JPH09183870A - Wear-resistant flame-retardant resin composition - Google Patents
Wear-resistant flame-retardant resin compositionInfo
- Publication number
- JPH09183870A JPH09183870A JP35321095A JP35321095A JPH09183870A JP H09183870 A JPH09183870 A JP H09183870A JP 35321095 A JP35321095 A JP 35321095A JP 35321095 A JP35321095 A JP 35321095A JP H09183870 A JPH09183870 A JP H09183870A
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- Japan
- Prior art keywords
- weight
- resin composition
- density polyethylene
- parts
- retardant resin
- Prior art date
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、自動車等の機器用電線
の絶縁層やジャケットに有用な耐摩耗性難燃樹脂組成物
に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wear-resistant flame-retardant resin composition useful for insulating layers and jackets of electric wires for equipment such as automobiles.
【０００２】[0002]
【従来技術および発明が解決しようとする課題】近年、
難燃性の組成物としては、燃焼時に有毒ガスを発生する
ハロゲン含有組成物に代えて、ポリオレフィン系樹脂に
多量の水和金属酸化物を配合してなるノンハロゲン組成
物が用いられている。しかし該組成物は耐摩耗性や引張
特性などの機械強度が劣るという問題があった。例え
ば、該組成物を自動車や電子機器などの機器内部に使用
される電線の被覆材や該電線を束ねるテープに用いた場
合、上記電線は、狭い機器内部に配線されるため、配線
時などに受ける強度のしごきや引張りに絶えうるべく耐
摩耗性や引張特性などの機械強度に優れることが要求さ
れる。BACKGROUND OF THE INVENTION In recent years,
As the flame-retardant composition, a non-halogen composition obtained by blending a large amount of a hydrated metal oxide with a polyolefin resin is used instead of the halogen-containing composition that produces a toxic gas during combustion. However, there is a problem that the composition is inferior in mechanical strength such as abrasion resistance and tensile properties. For example, when the composition is used as a coating material for electric wires used in the inside of devices such as automobiles and electronic devices and a tape for bundling the electric wires, the electric wires are wired inside a narrow device, and therefore, at the time of wiring. It is required to have excellent mechanical strength such as abrasion resistance and tensile properties in order to withstand the ironing and pulling of the strength.
【０００３】上記問題を解決するため、密度が０．８５
〜０．９４ｇ／ｃｍ3 のポリエチレンと密度が０．９４
ｇ／ｃｍ3 以上の高密度ポリエチレンとの混合物に水和
金属酸化物を配合してなる組成物が提案されている（特
開平５−３０１９９６号）。一方、近年、機器の小型化
および軽量化への要求が益々高まり、電線の被覆材の薄
肉化が強く望まれている。かかる状況下において、上記
組成物は耐摩耗性や引張特性などの機械強度が不十分で
あり、すなわち、上記組成物を機器用電線の被覆材に用
いて薄肉化した場合、機器内部への配線時などに受ける
強度のしごきや引張りに絶えうることができないという
問題があった。To solve the above problems, the density is 0.85.
~ 0.94g / cm 3 polyethylene and density 0.94
A composition has been proposed in which a hydrated metal oxide is mixed with a mixture of high density polyethylene of g / cm 3 or more (JP-A-5-301996). On the other hand, in recent years, there has been an increasing demand for smaller and lighter equipment, and there has been a strong demand for thinner electric wire coating materials. Under such circumstances, the composition has insufficient mechanical strength such as abrasion resistance and tensile properties, that is, when the composition is used as a coating material for electric wires for equipment to make it thinner, wiring inside the equipment There was a problem in that the strength received at times such as ironing and pulling could not be maintained.
【０００４】本発明は、耐摩耗性および引張特性に優れ
た耐摩耗性難燃樹脂組成物を提供するものであり、特
に、自動車等の機器用電線の絶縁層やジャケット、およ
び該電線を束ねるテープに有用な耐摩耗性難燃樹脂組成
物を提供するものである。The present invention provides a wear-resistant flame-retardant resin composition having excellent wear resistance and tensile properties, and in particular, an insulating layer and a jacket for electric wires for devices such as automobiles, and the electric wires are bundled. An abrasion-resistant flame-retardant resin composition useful for a tape is provided.
【０００５】[0005]
【課題を解決するための手段】本発明は、超低密度ポリ
エチレンと高密度ポリエチレンとからなる基礎樹脂１０
０重量部に対して、シリコングラフト化エチレン−メチ
ルメタクリレート共重合体、シリコングラフト化エチレ
ン−プロピレン−ジエン三元重合体、シリコングラフト
化ポリスチレンの群から選ばれた少なくとも１種または
２種以上３〜５０重量部、及び水和金属化合物５０〜２
００重量部配合してなることを特徴とする耐摩耗性難燃
樹脂組成物によって上記課題を解決するものである。ま
た、上記基礎樹脂において、超低密度ポリエチレンと高
密度ポリエチレンとの混合比が、重量比で８０：２０〜
５０：５０であることによって、さらに耐摩耗性及び引
張特性に優れる。また、上記の耐摩耗性難燃樹脂組成物
を電気絶縁用の被覆材として用いることによって、耐摩
耗性及び難燃性に優れた電気絶縁用の被覆材となる。ま
た、上記の耐摩耗性難燃樹脂組成物をテープ状に成形し
て用いることによって、耐摩耗性及び難燃性に優れたテ
ープとなる。DISCLOSURE OF THE INVENTION The present invention relates to a base resin 10 comprising ultra-low density polyethylene and high density polyethylene.
Based on 0 part by weight, at least one selected from the group of silicon-grafted ethylene-methyl methacrylate copolymer, silicon-grafted ethylene-propylene-diene terpolymer, and silicon-grafted polystyrene or two or more thereof 3 to 3 50 parts by weight, and hydrated metal compound 50-2
The above problem is solved by an abrasion-resistant flame-retardant resin composition characterized by being mixed in an amount of 00 parts by weight. In the above basic resin, the mixing ratio of ultra-low density polyethylene and high density polyethylene is 80:20 by weight.
When it is 50:50, the wear resistance and the tensile properties are further excellent. Further, by using the above-mentioned abrasion-resistant flame-retardant resin composition as a coating material for electrical insulation, it becomes a coating material for electrical insulation excellent in abrasion resistance and flame retardancy. Further, by using the above abrasion-resistant flame-retardant resin composition by molding it into a tape shape, a tape having excellent abrasion resistance and flame retardancy can be obtained.
【０００６】次に本発明で用いる材料について詳細に説
明する。本発明で用いる超低密度ポリエチレンは、エチ
レンとα−オレフィンとを重合させて得られるものであ
る。エチレンとα−オレフィンとの重合方法は、通常用
いられる方法であれば特に制限はなく、溶液法やスラリ
ー法の液相法、気相法、高圧法が挙げられる。上記のα
−オレフィンとしては、例えば、１−ブテン、１−ペン
テン、１−ヘキセン、１−オクテン、エチル−ヘキセン
−１、ｎ−デセン−１、４，４−ジメチルペンテンなど
が挙げられる。Next, the materials used in the present invention will be described in detail. The ultra low density polyethylene used in the present invention is obtained by polymerizing ethylene and α-olefin. The polymerization method of ethylene and α-olefin is not particularly limited as long as it is a commonly used method, and a liquid phase method such as a solution method or a slurry method, a gas phase method, and a high pressure method can be mentioned. The above α
Examples of the olefin include 1-butene, 1-pentene, 1-hexene, 1-octene, ethyl-hexene-1, n-decene-1,4,4-dimethylpentene and the like.
【０００７】上記の本発明に用いる超低密度ポリエチレ
ンとしては、密度が０．８８〜０．９１ｇ／ｃｍ3 のも
のが好ましい。また、本発明で用いる高密度ポリエチレ
ンとしては、密度が０．９４〜０．９７ｇ／ｃｍ3 のも
のが好ましい。なお、本発明における密度は、ＪＩＳ
Ｋ６７６０によって測定された値である。The ultra-low density polyethylene used in the present invention is preferably one having a density of 0.88 to 0.91 g / cm 3 . The high density polyethylene used in the present invention preferably has a density of 0.94 to 0.97 g / cm 3 . Incidentally, the density in the present invention is JIS
It is the value measured by K6760.
【０００８】本発明で用いる基礎樹脂は、上記の超低密
度ポリエチレンと高密度ポリエチレンとからなるもので
ある。該基礎樹脂における超低密度ポリエチレンと高密
度ポリエチレンとの配合比は、重量比で８０：２０〜５
０：５０が好ましく、機械特性の点から特に、７０：３
０〜６０：４０がより好ましい。超低密度ポリエチレン
の量が多すぎると耐摩耗性が低下する傾向にあり、ま
た、高密度ポリエチレンの配合量が多すぎると引張り特
性が低下する傾向にある。The basic resin used in the present invention comprises the above-mentioned ultra-low density polyethylene and high density polyethylene. The mixing ratio of the ultra low density polyethylene and the high density polyethylene in the base resin is 80:20 to 5 by weight.
0:50 is preferable and 70: 3 is particularly preferable from the viewpoint of mechanical properties.
0 to 60:40 is more preferable. If the amount of ultra-low density polyethylene is too large, the wear resistance tends to decrease, and if the amount of high density polyethylene is too large, the tensile properties tend to decrease.
【０００９】本発明においては、上記基礎樹脂にシリコ
ングラフト化ポリマーを配合するが、本発明に用いるシ
リコングラフト化ポリマーは、シリコングラフト化エチ
レン−メチルメタクリレート共重合体、シリコングラフ
ト化エチレン−プロピレン−ジエン三元重合体、シリコ
ングラフト化ポリスチレンの群から選ばれた少なくとも
１種または２種以上である。上記のシリコングラフト化
ポリマーは、エチレン−メチルメタクリレート共重合
体、エチレン−プロピレン−ジエン三元重合体、ポリス
チレンに、例えば、ポリオルガノシロキサンを加熱混合
することによって得ることができる。上記ポリオルガノ
シロキサンとしては特に制限はなく、例えば、ビニル基
やアクリル基などの脂肪族不飽和基、エチル基やブチル
基などの脂肪族炭化水素基、フェニル基やベンジル基な
どの芳香族炭化水素基、及び／又は、シクロヘキシル基
やシクロブチル基などの脂環式炭化水素基を有するオル
ガノシロキサンの重合体などが挙げられる。In the present invention, the above-mentioned basic resin is blended with a silicon-grafted polymer. The silicon-grafted polymer used in the present invention includes a silicon-grafted ethylene-methyl methacrylate copolymer and a silicon-grafted ethylene-propylene-diene. It is at least one type or two or more types selected from the group of terpolymers and silicon-grafted polystyrene. The above silicon-grafted polymer can be obtained by heat-mixing ethylene-methyl methacrylate copolymer, ethylene-propylene-diene terpolymer, and polystyrene with, for example, polyorganosiloxane. The polyorganosiloxane is not particularly limited, and examples thereof include an aliphatic unsaturated group such as a vinyl group and an acrylic group, an aliphatic hydrocarbon group such as an ethyl group and a butyl group, an aromatic hydrocarbon group such as a phenyl group and a benzyl group. Examples thereof include polymers of organosiloxane having a group and / or an alicyclic hydrocarbon group such as a cyclohexyl group and a cyclobutyl group.
【００１０】上記シリコングラフト化ポリマーの配合量
は基礎樹脂１００重量部に対して３〜５０重量部であ
り、機械特性の点から特に、５〜３０重量部が好まし
い。配合量が３重量部未満であると耐摩耗性が低下し、
５０重量部を超えると引張特性が低下するため好ましく
ない。The amount of the above-mentioned silicon-grafted polymer is 3 to 50 parts by weight with respect to 100 parts by weight of the base resin, and 5 to 30 parts by weight is particularly preferable from the viewpoint of mechanical properties. If the blending amount is less than 3 parts by weight, the wear resistance decreases,
If it exceeds 50 parts by weight, the tensile properties are deteriorated, which is not preferable.
【００１１】本発明に用いられる水和金属化合物として
は、水酸化マグネシウム、水酸化アルミニウム、水酸化
カルシウム、水酸化バリウム、酸化ジルコニウム水和
物、酸化スズ水和物、酸化マンガン水和物、酸化鉛水和
物、硫酸マグネシウム水和物、炭酸マグネシウム水和
物、硼酸亜鉛水和物、ハイドロタルサイト、ドウソナイ
トなどが挙げられ、難燃性の点から特に、水酸化マグネ
シウム、水酸化アルミニウムが好ましい。上記水和金属
化合物の配合量は基礎樹脂１００重量部に対して５０〜
２００重量部であり、難燃性および引張特性の点から特
に８０〜１５０重量部が好ましい。配合量が５０重量部
未満であると難燃性が低下し、２００重量部を超えると
引張特性が低下するため好ましくない。The hydrated metal compound used in the present invention includes magnesium hydroxide, aluminum hydroxide, calcium hydroxide, barium hydroxide, zirconium oxide hydrate, tin oxide hydrate, manganese oxide hydrate, and oxides. Lead hydrates, magnesium sulfate hydrates, magnesium carbonate hydrates, zinc borate hydrates, hydrotalcites, dawsonite, and the like can be mentioned, and magnesium hydroxide and aluminum hydroxide are particularly preferable from the viewpoint of flame retardancy. . The compounding amount of the hydrated metal compound is 50 to 100 parts by weight of the base resin.
It is 200 parts by weight, and particularly preferably 80 to 150 parts by weight from the viewpoint of flame retardancy and tensile properties. If the blending amount is less than 50 parts by weight, the flame retardancy is lowered, and if it exceeds 200 parts by weight, the tensile properties are lowered, which is not preferable.
【００１２】本発明の組成物は、必要に応じて架橋して
用いてもよい。この場合、架橋剤として有機過酸化物を
用いるのが好ましく、該有機過酸化物としては通常使用
されるものであれば特に制限はなく、例えば、ジクミル
パーオキサイド、ジ−ターシャリーブチルパーオキサイ
ド、２，５−ジメチル−２，５−ジ（ｔ−ブチルパーオ
キシヘキサン）等を適宜用いればよい。また、架橋助剤
を併用してもよく、該架橋助剤としては例えば、トリア
リルイソシアヌレート、トリアリルイソシアレート、ト
リアリルフマレートなどが挙げられる。また、本発明の
組成物は、シラン架橋、あるいは電子線照射によって架
橋してもよい。The composition of the present invention may be used after being crosslinked if necessary. In this case, it is preferable to use an organic peroxide as the cross-linking agent, and the organic peroxide is not particularly limited as long as it is usually used, and examples thereof include dicumyl peroxide and di-tertiary butyl peroxide. , 2,5-dimethyl-2,5-di (t-butylperoxyhexane) and the like may be appropriately used. Further, a crosslinking aid may be used in combination, and examples of the crosslinking aid include triallyl isocyanurate, triallyl isocyanurate, triallyl fumarate and the like. In addition, the composition of the present invention may be crosslinked by silane crosslinking or electron beam irradiation.
【００１３】本発明の組成物には、必要に応じて、タル
ク、クレー、炭酸カルシウム、炭酸マグネシウム、酸化
マグネシウム、硫酸バリウム、シリカなどの充填剤、ヒ
ンダードフェノール類、芳香族アミン類などの酸化防止
剤、赤リン、ホウ酸亜鉛、酸化アンチモンなどの難燃助
剤、ステアリン酸、オレイン酸、高級脂肪酸金属塩など
の滑剤、カーボンブラック、酸化チタン、ベンガラなど
の着色剤、その他、チタネート系やシラン系などのカッ
プリング剤、加工助剤などの添加剤を適宜添加してもよ
い。The composition of the present invention contains, if necessary, talc, clay, calcium carbonate, magnesium carbonate, magnesium oxide, barium sulfate, fillers such as silica, hindered phenols and aromatic amines. Inhibitors, red phosphorus, zinc borate, flame retardant aids such as antimony oxide, lubricants such as stearic acid, oleic acid, higher fatty acid metal salts, coloring agents such as carbon black, titanium oxide, red iron oxide, etc. Additives such as silane coupling agents and processing aids may be appropriately added.
【００１４】本発明の組成物は、通常の混練手段によっ
て、例えばバンバリーミキサー、ヘンシュルミキサー、
ニーダ、ロール、ブレンダなどによって混練され、次い
で押出機、射出成形機などの成形機を用いて適宜の形状
に成形される。本発明の組成物は、各種用途に適用可能
であり、例えば、電線の電気絶縁層及び外部シース等の
電気絶縁用の被覆材、テープ、各種シート、パイプ、回
路部品、封止材料等に用いられる。その中でも特に、電
線の電気絶縁用の被覆材および電線を束ねるテープとし
て有用であり、就中、自動車などの機器用電線の電気絶
縁用の被覆材および電線を束ねるテープとして好適に用
いられる。The composition of the present invention is prepared by a conventional kneading means, for example, Banbury mixer, Henshur mixer,
It is kneaded with a kneader, roll, blender, etc., and then molded into an appropriate shape using a molding machine such as an extruder or an injection molding machine. INDUSTRIAL APPLICABILITY The composition of the present invention is applicable to various uses, for example, used as a covering material for electric insulation such as an electric insulating layer of a wire and an outer sheath, a tape, various sheets, pipes, circuit parts, a sealing material and the like. To be Among them, it is particularly useful as a covering material for electric insulation of electric wires and a tape for bundling electric wires, and is particularly preferably used as a covering material for electric insulation of electric wires for devices such as automobiles and a tape for bundling electric wires.
【００１５】（実施例１〜３、比較例１〜４）表１に示
す各成分をミキシングロールを用いて１５０℃にて混練
し、押出機にて２００℃で加熱して、導体上に厚さ０．
４ｍｍで押出被覆した試料を得た。これら試料につい
て、耐摩耗性、引張特性、および、伸びを以下の方法で
評価した。結果を表１に示す。 （耐摩耗性）上記の試料について、ＪＡＳＯ（Ｊａｐａ
ｎｅｓｅ ＡｕｔｏｍｏｂｉｌｅＳｔａｎｄａｒｄ Ｏ
ｒｇａｎｉｚａｔｉｏｎ） Ｄ６１１の耐摩耗試験のブ
レード往復法に準拠して、加重３５０ｇにて測定した往
復回数によって評価した。往復回数が１０００回以上を
○、５００回を超えて１０００回未満を△、５００回以
下を×とした。 （引張特性）上記の試料について、ＪＩＳ Ｋ６７２３
に準拠して測定した引張強度により評価した。引張強度
が１３ＭＰａ以上を○、１３ＭＰａ未満を×とした。 （伸び）上記の試料について、ＪＩＳ Ｋ６７２３に準
拠して測定した伸び率により評価した。伸び率が１５０
％以上を○、１５０％未満を×とした。 （難燃性）表１に示す各成分をミキシングロールを用い
て１２０℃にて混練し、圧縮成形機中で１７０℃、１０
分の条件で加熱して成形し、厚さ３ｍｍのシート状の試
料を得た。これら試料について、ＪＩＳ Ｋ７２０１に
準拠して測定した酸素指数により難燃性を評価した。酸
素指数が２６％以上を○、２６％未満を×とした。結果
を表１に示す。(Examples 1 to 3 and Comparative Examples 1 to 4) The components shown in Table 1 were kneaded at 150 ° C. using a mixing roll and heated at 200 ° C. by an extruder to give a thick layer on the conductor. 0.
A 4 mm extrusion coated sample was obtained. These samples were evaluated for wear resistance, tensile properties and elongation by the following methods. The results are shown in Table 1. (Abrasion resistance) For the above samples, JASO (Japan
Nese AutomobileStandard O
Evaluation was performed by the number of reciprocations measured at a load of 350 g in accordance with the blade reciprocation method of the abrasion resistance test of D611. When the number of reciprocations was 1000 times or more, ◯ was given, when more than 500 times and less than 1000 times was given as Δ, and 500 times or less was given as x. (Tensile property) Regarding the above sample, JIS K6723
The tensile strength was measured according to A tensile strength of 13 MPa or more was evaluated as ◯, and a tensile strength of less than 13 MPa was evaluated as x. (Elongation) The above samples were evaluated by the elongation rate measured according to JIS K6723. Elongation rate is 150
% Or more was evaluated as ◯, and less than 150% was evaluated as x. (Flame retardancy) The components shown in Table 1 were kneaded at 120 ° C using a mixing roll, and then 170 ° C in a compression molding machine at 10 ° C.
It was heated and molded under the condition of minutes to obtain a sheet-like sample having a thickness of 3 mm. The flame retardancy of these samples was evaluated by the oxygen index measured according to JIS K7201. An oxygen index of 26% or more was evaluated as ◯, and an oxygen index of less than 26% was evaluated as x. The results are shown in Table 1.
【００１６】[0016]
【表１】 [Table 1]
【００１７】[0017]
【効果】本発明の耐摩耗性難燃樹脂組成物は、超低密度
ポリエチレンと高密度ポリエチレンとからなる基礎樹脂
１００重量部に対して、シリコングラフト化エチレン−
メチルメタクリレート共重合体、シリコングラフト化エ
チレン−プロピレン−ジエン三元重合体、シリコングラ
フト化ポリスチレンの群から選ばれた少なくとも１種ま
たは２種以上３〜５０重量部、及び水和金属化合物５０
〜２００重量部配合してなることによって、耐摩耗性や
引張特性などの機械特性に優れるため、本発明の組成物
をより薄肉成形とした場合にも、耐摩耗性や引張特性な
どの機械特性に優れた成形物が得られる。また、上記基
礎樹脂において、超低密度ポリエチレンと高密度ポリエ
チレンとの混合比が、重量比で８０：２０〜５０：５０
であることによって、さらに耐摩耗性及び引張り特性に
優れる。また、上記の耐摩耗性難燃樹脂組成物を電気絶
縁用の被覆材として用いることによって、耐摩耗性及び
難燃性に優れた特に機器用電線に好適な電気絶縁用の被
覆材となり、被覆材の薄肉化が可能になる。また、上記
の耐摩耗性難燃樹脂組成物をテープ状に成形して用いる
ことによって、耐摩耗性及び難燃性に優れた特に機器用
電線を束ねるのに好適なテープとなり、テープの薄肉化
が可能になる。[Effect] The wear-resistant flame-retardant resin composition of the present invention contains 100 parts by weight of a base resin composed of ultra-low density polyethylene and high-density polyethylene, and a silicone-grafted ethylene-
Methyl methacrylate copolymer, silicon-grafted ethylene-propylene-diene terpolymer, 3 to 50 parts by weight of at least one selected from the group of silicon-grafted polystyrene, and 50 to 50 parts of hydrated metal compound.
~ 200 parts by weight, because of excellent mechanical properties such as wear resistance and tensile properties, even when the composition of the present invention is formed into a thinner wall, mechanical properties such as wear resistance and tensile properties. An excellent molded product can be obtained. In the above basic resin, the mixing ratio of ultra-low density polyethylene and high-density polyethylene is 80:20 to 50:50 by weight.
By this, the wear resistance and the tensile properties are further excellent. Further, by using the above wear-resistant flame-retardant resin composition as a coating material for electrical insulation, it becomes a coating material for electrical insulation, which is excellent in wear resistance and flame retardancy and is particularly suitable for electric wires for devices, and coating The material can be made thinner. Further, by using the above abrasion-resistant flame-retardant resin composition formed into a tape shape, it becomes a tape excellent in abrasion resistance and flame retardancy, which is particularly suitable for bundling electric wires for equipment, and the tape is thinned. Will be possible.
Claims (4)
レンとからなる基礎樹脂１００重量部に対して、シリコ
ングラフト化エチレン−メチルメタクリレート共重合
体、シリコングラフト化エチレン−プロピレン−ジエン
三元重合体、シリコングラフト化ポリスチレンの群から
選ばれた少なくとも１種または２種以上３〜５０重量
部、及び水和金属化合物５０〜２００重量部配合してな
ることを特徴とする耐摩耗性難燃樹脂組成物。1. A silicon-grafted ethylene-methylmethacrylate copolymer, a silicon-grafted ethylene-propylene-diene terpolymer, and a silicone based on 100 parts by weight of a base resin composed of ultra-low-density polyethylene and high-density polyethylene. An abrasion-resistant flame-retardant resin composition comprising 3 to 50 parts by weight of at least one selected from the group of grafted polystyrene and 2 to 50 parts by weight, and 50 to 200 parts by weight of a hydrated metal compound.
チレンと高密度ポリエチレンとの混合比が、重量比で８
０：２０〜５０：５０である請求項１または請求項２記
載の耐摩耗性難燃樹脂組成物。2. The base resin, wherein the mixing ratio of ultra-low density polyethylene and high density polyethylene is 8 by weight.
The abrasion-resistant flame-retardant resin composition according to claim 1 or 2, which is 0:20 to 50:50.
求項１〜３いずれかに記載の耐摩耗性難燃樹脂組成物。3. The abrasion-resistant flame-retardant resin composition according to claim 1, which is used as a coating material for electrical insulation.
１〜４いずれかに記載の耐摩耗性難燃樹脂組成物。4. The abrasion-resistant flame-retardant resin composition according to claim 1, which is used in the form of a tape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP35321095A JPH09183870A (en) | 1995-12-28 | 1995-12-28 | Wear-resistant flame-retardant resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP35321095A JPH09183870A (en) | 1995-12-28 | 1995-12-28 | Wear-resistant flame-retardant resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH09183870A true JPH09183870A (en) | 1997-07-15 |
Family
ID=18429311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP35321095A Pending JPH09183870A (en) | 1995-12-28 | 1995-12-28 | Wear-resistant flame-retardant resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH09183870A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100601146B1 (en) * | 1999-11-12 | 2006-07-13 | 삼성토탈 주식회사 | Polyethylene resin composition for plastic closure and its article |
| WO2016031789A1 (en) * | 2014-08-25 | 2016-03-03 | 株式会社フジクラ | Flame-retardant resin composition, cable using same, and optical fiber cable |
| WO2019093288A1 (en) * | 2017-11-13 | 2019-05-16 | 住友電気工業株式会社 | Insulating material and insulated wire |
-
1995
- 1995-12-28 JP JP35321095A patent/JPH09183870A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100601146B1 (en) * | 1999-11-12 | 2006-07-13 | 삼성토탈 주식회사 | Polyethylene resin composition for plastic closure and its article |
| WO2016031789A1 (en) * | 2014-08-25 | 2016-03-03 | 株式会社フジクラ | Flame-retardant resin composition, cable using same, and optical fiber cable |
| JP5890077B1 (en) * | 2014-08-25 | 2016-03-22 | 株式会社フジクラ | Flame-retardant resin composition, cable using the same, and optical fiber cable |
| US10483017B2 (en) | 2014-08-25 | 2019-11-19 | Fujikura Ltd. | Flame retardant resin composition, cable using same and optical fiber cable |
| WO2019093288A1 (en) * | 2017-11-13 | 2019-05-16 | 住友電気工業株式会社 | Insulating material and insulated wire |
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