JPH10183078A - Self-adhesive tape or sheet - Google Patents
Self-adhesive tape or sheetInfo
- Publication number
- JPH10183078A JPH10183078A JP34873496A JP34873496A JPH10183078A JP H10183078 A JPH10183078 A JP H10183078A JP 34873496 A JP34873496 A JP 34873496A JP 34873496 A JP34873496 A JP 34873496A JP H10183078 A JPH10183078 A JP H10183078A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive tape
- pressure
- sensitive adhesive
- component
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は粘着テープまたはシ
ート（以下、粘着テープという）に関し、より詳しく
は、特に自動車等の塗装作業等に使用されるマスキング
用の粘着テープに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an adhesive tape or sheet (hereinafter referred to as "adhesive tape"), and more particularly to an adhesive tape for masking used in painting work of automobiles and the like.
【０００２】[0002]
【従来の技術】粘着テープの用途の１つとして、被着体
の非塗装部分に貼り付け、塗装作業終了後に剥離する用
途、所謂、マスキング用が知られている。また、通常、
粘着テープはロール状に巻回されて保管されており、こ
の状態では粘着剤層がテープ背面（基材の粘着剤層形成
面と反対面）に重ね合わさっている。使用に際しては粘
着テープは巻き戻されるが、一般に、作業性の点でこの
巻き戻し力が小さい方がよく、そのために粘着テープ背
面には剥離処理がなされている。2. Description of the Related Art As one of uses of an adhesive tape, there has been known a use of applying an adhesive tape to an unpainted portion of an adherend and peeling it after completion of a painting operation, so-called masking. Also, usually
The pressure-sensitive adhesive tape is wound in a roll and stored, and in this state, the pressure-sensitive adhesive layer is superimposed on the back surface of the tape (the surface opposite to the pressure-sensitive adhesive layer forming surface of the base material). At the time of use, the adhesive tape is rewound. Generally, the smaller the rewound force is, the better the workability is. For this reason, the back surface of the adhesive tape is subjected to a peeling treatment.
【０００３】粘着テープを塗装のマスキング用に使用し
た場合、塗装終了後には粘着テープ背面に塗料が一部付
着する。従来の粘着テープではテープ背面の塗料との密
着性が悪いため、このような粘着テープを被着体から剥
離した際には、粘着テープから塗料が剥がれ、この剥が
れた塗料が被着体の塗装部分に付着し、外観が悪くなる
といった問題があった。特に上記のようなテープ背面に
剥離処理がなされている粘着テープにおいては、その傾
向が顕著であった。[0003] When the adhesive tape is used for masking the coating, the coating partially adheres to the back surface of the adhesive tape after the coating is completed. Conventional adhesive tapes have poor adhesion to the paint on the back of the tape, so when such adhesive tape is peeled off from the adherend, the paint peels off from the adhesive tape, and this peeled paint is applied to the adherend. There was a problem that it adhered to the part and the appearance became poor. In particular, the tendency was remarkable in the pressure-sensitive adhesive tape in which the peeling treatment was performed on the back surface of the tape as described above.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、上記の問題
を解決しようとするものであり、その目的は、塗装のマ
スキング用に使用した場合に塗料との密着性が良好で、
かつ巻き戻し力が小さい粘着テープを提供することにあ
る。SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and an object of the present invention is to provide a paint having good adhesion to a coating when used for masking the coating.
Another object of the present invention is to provide an adhesive tape having a small unwinding force.
【０００５】[0005]
【課題を解決するための手段】本発明は、 (1)基材と、
基材上に形成された粘着剤層と、基材の粘着剤層形成面
と反対面上に形成された背面処理層を含む粘着テープで
あって、当該背面処理層が、塗料密着成分であるポリイ
ソシアネートと、剥離成分である長鎖アルキル系剥離剤
を含有することを特徴とする粘着テープである。好適な
実施態様は以下の通りである。 (2)ポリイソシアネート１００重量部に対し、長鎖アル
キル系剥離剤が１〜２０００重量部の割合で配合される
上記 (1)に記載の粘着テープ。 (3)さらに、バインダー成分として、アクリル共重合
体、ポリエステル樹脂、ウレタン樹脂、天然ゴムおよび
合成ゴムからなる群より選択される少なくとも１種を含
有する上記 (1)または (2)の粘着テープ。 (4)マスキング用である上記(1) 〜 (3)のいずれかの粘
着テープ。Means for Solving the Problems The present invention provides (1) a base material,
A pressure-sensitive adhesive layer formed on the base material, and a pressure-sensitive adhesive tape including a back surface treatment layer formed on the surface opposite to the surface on which the pressure-sensitive adhesive layer is formed of the substrate, wherein the back surface treatment layer is a paint adhesion component. An adhesive tape containing a polyisocyanate and a long-chain alkyl-based release agent as a release component. The preferred embodiment is as follows. (2) The pressure-sensitive adhesive tape according to the above (1), wherein the long-chain alkyl-based release agent is blended in an amount of 1 to 2,000 parts by weight based on 100 parts by weight of the polyisocyanate. (3) The pressure-sensitive adhesive tape according to the above (1) or (2), further containing at least one selected from the group consisting of an acrylic copolymer, a polyester resin, a urethane resin, a natural rubber and a synthetic rubber as a binder component. (4) The adhesive tape according to any one of (1) to (3) above, which is used for masking.
【０００６】[0006]
【発明の実施の形態】以下に本発明を詳細に説明する。
本発明の粘着テープは、基材と、基材上に形成された粘
着剤層と、基材の粘着剤層形成面と反対面（以下、粘着
テープ背面ともいう）上に形成された背面処理層を含
む。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.
The pressure-sensitive adhesive tape of the present invention includes a substrate, a pressure-sensitive adhesive layer formed on the substrate, and a back surface treatment formed on the surface of the substrate opposite to the surface on which the pressure-sensitive adhesive layer is formed (hereinafter, also referred to as the back surface of the pressure-sensitive adhesive tape). Including layers.
【０００７】本発明で使用される基材としては、クラフ
ト紙、クレープ紙、和紙等の紙、あるいは金属（例え
ば、アルミニウム、銅、鉛、ステンレス等）箔、プラス
チック（例えばポリエステル、ポリエチレン、ポリプロ
ピレン、ポリ塩化ビニル等）のフィルム、もしくはこれ
らの複合体が挙げられる。この基材の厚みは、通常１０
〜３００μｍ程度である。The base material used in the present invention includes paper such as kraft paper, crepe paper, and Japanese paper, or metal (eg, aluminum, copper, lead, stainless steel, etc.) foil, plastic (eg, polyester, polyethylene, polypropylene, Polyvinyl chloride) or a composite thereof. The thickness of this substrate is usually 10
About 300 μm.
【０００８】この基材の片面に粘着剤層が形成されてい
る。粘着剤層に使用される粘着剤としては、特に限定さ
れず、公知の粘着剤が使用され、例えば、アクリル系、
天然ゴム系、合成ゴム系、シリコーン系等が挙げられ
る。また必要に応じて、粘着付与剤、老化防止剤、軟化
剤等の添加剤を含有させてもよい。この粘着剤層の厚み
は、通常５〜１００μｍ程度である。An adhesive layer is formed on one side of the substrate. The pressure-sensitive adhesive used for the pressure-sensitive adhesive layer is not particularly limited, and a known pressure-sensitive adhesive is used.
Natural rubber type, synthetic rubber type, silicone type and the like can be mentioned. If necessary, additives such as a tackifier, an antioxidant, and a softener may be contained. The thickness of this pressure-sensitive adhesive layer is usually about 5 to 100 μm.
【０００９】基材の粘着剤層形成面と反対面上に背面処
理層が形成されており、この背面処理層は塗料密着成分
と剥離成分を含有するものである。A back surface treatment layer is formed on the surface of the substrate opposite to the surface on which the pressure-sensitive adhesive layer is formed, and this back surface treatment layer contains a paint adhesion component and a release component.
【００１０】塗料密着成分としてはポリイソシアネート
化合物が使用され、その具体例としては、例えば、エチ
レンジイソシアネート、ブチルジイソシアネート、ヘキ
サメチレンジイソシアネート等の低脂肪族ポリイソシア
ネート類；シクロペンチレンジイソシアネート、シクロ
ヘキシレンジイソシアネート、イソホロンジイソシアネ
ート等の脂環族ポリイソシアネート類；２，４−トリレ
ンジイソシアネート、４，４’−フェニルメタンジイソ
シアネート、キシリレンジイソシアネート等の芳香族ポ
リイソシアネート類等が挙げられる。その他、トリメチ
ロールプロパンのトリレンジイソシアネート付加物（日
本ポリウレタン（株）コロネートＬ）も挙げられる。こ
れらのポリイソシアネート化合物は、塗料中に存在する
カルボキシル基、水酸基等の官能基と反応して塗料を粘
着テープ背面に密着させる。A polyisocyanate compound is used as a coating adhesion component. Specific examples thereof include low aliphatic polyisocyanates such as ethylene diisocyanate, butyl diisocyanate, and hexamethylene diisocyanate; cyclopentylene diisocyanate, cyclohexylene diisocyanate, and the like. Alicyclic polyisocyanates such as isophorone diisocyanate; and aromatic polyisocyanates such as 2,4-tolylene diisocyanate, 4,4'-phenylmethane diisocyanate, and xylylene diisocyanate. Other examples include tolylene diisocyanate adduct of trimethylolpropane (Coronate L, Nippon Polyurethane Co., Ltd.). These polyisocyanate compounds react with functional groups such as a carboxyl group and a hydroxyl group present in the paint to adhere the paint to the back surface of the adhesive tape.
【００１１】剥離成分としては長鎖アルキル系剥離剤が
使用され、その具体例としては、例えば、ポリビニルア
ルコール、部分ケン化したポリ酢酸ビニルと、炭素数が
１０〜３０の長鎖アルキルイソシアネートの反応物；炭
素数が１０〜３０の長鎖アルキル（メタ）アクリレート
と、アクリル酸、イタコン酸、マレイン酸、酢酸ビニ
ル、アクリロニトリル等のエチレン性二重結合を有する
化合物との共重合物；炭素数が１０〜３０の長鎖アルキ
ルイソシアネートとポリエチレンイミン反応物；シェラ
ック等が挙げられる。As the release component, a long-chain alkyl-based release agent is used. Specific examples thereof include, for example, a reaction between polyvinyl alcohol, partially saponified polyvinyl acetate, and a long-chain alkyl isocyanate having 10 to 30 carbon atoms. A copolymer of a long-chain alkyl (meth) acrylate having 10 to 30 carbon atoms and a compound having an ethylenic double bond such as acrylic acid, itaconic acid, maleic acid, vinyl acetate, and acrylonitrile; 10-30 long-chain alkyl isocyanates and polyethyleneimine reactants; shellac and the like.
【００１２】上記の塗料密着成分と剥離成分との配合比
は、塗料密着成分１００重量部に対して剥離成分は、好
ましくは１〜２０００重量部、より好ましくは１０〜１
０００重量部である。この剥離成分が１重量部未満の場
合、得られる粘着テープの巻き戻し力が大きくなって作
業性が低下する恐れがあり、逆に２０００重量部を超え
る場合、密着成分の含有割合が少なくなって、得られる
粘着テープの塗料密着性が低下する恐れがある。The mixing ratio between the paint adhesion component and the release component is preferably 1 to 2000 parts by weight, more preferably 10 to 1 part by weight, based on 100 parts by weight of the paint adhesion component.
000 parts by weight. When the amount of the release component is less than 1 part by weight, the rewinding force of the obtained pressure-sensitive adhesive tape may be increased and the workability may be reduced. On the other hand, when the amount exceeds 2,000 parts by weight, the content ratio of the adhesion component may decrease. In addition, there is a possibility that the paint adhesion of the obtained pressure-sensitive adhesive tape is reduced.
【００１３】背面処理層は、さらにバインダー成分を含
有してもよい。バインダー成分としては、アクリル共重
合体、例えば、炭素数２〜１０の（メタ）アクリレート
と、アクリル酸、イタコン酸、マレイン酸、酢酸ビニ
ル、アクリロニトリル等のエチレン性二重結合を有する
化合物との共重合体や、ポリエステル樹脂、天然ゴム、
合成ゴム、ウレタン樹脂等を用いてもよい。このバイン
ダー成分は、塗料密着成分１００重量部に対して１〜１
００重量部程度配合される。The back treatment layer may further contain a binder component. As the binder component, an acrylic copolymer, for example, a (meth) acrylate having 2 to 10 carbon atoms and a compound having an ethylenic double bond such as acrylic acid, itaconic acid, maleic acid, vinyl acetate, and acrylonitrile are used. Polymers, polyester resins, natural rubber,
Synthetic rubber, urethane resin or the like may be used. The binder component is used in an amount of 1 to 1 with respect to 100 parts by weight of the paint adhesion component.
About 00 parts by weight are blended.
【００１４】上記の背面処理層の厚みは、通常、乾燥後
０．１μｍ〜２０μｍ程度、好ましくは１μｍ〜１０μ
ｍである。The thickness of the above-mentioned back treatment layer is usually about 0.1 μm to 20 μm after drying, preferably 1 μm to 10 μm.
m.
【００１５】本発明の粘着テープは、例えば以下のよう
にして作成される。まず、塗料密着成分、剥離成分、必
要に応じバインダー成分を混合し、これを基材に塗布・
乾燥することにより背面処理層を形成する。次いで基材
の反対面に粘着剤を塗布して粘着剤層を形成して粘着テ
ープを得る。The pressure-sensitive adhesive tape of the present invention is produced, for example, as follows. First, a paint adhesion component, a release component, and a binder component are mixed as necessary, and the mixture is applied to a substrate.
The back treatment layer is formed by drying. Next, an adhesive is applied to the opposite surface of the base material to form an adhesive layer to obtain an adhesive tape.
【００１６】このようにして得られた本発明の粘着テー
プは、テープ背面の塗料との密着性が良好であるので、
塗装終了後の粘着テープ剥離時にテープ背面に付着した
塗料が剥がれることがなく、従って、被着体の塗装部分
の外観が悪くなるといった問題がない。また巻き戻し力
が小さいので作業性が良好である。従って、マスキング
用として特に有用であり、例えば、自動車、航空機、家
具、建築等のあらゆる塗装に使用される。The thus obtained pressure-sensitive adhesive tape of the present invention has good adhesion to the paint on the back surface of the tape.
When the adhesive tape is peeled off after the coating is completed, the paint adhered to the back surface of the tape is not peeled off, and therefore, there is no problem that the appearance of the painted portion of the adherend is deteriorated. Also, the workability is good because the unwinding force is small. Therefore, it is particularly useful for masking, and is used for all coatings, for example, on automobiles, aircraft, furniture, architecture, and the like.
【００１７】[0017]
【実施例】以下に、本発明を実施例を挙げて説明する
が、本発明はこれらに限定されるものではない。 実施例１ 塗料密着成分としての、トリメチロールプロパンのトリ
レンジイソシアネート付加物（日本ポリウレタン（株）
コロネートＬ）１００重量部に対して、剥離成分として
のポリビニルアルコールとオクタデシルイソシアネート
の反応物を２０００重量部の割合で配合し、これを２５
μｍのポリエステルフィルム上に乾燥後の膜厚が５μｍ
になるように塗布して背面処理層を形成し、次いで、基
材の反対面にアクリル系粘着剤を塗布・乾燥（乾燥後の
粘着剤の厚みを３０μｍ）して、マスキング用粘着テー
プを得た。The present invention will be described below with reference to examples, but the present invention is not limited to these examples. Example 1 Tolylene diisocyanate adduct of trimethylolpropane as a coating adhesion component (Nippon Polyurethane Co., Ltd.)
A reactant of polyvinyl alcohol and octadecyl isocyanate as a peeling component was blended at a ratio of 2000 parts by weight with respect to 100 parts by weight of Coronate L), and this was mixed with 25 parts by weight.
5 μm film thickness after drying on μm polyester film
To form a back treatment layer, and then apply and dry an acrylic adhesive on the opposite surface of the substrate (thickness of the adhesive after drying is 30 μm) to obtain an adhesive tape for masking. Was.
【００１８】実施例２ 密着成分としての、ヘキサメチレンジイソシアネート
（日本ポリウレタン（株）コロネートＨＬ）１００重量
部に対して、剥離成分としてのポリビニルアルコールと
オクタデシルイソシアネートの反応物を１重量部の割合
で配合し、これを１００μｍの塩化ビニルフィルム上に
乾燥後の膜厚が５μｍになるように塗布して背面処理層
を形成し、次いで、基材の反対面にゴム系粘着剤を塗布
・乾燥（乾燥後の粘着剤の厚みを３０μｍ）して、マス
キング用粘着テープを得た。Example 2 1 part by weight of a reactant of polyvinyl alcohol and octadecyl isocyanate as a peeling component was added to 100 parts by weight of hexamethylene diisocyanate (Coronate HL, Nippon Polyurethane Co., Ltd.) as an adhesive component. This was applied on a 100 μm vinyl chloride film so that the film thickness after drying was 5 μm to form a back treatment layer, and then a rubber-based adhesive was applied to the opposite surface of the substrate and dried (dried) The thickness of the subsequent pressure-sensitive adhesive was 30 μm) to obtain a pressure-sensitive adhesive tape for masking.
【００１９】実施例３ 塗料密着成分としての、トリメチロールプロパンのトリ
レンジイソシアネート付加物（日本ポリウレタン（株）
コロネートＬ）１００重量部に対して、剥離成分として
のポリビニルアルコールとオクタデシルイソシアネート
の反応物を３００重量部の割合で配合し、これを４０μ
ｍのポリプロピレンフィルム上に乾燥後の膜厚が５μｍ
になるように塗布して背面処理層を形成し、次いで、基
材の反対面にアクリル系粘着剤を塗布・乾燥（乾燥後の
粘着剤の厚みを３０μｍ）して、マスキング用粘着テー
プを得た。Example 3 Tolylene diisocyanate adduct of trimethylolpropane as a coating adhesion component (Nippon Polyurethane Co., Ltd.)
A reactant of polyvinyl alcohol and octadecyl isocyanate as a peeling component was mixed at a ratio of 300 parts by weight with respect to 100 parts by weight of Coronate L), and this was mixed with 40 μm.
5 μm after drying on polypropylene film
To form a back treatment layer, and then apply and dry an acrylic adhesive on the opposite surface of the substrate (thickness of the adhesive after drying is 30 μm) to obtain an adhesive tape for masking. Was.
【００２０】実施例４ 塗料密着成分としてのエチレンジイソシアネートを１０
０重量部に対して、剥離成分としての、アクリルニトリ
ルとオクタデシルメタクリレートとアクリル酸との共重
合物を１００重量部、バインダー成分としてポリエステ
ル樹脂を２０重量部の割合で配合し、これを１００μｍ
のクレープ紙上に乾燥後の膜厚が５μｍになるように塗
布して背面処理層を形成し、次いで、基材の反対面にア
クリル系粘着剤を塗布・乾燥（乾燥後の粘着剤の厚みを
３０μｍ）して、マスキング用粘着テープを得た。Example 4 10 parts of ethylene diisocyanate was used as a paint adhesion component.
100 parts by weight of a copolymer of acrylonitrile, octadecyl methacrylate, and acrylic acid as a release component and 20 parts by weight of a polyester resin as a binder component were mixed with 0 part by weight, and this was mixed with 100 μm.
On the crepe paper so that the film thickness after drying becomes 5 μm to form a back treatment layer, and then apply and dry an acrylic pressure-sensitive adhesive on the opposite surface of the substrate (the thickness of the dried pressure-sensitive adhesive is 30 μm) to obtain an adhesive tape for masking.
【００２１】比較例１ 剥離成分としての、アクリルニトリルとオクタデシルメ
タクリレートとアクリル酸との共重合物１００重量部の
みからなる背面処理剤を、２５μｍのポリエステルフィ
ルムに乾燥後の膜厚が５μｍになるように塗布し、次い
で、基材の反対面にアクリル系粘着剤を塗布・乾燥（乾
燥後の粘着剤の厚みを３０μｍ）して、マスキング用粘
着テープを得た。COMPARATIVE EXAMPLE 1 A back surface treating agent consisting of only 100 parts by weight of a copolymer of acrylonitrile, octadecyl methacrylate and acrylic acid as a release component was applied to a 25 μm polyester film so that the film thickness after drying was 5 μm. Then, an acrylic pressure-sensitive adhesive was applied to the opposite surface of the substrate and dried (thickness of the dried pressure-sensitive adhesive was 30 μm) to obtain a pressure-sensitive adhesive tape for masking.
【００２２】比較例２ 実施例１において、背面処理層を形成しなかったこと以
外は、実施例１と同様にしてマスキング用粘着テープを
得た。Comparative Example 2 An adhesive tape for masking was obtained in the same manner as in Example 1 except that the back treatment layer was not formed.
【００２３】実施例１〜４および比較例１〜２で得られ
た粘着テープについて、塗料密着性および巻き戻し力を
評価した。その結果を表１に示す。なお、測定方法は下
記に示したとおりである。With respect to the pressure-sensitive adhesive tapes obtained in Examples 1 to 4 and Comparative Examples 1 and 2, paint adhesion and rewinding force were evaluated. Table 1 shows the results. In addition, the measuring method is as showing below.
【００２４】＜測定方法＞ １．塗料密着性 鉄板にマスキング用粘着テープを２ｋｇローラーにて貼
り付け、次いでアクリル系塗料を乾燥後の膜厚が６０μ
ｍになるように塗布し、１５０℃、３０分間乾燥させ試
験片とする。試験片を鉄板から手で引き剥がし、マスキ
ング用粘着テープの背面から、塗料の剥がれ状況を目視
で確認し、かつマスキング用粘着テープの粘着面側を折
り曲げ、塗料の剥がれ状況を目視にて以下の３段階に評
価した。 ○・・・塗料の剥がれが見られない。 △・・・塗料の剥がれが一部見られる。 ×・・・塗料の剥がれが全面に見られる。 ２．巻き戻し力 ＪＩＳ−Ｚ０２３７に準じて行う。<Measurement method> Paint adhesion Adhesive tape for masking is applied to the iron plate with a 2 kg roller, and then the acrylic paint has a thickness of 60 μm after drying.
m and dried at 150 ° C. for 30 minutes to obtain a test piece. Peel the test piece from the iron plate by hand, visually check the peeling state of the paint from the back of the adhesive tape for masking, and bend the adhesive side of the adhesive tape for masking, visually check the peeling state of the paint as follows. The evaluation was made in three stages.・ ・ ・: No peeling of paint was observed. Δ: Peeling of the paint is partially observed. ×: Peeling of the paint is seen on the entire surface. 2. Rewinding force is performed according to JIS-Z0237.
【００２５】[0025]
【表１】 [Table 1]
【００２６】表１から、実施例１〜４で得られた粘着テ
ープは塗料密着性に優れ、かつ巻き戻し力が小さいこと
がわかる。一方、比較例１で得られた粘着テープは巻き
戻し力は小さいが塗料密着性が悪く、比較例２で得られ
た粘着テープは塗料密着性が悪くかつ巻き戻し力は大き
いことがわかる。From Table 1, it can be seen that the pressure-sensitive adhesive tapes obtained in Examples 1 to 4 have excellent paint adhesion and low rewinding force. On the other hand, it can be seen that the adhesive tape obtained in Comparative Example 1 has a small unwinding force but poor paint adhesion, and the adhesive tape obtained in Comparative Example 2 has a poor paint adhesion and a large unwinding force.
【００２７】[0027]
【発明の効果】以上の説明で明らかなように、本発明に
よれば、塗料との密着性が良好で、かつ巻き戻し力が小
さい粘着テープを提供することができ、このような粘着
テープは、例えば、自動車、航空機、家具、建築等のあ
らゆる塗装のマスキング用として特に有用である。As is apparent from the above description, according to the present invention, it is possible to provide a pressure-sensitive adhesive tape having good adhesion to paint and low rewinding force. For example, it is particularly useful for masking any paint such as automobiles, aircraft, furniture, architecture, etc.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ // Ｃ０９Ｊ 133/04 Ｃ０９Ｊ 133/04 167/00 167/00 ──────────────────────────────────────────────────続 き Continued on front page (51) Int.Cl. 6 Identification symbol FI // C09J 133/04 C09J 133/04 167/00 167/00
Claims (4)
と、基材の粘着剤層形成面と反対面上に形成された背面
処理層を含む粘着テープまたはシートであって、当該背
面処理層が、塗料密着成分であるポリイソシアネート
と、剥離成分である長鎖アルキル系剥離剤を含有するこ
とを特徴とする粘着テープまたはシート。A pressure-sensitive adhesive tape or sheet comprising a substrate, a pressure-sensitive adhesive layer formed on the substrate, and a back treatment layer formed on the surface of the substrate opposite to the surface on which the pressure-sensitive adhesive layer is formed, A pressure-sensitive adhesive tape or sheet, wherein the back surface treatment layer contains a polyisocyanate as a paint adhesion component and a long-chain alkyl-based release agent as a release component.
し、長鎖アルキル系剥離剤が１〜２０００重量部の割合
で配合されることを特徴とする請求項１に記載の粘着テ
ープまたはシート。2. The pressure-sensitive adhesive tape or sheet according to claim 1, wherein the long-chain alkyl-based release agent is blended in an amount of 1 to 2,000 parts by weight based on 100 parts by weight of the polyisocyanate.
ル共重合体、ポリエステル樹脂、ウレタン樹脂、天然ゴ
ムおよび合成ゴムからなる群より選択される少なくとも
１種を含有することを特徴とする請求項１または２に記
載の粘着テープまたはシート。3. The method according to claim 1, further comprising at least one selected from the group consisting of an acrylic copolymer, a polyester resin, a urethane resin, a natural rubber and a synthetic rubber as a binder component. The adhesive tape or sheet according to item 1.
ずれかに記載の粘着テープまたはシート。4. The pressure-sensitive adhesive tape or sheet according to claim 1, which is used for masking.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34873496A JP3690892B2 (en) | 1996-12-26 | 1996-12-26 | Adhesive tape or sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34873496A JP3690892B2 (en) | 1996-12-26 | 1996-12-26 | Adhesive tape or sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10183078A true JPH10183078A (en) | 1998-07-07 |
| JP3690892B2 JP3690892B2 (en) | 2005-08-31 |
Family
ID=18399014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP34873496A Expired - Fee Related JP3690892B2 (en) | 1996-12-26 | 1996-12-26 | Adhesive tape or sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3690892B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003064152A1 (en) * | 2002-01-30 | 2003-08-07 | Mitsubishi Polyester Film Corporation | Release film |
| JP2004360156A (en) * | 2003-05-12 | 2004-12-24 | Lintec Corp | Adhesive paper tape |
| JP2006182878A (en) * | 2004-12-27 | 2006-07-13 | Nitto Denko Corp | Extensible pressure-sensitive adhesive product |
| JP2008133435A (en) * | 2006-10-31 | 2008-06-12 | Nitto Denko Corp | Surface protective film and optical film with surface protective film |
| WO2012020673A1 (en) * | 2010-08-11 | 2012-02-16 | リンテック株式会社 | Peeling agent composition, peeling sheet, and adhesive body |
| JP2015030795A (en) * | 2013-08-02 | 2015-02-16 | 一方社油脂工業株式会社 | Release film manufacturing method and release film |
| WO2016136759A1 (en) * | 2015-02-24 | 2016-09-01 | リンテック株式会社 | Release agent composition, release sheet, single-faced adhesive sheet, and double-faced adhesive sheet |
-
1996
- 1996-12-26 JP JP34873496A patent/JP3690892B2/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003064152A1 (en) * | 2002-01-30 | 2003-08-07 | Mitsubishi Polyester Film Corporation | Release film |
| JP2004360156A (en) * | 2003-05-12 | 2004-12-24 | Lintec Corp | Adhesive paper tape |
| JP4514462B2 (en) * | 2003-05-12 | 2010-07-28 | リンテック株式会社 | Paper adhesive tape |
| JP2006182878A (en) * | 2004-12-27 | 2006-07-13 | Nitto Denko Corp | Extensible pressure-sensitive adhesive product |
| JP2008133435A (en) * | 2006-10-31 | 2008-06-12 | Nitto Denko Corp | Surface protective film and optical film with surface protective film |
| WO2012020673A1 (en) * | 2010-08-11 | 2012-02-16 | リンテック株式会社 | Peeling agent composition, peeling sheet, and adhesive body |
| JP5842309B2 (en) * | 2010-08-11 | 2016-01-13 | リンテック株式会社 | Release agent composition, release sheet and adhesive |
| JP2015030795A (en) * | 2013-08-02 | 2015-02-16 | 一方社油脂工業株式会社 | Release film manufacturing method and release film |
| WO2016136759A1 (en) * | 2015-02-24 | 2016-09-01 | リンテック株式会社 | Release agent composition, release sheet, single-faced adhesive sheet, and double-faced adhesive sheet |
| US20180029329A1 (en) * | 2015-02-24 | 2018-02-01 | Lintec Corporation | Release agent composition, release sheet, single-sided pressure-sensitive adhesive sheet and double-sided (faced) pressure-sensitive adhesive sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3690892B2 (en) | 2005-08-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0816462B1 (en) | Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheets made therefrom, and sealants, reinforcing sheets and pressure-sensitive adhesive sheets for printing produced therefrom | |
| EP0106559B1 (en) | Storable, crosslinkable, pressure-sensitive adhesive tape | |
| JP5509079B2 (en) | Adhesive sheet | |
| JP2002356662A (en) | Peelable pressure-sensitive adhesive composition and sheet | |
| US6093464A (en) | Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheets | |
| JP2001240830A (en) | Adhesive composition and surface protective film | |
| JP5415725B2 (en) | Adhesive sheet | |
| JPH10183078A (en) | Self-adhesive tape or sheet | |
| JP2008222953A (en) | Adhesive sheet | |
| JP3974684B2 (en) | Heat-peelable pressure-sensitive adhesive composition, heat-peelable pressure-sensitive adhesive product and method of use | |
| JP2000239632A (en) | Strongly-adherent strippable pressure-sensitive adhesive and pressure-sensitive adhesive tape | |
| JPH08333554A (en) | Tacky tape or film | |
| JPH11116927A (en) | Acrylic pressure-sensitive adhesive composition, pressure-sensitive adhesive tape, and formation of pressure-sensitive adhesive layer | |
| JP2003292911A (en) | Colored adhesive tape | |
| JPH06116536A (en) | Adhesive tape | |
| JPH11269439A (en) | High-adhesion re-releasable pressure-sensitive adhesive and high-adhesion re-releasable pressure-sensitive adhesive tape | |
| JPH06145611A (en) | Tape for fixing abrasive material | |
| JP2000303048A (en) | Adhesive composition for soft polyvinyl chloride use adhesive product and adhered product | |
| JPH073235A (en) | Tacky adhesive composition | |
| JPH10168399A (en) | Tacky sheets and fastening system using the same | |
| JPH11116931A (en) | Heat activation type pressure-sensitive adhesive composition and heat activation type pressure-sensitive adhesive tape | |
| JPS6232166A (en) | Adhesive for fabrication of foams | |
| JPH06172723A (en) | Nitrocellulose-based adherent | |
| JPH1046115A (en) | Pressure-sensitive acrylic adhesive tape or sheet | |
| JPH05331434A (en) | Tacky tape or sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20041222 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20050315 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20050607 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20050614 |
|
| R150 | Certificate of patent (=grant) or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080624 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110624 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140624 Year of fee payment: 9 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |