JPH10139671A - Production of calcareous ovolite powder and traumatic dermatitis improver, bathing agent and deodorizing agent - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a dermatitis improver for animals, bathing agent and spray deodorizing agent using Calcareous ovolite powder. SOLUTION: Calcareous ovolite is charged into a ball mill in which alumina ball baked at 1600 deg.C is put and the resultant powder of the stone is filtered with a filter having >=200 mesh while grinding the stone with a grinding stone and the powder is treated by heat having 100 deg.C to 200 deg.C at about two nights and two days to form fine powder or Calcareous ovolite is subjected to hot air treatment (at 85 deg.C to 95 deg.C) for one week and then, pulverized at a high rotation rate by a pulverizer and the powder is flied by air pressure to classify particle size and sieved by a net to provide fine powder having >=200mesh.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing processed barley stone powder, and to a deodorant / improving agent for animal trauma dermatitis and a bath agent using the same.

[0002]

2. Description of the Related Art Hitherto, there has been no suitable wound dermatitis / deodorant for animals, particularly pet animals such as dogs and cats. However, at present, there is also a demand for animals to develop products that satisfy various demands, similarly to humans. Also, regardless of animals and humans, there are demands for bath agents having high effects such as sterilization and skin improvement.

The present inventors have paid attention to the fact that barley rice is a mineral but exerts various effects, and through repeated research and devising a processing method, animals, particularly pet animals such as dogs and cats, have been developed. In this way, a product that is easy to use and a highly effective bathing agent for animals and humans have been completed.

[0004]

So far, the efficacy of barley rice has been attracting attention for a long time. However, research has been conducted on animals to study the safe, effective size, proportion, and heat treatment method for ingestion. There was no device that was easy to apply or spray.

[0005] The inventor has conducted various experiments and studies and obtained the following conclusions. Since natural stone has soil bacteria, it must be treated to prevent the effects of soil bacteria on animals. It is necessary that the size of the particles does not impair the texture. Since barley rice ingested into the body is subject to digestive action in various organs of the body, it is necessary that the size and processing of the particles are appropriate. Ingenuity is required to bring out the deodorizing effect. When applying to animal skin, it is necessary to select an application method that does not hinder animal hair growing on the skin surface

[0006] In order to satisfy the above requirements, the present inventor first conducted research on barley stone itself, and obtained the following results. Barite is a type of granite porphyry, and the granite porphyry itself is a silicate mineral composed of quartz, alkali feldspar, mica and the like.

[0007] In the barite, part of the silicate mineral in the granite porphyry is converted to CO ₃ by natural hot water or carbon dioxide CO _2.
^It is transformed into a carbonate mineral containing ^2- ions and elutes. In the case of barite, part of the phenocrysts has been altered to calcite CaCO ₃ , a carbonate mineral. In other words, this is called "carbonation", and the geological definition is that "carbon dioxide dissociated from limestone works together with a hot water solution under low-metamorphic conditions to convert silicate minerals into calcite. -Replaced by carbonate minerals such as dolomite and siderite. " (Thus, carbonate minerals foam in dilute hydrochloric acid).

[0008] It is presumed that such a carbonation was carried out because a spring that had springed underground infiltrated and was immersed in the porphyry. Therefore, it is necessary that the barley stone used in the present application has always undergone carbonation.

Next, Table 1 shows an analysis table of barley stone, and Table 2 shows an analysis table of barite concentrate obtained during the production of barley feed by the wet method.
Shown in Table 3 shows the results of the adsorption test of barley stone on Escherichia coli. Tables 4 and 5 show the results of the adsorption test of barley stone on harmful substances.

[0010]

[Table 1]

[0011]

[Table 2]

[0012]

[Table 3]

[0013]

[Table 4]

[0014]

[Table 5]

From these analysis results, it can be seen that the barley stone and the barite concentrate concentrate contain a large amount of calcium, sodium, potassium and phosphate ions. (1) Calcium and phosphorus 70% or more of the minerals in the animal body consist of Ca and P, but both are closely related to nutrition.

About 99% of Ca and about 80% of P in the body are present in bones and teeth. Normally developed bone contains about 45% water, about 25% minerals, about 20% protein, and about 10% fat. The Ca content of mammalian minerals is about 36%, P is about 17%, Mg is about 0%. 0.8%. In general, the majority of bone minerals are composed of hydroxyapatite (hydrozyapatite,
3Ca ₃ (PO ₄ ) ₂ .Ca (OH) ₂ ). C other than those present in bones and teeth
Although a and P are widely distributed in various organs and tissues, most of the latter constitute an organic compound and play important functions.

[0017] Ca and P, together with Mg, are essential for the normal development of bones and teeth. Ca is hardly present in blood cells, but serum of various livestock is 9-12% in 100 ml.
mg of Ca, of which more than 60% is phosphate,
It is a bicarbonate, present in ionic form, which has an inhibitory effect on nerve stimulus sensitivity and is essential for blood coagulation and muscle contraction and relaxation. P is a component of nucleic acids, ATP, phospholipids and the like, and is indispensable for various phosphorylation reactions, and plays a large role in regulating the pH of body fluids as inorganic ions.

Typical Ca or P deficiencies are rickets in growing animals and osteomalacia in grown animals. The former is not only inhibited by normal bone development, but also enlarges the epiphysis and degenerates the bone. It is likely to occur in puppies, calves, piglets, wrinkles, etc., all of which stop growing and deform due to bone deformation. The latter have a reduced mineral content, and thus strength, in the grown bone and are more likely to occur during pregnancy and lactation.

The deficiency described in the preceding paragraph is a typical symptom that occurs when Ca or P nutrition is not appropriate.
For proper nutrition of Ca and P, sufficient supply of Ca and P respectively, that the ratio of Ca: P does not deviate much from 2-1: 1, and that vitamin D is present. It is important that the three conditions are satisfied.

(2) Sodium and potassium Most of these are present in body fluids and soft tissues.
Maintaining osmotic pressure and pH, regulating the transfer of nutrients into cells,
It also plays an important role in water metabolism. The amount of these inorganic elements stored in the body is limited, so it is necessary to take them every day.However, excessive intake leads to rapid excretion, and when intake is low, excretion is reduced. Has some adaptability to hold them properly. Nutritional problems are unlikely, as the required amount can be easily met and the harm from overdose is limited to special cases. Deficiency in any of these inorganic elements reduces appetite and growth, and decreases body weight and production.

Most of Na is present in extracellular fluid and most of K is present in intracellular fluid. Na is hardly found in blood cells,
Although 93% of the base in serum is Na, the K content of blood cells is as high as 20 times that of plasma. Although Na is considerably abundant in muscle, K reaches 6 times that of Na, and although its mechanism is unknown, it is thought to play a very important role in muscle activity, as well as in nerve activity . K
Both salts and Na salts are easily absorbed and excreted mainly in urine as chlorides and phosphates.

Therefore, it can be presumed that the barley stone powder and the barley stone concentrate have a good effect on animals by containing a large amount of these minerals. In addition, the results of the adsorption test of barley rice on Escherichia coli and harmful substances showed that the ability to remove Escherichia coli and harmful substances was very high.

[0023] In general, when barley stone, its powder, or extract is used, why it will last for a long time and why bacteria will be adsorbed. In this regard, the following can be considered.

The aluminosilicates (feldspar) contained in the barite have a chemical structure such as KAlSi ₃ O ₈ , NaAlSi ₃ O _8, or CaAl ₂ Si ₂ O ₈ , in which SiO ₂ silicate is a regular face of SiO ₄ It is already known that the body (FIG. 1) has a three-dimensionally arranged three-dimensional structure. Then, it is considered that aluminum is partially inserted into the structure as shown in FIG. 2 by receiving the coordination of the lawn pair from the bridge-like oxygen atom. It is considered that magnesium, calcium, sodium, and potassium are bonded to the terminal of the structure as shown in FIG.

[0025]

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The bond between Mg, Ca, Na and K and oxygen is ionic and ionizes little by little when barley stone is placed in water, and a radical --SiO is formed at the end of the structure.

[0027]

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The presence of the —SiO 2 ^— radical is clearly recognized in the infrared spectrum of barley stone. It is believed that the released -SiO ^- is involved not only in the adsorption of iron ions and mercury ions, but also in the adsorption of pigments and bacteria.
That is, the adsorption of Fe ³⁺ , Hg ²⁺ , and the like is a result of bonding with —SiO ⁻ , as shown in the following equation.

[0029]

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It can be considered that the adsorption of a dye or bacteria is caused by a bond between a positively charged nitrogen atom in a dye molecule and a similarly positively charged nitrogen atom in a bacterial protein. Especially in bacteria, the countless number of cells
N ⁺ - and the number of -SiO of barley Stones ^- binding and occurs over and over again, appears to be appear as an adsorption phenomenon to capture the cells. Furthermore, feldspars of barite are extremely porous due to weathering and dissolution, and have -Si compared to ordinary feldspars.
O ^- radicals are highly increased, would indicate a significant adsorption.

[0031]

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The above-mentioned hypothetical explanation can also be understood from the above-mentioned hypothetical explanation that the more the barley stone is made into fine powder, the more the ion elution and adsorption action increase. In other words, it is presumed that the free radical of —SiO in the barley stone takes in a nitrogen atom into the combined bond, thereby suppressing the activity of bacteria and the like.

[0033]

SUMMARY OF THE INVENTION In order to effectively incorporate the above-mentioned effects of barley stone into animals, the method for producing barley meal feed of the present invention is a ball mill containing alumina balls fired at 1600 ° C. After adding the barley stone and polishing it with a whetstone together with water, strain it with 200 mesh or more, treat it with heat of 100 ° C. to 200 ° C. over about two days and nights to make fine powder and Hot air treatment for one week (8
(5 ° C to 95 ° C), put it in a crusher, rotate at high speed with a spiral steel propeller, pulverize the barley stone, blow off the powder by wind pressure, classify the particle size and sieve with a net, sieve 200 mesh or more The gist is to make a fine powder of

Further, 20
An animal trauma dermatitis ameliorating agent containing 1 to 20% kneaded stone powder of 0 mesh or more kneaded with water,
Bath additive used by adding 5 to 20 g to liter,
Finally, concentrate the concentrate obtained at the time of manufacturing barley powder
The present invention provides a spray deodorant containing about 100%.

[0035]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention is applied to skin trauma, adheres to the body by taking a bath, and is sprayed in a spray form.
After treatment with hot air at ~ 95 ° C or straining,
It is first necessary to sterilize soil bacteria by treating with heat at ~ 200 ° C.

Next, there are two methods for making barley stone powder, one of which is a wet method, in which barley stone and water are put into a mill and mixed together. When the liquid becomes muddy, 2
Powders can be formed by drying the strainer with a fine mesh of 00 mesh or more. The strained liquid at this time becomes a concentrated concentrate of barley rice.

Another method is a dry method, in which barley stone is pulverized with a helical propeller at a high-speed rotating pulverizer, blown off by wind pressure, classified in particle size and sieved to obtain an appropriate size.

A creamy form containing kneaded stone powder in water and containing 1 to 20% is effective in improving trauma and dermatitis, and is not applied directly to the skin, but is applied to hot water. It is also effective to dissolve and use it as a bath agent to improve dermatitis. Further, a spray containing 10 to 100% is effective in providing a deodorizing effect. As a method of application, it is also possible to spray a maltstone concentrate in a spray form to improve trauma and dermatitis.

[0039]

EXAMPLES Examples 1 to 4 will be described below together with their data. [Example 1] Barley stone was made into 325 mesh powder by a wet method. That is, the same amount of maltstone is put into a ball mill containing alumina ceramic balls fired at 1600 ° C. and polished with a grindstone together with 10 liters of water. At a place where some particles are formed, strain with a 325 mesh strainer.
The operation of heat sterilization at 00 ° C. was continued for two days and nights, and then dried to produce a powder having a size of 325 mesh. This powder is kneaded with water filtered with barley stone, and the barley rice feed is 0.8 ~
An agent for improving animal trauma dermatitis containing 30% was produced.
This was applied to a pet (three dogs) having dermatitis for one week, and the progress was observed.

[0040]

[Table 8]

In each case, the reddish color began to appear from the second day, and the stiffness was improved. It seems that the sterilization effect of barley stone worked. The effect was observed at a barite content of 1 to 20%, and at 30%, symptoms such as a rough applied skin surface were observed.

[Example 2] Barley stone was added for 90 days to 90 days.
Perform hot air sterilization at ℃. Next, this barley stone is crushed by high-speed rotation with a crusher having a spiral steel propeller, and the powder is blown off by wind pressure to classify the particle size. The particle size was adjusted by a method using a pulverizer, and sieved with a net to obtain a fine powder of 250 mesh.

10 g of this barley rice powder was added to hot water 1 at about 30 ° C.
After dissolving in 00 liters, the dog with dermatitis was bathed there and the condition of the skin was observed. The progress up to one week is shown in Table 7 below.

[0044]

[Table 7]

As is clear from the table, it was found that, as shown in Example 3, the effect of the barley rice powder was not only applied directly to the skin but also used as a bath agent. Since barley stone also has a bactericidal action as described above,
If you use this bath as a shampoo substitute, it will also eliminate dermatitis and will not cause shampoo rash at all,
A favorable environmental condition for the animal can be maintained.

Example 3 The concentration of the concentrated solution obtained in Example 1 was changed to produce spray deodorants A to E, and the results were sprayed on pet dogs and cats 4 to 5 times a day. It is shown in Table 10.

[0047]

[Table 8]

A remarkable effect was observed with a concentrated liquid spray of 10% to 100% due to the adsorption ability of barley stone. In addition, although the above examples were conducted especially for pets (dogs and cats), this feed is applicable to all animals such as rabbits, birds, turtles, etc. Experiments have revealed that various effects can be obtained even by simply providing strained water as a drink.

[0049]

As described above, the barley rice powder of the present invention is treated safely against soil by heat treatment at the time of cutting out from the rough or after crushing. is there. In addition, there is no difference in the effect of powdering by either dry or wet method, there is no difference in dermatitis, bath agent,
It is effective for deodorization, especially for feces.

Claims (5)

[Claims] 1. A bar mill containing alumina balls fired at 1600 ° C. is charged with malt stone, and sieved with a whetstone with water, and strained with a mesh of 200 mesh or more. A method for producing barley rice powder, which is treated with heat at 200 ° C. to obtain a fine powder. 2. After heating the barnstone for one week with hot air, the barnstone is crushed by high-speed rotation with a crusher, and the powder is blown off by wind pressure to classify the particle size. A method for producing barley rice powder. 3. A method according to claim 1 or claim 2, wherein
An animal trauma dermatitis ameliorating agent containing 1 to 20% of a wool stone powder of 00 mesh or more kneaded with water. 4. A method according to claim 1 or claim 2, wherein
A bath additive characterized by adding 5 to 20 g of barley rice powder having a size of 00 mesh or more to 200 liters of hot water. 5. A spray deodorant containing 10 to 100% of a concentrate obtained when producing barley rice powder by the method according to claim 1.