JPH09202938A - Chromium-molybdenum cast steel excellent in machinability - Google Patents

Chromium-molybdenum cast steel excellent in machinability

Info

Publication number
JPH09202938A
JPH09202938A JP1074996A JP1074996A JPH09202938A JP H09202938 A JPH09202938 A JP H09202938A JP 1074996 A JP1074996 A JP 1074996A JP 1074996 A JP1074996 A JP 1074996A JP H09202938 A JPH09202938 A JP H09202938A
Authority
JP
Japan
Prior art keywords
mass
chromium
cast steel
secure
wear resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1074996A
Other languages
Japanese (ja)
Inventor
Kagehiro Amano
景博 天野
Noboru Kannou
昇 館農
Masahiko Fujiwara
晶彦 藤原
Hidekazu Todoroki
秀和 轟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Yakin Kogyo Co Ltd
Original Assignee
Nippon Yakin Kogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Yakin Kogyo Co Ltd filed Critical Nippon Yakin Kogyo Co Ltd
Priority to JP1074996A priority Critical patent/JPH09202938A/en
Publication of JPH09202938A publication Critical patent/JPH09202938A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain a cast steel excellent in mechanical properties, such as strength and wear resistance, by specifying the composition of a chromium- molybdenum cast steel. SOLUTION: This chromium-molybdenum cast steel has a composition consisting of, by mass, 0.1-0.5% C, 0.15-1.0% Si, 0.3-1.0% Mn, 0.90-1.50% Cr, 0.1-0.5% Mo, 0.005-1.0% Ti, 0.01-0.1% Al, and the balance Fe. This chromium- molybdenum cast steel has excellent turning and planing properties at (0.1 to 1.2)m/s cutting rate. The reasons why contents of the elements in the composition are regulated to the values in the above ranges are as follows: C, to secure strength and machinability; Si, to secure deoxidation, flowability of molten metal, castability, and toughness; Mn, to secure deoxidation, mechanical properties by improvement of hardenability, and wear resistance; Cr, to secure wear resistance and hardenability; Mo, to secure strength, such as high temp. creep resistance, and wear resistance; Ti, to refine structure and secure softening control after hot working; Al, to refine structure.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、強度および耐摩耗性
に優れるだけでなく、被削性にも優れたクロム−モリブ
デン鋳鋼に関し、特に内燃機関のロッカーアームとして
の用途に用いて好適なものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a chromium-molybdenum cast steel which is excellent not only in strength and wear resistance but also in machinability, and is particularly suitable for use as a rocker arm of an internal combustion engine. Is.

【0002】[0002]

【従来の技術】従来、内燃機関のロッカーアームとして
は、耐摩耗性に富むFe基鋳造合金および非鉄基焼結合金
が多く用いられてきた。このうち、Fe基鋳造合金に関し
ては、例えば特公平7−6031号公報に、主要成分として
C:2〜4%、Cr:10〜25%、Mo:1〜10%当が示され
ているように、いずれも比較的高合金であり、しかもそ
の要求特性は主に耐摩耗性に限られていた。
2. Description of the Related Art Conventionally, as a rocker arm for an internal combustion engine, Fe-based cast alloys and non-ferrous-base sintered alloys, which are rich in wear resistance, have been widely used. Among them, regarding the Fe-based casting alloy, for example, Japanese Examined Patent Publication No. 7-6031 discloses that C: 2 to 4%, Cr: 10 to 25%, and Mo: 1 to 10% as main components. In addition, all of them were relatively high alloys, and the required characteristics were mainly limited to wear resistance.

【0003】[0003]

【発明が解決しようとする課題】鋳造合金は、その製法
上、鋳造ままの状態で使用されることはほとんどなく、
切削および旋削等の機械加工、さらには熱処理を経て最
終製品とされることが多い。この点は、ロッカーアーム
も同様であるが、かかるロッカーアームは、上述したと
おり、主に強度や耐摩耗性等の機械的特性の向上を目的
として合金設計がなされているため、その反面で被削性
に劣るものが多く、従って十分な機械加工性が得られな
いだけでなく、切削工具の著しい損傷を招くところに問
題を残していた。
The cast alloy is rarely used as it is because of its manufacturing method.
In many cases, the final product is obtained through machining such as cutting and turning, and further heat treatment. This point is similar to the rocker arm, but as described above, the rocker arm has an alloy design mainly for the purpose of improving mechanical properties such as strength and wear resistance. Many of them are inferior in machinability, so that not only sufficient machinability is not obtained, but also a problem remains where the cutting tool is significantly damaged.

【0004】すなわち、鋳造ロッカーアームは、その用
途上、鋳造後、機械加工によって目的の形状に成形され
るのであるが、このとき切削後の表面仕上げが劣悪であ
れば、さらに研削加工を施さねばならず、製造工程の増
加により経済性が低下する。また、劣悪な仕上げ面の原
因として、切削工具の摩耗や損傷が挙げられるが、工具
の摩耗が著しいと工具寿命が短くなり、頻繁な工具交換
が必要となるので、この点も経済性の面で問題となる。
That is, the cast rocker arm is formed into a desired shape by machining after casting for the purpose of use, but if the surface finish after cutting is poor at this time, it must be further ground. In addition, the economic efficiency is lowered due to the increase in the manufacturing process. In addition, wear and damage of the cutting tool can be mentioned as the cause of the poor finish surface, but if the tool wear is remarkable, the tool life will be shortened and frequent tool replacement will be necessary, which is also economical. Will be a problem.

【0005】この発明は、上記の問題を有利に解決する
もので、強度や耐摩耗性等の機械的特性はいうまでもな
く、被削性に優れたクロム−モリブデン鋳鋼を提案する
ことを目的とする。
The present invention advantageously solves the above problems, and it is an object of the present invention to propose a chromium-molybdenum cast steel excellent in machinability, not to mention mechanical properties such as strength and wear resistance. And

【0006】[0006]

【課題を解決するための手段】さて、発明者等は、上記
の観点から、クロム−モリブデン鋳鋼の被削性を改善す
べく、新たな合金設計を試みた。その結果、 C:0.1 〜0.5 mass%、 Si:0.15〜1.0 mass%、 Mn:0.3 〜1.0 mass%、 Cr:0.90〜1.50mass%、 Mo:0.1 〜0.5 mass%、 Ti:0.005 〜1.0 mass%、 Al:0.01〜0.1 mass% を含有し、残部はFeおよび不可避的不純物の組成にする
ことが、所期した目的の達成に極めて有効であることを
見出し、この発明を完成させるに至ったのである。
From the above viewpoints, the inventors have attempted a new alloy design in order to improve the machinability of cast chromium-molybdenum steel. As a result, C: 0.1 to 0.5 mass%, Si: 0.15 to 1.0 mass%, Mn: 0.3 to 1.0 mass%, Cr: 0.90 to 1.50 mass%, Mo: 0.1 to 0.5 mass%, Ti: 0.005 to 1.0 mass% , Al: 0.01 to 0.1 mass% and balance Fe and unavoidable impurities in the balance were found to be extremely effective in achieving the intended purpose, and the present invention was completed. is there.

【0007】この発明の組成になるクロム−モリブデン
鋳鋼は、 0.1〜1.2 m/s の切削速度における旋削性およ
び平削性に優れており、ロッカーアームとしての用途に
用いてとりわけ有利に適合するものである。
The chromium-molybdenum cast steel having the composition of the present invention is excellent in turning property and planing property at a cutting speed of 0.1 to 1.2 m / s, and is particularly suitable for use as a rocker arm. Is.

【0008】[0008]

【発明の実施の形態】以下、この発明において、成分組
成を上記の範囲に限定した理由を以下に説明する。 C:0.1 〜0.5 mass% Cは、マトリクスに固溶し、強度を向上させる他、炭化
物を形成し耐摩耗性を向上させる等、機械的性質の改善
に有効に寄与するが、添加量に比例して硬化するので被
削性には不利となる。従って、これらの点を考慮し、ロ
ッカーアームとして必要な最低の強度を有し、しかも被
削性を劣化させない範囲として、 0.1〜0.5 mass%好ま
しくは 0.1〜0.2 mass%の範囲に限定した。
BEST MODE FOR CARRYING OUT THE INVENTION The reason why the component composition is limited to the above range in the present invention will be described below. C: 0.1 to 0.5 mass% C is a solid solution in the matrix to improve the strength, form carbides and improve wear resistance, and effectively contribute to the improvement of mechanical properties, but are proportional to the addition amount. And then hardens, which is disadvantageous for machinability. Therefore, in consideration of these points, the range is set to 0.1 to 0.5 mass%, preferably 0.1 to 0.2 mass% as a range that has the minimum strength required for a rocker arm and does not deteriorate machinability.

【0009】Si:0.15〜1.0 mass% Siは、脱酸作用の他、溶湯の流動性を改善して鋳造性を
向上させる作用がある。しかしながら、含有量が0.15ma
ss%に満たないとその添加効果に乏しく、一方1.0 mass
%を超えると靱性の低下を招くので、0.15〜1.0 mass%
の範囲に限定した。好ましくは 0.4〜1.0 mass%より好
ましくは 0.4〜0.8 mass%である。
Si: 0.15 to 1.0 mass% Si has a deoxidizing effect and an effect of improving the fluidity of the molten metal to improve the castability. However, the content is 0.15ma
If it is less than ss%, its addition effect is poor, while 1.0 mass
%, The toughness decreases, so 0.15 to 1.0 mass%
Limited to the range. It is preferably 0.4 to 1.0 mass%, more preferably 0.4 to 0.8 mass%.

【0010】Mn:0.3 〜1.0 mass% Mnは、Siと同様、脱酸作用がある他、焼入れ性を改善し
て機械的性質を向上させる働きがある。しかしながら、
含有量が0.3 mass%未満ではその添加効果に乏しく、一
方1.0 mass%を超えると耐摩耗性の劣化を招くので、
0.3〜1.0 mass%の範囲に限定した。好ましくは 0.5〜
1.0 mass%より好ましくは 0.5〜0.85mass%である。
Mn: 0.3 to 1.0 mass% Mn has a deoxidizing effect as well as Si, and also has the function of improving hardenability and improving mechanical properties. However,
If the content is less than 0.3 mass%, the effect of addition is poor, while if it exceeds 1.0 mass%, wear resistance deteriorates.
It was limited to the range of 0.3 to 1.0 mass%. Preferably 0.5 to
It is preferably 0.5 to 0.85 mass%, more preferably 1.0 mass%.

【0011】Cr:0.90〜1.50mass% Crは、炭化物を形成して耐摩耗性を改善させるだけでな
く、材料の焼入れ硬化能を著しく増大させる効果を有す
る。従って、多量の添加は被削性の低下を招く不利があ
る。この発明のように、ロッカーアーム用として必要な
耐摩耗性やクリープ強度から見れば、通常のNi−Cr鋼の
ように10mass%以上のCrを含有させる必要はないので、
かかる観点から、0.90〜1.50mass%の範囲に限定した。
より好ましい範囲は0.95〜1.15mass%である。
Cr: 0.90 to 1.50 mass% Cr not only has the effect of forming carbides to improve wear resistance, but also has the effect of significantly increasing the quench-hardenability of the material. Therefore, the addition of a large amount has the disadvantage of reducing the machinability. Like the present invention, from the viewpoint of wear resistance and creep strength required for rocker arms, it is not necessary to contain 10 mass% or more of Cr like ordinary Ni-Cr steel,
From this viewpoint, the range is limited to 0.90 to 1.50 mass%.
A more preferable range is 0.95 to 1.15 mass%.

【0012】Mo:0.1 〜0.5 mass% Moは、高温でのクリープ抵抗性など、強度を向上に有効
に寄与するだけでなく、炭化物を形成して耐摩耗性を改
善する作用があるが、ロッカーアームとして用いる場
合、500 ℃以上の高温にはならないので、それ以上の高
温での高強度は要求されない。また経済性の観点から見
ても多量添加は好ましくない。さらにこの発明のよう
に、1mass%程度のクロム含有量の場合、Moを0.5 mass
%を超えて添加してもそれ以上効果は期待できない。そ
こで、この発明では、Mo含有量につき、 0.1〜0.5 mass
%好ましくは 0.1〜0.3 mass%より好ましくは 0.1〜0.
2 mass%の範囲に限定した。
Mo: 0.1 to 0.5 mass% Mo not only effectively contributes to the improvement of strength such as creep resistance at high temperature but also acts to form carbides to improve wear resistance. When used as an arm, it does not reach a temperature higher than 500 ° C, so high strength at a higher temperature is not required. Also, from the viewpoint of economy, it is not preferable to add a large amount. Further, as in the present invention, when the chromium content is about 1 mass%, 0.5 mass of Mo is added.
Even if added in excess of%, no further effect can be expected. Therefore, in the present invention, the Mo content is 0.1 to 0.5 mass.
% Preferably 0.1-0.3 mass%, more preferably 0.1-0.
It was limited to the range of 2 mass%.

【0013】Ti:0.005 〜1.0 mass% Tiは、炭化物を形成し、材料中に均一に分散することに
より、組織の微細化および熱間加工後の軟化を抑制する
作用があるので、少なくとも0.005 mass%の添加が必要
である。しかしながら、1.0 mass%を超えて添加する
と、これら分散した炭化物が硬度を高め機械加工性を劣
化させるので、含有量は 0.005〜1.0 mass%の範囲に限
定した。好ましくは 0.005〜0.5 mass%より好ましくは
0.005〜0.05mass%である。
Ti: 0.005 to 1.0 mass% Ti forms carbides and disperses uniformly in the material, so that it has the effect of suppressing the refinement of the structure and softening after hot working, so at least 0.005 mass% % Addition is required. However, if added over 1.0 mass%, these dispersed carbides increase hardness and deteriorate machinability, so the content was limited to the range of 0.005 to 1.0 mass%. Preferably 0.005-0.5 mass%, more preferably
It is 0.005 to 0.05 mass%.

【0014】Al:0.01〜0.1 mass% Alは、脱酸作用の他、Tiとの共存により組織の微細化に
有効に寄与するが、含有量が0.01mass%未満ではその添
加効果に乏しく、一方1.0 mass%を超えると冷間での靱
性の著しい低下を招くので、含有量は0.01〜1.0 mass%
の範囲に限定した。
Al: 0.01 to 0.1 mass% Al effectively contributes to the refinement of the structure by coexisting with Ti in addition to the deoxidizing action, but if the content is less than 0.01 mass%, the addition effect is poor. If it exceeds 1.0 mass%, the toughness in the cold will drop significantly, so the content should be 0.01-1.0 mass%.
Limited to the range.

【0015】以上、必須成分について説明したが、その
他の不純物元素については次のとおりである。 S:0.020 mass%以下 Sが0.020 mass%を超えて含有されると、MnSなどの介
在物の形成が顕著となるので、Sの混入は極力抑制する
ことが好ましく、0.020 mass%以下とすることが望まし
い。 P:0.010 mass%以下 Pが0.010 mass%を超えて含有されると、鋳造性が劣化
するので、その混入は極力抑制することが好ましく、0.
010 mass%以下とすることが望ましい。 N:0.005 mass%以下 Nが0.005 mass%を超えて含有されると、固溶Nにより
強化され、切削性を低減させるので、その混入は極力抑
制することが好ましく、0.005 mass%以下とすることが
望ましい。 O:50 ppm以下 Oが50 ppmを超えて含有されると、Sの固定化に対する
寄与が減ずるので、その混入は極力抑制することが好ま
しく、50 ppm以下とすることが望ましい。
Although the essential components have been described above, the other impurity elements are as follows. S: 0.020 mass% or less If S is contained in excess of 0.020 mass%, inclusions such as MnS are significantly formed. Therefore, it is preferable to suppress the inclusion of S as much as possible, and 0.020 mass% or less. Is desirable. P: 0.010 mass% or less If P is contained in excess of 0.010 mass%, the castability deteriorates, so it is preferable to suppress its inclusion as much as possible.
It is desirable that the content be 010 mass% or less. N: 0.005 mass% or less When N exceeds 0.005 mass%, it is strengthened by solid solution N and reduces machinability. Therefore, it is preferable to suppress the mixture as much as possible, and the content should be 0.005 mass% or less. Is desirable. O: 50 ppm or less When O is contained in excess of 50 ppm, the contribution of S to the immobilization is reduced, so it is preferable to suppress the contamination as much as possible, and it is preferable to set it to 50 ppm or less.

【0016】次に、製造法について説明すると、この発
明鋼の鋳造に際し、その方法は何ら制限されることがな
く、通常のロストワックス法を初めとして、シェルモー
ルド法、砂型鋳造法等いずれもが有利に適合する。な
お、この発明材の主用途は、内燃機関のロッカーアーム
であるが、その他にも、各種耐磨耗部品等の用途が考え
られる。
Next, the manufacturing method will be described. When casting the steel of the present invention, the method is not limited at all, and any of the ordinary lost wax method, the shell mold method, the sand mold casting method and the like can be used. Fits in an advantageous way. The main use of the invention material is a rocker arm of an internal combustion engine, but other uses such as various wear resistant parts are also conceivable.

【0017】[0017]

【実施例】表1に示す成分組成になる溶鋼を、高周波誘
導溶解炉にて溶製後、ロストワックス法により、60mmφ
×200 mmHの棒に鋳造し、水冷した。被削性の調査は、
旋削試験により行った。試験に用いた工具はサーメット
製である。被削性は、切削後の材料表面粗さおよび切削
工具の摩耗量で評価した。図1に、切削速度と材料の仕
上げ面粗さ(Ra)との関係について調べた結果を、また
図2には、切削速度と工具摩耗量との関係について調べ
た結果を、それぞれ示す。
Example: Molten steel having the composition shown in Table 1 was melted in a high-frequency induction melting furnace and then 60 mmφ was formed by the lost wax method.
It was cast into a rod of × 200 mmH and cooled with water. The machinability survey is
A turning test was conducted. The tool used for the test is made of cermet. The machinability was evaluated by the surface roughness of the material after cutting and the amount of wear of the cutting tool. FIG. 1 shows the results of an examination of the relationship between the cutting speed and the finished surface roughness (Ra) of the material, and FIG. 2 shows the results of an examination of the relationship between the cutting speed and the amount of tool wear.

【0018】[0018]

【表1】 [Table 1]

【0019】図1より明らかなように、発明材はいずれ
も、比較材に比べて表面粗さが小さく、仕上げ面の性状
が良好であることを示している。また、図2に示したと
おり、Tiが上限の1.0 mass%のときは工具摩耗量が増加
する傾向を示すものの、それでも比較材と比べると、工
具摩耗量は小さく、優れた耐摩耗性を呈している。
As is clear from FIG. 1, all the invention materials have smaller surface roughness and better finished surface properties than the comparative materials. Further, as shown in FIG. 2, when Ti is at the upper limit of 1.0 mass%, the tool wear amount tends to increase, but the tool wear amount is still smaller than that of the comparative material, and excellent wear resistance is exhibited. ing.

【0020】[0020]

【発明の効果】かくして、この発明によれば、強度や耐
摩擦性はいうまでもなく、被削性に優れたクロム−モリ
ブデン鋳鋼を安価に得ることができ、特に内燃機関のロ
ッカーアームとしての用途に供して偉効を奏する。
As described above, according to the present invention, it is possible to inexpensively obtain a chrome-molybdenum cast steel which is excellent in machinability, not to mention strength and abrasion resistance, and particularly as a rocker arm for an internal combustion engine. Delivers a great effect when used.

【図面の簡単な説明】[Brief description of drawings]

【図1】切削速度と材料の表面粗さとの関係を示したグ
ラフである。
FIG. 1 is a graph showing the relationship between cutting speed and surface roughness of a material.

【図2】切削速度と切削工具摩耗量との関係を示したグ
ラフである。
FIG. 2 is a graph showing the relationship between cutting speed and wear amount of cutting tools.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 轟 秀和 神奈川県川崎市川崎区小島町4番2号 日 本冶金工業株式会社技術研究所内 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Hidekazu Todoroki 4-2 Kojima-cho, Kawasaki-ku, Kawasaki-shi, Kanagawa Nihon Metallurgical Industry Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 C:0.1 〜0.5 mass%、 Si:0.15〜1.0 mass%、 Mn:0.3 〜1.0 mass%、 Cr:0.90〜1.50mass%、 Mo:0.1 〜0.5 mass%、 Ti:0.005 〜1.0 mass%、 Al:0.01〜0.1 mass% を含有し、残部はFeおよび不可避的不純物の組成になる
ことを特徴とする被削性に優れたクロム−モリブデン鋳
鋼。
1. C: 0.1 to 0.5 mass%, Si: 0.15 to 1.0 mass%, Mn: 0.3 to 1.0 mass%, Cr: 0.90 to 1.50 mass%, Mo: 0.1 to 0.5 mass%, Ti: 0.005 to 1.0 A chromium-molybdenum cast steel with excellent machinability, characterized by containing mass% and Al: 0.01 to 0.1 mass% and the balance being Fe and inevitable impurities.
【請求項2】 請求項1において、 0.1〜1.2 m/s の切
削速度における旋削性および平削性に優れたロッカーア
ーム用のクロム−モリブデン鋳鋼。
2. The chromium-molybdenum cast steel for rocker arms according to claim 1, which has excellent turning properties and planing properties at a cutting speed of 0.1 to 1.2 m / s.
JP1074996A 1996-01-25 1996-01-25 Chromium-molybdenum cast steel excellent in machinability Pending JPH09202938A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1074996A JPH09202938A (en) 1996-01-25 1996-01-25 Chromium-molybdenum cast steel excellent in machinability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1074996A JPH09202938A (en) 1996-01-25 1996-01-25 Chromium-molybdenum cast steel excellent in machinability

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JPH09202938A true JPH09202938A (en) 1997-08-05

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100415626B1 (en) * 2001-06-30 2004-01-24 기아특수강 주식회사 High Strength Wear Resistance Steel with Excellent Hardenability
CN102002633A (en) * 2010-10-26 2011-04-06 攀钢集团钢铁钒钛股份有限公司 Carbon steel and manufacturing method thereof
CN102031452A (en) * 2010-10-26 2011-04-27 攀钢集团钢铁钒钛股份有限公司 Alloy steel and manufacturing method thereof
CN102260827A (en) * 2010-05-26 2011-11-30 攀钢集团钢铁钒钛股份有限公司 Drill collar steel and preparation method thereof
JP2015045069A (en) * 2013-08-29 2015-03-12 山陽特殊製鋼株式会社 Steel for machine structural use excellent in hardenability and toughness
CN105886901A (en) * 2016-05-30 2016-08-24 舞阳钢铁有限责任公司 Production method for ASTM A514 GrE high-strength steel plates

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100415626B1 (en) * 2001-06-30 2004-01-24 기아특수강 주식회사 High Strength Wear Resistance Steel with Excellent Hardenability
CN102260827A (en) * 2010-05-26 2011-11-30 攀钢集团钢铁钒钛股份有限公司 Drill collar steel and preparation method thereof
CN102002633A (en) * 2010-10-26 2011-04-06 攀钢集团钢铁钒钛股份有限公司 Carbon steel and manufacturing method thereof
CN102031452A (en) * 2010-10-26 2011-04-27 攀钢集团钢铁钒钛股份有限公司 Alloy steel and manufacturing method thereof
JP2015045069A (en) * 2013-08-29 2015-03-12 山陽特殊製鋼株式会社 Steel for machine structural use excellent in hardenability and toughness
CN105886901A (en) * 2016-05-30 2016-08-24 舞阳钢铁有限责任公司 Production method for ASTM A514 GrE high-strength steel plates

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