JPH0994438A - Dipping type production of purified water and device therefor - Google Patents
Dipping type production of purified water and device thereforInfo
- Publication number
- JPH0994438A JPH0994438A JP25282395A JP25282395A JPH0994438A JP H0994438 A JPH0994438 A JP H0994438A JP 25282395 A JP25282395 A JP 25282395A JP 25282395 A JP25282395 A JP 25282395A JP H0994438 A JPH0994438 A JP H0994438A
- Authority
- JP
- Japan
- Prior art keywords
- water
- reverse osmosis
- permeated water
- permeated
- osmosis membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、各種有機物やイオン類
を含んだ河川水、湖沼水、地下水または海水等の原水か
ら、逆浸透膜等の膜分離により、電気などの人工動力源
を用いることなく、洗浄用途や飲料用途に使用できる浄
水を製造する浸漬式浄水製造方法及びその装置に関す
る。より詳しくは、電源や水道がない場所や、電源のな
い戸外や、台風・地震等の災害が起こった後に、電源や
水道が一時的に停止するような場所であっても、任意の
時に浄水が安全かつ容易に製造できる浸漬式浄水製造方
法及びその装置に関する。TECHNICAL FIELD The present invention uses an artificial power source such as electricity from a raw water such as river water, lake water, groundwater or seawater containing various organic substances and ions by membrane separation such as reverse osmosis membrane. TECHNICAL FIELD The present invention relates to an immersion water purification method and apparatus for producing purified water that can be used for cleaning applications and beverage applications without the need. More specifically, even if there is no power supply or water supply, or if there is no power supply outside, or if the power supply or water supply is temporarily stopped after a disaster such as a typhoon or an earthquake, water purification can be performed at any time. The present invention relates to a method and an apparatus for manufacturing immersion-type purified water that can be manufactured safely and easily.
【0002】[0002]
【従来の技術】各種有機物やイオン類を含んだ河川水、
湖沼水、地下水または海水等の原水から、洗浄用途や飲
料用途に使用できる浄水を製造するには、含まれる各種
有機物やイオン類を所定濃度まで低減する必要がある。
浄水を製造する技術には、従来、上水技術で知られる通
り、砂濾過法、凝集沈殿法、塩素消毒法、活性炭吸着法
等の方法があり、それらを組合せたシステムとして各地
の浄水場で使用されている。2. Description of the Related Art River water containing various organic substances and ions,
In order to produce purified water that can be used for cleaning and drinking from raw water such as lake water, groundwater, or seawater, it is necessary to reduce various organic substances and ions contained in the purified water to predetermined concentrations.
Conventional water purification technologies include sand filtration, coagulation sedimentation, chlorination, and activated carbon adsorption, as known in the water supply technology. It is used.
【0003】最近の高分子技術の進歩に伴い、各種の分
離膜を利用して浄水を得る装置が普及し始めた。分離膜
には限外濾過膜や逆浸透膜があり、限外濾過膜は専ら水
中の微小な塵埃や大腸菌等を除去するために使われ、逆
浸透膜は専ら水中に溶解している各種有機物やイオン類
を除去するために使われる。With recent advances in polymer technology, devices for obtaining purified water using various separation membranes have become popular. Separation membranes include ultrafiltration membranes and reverse osmosis membranes.Ultrafiltration membranes are used exclusively to remove minute dust, Escherichia coli, etc. in water, and reverse osmosis membranes are all organic substances dissolved in water. And used to remove ions.
【0004】分離膜技術は、上述の従来技術に比べ、小
さなスペースで比較的大容量の水を処理することがで
き、将来的に装置の増設が簡単にできる利点がある。The separation membrane technology has an advantage that it can treat a relatively large volume of water in a small space as compared with the above-mentioned conventional technology, and can easily add an apparatus in the future.
【0005】上記分離膜技術では、取り扱う水質や動力
源の種類により、ある程度の用途分けがなされている。
原水水質がよい水道水等を対象とする場合は1〜4Kg/
cm2G程度の水圧だけで濾過できる限外濾過膜が使用され
るが、比較的原水水質が悪い浄水場では、5Kg/cm2G以
上の高圧を発生させる大きな動力を要する逆浸透膜が使
用されている。In the above-mentioned separation membrane technology, there are some uses depending on the quality of water to be handled and the type of power source.
1-4 kg / kg for tap water with good raw water quality
An ultrafiltration membrane that can be filtered with only a water pressure of about 2 cm is used, but a reverse osmosis membrane that requires a large power to generate a high pressure of 5 kg / cm 2 G or more is used at a water purification plant with relatively poor raw water quality. Have been.
【0006】各種有機物やイオン類を含んだ河川水、湖
沼水、地下水または海水等は比較的原水水質が悪いの
で、逆浸透膜が使用されている。従って、上記の原水か
ら洗浄用途や飲料用途に使用できる浄水を製造するに
は、電気などの人工動力源がある場合はモーター駆動の
高圧ポンプを用い、電気などの人工動力源が無い場合は
高圧操作の可能な手動式ポンプや、エンジンポンプなど
の戸外動力源を利用した高圧ポンプを用いることが一般
的である。Reverse osmosis membranes are used because river water, lake water, ground water, sea water and the like containing various organic substances and ions have relatively poor raw water quality. Therefore, in order to produce purified water that can be used for cleaning and drinking from the above raw water, use a motor-driven high-pressure pump if there is an artificial power source such as electricity, or use high pressure if there is no artificial power source such as electricity. It is common to use an operable manual pump or a high-pressure pump that uses an outdoor power source such as an engine pump.
【0007】[0007]
【発明が解決しようとする課題】ところが、水上や海上
の場合は陸上の場合と異なり、逆浸透膜の装置一式を設
置する場所の確保が困難な場合が多く、人工動力源が設
置されていることも少ない。そのために、水上や海上の
場合は簡易に浄水を得ることができないため、陸上で得
られた浄水を運搬しなければならなかった。However, unlike the case of land, it is often difficult to secure a place to install the reverse osmosis membrane device on water or sea, and an artificial power source is installed. There are few things. Therefore, because it is not possible to obtain purified water easily on water or on the sea, it was necessary to transport the purified water obtained on land.
【0008】本発明の目的は、前記従来技術の問題を解
決するためになされたものであって、各種有機物やイオ
ン類を含んだ河川水、湖沼水、地下水または海水等の原
水から、逆浸透膜の膜分離により、電気などの人工動力
源を用いることなく、また加圧用のポンプ機器を用いる
ことなく、洗浄用途や飲料用途に使用できる浄水を任意
の時に安全にかつ容易に製造できる浸漬式浄水製造方法
及びその装置を提供することにある。The object of the present invention is to solve the above-mentioned problems of the prior art, and reverse osmosis is performed from raw water such as river water, lake water, ground water or sea water containing various organic substances and ions. Immersion type that can safely and easily produce purified water that can be used for cleaning applications and beverage applications at any time without using an artificial power source such as electricity and without using a pumping device for pressurization due to membrane separation of the membrane It is to provide a purified water manufacturing method and an apparatus thereof.
【0009】[0009]
【課題を解決するための手段】本発明の浸漬式浄水製造
方法は、原水を逆浸透膜分離器へ供給して、逆浸透膜に
おいて濃縮水と透過水とに分離して浄水を得る浄水製造
方法において、逆浸透膜分離器を浸透圧以上の水圧がか
かる水深に沈め、該逆浸透膜分離器の透過水側と大気と
を連通させ、透過水受器に透過水を貯溜し、その後水面
まで引き上げて透過水を回収する構成である。また、本
発明の浸漬式浄水製造装置は、逆浸透膜分離器から透過
水を導出する導出路と、該導出路に配設される透過水受
器と、該逆浸透膜分離器と該透過水受器との間の該導出
路に配設される逆止弁と、該透過水受器と大気とを連通
する連通管と、該連通管は該逆浸透膜分離器を浸透圧以
上の水圧がかかる水深に沈める長さを有してなる構成で
ある。In the immersion type purified water production method of the present invention, raw water is supplied to a reverse osmosis membrane separator to obtain purified water by separating concentrated water and permeated water in the reverse osmosis membrane. In the method, the reverse osmosis membrane separator is submerged to a water depth above the osmotic pressure, the permeate side of the reverse osmosis membrane separator and the atmosphere are communicated with each other, and the permeated water is stored in a permeate receiver, and then the water surface. It is configured to collect the permeated water by pulling it up to. Further, the immersion water purifying apparatus of the present invention comprises a lead-out path for leading out permeated water from the reverse osmosis membrane separator, a permeated water receiver arranged in the lead-out path, the reverse osmosis membrane separator and the permeate. A check valve arranged in the outlet passage between the water receiver and a communication pipe for communicating the permeated water receiver with the atmosphere; and the communication pipe for connecting the reverse osmosis membrane separator to an osmotic pressure or more. It is configured to have a length that allows it to be submerged under water pressure.
【0010】[0010]
【発明の実施の形態】以下、図面を参照しつつ本発明の
実施の形態を説明する。図1は、本発明において使用す
る浸漬式浄水製造装置の一例を示す説明図である。図1
において、原水10は、浸透圧以上の水圧がかかる水深
に沈められた逆浸透膜分離器1の耐圧容器1Aに供給さ
れ、耐圧容器1A内の逆浸透膜1Bでは、各種有機物やイオ
ン類が除去されて水質が向上した透過水14と、逆に各
種有機物やイオン類が濃縮されて水質が低下した濃縮水
13とに分離される。透過水14は、導出路1Cを通り逆
止弁6の順方向を通過して透過水受器3に貯留される。
連通管5は上記透過水受器3と大気とが連通するもので
あって、結果的には逆浸透膜分離器1と大気とが連通す
るものである。該連通管5は該逆浸透膜分離器1を浸透
圧以上の水圧がかかる水深に沈める長さを有する。手元
弁4は該連通管5の大気側即ち水面側に配管される。BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is an explanatory view showing an example of the immersion type water purifying apparatus used in the present invention. FIG.
In the above, the raw water 10 is supplied to the pressure resistant container 1A of the reverse osmosis membrane separator 1 which is submerged in a water depth where a water pressure higher than the osmotic pressure is applied, and various organic substances and ions are removed in the reverse osmosis membrane 1B in the pressure resistant container 1A. Thus, the permeated water 14 having improved water quality and, conversely, the concentrated water 13 in which various organic substances and ions are concentrated and the water quality is reduced are separated. The permeated water 14 passes through the outlet passage 1C, passes through the check valve 6 in the forward direction, and is stored in the permeated water receiver 3.
The communication pipe 5 connects the permeated water receiver 3 and the atmosphere, and consequently the reverse osmosis membrane separator 1 and the atmosphere. The communication pipe 5 has a length such that the reverse osmosis membrane separator 1 is submerged in a water depth to which a water pressure higher than the osmotic pressure is applied. The hand valve 4 is arranged on the atmosphere side of the communication pipe 5, that is, on the water surface side.
【0011】本発明で処理する原水は、各種有機物やイ
オン類を含んだ河川水、湖沼水、地下水または海水等で
あって、洗浄用途や飲料用途にそのままでは使用できな
い水を用いる。また、洗浄用途や飲料用途にそのままで
使用できるが、さらに浄化度を高める場合にも用いるこ
とができる。The raw water to be treated in the present invention is river water, lake water, ground water, seawater or the like containing various organic substances and ions, and water that cannot be used as it is for cleaning or drinking is used. Further, although it can be used as it is for cleaning applications and beverage applications, it can also be used for further enhancing the degree of purification.
【0012】分離手段としての逆浸透膜分離器1は、低
圧操作であっても高除去率と高透過流束を有する分離膜
を搭載することが好ましく、例えば、日東電工 (株) 製
のポリアミド系逆浸透複合膜が適している。分離膜のモ
ジュール型式は、中空糸型やスパイラル型が用いられる
が、モジュ−ルの着脱作業が容易でメインテナンスが簡
単にできるスパイラル型が好ましく用いられる。逆浸透
膜1Bの材質は特に限定されるものではないが、ポリアミ
ド系逆浸透複合膜が好ましく用いられる。The reverse osmosis membrane separator 1 as a separating means is preferably equipped with a separation membrane having a high removal rate and a high permeation flux even under a low pressure operation. For example, polyamide manufactured by Nitto Denko KK System reverse osmosis composite membranes are suitable. As the module type of the separation membrane, a hollow fiber type or a spiral type is used, but a spiral type that can easily attach and detach the module and can be easily maintained is preferably used. The material of the reverse osmosis membrane 1B is not particularly limited, but a polyamide-based reverse osmosis composite membrane is preferably used.
【0013】耐圧容器1Aと透過水受器3は水圧に耐えら
れる耐圧材料であれば特に限定されないが、金属材料で
あるSUS316L,SUS316,SUS304Lや
SUS304などのステンレス鋼が好ましく用いられ
る。The pressure vessel 1A and the permeated water receiver 3 are not particularly limited as long as they are pressure resistant materials that can withstand water pressure, but stainless steel such as metal materials SUS316L, SUS316, SUS304L and SUS304 are preferably used.
【0014】逆止弁6と手元弁4の材質や型式について
は特に限定されるものではないが、腐食が少ないSUS
316ステンレス製で、逆止弁6はリフト式逆止弁が、
手元弁4はボール弁が、好ましく用いられる。The materials and models of the check valve 6 and the hand valve 4 are not particularly limited, but SUS which is less corrosive.
Made of 316 stainless steel, the check valve 6 is a lift type check valve,
The hand valve 4 is preferably a ball valve.
【0015】連通管5の材質は水圧に耐えられる耐圧材
料であれば特に限定されないが、ポリプロピレン製やポ
リエチレン製のフレキシブルなチューブが好ましく用い
られる。The material of the communication pipe 5 is not particularly limited as long as it is a pressure resistant material capable of withstanding water pressure, but a flexible tube made of polypropylene or polyethylene is preferably used.
【0016】本発明に係る浸漬式浄水製造方法により原
水を分離して浄水を得るには、図1に示すように、逆浸
透膜分離器1を浸透圧以上の水圧がかかる水深に沈めて
から連通管5の水面上にある手元弁4を開くと、該水深
下の該逆浸透膜分離器1の耐圧容器1A内の逆浸透膜1
Bを透過した透過水が透過水受器3に貯留される。同時
に該透過水受器3に入っていた空気が連通管5を通って
大気側へ排出される。該透過水受器3に貯留される透過
水は逆止弁6が作動するので該透過水受器3から逆浸透
膜分離器1への逆流はない。該逆浸透膜分離器1への原
水供給の流れを発生させ、逆浸透膜1Bの膜面上の汚れ
を除去し、逆浸透膜1Bの性能を維持するために、上記
原水を分離中に該逆浸透膜分離器1を上下あるいは左右
に運動させることが好ましい。具体的には支持ロープ1
1をたとえば2m程引き上げた後に、同じ長さを下ろす
ことを繰り返すことによって達成できる。あるいは船上
であれば、船を運行することによっても達成できる。透
過水を回収するには、逆浸透膜分離器1や透過水受器3
などに接続した支持ロープ11を少なくとも透過水受器
3が水面上にあがるまで引き上げることにより達成され
る。上記の運転により、原水10から所望の浄水を得る
ことが出来る。In order to obtain the purified water by separating the raw water by the immersion type purified water manufacturing method according to the present invention, as shown in FIG. 1, the reverse osmosis membrane separator 1 is submerged in a water depth to which a water pressure higher than the osmotic pressure is applied. When the hand valve 4 on the water surface of the communication pipe 5 is opened, the reverse osmosis membrane 1 in the pressure resistant container 1A of the reverse osmosis membrane separator 1 under the water depth is opened.
The permeated water that has permeated B is stored in the permeated water receiver 3. At the same time, the air contained in the permeated water receiver 3 is discharged to the atmosphere side through the communication pipe 5. Since the check valve 6 operates, the permeated water stored in the permeated water receiver 3 does not flow back from the permeated water receiver 3 to the reverse osmosis membrane separator 1. In order to generate a flow of raw water supply to the reverse osmosis membrane separator 1, remove dirt on the membrane surface of the reverse osmosis membrane 1B, and maintain the performance of the reverse osmosis membrane 1B, the raw water is separated during the separation. It is preferable to move the reverse osmosis membrane separator 1 vertically or horizontally. Specifically, support rope 1
This can be achieved by repeatedly pulling up 1 for about 2 m and then lowering the same length. Alternatively, if it is on board, it can be achieved by operating the ship. To collect permeated water, reverse osmosis membrane separator 1 and permeated water receiver 3
This is achieved by pulling up the support rope 11 connected to, for example, at least until the permeated water receiver 3 rises above the water surface. By the above operation, desired purified water can be obtained from the raw water 10.
【0017】[0017]
〔実施例1〕次に実施例1に基づき更に本発明を具体的
かつ詳細に説明する。図1において、原水10として、
滋賀県近江八幡市付近の琵琶湖の湖水を用いた。逆浸透
膜1Bとして、日東電工(株)社製逆浸透膜(NTR−
759HR−S2、膜面積1.7m2)をスパイラル型膜モ
ジュールとして用い、耐圧容器1Aとして、日東電工
(株)社製のSUS316製シェル1本を使用した。手
元弁4として、15AのSUS316製ボールバルブを
用い、逆止弁6として、SUS316製リフト式逆止弁
を用いた。透過水受器3として、SUS316製の円筒
形1L容器を用い、連通管5として、口径6mm のポ
リプロピレン製耐圧チューブを用いた。水深は50m程
度とし、該水深に対して±2mの上下運動を1分間あた
り10回の回数で行った。約5分間継続したのち、材質
ポリエチレン製の支持ロープ11を用いて逆浸透膜分離
器1と透過水受器3など一式を水面上に引き上げ、1L
の透過水を回収した。上記の運転により、原水10と得
られた透過水の水質を分析したところ、該透過水は浄水
として十分に満足できるものであった。種々の測定結果
を表1に示した。[Embodiment 1] Next, the present invention will be described in more detail with reference to Embodiment 1. In FIG. 1, as raw water 10,
Water from Lake Biwa near Omihachiman City, Shiga Prefecture was used. As the reverse osmosis membrane 1B, a reverse osmosis membrane (NTR- manufactured by Nitto Denko Corporation) is used.
759HR-S2, membrane area 1.7 m 2 ) was used as a spiral wound type membrane module, and one SUS316 shell manufactured by Nitto Denko KK was used as a pressure resistant container 1A. A 15A SUS316 ball valve was used as the hand valve 4, and a SUS316 lift type check valve was used as the check valve 6. A cylindrical 1 L container made of SUS316 was used as the permeated water receiver 3, and a polypropylene pressure-resistant tube having a diameter of 6 mm was used as the communication pipe 5. The water depth was about 50 m, and up and down movements of ± 2 m with respect to the water depth were performed 10 times per minute. After continuing for about 5 minutes, the set such as the reverse osmosis membrane separator 1 and the permeated water receiver 3 was pulled up to the surface of the water by using the support rope 11 made of polyethylene, and 1L
Permeate was collected. When the raw water 10 and the quality of the permeated water obtained by the above operation were analyzed, the permeated water was sufficiently satisfactory as purified water. Various measurement results are shown in Table 1.
【表1】 [Table 1]
【0018】[0018]
【発明の効果】本発明によれば、各種有機物やイオン類
を含んだ河川水、湖沼水、地下水または海水等の原水か
ら、逆浸透膜の膜分離により、手動式ポンプを用いるの
で電気などの人工動力源を用いることなく、洗浄用途や
飲料用途に使用できる浄化水を任意の時に安全にかつ容
易に製造できる。また、非透過側の濃縮水の処理を管理
することなく使用できるので、該管理を怠ることによる
逆浸透膜の透過性能や耐久性の低下を招くことはない。EFFECTS OF THE INVENTION According to the present invention, since a manual pump is used by membrane separation of a reverse osmosis membrane from raw water such as river water, lake water, groundwater or seawater containing various organic substances and ions, it is possible to reduce electricity consumption. It is possible to safely and easily produce purified water that can be used for cleaning applications and beverage applications at any time without using an artificial power source. Further, since the treatment of the concentrated water on the non-permeate side can be used without controlling, the permeation performance and durability of the reverse osmosis membrane will not be deteriorated by neglecting the control.
【図1】本発明において使用する手動式逆浸透膜浄水器
の一例を示す説明図である。FIG. 1 is an explanatory view showing an example of a manual reverse osmosis membrane water purifier used in the present invention.
1 逆浸透膜分離器 1A 耐圧容器 1B 逆浸透膜 3 透過水受器 4 手元弁 5 連通管 6 逆止弁 11 支持ロープ 1 Reverse Osmosis Membrane Separator 1A Pressure Resistant Container 1B Reverse Osmosis Membrane 3 Permeate Water Receiver 4 Hand Valve 5 Communication Tube 6 Check Valve 11 Support Rope
Claims (2)
透膜において濃縮水と透過水とに分離して浄水を得る浄
水製造方法において、逆浸透膜分離器を浸透圧以上の水
圧がかかる水深に沈め、該逆浸透膜分離器の透過水側と
大気とを連通させ、透過水受器に透過水を貯溜し、その
後水面まで引き上げて透過水を回収することを特徴とす
る浸漬式浄水製造方法。1. A method for producing purified water in which raw water is supplied to a reverse osmosis membrane separator to separate concentrated water and permeated water in the reverse osmosis membrane to obtain purified water. Immersion characterized in that the permeated water is submerged in such a depth that the permeated water side of the reverse osmosis membrane separator communicates with the atmosphere, the permeated water is stored in the permeated water receiver, and then the permeated water is pulled up to the water surface to recover the permeated water Water purification method.
出路と、該導出路に配設される透過水受器と、該逆浸透
膜分離器と該透過水受器との間の該導出路に配設される
逆止弁と、該透過水受器と大気とを連通する連通管と、
該連通管は該逆浸透膜分離器を浸透圧以上の水圧がかか
る水深に沈める長さを有してなることを特徴とする浸漬
式浄水製造装置。2. A lead-out path for leading out permeated water from the reverse osmosis membrane separator, a permeated water receiver arranged in the lead-out path, and between the reverse osmosis membrane separator and the permeated water receiver. A check valve arranged in the outlet passage, and a communication pipe for communicating the permeated water receiver with the atmosphere,
The immersion pipe water purification apparatus, wherein the communication pipe has a length such that the reverse osmosis membrane separator is submerged in a water depth to which a water pressure equal to or higher than an osmotic pressure is applied.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25282395A JPH0994438A (en) | 1995-09-29 | 1995-09-29 | Dipping type production of purified water and device therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25282395A JPH0994438A (en) | 1995-09-29 | 1995-09-29 | Dipping type production of purified water and device therefor |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0994438A true JPH0994438A (en) | 1997-04-08 |
Family
ID=17242712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25282395A Pending JPH0994438A (en) | 1995-09-29 | 1995-09-29 | Dipping type production of purified water and device therefor |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0994438A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2125630A1 (en) * | 2007-02-14 | 2009-12-02 | DXV Water Technologies, Llc | Depth exposed membrane for water extraction |
JP2013240776A (en) * | 2012-05-21 | 2013-12-05 | Isao Kato | Apparatus for collecting fresh water from seawater |
US10513446B2 (en) | 2014-10-10 | 2019-12-24 | EcoDesal, LLC | Depth exposed membrane for water extraction |
-
1995
- 1995-09-29 JP JP25282395A patent/JPH0994438A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2125630A1 (en) * | 2007-02-14 | 2009-12-02 | DXV Water Technologies, Llc | Depth exposed membrane for water extraction |
EP2125630A4 (en) * | 2007-02-14 | 2011-10-05 | Dxv Water Technologies Llc | Depth exposed membrane for water extraction |
JP2013240776A (en) * | 2012-05-21 | 2013-12-05 | Isao Kato | Apparatus for collecting fresh water from seawater |
US10513446B2 (en) | 2014-10-10 | 2019-12-24 | EcoDesal, LLC | Depth exposed membrane for water extraction |
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