JPH0948710A - Lip stick composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a lip stick composition in which both smooth feeling in use and secondary adherence property are improved by compounding a mixture consisting of a volatile oil component and a nonvolatile oil component with a water repellent polymer together with powder having specific particle diameters. SOLUTION: This composition is obtained by compounding a volatile oil component, a water repellent polymer, powder (capable of being covered with the polymer in a state where the volatile oil component is absent) and a nonvolatile coil component (compatible with the volatile oil component). The powder contains at least large diameter particles and ultra fine particles. The particle diameters of ultra fine particles are 0.01-0.1μm, and the ratio of particle diameter of the ultra fine particle to that of the large diameter particle is 1:20 to 1:500. Preferably, in the composition, the volatile oil component is compounded in an amount of 10-50wt.%, the water repellent polymer 10-35wt.%, the powder 2-20wt.% and the nonvolatile oil component 10-40wt.%. The ultra fine particle is preferably silica. The volatile oil component and the water repellent polymer are preferably a volatile silicone oil and a silicone resin, respectively.

Description

Detailed Description of the Invention

[0001]

FIELD OF THE INVENTION The present invention relates to lipstick compositions, and more particularly to improving secondary adhesion.

[0002]

2. Description of the Related Art Lipsticks are one of the most popular cosmetics, but due to the nature of being applied to the lips, they are required to be non-irritating and harmless to the lips and have no unpleasant taste or smell. . By the way, recently, after the lipstick is applied to the lips, there is a strong demand for improvement in so-called secondary adhesiveness, in which the lipstick is transferred to a portion such as a cup that comes into contact with the lips. Therefore, in recent years, as a “cosmetic composition with improved anti-depression property” having improved secondary adhesion, Japanese Patent Application Laid-Open No.
What is described in 99630 gazette is reported.
This cosmetic composition, a volatile solvent, a silicone resin,
It is characterized by containing wax, powder and oil. And, when such a cosmetic composition is used, the secondary adhesion is improved.

[0003]

However, the cosmetic composition described in JP-A-6-199630 still has problems in terms of elongation during application, smooth feeling during use, and water retention during use. ing. Then, the lipstick is smooth on the lips, and this smooth feeling of use is maintained, and it is required to be kept fresh, and the improvement of the secondary adhesiveness is a requirement for maintaining and smoothing the smooth feeling of use. It is desired to develop a lipstick composition having both of them. The present invention has been made in view of the above problems of the prior art, and an object thereof is to provide a composition for lipstick which has a smooth feeling of use and improved secondary adhesion.

[0004]

Means for Solving the Problems As a result of intensive studies by the present inventors in order to achieve the above-mentioned object, by blending a powder having a specific particle size with a water-repellent polymer, a smooth feeling of use can be obtained. It was found that a composition for lipsticks having improved both secondary adhesiveness was obtained, and completed the present invention.

That is, the lipstick composition according to claim 1 of the present application comprises a volatile oil component, a water-repellent polymer soluble in the volatile oil component, and the volatile oil component not present.
A powder that can be coated with the water-repellent polymer and a non-volatile oil component that is compatible with the volatile oil component. At least large particles and ultrafine particles are present as the powder, and the particle size of the ultrafine particle is Is 0.01 to 0.1 μm, and the ratio of the particle size of the ultrafine particles to the particle size of the large particles is 1:20 to 1:
It is characterized by being 500.

The composition according to claim 2 comprises 10 to 50% by weight of the volatile oil and 10 to 35% of the water repellent polymer.
% By weight, 2 to 20% by weight of the powder, and 10 to 40% by weight of the non-volatile oil content. The composition according to claim 3, wherein the ultrafine particles and the large-sized particles are 1:19.
It is characterized by being mixed in a ratio of 10: 1. The composition according to claim 4 is characterized in that the ultrafine particles are silica. The composition according to claim 5 is characterized in that the volatile oil component is a volatile silicone oil and the water-repellent polymer is a silicone resin.

[0007]

DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described in more detail. Volatile oil components preferably used in the present invention include chain polysiloxanes such as decamethyltetrasiloxane, hexamethyldisiloxane and dodecamethylpentasiloxane, and cyclic polysiloxanes such as octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane. , Light liquid isoparaffin such as shell sol (shell chemistry) and isoper (esso chemistry). Further, as the water-repellent polymer preferably used in the present invention, silicone resin, silicone rubber,
Examples thereof include fluorine-modified silicone resin and alkyl-modified silicone resin.

As the powder preferably used in the present invention, any powder which is usually used in cosmetics can be used. For example, talc, kaolin, sericite, muscovite, phlogopite, Synthetic mica, red mica,
Biotite, Lithium mica, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, bentonite, barium sulfate, Inorganic powder such as calcined calcium sulfate (calculated gypsum), calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, boron nitride, titanium dioxide, zinc oxide, polyamide resin powder, nylon powder, polyethylene powder, polypropylene powder, polyester powder, polymethacryl Methyl acid powder, polystyrene powder,
Examples thereof include copolymer resin powder of styrene and acrylic acid, silicon resin powder, benzoguanamine resin powder, polytetrafluoroethylene powder, organic powder such as cellulose powder, and various pigments.

Some of these powders have a particle size of 0.01.
It is preferably ultrafine particles of 0.1 μm. Examples of ultrafine particles having a particle size of 0.01 to 0.1 μm include ultrafine silica, ultrafine titanium dioxide, ultrafine barium sulfate, and ultrafine zinc white. Among these, those having high transparency are preferable because they do not impair the color tone of the lipstick, and when volatile silicone oil is used as the volatile oil and silicone resin is used as the water-repellent polymer, compatibility with them is obtained. Therefore, silica is particularly preferable. In addition, it is preferable to mix large particles with these ultrafine particles. The large particle means a particle having a ratio of the particle diameter of the ultrafine particles to the particle diameter of the large particle of 1:20 to 1: 500. 1:20
In the following, the stickiness cannot be suppressed, and it is 1: 500.
In the above case, the effect of the powder to be blended is great and a good feeling of use cannot be obtained.

Further, as the non-volatile oil component preferably used in the present invention, if it has high skin safety,
It can be used. For example, liquid paraffin, squalane,
Castor oil, olive oil, jojoba oil, glyceryl diisostearate, trimethylolpropane tri-2 ethyl isostearate, glycerol tri-2 ethyl hexanoate, isopropyl myristate, cetyl 2 ethyl hexanoate, glyceryl triisostearate, 2 Examples include heptyl undecyl palmitate, methyl polysiloxane, polybutene, glycerin triisostearate, diisostearyl malate, and lanolin, and one or more of these are arbitrarily selected. Other,
In the case of producing a stick-shaped lipstick, it is preferable that 5 to 20% by weight of ceresin wax, carnauba wax, polyethylene wax, paraffin wax, etc. is blended as a shape-retaining agent.

In the present invention, the suitable amount of the volatile oil component in the composition is 10 to 50% by weight.
If it is less than 10% by weight, the amount of other components relatively increases, and the spreadability upon application to the lips may be lacked. Also,
When it exceeds 50% by weight, other components are relatively reduced, and when molding, sufficient strength may not be obtained in some cases.
Further, in the present invention, a suitable blending amount of the water-repellent polymer in the composition is 10 to 35% by weight, particularly preferably 15 to 30% by weight. When the amount of the water-repellent polymer is less than 10% by weight, the secondary adhesion may not be sufficiently improved. On the other hand, if the blending amount of the water-repellent polymer exceeds 35% by weight, stickiness may occur.

In the present invention, the powder content in the composition is preferably 2 to 20% by weight. If the amount of the powder is less than 1% by weight, the effect of suppressing stickiness may be poor, and if the amount of the powder exceeds 20% by weight, the feeling of use may deteriorate. In particular, when the ultrafine particles are used in an amount of 1.0 to 10% by weight, and more preferably 1 to 8% by weight, the feeling in use and the secondary adhesiveness are suitable. In the present invention, the compounding amount of the ultrafine particles and the large particles is preferably 1:19 to 10: 1. If the amount of the large particles is too large relative to the amount of the ultrafine particles, stickiness may occur during use. On the other hand, when the blending amount of the large-diameter particles is too small, spreadability during coating is poor and gloss after coating cannot be obtained.

In the present invention, the suitable blending amount of the non-volatile oil component in the composition is 10 to 40% by weight, particularly preferably 15 to 30% by weight. Non-volatile oil content is 10%
If the amount is less than the above, the feeling after coating and drying may be poor, and in some cases, it may be difficult to maintain the solid form. Also,
If it exceeds 40% by weight, stickiness may occur.

Furthermore, the composition for lipstick according to the present invention contains various drugs such as vitamins A, B ₁ , B ₂ , B ₆ and
B ₁₂ , C, D, E, F, K, U and salts or derivatives thereof, pantothenic acid and salts or derivatives thereof, biotin,
Royal jelly extract, pyridoxine hydrochloride, nicotinic acid and its salts or derivatives, folic acid, vitamins such as γ-oryzanol, stearyl glycyrrhetinate, 1-menthol, camphor, camphor, calamine, indomethacin, methyl salicylate, ethyl aminobenzoate, crotamiton. Anti-inflammatory agents such as anti-inflammatory agents such as hinokitiol, glycyrrhetinic acid, glycyrrhizic acid and salts or derivatives thereof, allantoin, azulene, ε-aminocaproic acid, tranexamic acid and salts or derivatives thereof, cystine,
Amino acids such as cysteine, methionine, serine, leucine, tryptophan, amino acid extract, hamamelis,
Yellow orchid, Chinese mackerel, Yarrow, Lily, Lily, Luffa, Safflower, Horse chestnut, Eucalyptus oil, horse chestnut, β-carotene, aloe extract, carrot extract, licorice extract, psyllium extract, chamomile extract, loquat extract, yellowtail extract, Cepharanthin,
Animal and plant extracts and extracts such as toki extract, placenta extract, estradiol and its salts or derivatives, estrogen such as ethinyl estradiol, cortisone and its salts or derivatives, hydrocortisone and its salts or derivatives, prednisone, prednisolone, dexamethasone, betamethasone, etc. Hormonal agents such as corticosteroids, anti-histamines such as diphenhydramine hydrochloride, chlorpheniramine maleate, benzalkonium chloride,
A bactericidal agent such as benzethonium chloride, halocarban, and chlorhexidine chloride can be added. The compounding amount of these drugs is preferably mixed in an amount sufficient for each drug to function, and is not particularly limited. However, as an appropriate compounding amount to the lipstick composition, the lipstick composition The content is 0.001 to 5% by weight.

The composition for lipstick according to the present invention comprises:
Various components usually added to cosmetics such as lipstick, for example, antioxidants, ultraviolet absorbers, ultraviolet shielding agents, preservatives, humectants, dyes, etc. can be added.

The lipstick composition according to the present invention, having the above-mentioned constitution, has a water-repellent polymer, a powder and a non-volatile oil component dispersed in the volatile oil component as a product form before coating. It spreads well when applied to the lips and gives a smooth feeling of use. After the application to the lips, the volatile oil content is volatilized, and the water-repellent polymer, powder, and non-volatile oil content remain on the lips. The water-repellent polymer is generally extremely sticky by itself, but in the present invention, ultrafine particles such as ultrafine silica and large-diameter particles are blended, and it is considered that the powder suppresses the stickiness of the water-repellent polymer. Also, by mixing ultrafine particles and large-diameter particles, it is possible to produce gloss during use.

[0017]

DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will be described below. The present invention is not limited to these examples. In addition, unless otherwise specified, the compounding amount and the like are shown by weight%. First, the present inventors created a lipstick having the following composition, and examined its feeling of use, secondary adhesion, and the like. In each of the following formulation examples, a small amount of surfactant is used. The particle size ratio between the ultrafine particles and the large particles (hereinafter referred to as the particle size ratio) was determined by the particle size of the ultrafine particles / the particle size of the large particles. The usability was evaluated by the following method.

[Evaluation Method of Usability] A use test was conducted on each of the examples using a panel dedicated to makeup. The evaluation criteria were determined according to the following. ⊚: 16 to 20 were judged to be good ○: 11 to 15 were judged to be good Δ: 8 to 10 were judged to be good ×: 0 to 5 were judged to be good

[0019]

[Table 1] Actual Example 1 2 3 4 5 6 7 8 Nonvolatile oil Liquid paraffin 20 20 20 20 20 20 20 20 Volatile oil Octamethylcyclotetrasiloxane 60 60 60 60 60 60 60 60 Polymer Silicon resin A 25 25 25 25 25 25 25 25 Powder Silica (particle size 0.02μm)---5 5 5 5 5 Silica (particle size 2μm)--5-----Mica (particle size 3μm)-10---- -10 Pigment (particle size 7μm)------5-Pigment (particle size 2μm)-----5--Pigment (particle size 0.5μm)----5---Wax ceresin wax 15 15 15 15 15 15 15 15 Particle size ratio----0.04 0.01 0.003 0.007 ────────────────────────────────── ─── Elongation ○ ○ ○ ○ ○ ○ ○ ○ Gloss ◎ △ △ △ △ ◎ ○ ○ ○ Secondary adhesion × △ △ ○ ○ ○ ○ ○ Stickiness × △ △ △ ○ ○ ○ ○

The silicone resin A is about 300
Having a molecular weight of 0 and (CH ₃ ) ₃ SiO _1/2 : SiO ₂
Average formula (CH ₃ ) _1.33 SiO consisting of units = 0.8: 1
_The silicone resin represented by _1.34 is used (hereinafter referred to as silicone resin A). As is clear from the above examination results, when the powder is not added at all, no improvement in secondary adhesion or stickiness is observed. Further, if only powder having a large particle size is blended, it is not possible to sufficiently improve the secondary adhesion. On the other hand, if you mix ultrafine silica,
Improvement is insufficient in terms of luster and stickiness. Then, when various large-sized particles were blended together with ultrafine silica, it was possible to obtain a composition excellent in all aspects of secondary adhesion, stickiness and luster.

Next, the present inventors have studied the effective blending amount of each component. Amount of water-repellent polymer blended First, the present inventors examined the amount of the water-repellent polymer blended. The particle size ratio of ultrafine particles and large particles in this test is 0.004.

[Table 2] Example 9 10 11 12 13 14 15 16 Non-volatile oil component Liquid paraffin 20 20 20 20 20 20 20 20 Volatile oil component Octamethylcyclotetrasiloxane 50 45 40 35 30 25 20 15 Polymer Silicon resin A 5 10 15 20 25 30 35 40 Powdered silica (particle size 0.02 μm) 5 5 5 5 5 5 5 5 5 Pigment (particle size 5 μm) 5 5 5 5 5 5 5 5 Wax ceresin wax 15 15 15 15 15 15 15 15 Elongation ○ ○ ○ ○ ○ ○ ○ ○ Gloss ○ ○ ○ ○ ○ ○ ○ ○ Secondary adhesiveness △ ○ ◎ ◎ ◎ ◎ ◎ ◎ ○ × Stickiness ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ ○ Improve the secondary adhesion from the above examination results In the above, the water-repellent polymer content is preferably 10% by weight or more, and particularly preferably 15% by weight or more. However, 35% by weight of water repellent polymer
When it exceeds the above range, a sticky feeling may occur, and it is particularly preferably up to 30% by weight.

Powder blending amount Next, the present inventors examined the powder blending amount. First, the blending amount of ultrafine particles was examined.

[Table 3] Example 17 18 19 20 21 22 23 24 Non-volatile oil component Liquid paraffin 20 20 20 20 20 20 20 20 Volatile oil component Octamethylcyclotetrasiloxane 39.5 39.0 38.0 35.0 32.0 30.0 25.0 20.0 Polymer Silicon resin A 20 20 20 20 20 20 20 20 Powdered silica (particle size 0.02 μm) 0.5 1.0 2.0 5.0 8.0 10.0 15.0 20.0 Pigment (particle size 5 μm) 5 5 5 5 5 5 5 5 Wax ceresin wax 15 15 15 15 15 15 15 15 Elongation ◎ ◎ ◎ ◎ ○ ○ × × Gloss ○ ○ ○ ○ ○ ○ △ × Secondary adhesion ○ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Stickiness △ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ From the above examination results, in improving stickiness The amount of silica blended is preferably 1.0% by weight or more. However, if the blending amount of silica exceeds 10% by weight, the feeling of use such as elongation may deteriorate and the gloss may deteriorate to some extent. Therefore,
In order to suppress stickiness while maintaining gloss, the powder content is 1.0 to 10% by weight, particularly 1.0 to 8.0% by weight.
It is preferred that

Further, the blending ratio of ultrafine particles and large particles was examined. The particle size ratio in this test is 0.004.
It is.

[Table 4] Example 25 26 27 28 29 30 31 32 Non-volatile oil component Liquid paraffin 20 20 20 20 20 20 20 20 Volatile oil component Octamethylcyclotetrasiloxane 24 25 25 25 25 25 30 34 Polymer Silicone resin A 25 25 25 25 25 25 25 25 Powder Silica (particle size 0.02 μm) 1.0 2.0 3.0 5.0 8.0 10.0 10.0 10.0 Pigment (particle size 5 μm) 19.0 18.0 17.0 15.0 12.0 10.0 5.0 1.0 Wax ceresin wax 10 10 10 10 10 10 10 10 Over Fine particles / Large particles 1/19 1/9 3/17 1/3 2/3 1/1 2/1 10/1 Elongation ◎ ◎ ◎ ◎ ○ ○ ○ ○ Gloss ○ ○ ○ ◎ ◎ ○ ○ ○ Secondary adhesion Properties ○ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Stickiness ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ As is clear from the above results, when the blending ratio of ultrafine particles and large-diameter particles is 1:19 to 10: 1, the feeling of use It is possible to obtain a composition with improved secondary adhesion.

Ratio of Oil Content to Polymer In carrying out the above investigation, the present inventors have found that the ratio of the non-volatile oil content to the water-repellent polymer has a great influence on the feeling of use and the secondary adhesion. That is, when the non-volatile oil content is relatively significantly low, the water-repellent polymer exerts a strong influence, which may cause stickiness, poor elongation, and the like. It is considered that the action of the water-repellent polymer is hindered by the non-volatile oil component and the secondary adhesion property is deteriorated.

[Table 4] Example 33 34 35 36 37 38 39 40 Non-volatile oil Liquid paraffin 5 10 14.9 19.8 24.7 29.5 34.3 39.0 Castor oil--0.1 0.2 0.3 0.5 0.7 1.0 Volatile oil Octamethylcyclotetrasiloxane 30 30 30 30 30 30 30 30 Polymer Silicone resin A 40 35 30 25 20 15 10 5 Powder silica (particle size 0.02μm) 5 5 5 5 5 5 5 5 Pigment (particle size 5μm) 5 5 5 5 5 5 5 5 Wax ceresin Wax 15 15 15 15 15 15 15 15 Resin / non-volatile oil 8/1 7/2 2/1 5/4 4/5 1/2 2/7 1/8 Elongation × △ ○ ○ ○ ○ ○ ○ Gloss △ △ ○ ○ ○ ○ ○ ○ Secondary adhesiveness × △ ◎ ◎ ◎ ◎ ○ △ × Stickiness × △ ○ ◎ ◎ ◎ ◎ ◎ ◎ From the above examination results, it is expected that the elongation will increase when the ratio of resin to non-volatile oil exceeds 1/2. However, the gloss was poor, and improvement in secondary adhesion and stickiness was not observed so much. Further, if the ratio of the resin to the non-volatile oil is less than 2/1, the characteristics of the resin cannot be sufficiently exhibited, and the effect of improving the secondary adhesion may be insufficient. Therefore, the ratio of the resin to the non-volatile oil is preferably 1/2 or more and 2/1 or less.

A more specific formulation example of the present invention will be described below. In each case, the secondary adhesion was low, and a sticky feeling was rarely generated.

Formulation Example 1 Stick lipstick ceresin 15.0% by weight Carnauba wax 2.0 Glyceryl diisostearate 15.0 Lanolin 0.2 Macadamia nut oil 0.1 Diisostearyl malate 3.0 Trimethylolpropane tri-2 ethyl Hexanoate 1.5 Glyceryl triisostearate 1.5 Average formula (CH ₃ ) having a molecular weight of about 3000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 _1.33 SiO _1.34 Silicon resin 30.0 Octamethylcyclotetrasiloxane 21.7 Silica (particle size 0.02 μm) 5.0 Red No. 202 (particle size 0.933 μm) 5.0 Perfume proper amount ─── ───────────────────────────────── Total 100.0% by weight Particle size ratio (ultrafine particles Large diameter particles): 0.021 Rating: growth ◎, gloss ○, secondary adhesion ◎, stickiness ◎

Formulation 2 Stick lipstick ceresin 15.0% by weight carnauba wax 2.0 glyceryl diisostearate 15.0 lanolin 0.2 macadamia nut oil 0.1 diisostearyl malate 3.0 trimethylolpropane tri-2 ethyl Hexanoate 1.5 Glyceryl triisostearate 1.5 Average formula (CH ₃ ) having a molecular weight of about 3000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 _1.33 SiO _1.34 Silicon resin 30.0 Octamethylcyclotetrasiloxane 21.7 Silica (particle size 0.03 μm) 5.0 Titanium mica (particle size 6.9 μm) 5.0 Perfume Suitable amount ─── ──────────────────────────────── Total 100.0% by weight Particle size ratio (ultrafine particles / large diameter) Child): 0.0043 Rating: growth ◎, gloss ○, secondary adhesion ◎, stickiness ◎

Formulation Example 3 Stick lipstick ceresin 15.0% by weight Carnauba wax 2.0 Glyceryl diisostearate 15.0 Lanolin 0.2 Macadamia nut oil 0.1 Diisostearyl malate 3.0 Trimethylolpropane tri-2 ethyl Hexanoate 1.5 Glyceryl triisostearate 1.5 Average formula (CH ₃ ) having a molecular weight of about 3000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 _1.33 SiO _1.34 Silicon resin 30.0 Octamethylcyclotetrasiloxane 21.7 Fine particle barium sulphate (particle size 0.08 μm) 5.0 Mica titanium (particle size 6.9 μm) 5.0 Perfume proper amount ── ────────────────────────────────── Total 100.0% by weight Particle size ratio Particle / large particles): 0.012 Rating: growth ◎, gloss ○, secondary adhesion ◎, stickiness ◎

Formulation Example 4 Stick-shaped lipstick polyethylene wax 8.0% by weight candelilla wax 3.0 squalane 8.0 macadamia nut oil fatty acid ester 2.5 glyceryl tri-2-ethylhexanoate 4.5 having a molecular weight of about 6000. And a silicon resin represented by the average formula (CH ₃ ) _1.33 SiO _1.34 consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 20.0 decamethylcyclopentasiloxane 44.0 silica (Particle size 0.02 μm) 5.0 Red No. 226 (Particle size 0.407 μm) 5.0 Perfume Appropriate amount ───────────────────────── ──────────── Total 100.0% by weight Particle size ratio (Ultrafine particle / Large particle): 0.049 Evaluation: Elongation ◎, Gloss ○, Secondary adhesion ◎, Stickiness ◎

Formulation Example 5 Emulsion type stick-shaped lipstick paraffin wax 10.0% by weight microcrystalline wax 4.0 Glyceryl diisostearate 7.0 Macadamia nut oil 3.0 Polybutene 3.0 Diisostearyl malate 4.0 About Silicon resin having an average formula of (CH ₃ ) _1.33 SiO _1.34 having a molecular weight of 8000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 30.0 decamethylcyclo Pentasiloxane 10.5 Octamethylcyclotetrasiloxane 7.0 Dimethylpolysiloxane (viscosity 6 cs) 5.0 Silica (particle size 0.02 μm) 3.0 Synthetic sodium silicate-magnesium 1.0 Polyoxyethylene-methylpolysiloxane Copolymer 2.0 Ion-exchanged water 5.0 Glycerin 1.0 Red acid Iron (particle size 0.602 μm) 4.5 Perfume Suitable amount ───────────────────────────────────── Total 100.0% by weight Particle size ratio (ultrafine particle / large particle): 0.033 Evaluation: Elongation ◎, Gloss ○, Secondary adhesion ◎, Stickiness ◎

Formulation Example 6 Paste lipstick Vaseline 10.0% by weight Squalane 15.0 Castor oil 3.0 Glyceryl diisostearate 2.0 Having a molecular weight of about 5000 and (CH ₃ ) ₃ SiO _1/2 : SiO ₂ unit = 0.8: 1 average formula (CH ₃ ) _1.33 Silicon resin represented by SiO _1.34 25.0 Decamethylcyclopentasiloxane 39.5 Silica (particle diameter 0.02 μm) 2.5 Red No. 202 (particle size 0.933 μm) 3.0 Perfume Suitable amount ──────────────────────────────────── ─ Total 100.0% by weight Particle size ratio (ultrafine particles / large particles): 0.021 Evaluation: Elongation ◎, Gloss ○, Secondary adhesion ◎, Stickiness ◎

Formulation 7 Stick-shaped lipstick ceresin 15.0% by weight Carnauba wax 2.0 Glyceryl diisostearate 15.0 Lanolin 0.2 Macadamia nut oil 0.1 Diisostearyl malate 3.0 Trimethylolpropane tri-2ethyl Hexanoate 1.5 Glyceryl triisostearate 1.5 Average formula (CH ₃ ) having a molecular weight of about 3000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 _1.33 SiO _1.34 Silicon resin 30.0 Octamethylcyclotetrasiloxane 21.68 Silica (particle size 0.02 μm) 5.0 Red No. 202 (particle size 0.933 μm) 5.0 l-Menthol 0.01 Camphor 0.01 Perfume Suitable amount ───────────────────────────────── ── Total 100.0% by weight, particle size ratio (ultra-fine particles / large particles): 0.021 Rating: growth ◎, gloss ○, secondary adhesion ◎, stickiness ◎

Formulation 8 Stick lipstick ceresin 15.0% by weight Carnauba wax 2.0 Glyceryl diisostearate 15.0 Lanolin 0.2 Macadamia nut oil 0.1 Diisostearyl malate 3.0 Trimethylolpropane tri-2 ethyl Hexanoate 1.5 Glyceryl triisostearate 1.5 Average formula (CH ₃ ) having a molecular weight of about 3000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 _1.33 SiO _1.34 Silicon resin 30.0 Octamethylcyclotetrasiloxane 21.6 Silica (particle size 0.03 μm) 5.0 Mica titanium (particle size 6.9 μm) 5.0 Stearyl glycyrrhizinate 0.1 Perfume Appropriate amount ──────────────────────────────────── Total 100 0% by weight of particle size ratio (ultra-fine particles / large particles): 0.0043 Rating: growth ◎, gloss ○, secondary adhesion ◎, stickiness ◎

Formulation 9 Stick-shaped lipstick ceresin 15.0% by weight Carnauba wax 2.0 Glyceryl diisostearate 15.0 Lanolin 0.2 Macadamia nut oil 0.1 Diisostearyl malate 3.0 Trimethylolpropane tri-2 ethyl Hexanoate 1.5 Glyceryl triisostearate 1.5 Average formula (CH ₃ ) having a molecular weight of about 3000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 _1.33 SiO _1.34 Silicon resin 30.0 Octamethylcyclotetrasiloxane 21.69 Fine particle barium sulfate (particle size 0.08 μm) 5.0 Mica titanium (particle size 6.9 μm) 5.0 Vitamin E acetate 0.1. 01 Perfume Appropriate amount ──────────────────────────────────── Total 100.0% by weight, particle size ratio (ultra-fine particles / large particles): 0.012 Rating: growth ◎, gloss ○, secondary adhesion ◎, stickiness ◎

Formulation 10 Sticky Lipstick Polyethylene Wax 8.0 wt% Candelilla Wax 3.0 Squalane 8.0 Macadamia Nut Oil Fatty Acid Ester 2.5 Glyceryltri-2-ethylhexanoate 4.5 Has a molecular weight of about 6000. And a silicon resin represented by the average formula (CH ₃ ) _1.33 SiO _1.34 consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 20.0 decamethylcyclopentasiloxane 43.99 silica (Particle size 0.02 μm) 5.0 Red No. 226 (particle size 0.407 μm) 5.0 β-carotene 0.01 Fragrance suitable amount ─────────────────── ────────────────── Total 100.0% by weight Particle size ratio (Ultrafine particle / Large particle): 0.049 Evaluation: Elongation ◎, Gloss ○, Secondary adhesion ◎, solid Tsuki ◎

Formulation Example 11 Emulsion type stick-shaped lipstick paraffin wax 10.0% by weight Microcrystalline wax 4.0 Glyceryl diisostearate 7.0 Macadamia nut oil 3.0 Polybutene 3.0 Diisostearyl malate 4.0 Approx. Silicon resin having an average formula of (CH ₃ ) _1.33 SiO _1.34 having a molecular weight of 8000 and consisting of (CH ₃ ) ₃ SiO _1/2 : SiO ₂ units = 0.8: 1 30.0 decamethylcyclo Pentasiloxane 10.37 Octamethylcyclotetrasiloxane 7.0 Dimethylpolysiloxane (viscosity 6 cs) 5.0 Silica (particle diameter 0.02 μm) 3.0 Synthetic sodium silicate-magnesium 1.0 Polyoxyethylene-methylpolysiloxane Copolymer 2.0 Ion-exchanged water 5.0 Royal jelly extract 0.1 Pantothenyl ethyl ether 0.01 Pyridoxine hydrochloride 0.02 Glycerin 1.0 Red iron oxide (particle size 0.602 μm) 4.5 Perfume proper amount ─────────────── ───────────────────── Total 100.0% by weight Particle size ratio (ultrafine particle / large particle): 0.033 Rating: Elongation ◎, Gloss ○, Secondary adhesion ◎, Stickiness ◎

Formulation 12 Pasty lipstick Vaseline 10.0% by weight Squalane 15.0 Castor oil 3.0 Glyceryl diisostearate 2.0 Having a molecular weight of about 5000 and (CH ₃ ) ₃ SiO _1/2 : SiO ₂ unit = 0.8: 1 average formula (CH ₃ ) _1.33 Silicone resin represented by SiO _1.34 25.0 Decamethylcyclopentasiloxane 39.46 Silica (particle diameter 0.02 μm) 2.5 Red No. 202 (particle size 0.933 μm) 3.0 Vitamin E acetate 0.01 Stearyl glycyrrhetinate 0.03 Perfume proper amount ─────────────────────── ───────────── Total 100.0% by weight Particle size ratio (ultrafine particle / large particle): 0.021 Evaluation: Elongation ◎, Gloss ○, Secondary adhesion ◎, Stickiness ◎

[0038]

As described above, according to the composition for lipstick according to the present invention, since the powder is blended together with the water-repellent polymer, the secondary adhesion is low and the sticky feeling is not generated.

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Junko Hirayama 1050 Shinba-cho, Kohoku-ku, Yokohama-shi, Kanagawa Prefecture Shiseido Daiichi Research Center

Claims (5)

[Claims] 1. A volatile oil component, a water-repellent polymer that dissolves in the volatile oil component, a powder that can be coated on the water-repellent polymer in the absence of the volatile oil component, and a volatile oil component. And a non-volatile oil component having solubility, at least large particles and ultrafine particles are present as the powder, and the ultrafine particles have a particle size of 0.01 to 0.1 μm. The particle size ratio of the large particles is 1: 2.
The composition for lipsticks, which is 0 to 1: 500. 2. The composition according to claim 1, wherein the volatile oil content is 10 to 50% by weight, the water repellent polymer is 10 to 35% by weight, the powder is 2 to 20% by weight, and the non-volatile oil content is 10 to 50% by weight. 40% by weight of a lipstick composition. 3. The lipstick composition according to claim 1 or 2, wherein ultrafine particles and large-diameter particles are mixed in a ratio of 1:19 to 10: 1. 4. The lipstick composition according to any one of claims 1 to 3, wherein the ultrafine particles are silica. 5. The lipstick composition according to claim 1, wherein the volatile oil is a volatile silicone oil and the water-repellent polymer is a silicone resin. .