylene-propylene copolymer / polypropylene,
Ethylene-butene-1-propylene terpolymer / polypropylene, high density polyethylene / polyethylene terephthalate, high density polyethylene / polybutylene terephthalate, polyethylene terephthalate / modified polyester, polypropylene / polyethylene, polyolefin /
Polyamide and the like can be mentioned.
【0017】特に、エチレン−プロピレン共重合体/ポ
リプロピレン、もしくはエチレン−ブテン-1−プロピレ
ン三元共重合体/ポリプロピレンの組み合わせからなる
潜在捲縮性複合繊維は、比較的低い温度(130℃〜1
45℃)で熱接着させることが可能であり、また高い捲
縮能を有するため、好ましく使用される。In particular, the latently crimpable conjugate fiber composed of a combination of ethylene-propylene copolymer / polypropylene or ethylene-butene-1-propylene terpolymer / polypropylene has a relatively low temperature (130 ° C. to 1 ° C.).
(45 ° C.), and is preferably used because it has high crimpability.
【0018】潜在捲縮性複合繊維が不織布中に占める割
合は20重量%以上、50重量%以下であることが望ま
しい。20重量%未満では不織布強力が小さくなる。5
0重量%を超えると不織布の柔軟性、触感が低下するば
かりでなく、立体捲縮の発現に起因する熱処理後の不織
布の面積収縮率が大きくなる。The ratio of the latently crimpable conjugate fiber to the nonwoven fabric is desirably 20% by weight or more and 50% by weight or less. If the amount is less than 20% by weight, the strength of the nonwoven fabric is reduced. 5
If the content exceeds 0% by weight, not only the flexibility and touch feeling of the nonwoven fabric are reduced, but also the area shrinkage of the nonwoven fabric after the heat treatment due to the development of three-dimensional crimp becomes large.
【0019】本発明の不織布は潜在捲縮性複合繊維と非
熱接着性繊維とからなる。ここで非熱接着性繊維とは、
後述する熱処理を施したときに実質的に軟化あるいは溶
融せず、熱接着性を示さない繊維をいい、本発明では不
織布の触感や吸水性を向上させるために使用する。この
条件を満たす限りその素材等は特に限定されず、レーヨ
ン等の再生繊維、綿、羊毛等の天然繊維、アセテート等
の半合成繊維、ナイロン6、ナイロン66等のポリアミ
ド系繊維、ポリエチレンテレフタレート、ポリブチレン
テレフタレート等のポリエステル系繊維、ポリエチレ
ン、ポリプロピレン等のポリオレフィン系繊維等の中か
ら任意に一あるいは二以上選択して使用するとよい。The nonwoven fabric of the present invention comprises a latently crimpable conjugate fiber and a non-heat-adhesive fiber. Here, the non-heat-bonding fiber is
A fiber that does not substantially soften or melt when subjected to the heat treatment described below and does not exhibit thermal adhesion. In the present invention, it is used to improve the feel and water absorption of the nonwoven fabric. The material is not particularly limited as long as this condition is satisfied. Regenerated fibers such as rayon, natural fibers such as cotton and wool, semi-synthetic fibers such as acetate, polyamide fibers such as nylon 6, nylon 66, polyethylene terephthalate, and poly One or more selected from polyester fibers such as butylene terephthalate and polyolefin fibers such as polyethylene and polypropylene may be used.
【0020】中でもレーヨン繊維は不織布の触感を良好
にするので、不織布の用途がおむつのトップシート等、
人体に触れるものである場合に好ましく用いられる。ま
た、レーヨン繊維を含む不織布をおむつのバックシート
(最外層)に用いれば、母親や介護者に対して触り心地
のよいおむつを提供することができる。レーヨン繊維や
綿等の親水性繊維を使用すれば不織布に吸水性が付与さ
れるので、ウェットティッシュやワイパーに適した不織
布を得ることができる。Among them, rayon fiber improves the feel of the nonwoven fabric.
It is preferably used when it touches the human body. Further, if a nonwoven fabric containing rayon fibers is used for the backsheet (outermost layer) of the diaper, a diaper that is comfortable to the mother and caregiver can be provided. If hydrophilic fibers such as rayon fibers and cotton are used, water absorption is imparted to the nonwoven fabric, so that a nonwoven fabric suitable for wet tissues and wipers can be obtained.
【0021】また、前述のエチレン−プロピレン共重合
体/ポリプロピレンの組み合わせからなる潜在捲縮性複
合繊維とレーヨン繊維とから構成した不織布は、それら
を互いにヒートシールさせると高いヒートシール強力を
示す。その理由は定かでないが、何らかの要因により両
繊維が特に加熱加圧下において接着しやすくなっている
ものと考えられる。The nonwoven fabric composed of the latent crimpable conjugate fiber composed of the above-described ethylene-propylene copolymer / polypropylene combination and rayon fiber exhibits high heat sealing strength when they are heat-sealed to each other. Although the reason is not clear, it is considered that both fibers are likely to adhere to each other particularly under heat and pressure for some reason.
【0022】非熱接着性繊維が不織布に占める割合は、
50重量%以上、80重量%以下が望ましい。50重量
%未満では不織布の柔軟性、触感が低下し、80重量%
を超えると不織布強力が小さくなる。The ratio of the non-thermo-bonding fiber to the nonwoven fabric is as follows:
It is desirable that the content be 50% by weight or more and 80% by weight or less. If the content is less than 50% by weight, the softness and feel of the nonwoven fabric are reduced, and the content is 80% by weight.
If it exceeds, the strength of the nonwoven fabric is reduced.
【0023】以上説明した潜在捲縮性複合繊維および非
熱接着性繊維とも、その繊度及び繊維長は最終的に得よ
うとする不織布に応じて任意に選択することができる。
後述するように繊維同士を高圧水流処理によって交絡さ
せる場合には、繊度を1〜6デニール、繊維長を38〜
64mmとすることが望ましい。The fineness and fiber length of both the latently crimpable conjugate fiber and the non-heat-bondable fiber described above can be arbitrarily selected according to the finally obtained nonwoven fabric.
When the fibers are entangled by the high-pressure water flow treatment as described below, the fineness is 1 to 6 denier and the fiber length is 38 to
Desirably, it is 64 mm.
【0024】次に本発明の不織布の構造を不織布の製造
方法とともに説明する。本発明の不織布は構成繊維同士
が交絡してなるものであるが、繊維同士を交絡させる前
に、使用する繊維を混合して予め繊維ウェブの状態にし
ておく必要がある。ウェブの態様は特に限定されず、パ
ラレルウェブ、クロスウェブ、セミランダムウェブ、ラ
ンダムウェブ等いずれであってもよい。また、ウェブの
目付は最終的に得ようとする不織布の用途等に応じて決
定することができる。例えば、本発明の不織布をおむつ
のバックシートやウェットティッシュ、ワイパーとして
用いる場合は、20〜50g/m2 にすることが望まし
い。Next, the structure of the nonwoven fabric of the present invention will be described together with the method for producing the nonwoven fabric. Although the nonwoven fabric of the present invention is formed by entanglement of the constituent fibers, it is necessary to mix fibers to be used and to form a fibrous web in advance before entanglement of the fibers. The form of the web is not particularly limited, and may be any of a parallel web, a cross web, a semi-random web, a random web, and the like. The basis weight of the web can be determined according to the use of the nonwoven fabric to be finally obtained. For example, when the nonwoven fabric of the present invention is used as a diaper backsheet, a wet tissue, or a wiper, it is preferable that the nonwoven fabric be 20 to 50 g / m 2 .
【0025】繊維同士はニードルパンチや高圧水流処理
によって交絡させることができる。本発明では、高圧水
流処理を採用することが望ましい。高圧水流処理によれ
ば、柔軟で触感の良い不織布を得ることができる。また
高圧水流処理は低目付の繊維ウェブを処理するのに適し
ている。The fibers can be entangled by needle punching or high-pressure water flow treatment. In the present invention, it is desirable to employ high-pressure water flow treatment. According to the high-pressure water flow treatment, a nonwoven fabric which is flexible and has a good touch can be obtained. High-pressure water flow treatment is also suitable for treating low-weight fiber webs.
【0026】高圧水流処理は、公知の方法を任意に採用
して行えばよく、その条件は繊維ウェブの目付等に応じ
て設定するとよい。例えば、目付20〜50g/m2 の
繊維ウェブを処理する場合には、孔径0.05〜0.5
mmのオリフィスが0.5〜1.5mmの間隔で設けられた
ノズルから水圧20〜80kg/cm2 の柱状水流を、ウェ
ブの表裏面側からそれぞれ1〜4回ずつ噴射するとよ
い。The high-pressure water flow treatment may be performed by any known method, and the conditions may be set according to the basis weight of the fiber web. For example, when treating a fibrous web having a basis weight of 20 to 50 g / m 2 , a pore size of 0.05 to 0.5
A columnar water stream having a water pressure of 20 to 80 kg / cm 2 may be sprayed from the front and back sides of the web one to four times from nozzles provided with 0.5 mm orifices at intervals of 0.5 to 1.5 mm.
【0027】繊維同士を交絡させた後、熱処理を施して
潜在捲縮性複合繊維の低融点成分を軟化あるいは溶融さ
せると同時に潜在捲縮性複合繊維に立体捲縮を発現させ
る。熱処理温度は、潜在捲縮性繊維の低融点成分が軟化
もしくは溶融する温度よりも高く、潜在捲縮性繊維のそ
の他の成分すなわち低融点成分以外の成分が溶融する温
度よりも低い温度とする。さらに、非熱接着性繊維とし
て熱可塑性樹脂からなる繊維を使用する場合、非熱接着
性繊維が溶融する温度よりも低い温度で処理をする必要
がある。かかる条件を満たす場合でも、熱処理温度が高
すぎると立体捲縮が過度に進行し、不織布の面積収縮が
大きくなる。また、熱処理温度が低融点成分が軟化する
温度よりも低いと、立体捲縮が発現するのみで熱接着さ
れず、不織布の強力が小さくなる。After the fibers are entangled with each other, a heat treatment is applied to soften or melt the low melting point component of the latently crimpable conjugate fiber, and at the same time, develop the three-dimensional crimp in the latently crimpable conjugate fiber. The heat treatment temperature is higher than the temperature at which the low melting point component of the latently crimpable fiber softens or melts, and lower than the temperature at which the other components of the latently crimpable fiber, that is, components other than the low melting point component, melt. Further, when a fiber made of a thermoplastic resin is used as the non-thermo-bonding fiber, it is necessary to perform the treatment at a temperature lower than the temperature at which the non-thermo-bonding fiber melts. Even when such a condition is satisfied, if the heat treatment temperature is too high, three-dimensional crimping proceeds excessively, and the area shrinkage of the nonwoven fabric increases. On the other hand, when the heat treatment temperature is lower than the temperature at which the low melting point component is softened, only the three-dimensional crimp is developed and the heat bonding is not performed, and the strength of the nonwoven fabric is reduced.
【0028】さらに本発明において重要なことは、熱処
理の際に生じる不織布の面積収縮を抑えることである。
面積収縮は立体捲縮の発現に起因して生じるため、本発
明においてもある程度の収縮は必然的に生じる。しか
し、あまり大きくなると面積収縮分を見込んでウェブの
目付を決定する必要があるため、工程管理が煩雑とな
る。また、低目付の不織布を製造する場合には、かなり
低い目付のウェブを用意しなければならない。しかし低
目付なウェブほど均一性に欠け、最終的に得られる不織
布も均一でなくなるから、ウェブの目付を低く設定する
ことは避けることが望ましい。そこで、本発明では熱処
理後の不織布の面積収縮率が10%以下となるような条
件で熱処理を施すことが望ましい。Further, it is important in the present invention to suppress the area shrinkage of the nonwoven fabric which occurs during the heat treatment.
Since the area shrinkage is caused by the appearance of the three-dimensional crimp, a certain degree of shrinkage inevitably occurs also in the present invention. However, if it is too large, it is necessary to determine the basis weight of the web in consideration of the area shrinkage, so that the process management becomes complicated. Also, when producing a nonwoven fabric having a low basis weight, a web having a fairly low basis weight must be prepared. However, the lower the web weight, the less uniform the web becomes and the resulting nonwoven fabric also becomes less uniform. Therefore, it is desirable to avoid setting the web weight low. Therefore, in the present invention, it is desirable to perform the heat treatment under the condition that the area shrinkage of the nonwoven fabric after the heat treatment is 10% or less.
【0029】この条件を満たすためには、潜在捲縮性複
合繊維の種類に応じて温度、時間等を設定する必要があ
る。例えば前述のエチレン−プロピレン共重合体/ポリ
プロピレンからなる潜在捲縮性複合繊維を使用する場
合、熱風貫通型乾燥機を用いて130〜145℃の熱処
理温度で5〜20秒処理するとよい。In order to satisfy this condition, it is necessary to set the temperature, time and the like according to the type of the latently crimpable conjugate fiber. For example, when using the latent crimpable conjugate fiber composed of the above-mentioned ethylene-propylene copolymer / polypropylene, it is preferable to use a hot air penetration type drier at a heat treatment temperature of 130 to 145 ° C for 5 to 20 seconds.
【0030】このようにして得られる本発明の不織布
は、潜在捲縮性複合繊維に立体捲縮が発現し、かつ潜在
捲縮性複合繊維の低融点成分によって繊維同士が熱接着
されたものである。この不織布は実用に耐える十分な強
力を有するとともに、優れた柔軟性および触感を示す。
また、潜在捲縮性複合繊維の割合を増やした場合でも、
通常の熱接着性複合繊維を使用する場合に比べ、柔軟性
および触感の低下の度合いは小さい。The thus obtained nonwoven fabric of the present invention is a non-woven fabric in which latently crimped conjugate fibers exhibit three-dimensional crimp, and the fibers are thermally bonded to each other by the low melting point component of the latently crimpable conjugate fibers. is there. This nonwoven fabric has sufficient strength to withstand practical use, and exhibits excellent flexibility and touch.
In addition, even when the proportion of the latently crimpable conjugate fiber is increased,
The degree of decrease in flexibility and tactile sensation is smaller than in the case of using normal heat-adhesive conjugate fibers.
【0031】さらに、本発明の不織布は通常の熱接着性
複合繊維を混合した不織布に比べて毛羽抜けが少ないと
いう利点を有する。その理由は定かではないが、不織布
表面の立体捲縮が何らかの形で毛羽抜け防止に寄与して
いるものと推測される。Further, the non-woven fabric of the present invention has an advantage that the fluff is reduced compared to a non-woven fabric mixed with ordinary thermo-adhesive conjugate fibers. Although the reason is not clear, it is presumed that the three-dimensional crimp on the surface of the nonwoven fabric contributes in some way to preventing fluff.
【0032】[0032]
【実施例】以下、本発明の内容を実施例により説明す
る。なお、得られた熱接着不織布の物性はそれぞれ次の
方法により評価した。DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the contents of the present invention will be described with reference to embodiments. The properties of the obtained heat-bonded nonwoven fabric were evaluated by the following methods.
【0033】(1)厚み:厚み測定機(商品名:THICKN
ESS GAUGE モデル CR-60A (株)大栄科学精器製作所
製)を用い、不織布に3g/cm2 の荷重を加えた状態で
測定した。 (2)強力、伸度:JIS L1096に準じ、幅5c
m、長さ15cmの試料をつかみ間隔10cmで把持し、定
速伸長型引張試験機を用いて30cm/分の速度で伸長
し、切断時の荷重値および伸長率を、それぞれ強力、伸
度とした。 (3)熱処理後の面積収縮率:熱処理前の不織布表面に
20cm×20cmの正方形の枠を置き、各辺の中点に相当
する箇所に印をつける。そして、熱処理後、互いに向か
い合う中点同士を線で結び、熱処理により正方形がそれ
らの線をタテ、ヨコとする長方形になったものとみなし
て長方形の面積を算出し、面積収縮率(%)={(40
0−長方形の面積(cm2 ))/400}×100の式か
ら面積収縮率を求めた。 (4)曲げ長さ(柔軟性):カンチレバー法(JIS
L 1096.6.19.1A法)により測定した。 (5)触感:10人のパネラーによる官能試験を行っ
た。触感の良い順に3、2、1点を付けてもらい、合計
の点数が高かったものの順に○、△、×で表した。 (6)毛羽抜け:拭き取り面が11cm×26cmのフロー
リングワイパー用モップの治具に試料をとりつけ、幅3
2cm、長さ92cmのポリエステルモノフィラメントの平
織物(33メッシュ/25mm)上で、30回往復運動さ
せた。往復運動後、試料の摩擦面の中央に幅2cm、長さ
10cmのメンディングテープ(住友スリーエム社製)を
貼り、その上を500gのおもりを2回通過させた。メ
ンディングテープを剥がし黒紙に貼りつけ、毛羽の抜け
具合いを目視し、毛羽抜けの少なかったものを○、多か
ったものを×で表した。 (7)ヒートシール強力:幅20cm、長さ10cmの試料
2枚を重ね、上部から1cmのところで、ヒートシール幅
2mm、加熱温度140℃、押圧2kg/cm2 、ヒートシー
ル時間1秒間にて接着させた。これを、ヒートシール部
分が幅方向となるように幅3cmにカットする。カットし
た試料をヒートシール部分が中央にくるようにしてつか
み間隔10cmで把持し、定速伸長型引張試験機を用いて
30cm/分の速度で引っ張り、ヒートシール部の剥離強
力をヒートシール強力とした。(1) Thickness: thickness measuring machine (trade name: THICKN
Using an ESS GAUGE model CR-60A (manufactured by Daiei Kagaku Seiki Seisaku-Sho, Ltd.), the measurement was performed with a load of 3 g / cm 2 applied to the nonwoven fabric. (2) Strength, elongation: width 5c according to JIS L1096
m, a sample with a length of 15 cm is gripped at a spacing of 10 cm, and is stretched at a speed of 30 cm / min using a constant-speed stretching type tensile tester. did. (3) Area shrinkage after heat treatment: A square frame of 20 cm × 20 cm is placed on the surface of the non-woven fabric before heat treatment, and a mark corresponding to the midpoint of each side is marked. Then, after the heat treatment, the midpoints facing each other are connected by a line, and the heat treatment is performed to calculate the area of the rectangle assuming that the square has become a rectangle in which the line is vertical and horizontal, and the area shrinkage rate (%) = {(40
The area shrinkage was determined from the equation: 0−area of rectangle (cm 2 )) / 400 ° × 100. (4) Bending length (flexibility): Cantilever method (JIS
L 1096.6.9.1A method). (5) Tactile sensation: A sensory test was conducted by 10 panelists. Three, two, and one points were assigned in the order of good tactile sensation, and the points with the highest total score were represented by ○, Δ, and ×. (6) Fluff removal: A sample was attached to a jig of a flooring wiper mop having a wiping surface of 11 cm x 26 cm, and the width was 3 mm.
It was reciprocated 30 times on a plain fabric (33 mesh / 25 mm) of a polyester monofilament 2 cm long and 92 cm long. After the reciprocating motion, a 2 cm wide and 10 cm long mending tape (manufactured by Sumitomo 3M Limited) was applied to the center of the friction surface of the sample, and a 500 g weight was passed twice over it. The mending tape was peeled off and affixed to black paper, and the degree of fluff removal was visually observed. (7) Heat seal strength: Two samples of 20 cm width and 10 cm length are stacked and bonded at 1 cm from the top at a heat seal width of 2 mm, a heating temperature of 140 ° C., a pressure of 2 kg / cm 2 , and a heat seal time of 1 second. I let it. This is cut to a width of 3 cm so that the heat-sealed portion is in the width direction. The cut sample is gripped at a grip interval of 10 cm so that the heat-sealed portion is located at the center, and pulled at a speed of 30 cm / min using a constant-speed elongation type tensile tester. did.
【0034】[実施例1]潜在捲縮性複合繊維として、
融点142℃のエチレン−プロピレン共重合体を鞘成
分、融点162℃のポリプロピレンを芯成分とする、繊
度2デニール、繊維長51mmの偏心型の芯鞘型複合繊維
(商品名:CPP 大和紡績(株)製)を用意した。こ
の繊維は、自由な状態で130℃の雰囲気下に置かれた
とき12秒以内に40個/インチの立体捲縮を発現する
ものであった。Example 1 As a latently crimpable conjugate fiber,
An eccentric core-sheath composite fiber having a fineness of 2 denier and a fiber length of 51 mm (trade name: CPP, Daiwa Spinning Co., Ltd.) having an ethylene-propylene copolymer having a melting point of 142 ° C. as a sheath component and polypropylene having a melting point of 162 ° C. as a core component. )) Was prepared. The fibers exhibited a three-dimensional crimp of 40 pieces / inch within 12 seconds when freely placed in an atmosphere at 130 ° C.
【0035】この潜在捲縮性複合繊維40重量%と、繊
度1.5デニール、繊維長40mmのレーヨン繊維(商品
名:コロナ ダイワボウレーヨン(株)製)60重量%
とを混合し、パラレルカードを用いて目付35g/m2
の繊維ウェブを作成した。40% by weight of the latent crimpable conjugate fiber and 60% by weight of rayon fiber (trade name: Corona Daiwabo Rayon Co., Ltd.) having a denier of 1.5 denier and a fiber length of 40 mm.
And 35 g / m 2 using a parallel card.
A fiber web was prepared.
【0036】次に、孔径0.12mmのオリフィスが0.
6mm間隔で設けられたノズルから、繊維ウェブの表面側
に水圧40kg/cm2 、60kg/cm2 の柱状水流を2回ず
つ噴射し、繊維ウェブの裏面側に水圧40kg/cm2 の柱
状水流を1回、水圧50kg/cm2 の柱状水流を2回噴射
して、繊維同士を交絡させた。Next, an orifice having a hole diameter of 0.12 mm is used.
From a nozzle provided at 6mm intervals, on the surface side of the fibrous web columnar water flow pressure 40kg / cm 2, 60kg / cm 2 was injected twice, on the back side of the fibrous web columnar water flow pressure 40 kg / cm 2 One time, a columnar water stream with a water pressure of 50 kg / cm 2 was jetted twice to entangle the fibers.
【0037】続いてこれに熱処理を施し、潜在捲縮性複
合繊維に立体捲縮を発現させると同時に潜在捲縮性複合
繊維のエチレン−プロピレン共重合体を軟化させて繊維
同士を接着させ、熱接着不織布を得た。熱処理は、13
5℃に設定した熱風貫通型乾燥機内で12秒間行った。Subsequently, this is subjected to a heat treatment to cause the latently crimpable conjugate fiber to exhibit three-dimensional crimp, and at the same time, soften the ethylene-propylene copolymer of the latently crimpable conjugate fiber to bond the fibers to each other. An adhesive nonwoven was obtained. Heat treatment is 13
This was performed for 12 seconds in a hot air penetration type dryer set at 5 ° C.
【0038】[比較例1]潜在捲縮性複合繊維の割合を
60重量%、レーヨン繊維の割合を40重量%とする以
外は、実施例1と全く同じ方法で熱接着不織布を得た。Comparative Example 1 A heat-bonded nonwoven fabric was obtained in exactly the same manner as in Example 1, except that the proportion of the latent crimpable conjugate fiber was 60% by weight and the proportion of the rayon fiber was 40% by weight.
【0039】[比較例2]融点132℃の高密度ポリエ
チレンを鞘成分とし、融点162℃のポリプロピレンを
芯成分とする繊度2デニール、繊維長51mmの芯鞘型複
合繊維(商品名:NBF(H) 大和紡績(株)製)を
熱接着性繊維として用意した。そして、この熱接着性繊
維40重量%と、実施例1で使用したものと同じレーヨ
ン繊維60重量%とを混合して、実施例1と全く同じ方
法で熱接着不織布を得た。Comparative Example 2 A core-sheath type composite fiber having a fineness of 2 denier and a fiber length of 51 mm (trade name: NBF (H ) (Manufactured by Daiwa Spinning Co., Ltd.) was prepared as a heat-adhesive fiber. Then, 40% by weight of the heat-adhesive fiber and 60% by weight of the same rayon fiber used in Example 1 were mixed, and a heat-bonded nonwoven fabric was obtained in exactly the same manner as in Example 1.
【0040】実施例1および比較例1、2で得られた熱
接着不織布の物性を表1に、実施例1と比較例2のヒー
トシール強力を表2に示す。Table 1 shows the physical properties of the heat-bonded nonwoven fabric obtained in Example 1 and Comparative Examples 1 and 2, and Table 2 shows the heat seal strength of Example 1 and Comparative Example 2.
【0041】[0041]
【表1】 [Table 1]
【0042】[0042]
【表2】 [Table 2]
【0043】実施例1の不織布は、各比較例よりも柔軟
性および触感の点で優れており、毛羽抜けも少ない。強
力はやや小さいが、十分実用に耐えるものである。ま
た、実施例1の面積収縮率は10%以下である。比較例
1のものは毛羽抜けは少ないが、潜在捲縮性複合繊維の
割合が大きいため柔軟性の点でやや劣り、面積収縮率も
高い。比較例2のものは、柔軟性、触感、毛羽抜けの点
において劣っていた。また、比較例2は不織布強力は高
いもののヒートシール強力は実施例1に比べて小さかっ
た。The nonwoven fabric of Example 1 is superior in flexibility and touch to each of the comparative examples, and has less fluff. Although the strength is rather small, it is enough for practical use. In addition, the area shrinkage rate of Example 1 is 10% or less. The fiber of Comparative Example 1 has a small amount of fluff, but is slightly inferior in flexibility and has a high area shrinkage due to a large proportion of the latently crimpable conjugate fiber. Comparative Example 2 was inferior in flexibility, tactile sensation, and fluff removal. In Comparative Example 2, although the nonwoven fabric strength was high, the heat seal strength was smaller than that in Example 1.
【0044】[0044]
【発明の効果】本発明の熱接着不織布は、立体捲縮が発
現した潜在捲縮性複合繊維20〜50重量%と、非熱接
着性繊維80〜50重量%とからなり、繊維同士が交絡
してなる不織布であって、潜在捲縮性複合繊維の低融点
成分により繊維同士が熱接着されていることを特徴とす
る。熱接着性繊維として潜在捲縮性複合繊維を使用する
ことで、優れた柔軟性と触感が不織布に付与され、毛羽
抜けも防止される。また、熱処理の際の捲縮発現に伴っ
て生じる不織布の収縮を一定率以下に抑えることで、低
目付な不織布を得ることが可能となる。かかる特性によ
り、本発明の熱接着不織布はおむつのトップシートやバ
ックシート、ウェットティッシュ、ワイパー等として有
利に使用することができる。The heat-bonded nonwoven fabric according to the present invention comprises 20 to 50% by weight of a latently crimpable conjugate fiber exhibiting three-dimensional crimp and 80 to 50% by weight of a non-heat-bondable fiber. Wherein the fibers are thermally bonded to each other by a low melting point component of the latently crimpable conjugate fiber. By using a latently crimpable conjugate fiber as the heat-adhesive fiber, excellent flexibility and tactile sensation are imparted to the nonwoven fabric, and fluff is prevented. Further, by suppressing the shrinkage of the nonwoven fabric caused by the appearance of crimp during the heat treatment to a certain rate or less, it becomes possible to obtain a nonwoven fabric having a low basis weight. Due to such properties, the heat-bonded nonwoven fabric of the present invention can be advantageously used as a diaper top sheet, back sheet, wet tissue, wiper, and the like.
【図1】立体捲縮が発現した潜在捲縮性複合繊維の一例
の側面図である。FIG. 1 is a side view of an example of a latently crimpable conjugate fiber in which a three-dimensional crimp has been developed.
【図2】立体捲縮が発現した潜在捲縮性複合繊維の一例
の側面図である。FIG. 2 is a side view of an example of a latently crimpable conjugate fiber in which a three-dimensional crimp has been developed.
【図3】立体捲縮が発現した潜在捲縮性複合繊維の一例
の側面図である。FIG. 3 is a side view of an example of a latently crimpable conjugate fiber in which a three-dimensional crimp has been developed.
Claims (8)
20〜50重量%と、非熱接着性繊維80〜50重量%
とからなり、繊維同士が交絡してなる不織布において、
潜在捲縮性複合繊維の低融点成分により繊維同士が熱接
着されていることを特徴とする熱接着不織布。Claims 1. A latently crimpable conjugate fiber exhibiting a three-dimensional crimp, 20 to 50% by weight, and a non-heat-adhesive fiber, 80 to 50% by weight.
In a non-woven fabric consisting of fibers entangled with each other,
A thermally bonded nonwoven fabric, wherein the fibers are thermally bonded to each other by a low melting point component of the latently crimpable conjugate fiber.
と、非熱接着性繊維80〜50重量%とからなる繊維ウ
ェブに、機械的な交絡処理を施して繊維同士を交絡させ
て一体化した後、熱処理を施して潜在捲縮性複合繊維に
立体捲縮を発現させると同時に潜在捲縮性複合繊維の低
融点成分により繊維同士を熱接着させた不織布であっ
て、前記熱処理が繊維ウェブの面積収縮率が10%以下
となるように施されていることを特徴とする熱接着不織
布。2. A latently crimpable conjugate fiber of 20 to 50% by weight.
And a fibrous web consisting of 80 to 50% by weight of the non-heat-adhesive fiber is subjected to a mechanical entanglement treatment so that the fibers are entangled and integrated, and then subjected to a heat treatment to give a three-dimensionally crimped conjugate fiber. A nonwoven fabric in which fibers are thermally bonded to each other with a low melting point component of a latently crimpable conjugate fiber at the same time as exhibiting crimping, wherein the heat treatment is performed so that the area shrinkage of the fiber web is 10% or less. A heat-bonded non-woven fabric.
m −15≦T<Tm(Tm は潜在捲縮性複合繊維の低融
点成分の融点)の熱処理温度(T℃)で加熱されたとき
に30個/インチ以上の立体的な捲縮を発現する性質を
有する繊維である請求項1もしくは請求項2に記載の熱
接着不織布。3. The latently crimpable conjugate fiber is freely T
When heated at a heat treatment temperature (T ° C.) of m−15 ≦ T <Tm (Tm is the melting point of the low melting point component of the latently crimpable conjugate fiber), a three-dimensional crimp of 30 / inch or more is developed. The heat-bonded nonwoven fabric according to claim 1 or 2, which is a fiber having properties.
ピレン共重合体を第一成分、ポリプロピレンを第二成分
とし、第一成分を鞘成分、第二成分を芯成分とする偏心
型の芯鞘型複合繊維、もしくは両成分がサイドバイサイ
ド型に接合された複合繊維である請求項3に記載の熱接
着不織布。4. An eccentric core comprising a latent crimpable conjugate fiber comprising an ethylene-propylene copolymer as a first component, polypropylene as a second component, a first component as a sheath component, and a second component as a core component. The heat-bonded nonwoven fabric according to claim 3, which is a sheath-type composite fiber or a composite fiber in which both components are joined in a side-by-side type.
求項1〜4いずれか一項に記載の熱接着不織布。5. The heat-bonded nonwoven fabric according to claim 1, wherein the non-heat-bondable fiber is rayon fiber.
る請求項1〜5いずれか一項に記載の熱接着不織布。6. The heat-bonded nonwoven fabric according to claim 1, wherein the mechanical entanglement treatment is a high-pressure water flow treatment.
1〜6いずれか一項に記載の熱接着不織布。7. The heat-bonded nonwoven fabric according to claim 1, wherein the basis weight is 20 to 50 g / m 2 .
と、非熱接着性繊維80〜50重量%とからなる繊維ウ
ェブに高圧水流処理を施して繊維同士を交絡させた後、
潜在捲縮性複合繊維の低融点成分が軟化する温度よりも
高く、潜在捲縮性複合繊維のその他の成分の融点よりも
低い温度で、繊維ウェブの熱収縮率が10%以下となる
ように熱処理を施し、潜在捲縮性複合繊維に立体捲縮を
発現させると同時に低融点成分により繊維同士を熱接着
させることを特徴とする熱接着不織布の製造方法。8. A latently crimpable conjugate fiber of 20 to 50% by weight.
And after applying a high-pressure water-flow treatment to a fibrous web composed of 80 to 50% by weight of the non-heat-adhesive fibers to entangle the fibers,
At a temperature higher than the temperature at which the low melting point component of the latently crimpable conjugate fiber softens and lower than the melting point of the other components of the latently crimpable conjugate fiber, the heat shrinkage of the fiber web is 10% or less. A method for producing a heat-bonded nonwoven fabric, comprising heat-treating a latently-crimpable conjugate fiber to develop a three-dimensional crimp and simultaneously heat-bonding the fibers by a low-melting-point component.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5095897A JP3276578B2 (en) | 1997-02-18 | 1997-02-18 | Thermally bonded nonwoven fabric and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5095897A JP3276578B2 (en) | 1997-02-18 | 1997-02-18 | Thermally bonded nonwoven fabric and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10237751A true JPH10237751A (en) | 1998-09-08 |
JP3276578B2 JP3276578B2 (en) | 2002-04-22 |
Family
ID=12873338
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5095897A Expired - Fee Related JP3276578B2 (en) | 1997-02-18 | 1997-02-18 | Thermally bonded nonwoven fabric and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3276578B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005520059A (en) * | 2001-12-21 | 2005-07-07 | インビスタ・テクノロジーズ・エス・エイ・アール・エル | Method for producing high bulk composite sheet |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1206753C (en) | 2001-04-11 | 2005-06-15 | 日立马库塞鲁株式会社 | Flat nonaqueous electrolyte battery |
JP5560170B2 (en) * | 2010-11-22 | 2014-07-23 | ハビックス株式会社 | Nonwoven fabric and method for producing the same |
JP5831840B2 (en) * | 2011-07-12 | 2015-12-09 | Jnc株式会社 | Stretchable nonwoven fabric and method for producing the same |
-
1997
- 1997-02-18 JP JP5095897A patent/JP3276578B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005520059A (en) * | 2001-12-21 | 2005-07-07 | インビスタ・テクノロジーズ・エス・エイ・アール・エル | Method for producing high bulk composite sheet |
Also Published As
Publication number | Publication date |
---|---|
JP3276578B2 (en) | 2002-04-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100739404B1 (en) | Absorbent article having fibrillary layer on surface thereof | |
JP3875007B2 (en) | Absorbent article using surface layer having continuous filament and method for producing the same | |
JP3333718B2 (en) | Laminate for wiper | |
KR20160130784A (en) | Nonwoven fabric for skin covering sheet to be impregnated with cosmetic preparation, and process for producing same | |
JP2001140158A (en) | Stretchable composite nonwoven fabric and absorbing article using the same | |
JP3131559B2 (en) | Bulk nonwoven fabric, method for producing the same, and female fastener material | |
JPH09291454A (en) | Stretchable elastic nonwoven fabric | |
JP3668184B2 (en) | Skin moist sheet and method for producing the same | |
JPH0446146B2 (en) | ||
JPH1086256A (en) | Composite nonwoven fabric and absorbent article using the same | |
JP4446579B2 (en) | Perforated nonwoven fabric and method for producing the same | |
JP4320080B2 (en) | Stretchable nonwoven fabric excellent in heat sealability and method for producing the same | |
JP3276578B2 (en) | Thermally bonded nonwoven fabric and method for producing the same | |
JP3986505B2 (en) | Fiber sheet | |
JP2910862B2 (en) | Polyolefin-based stretchable nonwoven fabric and method for producing the same | |
JP5326104B2 (en) | Non-woven fabric for wiper and method for producing the same | |
JP3846979B2 (en) | Surface fastener female material excellent in peel strength and method for producing the same | |
JP3244441B2 (en) | Composite elastic sheet | |
JP3056403B2 (en) | Stretchable nonwoven fabric and method for producing the same | |
JPH06136654A (en) | Laminated nonwoven fabric and its production | |
JPH0967748A (en) | Bulky nonwoven fabric and its production | |
JP4013346B2 (en) | Nonwoven fabric and absorbent article using the same | |
JP3967848B2 (en) | Nonwoven fabric for cleaning and method for producing the same | |
JP3126510B2 (en) | Super absorbent nonwoven material | |
US7452834B2 (en) | Fibrous sheet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090208 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090208 Year of fee payment: 7 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100208 Year of fee payment: 8 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110208 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110208 Year of fee payment: 9 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110208 Year of fee payment: 9 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110208 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120208 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120208 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130208 Year of fee payment: 11 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |