JPH0965837A - Oolite feed, its production, injury and dermatitis-improving agent, bathing agent, deodorant - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a feed for pet animals, useful for the supply of minerals, deodorization, the increase of hair luster, the elimination of stress, the prevention of obesity, an intestinal state-normalizing action, and the improvement of dermatitis. SOLUTION: Oolite is charged in a ball mill in which alumina balls sintered at 1600 deg.C are charged, ground with both water and grinding stones and simultaneously filtered with a >=200 mesh sieve. The obtained fine powder is thermally sterilized at 100-200 deg.C approximately over two days and two nights. Or, the oolite is sterilized with hot air for a week (at 85-95 deg.C) and subsequently ground with a grinder rotated at a high speed. The produced powder is classified into plural particle sizes with the pressure of a wind, and subsequently filtered with a sieve to give fine powder having particle sizes of >=200 meshes.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a feed containing processed barley stone, a method for producing the same, a deodorant / traumatic dermatitis improving agent and a bath salt.

[0002]

2. Description of the Related Art Conventionally, with regard to the production of feed for animals, particularly pet animals such as dogs and cats, emphasis has been placed only on nutrition and bite, stress reduction and reduction of intestinal bacteria, mineral supplementation, There was no demand for disease prevention, dermatitis improvement, and even deodorant effect. But even for animals,
At present, there is a demand for the development of products that satisfy various demands as well as for humans.

The inventors of the present invention have paid attention to the fact that bourhanite has various effects, although it is a mineral, and have conducted extensive research to devise a processing method to make animals, particularly pet animals such as dogs and cats. We have completed a product that is easy to use.

[0004]

So far, the efficacy of barley rice has been attracting attention for a long time. However, research has been conducted on animals to study the safe, effective size, proportion, and heat treatment method for ingestion. There was no device that was easy to apply or spray.

Therefore, the present inventor has conducted various experiments and studies and has come to the following conclusions. Since natural stones carry soil fungi, it is necessary to treat natural stones to prevent them from affecting animals. It is necessary that the size of the particles does not impair the texture. Since boiled stone ingested by the body is digested by each organ of the body, it is necessary that the particle size and treatment be appropriate. Ingenuity is required to bring out the deodorizing effect. When applying to animal skin, it is necessary to select an application method that does not hinder animal hair growing on the skin surface

In order to satisfy the above-mentioned requirements, the present inventor first conducted a study on bakuhanishi itself and obtained the following results. Bakuhanite is a kind of granite porphyry, and the granite porphyry itself is a silicate mineral composed of quartz, alkali feldspar, and mica.

[0007] In bakuhanishi, a part of the silicate mineral in the granite porphyry is converted into CO ₃ by natural hot water or carbon dioxide CO _2.
^It is a carbonate mineral that contains ^2- ions and is melted out. In the case of barite, a part of the phenocryst feldspar is transformed into calcite CaCO ₃ which is a carbonate mineral. In other words, this is called "carbonation". As a geological definition, "carbon dioxide gas dissociated from limestone acts together with hot aqueous solution under low-metamorphic conditions, so that silicate minerals become calcite.・ To be replaced by carbonate minerals such as dolomite and siderite. ” (For this reason, carbonate minerals foam in dilute hydrochloric acid).

It is speculated that such carbonation was carried out because a mineral spring that had springed underground underground permeated and immersed in this porphyry. Therefore, it is necessary that the barley stone used in the present application is always subjected to carbonation.

[0009] Next, Table 1 shows the analysis table of barley stone, and Table 2 shows the analysis table of the concentrated solution of barite stone obtained during the production of barley stone feed by the wet method.
Shown in Table 3 shows the results of the adsorption test of bakuhanishi on E. coli. Further, Tables 4 and 5 show the results of the adsorption test of bakuhanishi on harmful substances.

[0010]

[Table 1]

[0011]

[Table 2]

[0012]

[Table 3]

[0013]

[Table 4]

[0014]

[Table 5]

From these analysis results, it can be seen that barley stone and barley stone concentrated liquid contain a large amount of calcium, sodium, potassium and phosphate ions. (1) About Calcium and Phosphorus 70% or more of the minerals of the animal body consist of Ca and P, but both are closely related nutritionally.

About 99% of Ca and about 80% of P in the body are present in bones and teeth. Normally developed bone contains about 45% water, about 25% minerals, about 20% protein and about 10% fat, and the Ca content of mammalian minerals is about 36%, P is about 17%, Mg is about 0%. 0.8%. Generally, most of the bone minerals are hydroxyzymapatite,
It is considered to exist in the form of 3Ca ₃ (PO ₄ ) ₂ · Ca (OH) ₂ . C other than those present in bones and teeth
Although a and P are widely distributed in various organs and tissues, most of the latter constitute organic compounds and perform important functions.

Ca and P together with Mg are indispensable for normal bone and tooth development. Ca is almost absent in blood cells, but serum of various domestic animals is 9-12 in 100 ml.
Contains mg of Ca, 60% or more of which is phosphate,
It is a bicarbonate and exists in the ionic form, which suppressively acts on nerve sensitivities and is essential for blood coagulation and muscle contraction and relaxation. P is essential as a component of nucleic acids, ATP, phospholipids, and in various phosphorylation reactions, and plays a major role in adjusting the pH of body fluid as an inorganic ion.

The Ca or P deficiency is typically rickets in growing animals and osteomala in growing animals. The former is not only inhibited by normal bone development, but also the epiphyses are enlarged and bones are degenerated. It easily occurs in puppies, calves, piglets, wrinkles, etc., all of which stop growing and cause malformations due to bone deformation. The latter reduces the mineral content and thus strength of grown bone and is more likely to occur during pregnancy and lactation.

The deficiency described in the preceding paragraph is a typical symptom that occurs when Ca or P nutrition is not appropriate.
For proper nutrition of Ca and P, Ca and P should be well supplied, Ca: P ratio should not deviate from 2-1: 1, and vitamin D should be present. It is important that the three conditions are met.

(2) Sodium and potassium Most of these are present in body fluids and soft tissues,
Maintenance of osmotic pressure and pH, regulation of nutrient transfer into cells,
It also plays an important role in water metabolism. The amount of these inorganic elements stored in the body is limited, so it is necessary to take them daily. Has some adaptability to keep them properly. It is unlikely that nutritional problems will occur because the required amount can be easily met, and the harm of excessive intake is limited to special cases. Deficiency of any of these inorganic elements reduces appetite and growth, and reduces body weight and production.

Most of Na is present in extracellular fluid and most of K is present in intracellular fluid. There is almost no Na in blood cells,
Although 93% of the base in serum is Na, the K content of blood cells reaches 20 times that in plasma. Na is considerably abundant in muscle, but K reaches up to 6 times that of Na, and although its mechanism is unknown, it is thought to play an extremely important role in muscle activity, and also in nerve activity. . K
Both salt and Na salt are easily absorbed and excreted mainly in urine as chlorides and phosphates.

Therefore, it can be inferred that the boiled stone powder and the boiled stone concentrated solution have a good effect on animals by containing a large amount of these minerals. In addition, the adsorption test results of Bakuhanishi for E. coli and harmful substances revealed that the removal ability of E. coli and harmful substances was very high.

[0023] In general, when using barley stone, its powder or extract, why it lasts longer and why bacteria are adsorbed. Regarding this point, the following can be considered.

The aluminosilicates (feldspars) contained in barite are chemical structures such as KAlSi ₃ O ₈ , NaAlSi ₃ O ₈ or CaAl ₂ Si ₂ O ₈ , in which the silicic acid SiO ₂ is tetrahedral of SiO ₄ . It is already known that the body (FIG. 1) has a three-dimensionally arranged three-dimensional structure. It is considered that aluminum is inserted into a part of the structure as shown in FIG. 2 by being coordinated with a loan pair from the bridge oxygen atom. In addition, it is considered that magnesium, calcium, sodium and potassium are bound to the ends of the structure as shown in FIG.

[0025]

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The bond between Mg, Ca, Na and K and oxygen is ionic bond, and when barite stone is placed in water, it is gradually ionized to form a radical --SiO at the end of the structure.

[0027]

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[0028] This -SiO ^- the presence of the radical is apparently also observed in the infrared spectrum of Elvan. It is considered that the liberated --SiO 2 ^- is involved in the adsorption of iron ions, mercury ions, etc. as well as the adsorption of pigments and bacteria.
That is, the adsorption of Fe ³⁺ , Hg ²⁺ , etc. is the result of the bond with —SiO 2 ⁻ , as shown in the following equation.

[0029]

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Further, it can be considered that the adsorption of the dye or the bacterium is caused by the bond between the + -charged nitrogen atom in the dye molecule and the similarly + -charged nitrogen atom in the bacterial protein. Especially in bacteria, the myriad of cells have
It is considered that N ⁺ − and a large number of —SiO ^{− in} the bakuhanishi are bound to each other in multiple layers and appear as an adsorption phenomenon for catching the bacterial cells. In addition, the feldspar of bakuhanseki becomes extremely porous due to weathering and dissolution, and is -Si more than ordinary feldspar.
It is considered that the O ⁻ radicals are greatly increased and show a remarkable adsorption action.

[0031]

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It can also be understood from the above-mentioned hypothetical explanation that the finer the powder of barley stone, the more the ion elution and adsorption action increase. In other words, it is speculated that the -SiO free radicals in barley stone incorporate a nitrogen atom into the accumulated bonds, thereby suppressing the activity of bacteria and the like.

[0033]

[Means for Solving the Problems] In order to effectively incorporate the above-mentioned effects of barley stone into animals, the method for manufacturing the barley stone feed of the present invention is a ball mill containing alumina balls baked at 1600 ° C. While pouring boiled rice stones and polishing with a whetstone together with water, strain it with 200 mesh or more, and sterilize it with heat of 100 ° C to 200 ° C for about 2 days and nights to obtain fine powder and boiled rice stones. Hot air sterilization for 1 week (8
(5 ℃ ~ 95 ℃), put it in a crusher, rotate at high speed with a spiral steel propeller, crush the barley stone, then blow the powder by wind pressure, classify the particle size and sieve with a mesh 200 mesh or more The main point is to use fine powder of.

Further, the barley stone feed of the present invention is a barley stone feed of 200 mesh or more produced by these methods, a barley stone containing animal feed containing 1 to 20% of the barley stone feed, and further a barley stone feed with water. Animal traumatic dermatitis improving agent containing 1 to 20% of kneading, bath salt used by adding 5 to 20 g of barley stone feed to 200 liters of hot water, and finally concentrated liquid obtained when producing barley stone feed 10 to 1
A spray-type deodorant containing 100% is provided.

[0035]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention is added to animal feed,
Since it is taken up into the body of an animal or applied to skin trauma, first, the quarry barley stone is sterilized with hot air at 85 ° C to 95 ° C or strained, and then sterilized with heat at 100 ° C to 200 ° C, so that the soil fungus is sterilized. It is first necessary to sterilize.

Next, there are two methods for making the size suitable for animal feed, one is wet, and boiled stone and water are put in a mill and co-sold. When it becomes a muddy liquid, it can be made into powder by drying it after filtering it with a fine mesh of 200 mesh or more. The strained liquid at this time becomes a barley stone concentrate.

Another method is a dry method, in which barley stone is crushed by a crusher rotating at high speed with a spiral propeller, blown by wind pressure, and the particle size is classified and sieved to obtain an appropriate size.
The addition ratio to animal feed is preferably 1 to 20%. This is because if the amount is less than 1%, the effect is not recognized so much, and if it exceeds 20%, the animal does not like the texture and taste.

A creamy product prepared by kneading barley stone powder with water in an amount of 1 to 20% is effective in improving wounds and dermatitis, and is not applied directly to the skin, but the barley stone powder is hot water. It is also effective to dissolve in water and be used as a bathing agent to improve dermatitis. Further, a spray containing 10 to 100% is effective in providing a deodorizing effect. As a method of application, it is also possible to spray a maltstone concentrate in a spray form to improve trauma and dermatitis.

[0039]

EXAMPLES Examples 1 to 4 will be described below together with their data. [Example 1] Barley stone was made into 325 mesh powder by a wet method. That is, the same amount of maltstone is put into a ball mill containing alumina ceramic balls fired at 1600 ° C. and polished with a grindstone together with 10 liters of water. At a place where some particles are formed, strain with a 325 mesh strainer.
The operation of heat sterilization at 00 ° C. was continued for two days and nights, and then dried to produce a powder having a size of 325 mesh. Table 6 shows the average of the results of feeding this powder to the supplementary feed of pet dogs (maltese and 5 others) at various rates for 3 months.

[0040]

[Table 6]

From this experiment, it can be seen that since boiled stone has no taste and is in a powder state, the addition ratio to the feed must be 20% or less in the sense that the biting is not deteriorated. In addition, the effect of intestinal regulation, reduction of fecal odor, improvement of hair gloss, improvement of stress, and antioxidant of feed are 1%.
Permitted at addition rates of ~ 20%. Specifically, the weight of one cow is 50 g, and the weight of one pig is about 10 g.

Example 2 This powder was applied to 2 cats (10).
Table 7 shows the average of the results of giving different sizes over a period of months.

[0043]

[Table 7]

From the above results, it can be seen that if the mesh size is 200 mesh or more, it can be given to pets without any problem in texture. In terms of the effect, no difference is observed depending on the particle size, but if it is 500 mesh or more, it is not preferable because scattering during manufacture and loss due to adhesion become very large and handling becomes difficult. Therefore,
200-500 mesh is suitable in terms of texture and handling.

[Example 3] The barley stone feed produced in Example 1 was kneaded with water filtered with barley stone to give a barley stone feed of 0.8 to
An agent for improving animal trauma dermatitis containing 30% was produced.
This was applied to a pet (three dogs) having dermatitis for one week, and the progress was observed.

[0046]

[Table 8]

In each case, the reddishness disappeared from around the second day, and the slumpy condition was improved. It seems that the sterilization effect of barley stone worked. The effect was observed at a barite content of 1 to 20%, and at 30%, symptoms such as a rough applied skin surface were observed.

[Example 4] 90% of boiled stone for one week
Perform hot air sterilization at ℃. Next, the barley stone was crushed by rotating at high speed with a crusher having a spiral steel propeller, and the powder was blown by wind pressure to classify the particle size and sieved with a net to obtain a fine powder of 250 mesh.

10 g of this boiled stone powder is added to hot water 1 at about 30 ° C.
After dissolving in 00 liters, the dog with dermatitis was bathed there and the condition of the skin was observed. The progress up to 1 week is shown in Table 9 below.

[0050]

[Table 9]

As is clear from the table, it has been found that the barley stone powder has an effect not only when it is directly applied to the skin as shown in Example 3 but also when it is used as a bathing agent. Since barley stone also has a bactericidal action as described above,
If you use this bath as a shampoo substitute, it will also eliminate dermatitis and will not cause shampoo rash at all,
Environmental conditions favorable for animals can be maintained.

Example 5 The concentration of the concentrated liquid obtained in Example 1 was changed to produce spray deodorants A to E, and the results were obtained by spraying pet dogs and cats 4 to 5 times a day. It shows in Table 10.

[0053]

[Table 10]

A remarkable effect was observed in a concentrated liquid spray of 10% to 100% due to the adsorption capacity of barley stone. In addition, although the above examples were conducted especially for pets (dogs and cats), this feed is applicable to all animals such as rabbits, birds, turtles, etc. Experiments have revealed that various effects can be obtained even by simply providing strained water as a drink.

[0055]

As described above, the barley stone feed of the present invention is treated safely with no problems even if it is ingested into the animal body because it is treated with soil bacteria by heat treatment at the time of cutting from the rough stone or after crushing. is there. In addition, there is no difference in the effect of powdering by either dry or wet method, and the size is suitable for appetite and digestion in the body, hair gloss, intestinal action, stress relief, obesity prevention, appetite reduction prevention, dermatitis improvement , Effective for deodorizing feces.

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[Procedure amendment]

[Submission date] August 31, 1995

[Procedure amendment 1]

[Document name to be amended] Statement

[Correction target item name] Brief description of drawings

[Correction method] Added

[Correction contents]

[Brief description of drawings]

FIG. 1 is a cubic tetrahedral cubic three-dimensional structure diagram of SiO ₄ .

FIG. 2 is a diagram showing a state of aluminum atoms in aluminosilicates.

[Procedure amendment 2]

[Document name to be amended] Drawing

[Correction target item name] Fig. 1

[Correction method] Added

[Correction contents]

FIG.

[Procedure 3]

[Document name to be amended] Drawing

[Correction target item name] Figure 2

[Correction method] Added

[Correction contents]

[Fig. 2]

Continuation of the front page (51) Int.Cl. ⁶ Identification code Office reference number FI Technical display area A61L 9/01 A61L 9/01 RB

Claims (7)

[Claims] 1. A ball mill containing alumina balls fired at 1600 ° C. is charged with barley stone, and while being polished with a grindstone together with water, strained with 200 mesh or more, and then at about 100 ° C. for about 2 days and nights. A method of producing a barley stone feed, which comprises sterilizing with heat of 200 ° C. to obtain fine powder. 2. Boiled stone is sterilized with hot air for 1 week (85 ° C. to 95 ° C.).
℃), crushed the barley stone at high speed with a crusher, blasted the powder with wind pressure to classify the particle size, and sieved with a net 200
A method for producing a barley stone feed, which comprises using a fine powder of a mesh or more. 3. A product produced by the method according to claim 1 or 2.
A powdered barley rice stone feed of 00 mesh or more. 4. 1 to 20% of the barley rice stone feed according to claim 3.
An animal feed containing boiled stone. 5. The kneaded stone feed according to claim 3 is kneaded with water 1
An agent for improving traumatic dermatitis for animals, which comprises ˜20%. 6. A bath salt, characterized in that 5 to 20 g of the barley rice stone feed according to claim 3 is added to 200 liters of hot water. 7. A spray-type deodorant containing 10 to 100% of the concentrate obtained when producing a barley stone feed by the method according to claim 1.