JPH10106547A - Battery electrode plate and its manufacture - Google Patents

Battery electrode plate and its manufacture

Info

Publication number
JPH10106547A
JPH10106547A JP9248373A JP24837397A JPH10106547A JP H10106547 A JPH10106547 A JP H10106547A JP 9248373 A JP9248373 A JP 9248373A JP 24837397 A JP24837397 A JP 24837397A JP H10106547 A JPH10106547 A JP H10106547A
Authority
JP
Japan
Prior art keywords
active material
electrode plate
plate
battery
current collector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP9248373A
Other languages
Japanese (ja)
Inventor
Tetsuu Ryu
哲雨 劉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Samsung SDI Co Ltd
Original Assignee
Samsung Electron Devices Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung Electron Devices Co Ltd filed Critical Samsung Electron Devices Co Ltd
Publication of JPH10106547A publication Critical patent/JPH10106547A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/24Electrodes for alkaline accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/24Electrodes for alkaline accumulators
    • H01M4/26Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/34Gastight accumulators
    • H01M10/345Gastight metal hydride accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0404Methods of deposition of the material by coating on electrode collectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/043Processes of manufacture in general involving compressing or compaction
    • H01M4/0435Rolling or calendering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0471Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an electrode plate of battery with prolonged lifetime and offer a method for manufacturing such electrode plate with which occurrence of electric shortcircuiting is prevented and the charging efficiency of the battery is enhanced by eliminating the risk of separation of an active material applied to the side face of the edge of each electrode plate. SOLUTION: An active material 22 in viscous liquid state is applied to an electricity collecting plate 21 of a matel material, followed by drying, press rolling, and cutting, and an adhesive substance 23 such as polyvinyl alcohol is applied for preventing separation of the active material 22 from the side face of the edge of each electrode plate where the bonding power is weak relatively because of cutting. Thereby the active material applied to the electrode plate is precluded from separation.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は電池の極板及びその
製造方法に係り、さらに詳細には極板の縁部に塗布され
た活物質の離脱を防止し得るように接着層を有する電池
の極板及びその製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a battery electrode plate and a method of manufacturing the same, and more particularly, to a battery electrode having an adhesive layer so as to prevent the active material applied to the edge of the electrode plate from coming off. The present invention relates to an electrode plate and a method for manufacturing the same.

【0002】[0002]

【従来の技術】図2を参照すると、一般の電池は円筒形
ケース1と、前記ケース1の内部に設けられる充電要素
2と、前記ケース1を密封するキャップ3とを具備す
る。
2. Description of the Related Art Referring to FIG. 2, a general battery includes a cylindrical case 1, a charging element 2 provided inside the case 1, and a cap 3 for sealing the case 1.

【0003】前記充電要素2は陽極の活物質が塗布され
た陽極板2a、陰極の活物質が塗布された陰極板2c及
び陽極板2aと陰極板2cを相互絶縁させるためにその
間に介在される仕切板2bを含む。
The charging element 2 is interposed between the anode plate 2a coated with an anode active material, the cathode plate 2c coated with a cathode active material, and the anode plate 2a and the cathode plate 2c for mutual insulation. Including the partition plate 2b.

【0004】この陽極板2a、仕切板2b及び陰極板2
cは、順次に積層された後、ロール状に巻かれてケース
1の内に設けられ、キャップ3によってケース1の開口
が密封される。
The anode plate 2a, the partition plate 2b and the cathode plate 2
After the layers c are sequentially stacked, they are wound into a roll and provided in the case 1, and the opening of the case 1 is sealed by the cap 3.

【0005】電池の構成要素である前記陽極板2a及び
陰極板2c( 以下、極板と総称する) は金属素材に異種
の活物質を塗布することによってなる。
The anode plate 2a and the cathode plate 2c (hereinafter, collectively referred to as "electrodes"), which are components of the battery, are formed by applying a different kind of active material to a metal material.

【0006】図3に示した従来の極板10は金属素材の
集電プレート11と、前記集電プレート11に塗布され
た活物質層12よりなる。
The conventional electrode plate 10 shown in FIG. 3 includes a current collecting plate 11 made of a metal material and an active material layer 12 applied to the current collecting plate 11.

【0007】このような構造の極板10の製造工程にお
いて、まず気孔を有した金属素材の集電プレート11を
粘液状態の活物質に浸して活物質層12を形成させた
後、乾燥、圧延及び切断工程を通じて望む規格の極板1
0を製造する。
In the manufacturing process of the electrode plate 10 having such a structure, first, a current collector plate 11 made of a metal material having pores is immersed in an active material in a mucus state to form an active material layer 12, which is then dried and rolled. And electrode plate 1 of desired standard through cutting process
0 is produced.

【0008】前記集電プレート11に塗布される活物質
は、電池の充放電に寄与する活性材料と、その活性材料
同士間の接着力を向上させるために混合された接着剤を
含む。
The active material applied to the current collecting plate 11 includes an active material that contributes to charging and discharging of the battery, and an adhesive mixed to improve the adhesive force between the active materials.

【0009】ここで、実際に電気的な充放電に寄与する
活性材料の混合比が接着剤の混合比より相対的に高いほ
ど充電効率が増大される。前記活物質は集電プレート1
1に塗布された後、圧延過程を通じて薄板状に圧出され
る時、集電プレート11から離脱されない程度の範囲内
でその混合比が決定される。
Here, the charging efficiency increases as the mixing ratio of the active material that actually contributes to the electrical charging and discharging is relatively higher than the mixing ratio of the adhesive. The active material is a current collector plate 1
When it is applied to No. 1 and then extruded into a thin plate through a rolling process, its mixing ratio is determined within a range that does not separate from the current collecting plate 11.

【0010】しかし、ケースの大きさによって前記極板
10を望む大きさに切断する過程で、切断面及び切断面
近くの活物質は容易に離脱したり、その接着力が他の部
分に対して相対的に弱まる傾向がある。さらに、各々異
なる活物質が塗布された陽極板2a( 図2)と陰極板2
cを切断して製作した後、前記両極板10の間に仕切板
2bを介在させてロール状に巻く時、極板10に塗布さ
れた活物質層12は隣接した仕切板及び極板との圧着力
によって剪断力を受け、このような剪断力は極板10の
縁部側面で最も著しい。従って、両極板10の縁部切断
面から活物質が離脱しやすく、離脱された活物質が両極
板10を電気的に短絡させるという問題点があった。
However, in the process of cutting the electrode plate 10 into a desired size according to the size of the case, the cut surface and the active material near the cut surface are easily detached, and the adhesive strength of the active material to other parts is reduced. They tend to weaken relatively. Further, an anode plate 2a (FIG. 2) and a cathode plate 2 each coated with a different active material.
c, after cutting, the active material layer 12 applied to the electrode plate 10 is wound between the two electrode plates 10 with a partition plate 2b interposed between the two electrode plates 10 and rolled into a roll. A shear force is applied by the crimping force, and such a shear force is most remarkable on the edge side surface of the electrode plate 10. Therefore, there is a problem that the active material is easily detached from the edge cut surface of the bipolar plate 10 and the detached active material causes an electrical short circuit between the bipolar plates 10.

【0011】このように活物質の離脱によって引き起こ
される電気的な短絡は充電効率を低下させ、且つ電池の
寿命を縮める。
The electric short circuit caused by the detachment of the active material reduces the charging efficiency and shortens the life of the battery.

【0012】[0012]

【発明が解決しようとする課題】本発明は前記のごとき
従来の問題点に鑑みてなされたもので、極板の縁部の側
面に塗布された活物質の離脱を防止することによって電
気的な短絡を防止し、電池の充電効率を向上させ、寿命
を延ばすことのできる電池の極板及びその製造方法を提
供することにその目的がある。
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned conventional problems, and is intended to prevent the active material applied to the side surface of the edge portion of the electrode plate from coming off, thereby preventing the electric material from coming off. It is an object of the present invention to provide a battery electrode plate capable of preventing a short circuit, improving the charging efficiency of the battery, and extending the life, and a method for manufacturing the same.

【0013】[0013]

【課題を解決するための手段】前記目的を達成するため
に本発明による電池の極板は、気孔の形成された金属素
材よりなる集電プレートと、前記集電プレートに塗布さ
れた活物質層と、前記集電プレート縁部の側面に塗布さ
れて活物質の離脱を防止する接着層とを含むことを特徴
とする。
In order to achieve the above object, an electrode plate of a battery according to the present invention comprises a current collector plate made of a metal material having pores, and an active material layer applied to the current collector plate. And an adhesive layer applied to the side surface of the edge portion of the current collecting plate to prevent the active material from separating.

【0014】また、前記の目的を達成するために本発明
による電池の極板製造方法は、気孔の形成された金属素
材の集電プレートに粘液状の活物質を塗布して活物質層
を形成させる段階と、前記活物質が前記集電プレートに
固着されるように乾燥させる段階と、前記活物質の塗布
された前記集電プレートを所定の厚さに圧延させる圧延
段階と、前記集電プレートを所定の幅と長さに切断する
段階と、前記切断された極板の縁部側面に塗布された活
物質層の上に前記活物質の離脱を防止するために接着物
質を塗布する段階と、前記極板を巻いて充電要素を形成
する段階を含むことを特徴とする。
According to another aspect of the present invention, there is provided a method for manufacturing an electrode plate for a battery, comprising forming an active material layer by applying a viscous liquid active material to a current collector plate made of a metal material having pores. And d) drying the active material so that the active material is fixed to the current collecting plate; rolling the current collecting plate coated with the active material to a predetermined thickness; Cutting to a predetermined width and length, and applying an adhesive material on the active material layer applied to the edge side surface of the cut electrode plate to prevent the active material from separating. And winding the electrode plate to form a charging element.

【0015】[0015]

【発明の実施の形態】以下、添付した図面に基づいて本
発明の望ましい実施形態を説明する。
Preferred embodiments of the present invention will be described below with reference to the accompanying drawings.

【0016】図1を参照すれば、本発明による電池の極
板20は気孔を有する金属素材の集電プレート21、前
記集電プレート21の上に塗布された活物質層22及び
集電プレート21の縁部側面上に塗布された活物質層2
2の上に塗布された接着層23を含む。
Referring to FIG. 1, an electrode plate 20 of a battery according to the present invention includes a current collecting plate 21 made of a metal material having pores, an active material layer 22 coated on the current collecting plate 21, and a current collecting plate 21. Active material layer 2 applied on the side surface of the edge
2 includes an adhesive layer 23 applied thereon.

【0017】前記接着層23は集電プレート21の縁部
側面に塗布された活物質の離脱を防止するために塗布さ
れ、接着力の強い物質であることが望ましい。本実施形
態ではポリビニールアルコール(PVA:polyvinyl alcoho
l) を活物質層22に塗布させることによって活物質の
接着力を増大させた。
The adhesive layer 23 is applied to prevent the active material applied on the side surface of the edge of the current collector plate 21 from coming off, and is preferably a material having a strong adhesive force. In the present embodiment, polyvinyl alcohol (PVA: polyvinyl alcoho
l) was applied to the active material layer 22 to increase the adhesive strength of the active material.

【0018】以上のような構造を有する本発明の極板2
0の製造において、まずニッケル−水素電池またはニッ
ケル−メタルハライド電池などのような電池の種類によ
って、気孔を有する金属素材よりなる集電プレート21
を形成する。
The electrode plate 2 of the present invention having the above structure
In the manufacture of the battery 21, first, depending on the type of a battery such as a nickel-metal hydride battery or a nickel-metal halide battery, the current collecting plate 21 made of a metal material having pores is used.
To form

【0019】次に、前記集電プレート21に水分の含ま
れた粘液状の活物質を塗布して活物質層22を形成す
る。
Next, an active material layer 22 is formed by applying a viscous active material containing water to the current collecting plate 21.

【0020】次に、活物質の塗布された集電プレート2
1を乾燥器に通過させることによって、活物質層22に
含まれている水分を蒸発させ、それによる収縮力によっ
て活物質を集電プレート21に固着させる。
Next, a current collecting plate 2 coated with an active material
By passing 1 through a dryer, the moisture contained in the active material layer 22 is evaporated, and the active material is fixed to the current collecting plate 21 by the shrinkage force thereby.

【0021】次に、プレスによって極板20を所定の厚
さに圧延させた後、充電容量を考慮して一定の大きさで
切断する。
Next, after the electrode plate 20 is rolled to a predetermined thickness by a press, the electrode plate 20 is cut into a predetermined size in consideration of the charging capacity.

【0022】次に、切断された極板20を並行に積層し
た後、極板20の縁部側面にポリビニールアルコールの
ような接着層23を塗布する。このような接着層23は
極板20の縁部側面に塗布された活物質層22に吸着さ
れて活物質の相互結合力を増大させる。
Next, after the cut electrode plates 20 are stacked in parallel, an adhesive layer 23 such as polyvinyl alcohol is applied to the side surface of the edge of the electrode plate 20. Such an adhesive layer 23 is adsorbed by the active material layer 22 applied to the side surface of the edge of the electrode plate 20 to increase the mutual bonding force of the active material.

【0023】次に、仕切板2bの介在された陽極板2a
( 図2参照) と陰極板2cをロール状に巻く。この時、
極板20の縁部側面には剪断力が集中されるが、縁部側
面に塗布された接着層23によって活物質層22が維持
されることによって、活物質の離脱が防止される。前記
ロール状に巻かれた充電要素は電池ケースの内部空間の
約95%程度を占める体積とすることが望ましい。
Next, the anode plate 2a with the partition plate 2b interposed
(See FIG. 2) and the cathode plate 2c are wound into a roll. At this time,
Although the shearing force is concentrated on the side surface of the edge of the electrode plate 20, the active material layer 22 is maintained by the adhesive layer 23 applied to the side surface of the electrode, thereby preventing the active material from being detached. Preferably, the charging element wound in a roll shape has a volume occupying about 95% of the internal space of the battery case.

【0024】[0024]

【発明の効果】以上説明したように本発明によれば、製
造された極板をロール状に巻くためのワィンディング工
程で極板に塗布された活物質の離脱が防止されて電池の
電気的な短絡が防止され、よって電池の充電効率を向上
し、且つ寿命も延びるという効果を奏する。
As described above, according to the present invention, the active material applied to the electrode plate is prevented from being separated in the winding step for winding the manufactured electrode plate into a roll shape, and the electric power of the battery is prevented. The short circuit is prevented, and thus, the charging efficiency of the battery is improved, and the life is extended.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施形態にともなう電池の極板を概略
的に図示した部分切開斜視図。
FIG. 1 is a partially cutaway perspective view schematically illustrating an electrode plate of a battery according to an embodiment of the present invention.

【図2】一般の電池の概略的な分離斜視図。FIG. 2 is a schematic exploded perspective view of a general battery.

【図3】図2の電池に採用された従来の極板を概略的に
示した部分切開斜視図。
FIG. 3 is a partially cutaway perspective view schematically illustrating a conventional electrode plate employed in the battery of FIG. 2;

【符号の説明】[Explanation of symbols]

20 電池の極板 21 集電プレート 22 活物質層 23 接着層 Reference Signs List 20 Battery plate 21 Current collecting plate 22 Active material layer 23 Adhesive layer

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 気孔の形成された金属素材からなる集電
プレートと、 前記集電プレートに塗布された活物質層と、 前記集電プレートの縁部側面に塗布された前記活物質層
上に塗布されて活物質の離脱を防止する接着層を含むこ
とを特徴とする電池の極板。
A current collector plate made of a metal material having pores; an active material layer applied to the current collector plate; and an active material layer applied to an edge of the current collector plate. An electrode plate for a battery, comprising an adhesive layer which is applied to prevent the active material from separating.
【請求項2】 前記接着層はポリビニールアルコールよ
りなることを特徴とする請求項1に記載の電池の極板。
2. The electrode plate according to claim 1, wherein the adhesive layer is made of polyvinyl alcohol.
【請求項3】 気孔の形成された金属素材の集電プレー
トに粘液状態の活物質を塗布して活物質層を形成させる
段階と、 前記活物質が前記集電プレートに固着されるように乾燥
させる段階と、 前記活物質の塗布された前記集電プレートを所定の厚さ
に圧延させる圧延段階と、 前記集電プレートを所定の幅と長さに切断する段階と、 前記切断された極板の縁部側面に塗布された活物質層の
上に前記活物質の離脱を防止するために接着物質を塗布
する段階と、 前記極板を巻いて充電要素を形成する段階と、 を含むことを特徴とする電池の極板製造方法。
3. A step of applying an active material in a mucus state to a current collector plate of a metal material having pores to form an active material layer, and drying the active material so that the active material is fixed to the current collector plate. Rolling the current collector plate coated with the active material to a predetermined thickness; cutting the current collector plate to a predetermined width and length; and the cut electrode plate Applying an adhesive material on the active material layer applied to the side surface of the edge to prevent detachment of the active material, and winding the electrode plate to form a charging element. A method of manufacturing a battery electrode plate.
【請求項4】 前記接着物質はポリビニールアルコール
であることを特徴とする請求項3に記載の電池の極板製
造方法。
4. The method of claim 3, wherein the adhesive is polyvinyl alcohol.
JP9248373A 1996-09-20 1997-09-12 Battery electrode plate and its manufacture Withdrawn JPH10106547A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1996-41378 1996-09-20
KR1019960041378A KR19980022276A (en) 1996-09-20 1996-09-20 Battery plate and its manufacturing method

Publications (1)

Publication Number Publication Date
JPH10106547A true JPH10106547A (en) 1998-04-24

Family

ID=19474674

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9248373A Withdrawn JPH10106547A (en) 1996-09-20 1997-09-12 Battery electrode plate and its manufacture

Country Status (2)

Country Link
JP (1) JPH10106547A (en)
KR (1) KR19980022276A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999025039A1 (en) * 1997-11-10 1999-05-20 Nippon Zeon Co., Ltd. Binder containing vinyl alcohol polymer, slurry, electrode, and secondary battery with nonaqueous electrolyte

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100428976B1 (en) * 2001-11-15 2004-04-29 삼성에스디아이 주식회사 Electrode for lithium secondary battery and manufacturing method thereof
KR100800969B1 (en) * 2006-01-18 2008-02-11 주식회사 엘지화학 Electrode Material Containing Polyvinyl Alcohol as Binder and Rechargeable Lithium Battery Comprising the Same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999025039A1 (en) * 1997-11-10 1999-05-20 Nippon Zeon Co., Ltd. Binder containing vinyl alcohol polymer, slurry, electrode, and secondary battery with nonaqueous electrolyte

Also Published As

Publication number Publication date
MX9707092A (en) 1998-03-31
KR19980022276A (en) 1998-07-06

Similar Documents

Publication Publication Date Title
JP4825344B2 (en) Battery / capacitor composite element
JP2695684B2 (en) Wound electrode assembly for electrochemical cell
JPH09298057A (en) Lithium ion battery
JPH0888019A (en) Sealed storage battery
JP2000299133A (en) Manufacture of rectangular lithium secondary battery
JPH09134726A (en) Collector of electrochemical element, and manufacture of electrochemical element and collector of electrochemical element
US5045415A (en) Electrode plate structure
JPH09147834A (en) Battery
JPH10275751A (en) Electric double layer capacitor and its manufacture
JP4590723B2 (en) Winding electrode battery and method for manufacturing the same
US6180285B1 (en) Exposed conductive core battery
JPH10106547A (en) Battery electrode plate and its manufacture
GB2080999A (en) Dry cell and process for producing same
US3261715A (en) Negative electrode assembly for alkaline batteries
EP0465475A4 (en) Improved electrode plate structure
US4572879A (en) Lead-acid cell and method of producing same
CN1179016A (en) Electrode plate of battery and its producing method
JPH04206468A (en) Sealed alkali-zinc storage battery
JPH11111274A (en) Lead-acid battery
JPH0785885A (en) Rectangular battery
CN218975471U (en) Battery cell pole piece, battery cell and battery
JPH10199502A (en) Separator and battery using the same
JP3402628B2 (en) Organic electrolyte battery
RU2098892C1 (en) Combined electrode for alkali storage battery
JPH066462Y2 (en) Non-aqueous electrolyte battery

Legal Events

Date Code Title Description
A300 Application deemed to be withdrawn because no request for examination was validly filed

Free format text: JAPANESE INTERMEDIATE CODE: A300

Effective date: 20041207