JPH0914751A - Hot water heater - Google Patents
Hot water heaterInfo
- Publication number
- JPH0914751A JPH0914751A JP15809695A JP15809695A JPH0914751A JP H0914751 A JPH0914751 A JP H0914751A JP 15809695 A JP15809695 A JP 15809695A JP 15809695 A JP15809695 A JP 15809695A JP H0914751 A JPH0914751 A JP H0914751A
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- hot water
- set temperature
- time
- delivery hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Control Of Combustion (AREA)
- Instantaneous Water Boilers, Portable Hot-Water Supply Apparatuses, And Control Of Portable Hot-Water Supply Apparatuses (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、設定温度と出湯温度と
を所定の条件で比較して異常を検知し、燃焼停止等の処
理を行う安全機能を備えた給湯装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hot water supply apparatus having a safety function of comparing a set temperature with a hot water discharge temperature under a predetermined condition to detect an abnormality and perform processing such as combustion stop.
【0002】[0002]
【従来の技術】上記給湯装置における従来の安全機能を
図4のフローチャートに示す。これは、S4の湯温制御
により給湯される出湯温度が、S5で設定温度より所定
温度以上高いか否かを判断し、高い場合には続いてS6
でその状態が所定時間以上続くか否かを判断して、この
所定時間経過時点で燃焼停止等させるものである。一方
図3は、大阪ガス株式会社の商品技術開発部が作成した
「家庭用ガス機器性能基準」における「皮膚のやけどに
対すると時間と温度の関係」を示すグラフで、縦軸が皮
膚表面温度(℃)、横軸が経過時間(s)を現わし、実
線bより上が、皮膚が損傷を受ける領域、破線aより下
が、安全な領域で、又破線aと実線bとの間は元の状態
に戻り得る領域となっている。これによれば、例えば5
0℃では2分、55℃では10秒弱、60℃では約2.
5秒の経過時間でやけどになることがわかる。このよう
にやけどをする可能性は温度と時間との関係によって変
化し、温度が高くなるに従って時間が短くなる破線a
(以下やけど曲線という)で現われることが理解でき
る。2. Description of the Related Art A conventional safety function of the above hot water supply apparatus is shown in the flowchart of FIG. It is determined whether or not the temperature of the hot water supplied by the hot water temperature control in S4 is higher than the set temperature by a predetermined temperature or more in S5.
Then, it is judged whether or not the state continues for a predetermined time or longer, and the combustion is stopped when the predetermined time elapses. On the other hand, FIG. 3 is a graph showing "relationship between time and temperature for skin burns" in "Household Gas Appliance Performance Standards" created by the Product Technology Development Department of Osaka Gas Co., Ltd., where the vertical axis indicates the skin surface temperature ( C), the horizontal axis represents the elapsed time (s), the area above the solid line b is the area where the skin is damaged, the area below the broken line a is the safe area, and the area between the broken line a and the solid line b is the original It is an area where you can return to the state of. According to this, for example, 5
2 minutes at 0 ° C, less than 10 seconds at 55 ° C, about 2. at 60 ° C.
You can see that it burns after 5 seconds. Like this, the possibility of being burned changes depending on the relationship between temperature and time, and the higher the temperature, the shorter the time.
You can understand that it appears (hereinafter called a burn curve).
【0003】[0003]
【発明が解決しようとする課題】ところが上記従来の安
全機能にあっては、異常判断する所定時間が設定温度に
関係なく一定となっているから、例えば設定温度が、使
用者が意識して湯に触れようとする温度の50℃以下の
場合、出湯温度が60℃であると、上記のように短時間
でやけどになるため、異常判断がなされて燃焼停止等し
ても間に合わない可能性がある。又異常判断する温度よ
りも低い温度では異常検知しないが、やけど曲線におけ
る相応の温度と時間によりやけどの危険性はあるので、
安全上問題がある。一方給湯装置においては、入水温度
が比較的高く、流量が少ない場合等に、設定温度より出
湯温度がかなり高くなることがある(例えばソーラーシ
ステムを採用した装置では、入水温度40℃、入水量3
〜4リットル、設定温度60℃の場合で、出湯温度が8
0℃以上となることがある)。しかしこの場合、使用者
は設定温度が高温であることを認識しているため、湯に
触れてやけどを起こすことは考えにくく、逆にこの場合
に所定時間経過で燃焼停止等の処理がされると、使い勝
手が悪くなってしまう。However, in the above-mentioned conventional safety function, since the predetermined time for judging an abnormality is constant regardless of the set temperature, for example, the user is aware of the set temperature. If the hot water temperature is 50 ° C or less and the hot water temperature is 60 ° C, you may get burned in a short time as described above, so it may not be in time even if an abnormal judgment is made and combustion is stopped. is there. Moreover, although the temperature is lower than the temperature for judging abnormalities, the abnormality is not detected, but there is a risk of burns due to the corresponding temperature and time on the burn curve.
There is a safety problem. On the other hand, in the hot water supply device, the hot water discharge temperature may be considerably higher than the set temperature when the incoming water temperature is relatively high and the flow rate is small (for example, in the device employing the solar system, the incoming water temperature is 40 ° C and the incoming water amount is 3
~ 4 liters, set temperature 60 ℃, hot water temperature is 8
It may be 0 ° C or higher). However, in this case, since the user recognizes that the set temperature is high, it is unlikely that the user will touch the hot water and cause a burn, and conversely, in this case, processing such as combustion stop is performed after a predetermined time elapses. Then, the usability becomes worse.
【0004】[0004]
【課題を解決するための手段】そこで本発明は、上記や
けど曲線による温度と時間との関係に着目し、より安全
で、而も使い勝手の損なわれない給湯装置を提供するも
ので、その構成は、出湯される湯の温度を設定する温度
設定手段と、出湯される湯の温度を検出する温度検出手
段と、前記温度設定手段で設定された設定温度と温度検
出手段で検出された出湯温度とを所定の条件で比較して
作動異常の判断をする判断手段とを備えた給湯装置にお
いて、前記条件を、任意の設定温度の範囲で、出湯温度
が設定温度より所定の温度以上高い状態で所定時間以上
続いた場合に異常とみなすものとすると共に、前記所定
時間を、やけどをする可能性のある温度と時間との関係
に従い、出湯温度が高温となるにつれて短くなるように
したことを特徴とするものである。又前記任意の設定温
度の範囲の上限は50℃とするのが望ましい。SUMMARY OF THE INVENTION Therefore, the present invention focuses on the relationship between temperature and time based on the above-mentioned burn curve, and provides a safer hot water supply apparatus which does not impair usability. A temperature setting means for setting the temperature of the hot water to be discharged, a temperature detecting means for detecting the temperature of the hot water to be discharged, a set temperature set by the temperature setting means and a hot water temperature detected by the temperature detecting means. In a hot water supply device provided with a determination means for comparing the above conditions with a predetermined condition to determine an abnormal operation, the condition is set to a predetermined value in a range of an arbitrary set temperature, in which the hot water discharge temperature is higher than the set temperature by a predetermined temperature or more. It is considered to be abnormal when it continues for more than a time, and the predetermined time is shortened as the hot water temperature rises in accordance with the relationship between the temperature and the time that may cause burns. Is shall. Further, it is desirable that the upper limit of the arbitrary set temperature range is 50 ° C.
【0005】[0005]
【作用】使用者が意識して湯に触れようとする温度以下
等の任意の設定温度の範囲に限って、出湯温度が設定温
度より所定温度以上高い状態が続くと、その出湯温度に
よりやけどを起こす時間の経過前に異常判断が行われて
燃焼停止等がなされる。この時間は高温となるに従って
短くなる。逆に前記任意の設定温度範囲外では、出湯温
度が高くなることがあっても、やけどと温度と時間との
関係での異常判断がなされないから、使い勝手が損なわ
れることがない。又上記任意の設定温度範囲の上限の5
0℃は、使用者が意識して湯に触れ得る温度の上限とし
て最適値と考えられる。[Operation] If the hot water temperature continues to be higher than the set temperature by a predetermined temperature or more within a range of an arbitrary set temperature such as a temperature below which the user is consciously trying to touch the hot water, the hot water temperature causes burns. Abnormality judgment is made before the elapse of the wake-up time and combustion is stopped. This time becomes shorter as the temperature becomes higher. On the contrary, even if the hot water outlet temperature rises outside the above-mentioned arbitrary set temperature range, an abnormality judgment is not made in the relation between the burn, the temperature and the time, so the usability is not impaired. Also, the upper limit of the above-mentioned arbitrary set temperature range is 5
0 ° C. is considered to be the optimum value as the upper limit of the temperature at which the user can consciously touch the hot water.
【0006】[0006]
【実施例】以下本発明の実施例を図面に基づいて説明す
る。図1は本発明を適用した給湯器の概略図を示すもの
で、ハウジング1内の燃焼室2には、ガスバーナ3と熱
交換器4とが設けられ、熱交換器4内を通過する通水管
5の上流側に、上水道に連結された給水管6が、下流側
に、浴室や洗面所等の蛇口7が設けられた出湯管8が夫
々接続されている。前記ガスバーナ3には、図示しない
点火装置が具備されると共に、ガス供給管9が接続さ
れ、そのガス供給管9には、上流側より元弁10、比例
制御弁11、主弁12の順に3つの電磁弁が設けられて
いる。そして前記給水管6には、水量を検知する水量セ
ンサ13と、入水温度を検出する温度センサ14が、又
出湯管8には、出湯温度を検出する温度センサ15が夫
々備えられ、これらはバーナコントローラ16に接続さ
れて、通水の有無と入水温度、出湯温度が夫々入力され
るものとなっている。更にバーナコントローラ16は、
出湯温度を設定する温度設定つまみを備えたリモコン1
7の操作情報が受信可能となっており、それらの情報に
基づいて、元弁10と主弁12の開閉操作及び比例制御
弁11の調整操作がなされるものである。よってこのよ
うに構成された給湯器においては、出湯管8に取り付け
られている蛇口7を開くことによって給水管6内を水が
通過すると、その水の通過を水量センサ13が検知して
バーナコントローラ16に信号が送られ、水の通過信号
を受けたバーナコントローラ16からは燃焼指令信号が
出力されて、元弁10、主弁12を開放すると共にガス
バーナ3を点火させるものである。Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a schematic view of a water heater to which the present invention is applied. A gas burner 3 and a heat exchanger 4 are provided in a combustion chamber 2 in a housing 1, and a water pipe passing through the heat exchanger 4 is provided. 5, a water supply pipe 6 connected to the water supply is connected to the upstream side, and a tap water pipe 8 provided with a faucet 7 such as a bathroom or a washroom is connected to the downstream side. The gas burner 3 is equipped with an ignition device (not shown), and a gas supply pipe 9 is connected to the gas burner 3. The main valve 10, the proportional control valve 11, and the main valve 12 are arranged in this order from the upstream side. Two solenoid valves are provided. The water supply pipe 6 is provided with a water amount sensor 13 for detecting the amount of water, a temperature sensor 14 for detecting the incoming water temperature, and the hot water outlet pipe 8 is provided with a temperature sensor 15 for detecting the hot water outlet temperature. It is connected to the controller 16 to input the presence / absence of water flow, the incoming water temperature, and the outgoing hot water temperature, respectively. Furthermore, the burner controller 16
Remote control 1 with a temperature setting knob to set the hot water temperature
The operation information of No. 7 can be received, and the opening / closing operation of the main valve 10 and the main valve 12 and the adjustment operation of the proportional control valve 11 are performed based on the information. Therefore, in the water heater thus configured, when water passes through the water supply pipe 6 by opening the faucet 7 attached to the hot water outlet pipe 8, the water amount sensor 13 detects the passage of the water and the burner controller A signal is sent to the burner controller 16, and a combustion command signal is output from the burner controller 16 which receives the water passage signal, which opens the main valve 10 and the main valve 12 and ignites the gas burner 3.
【0007】そして上記バーナコントローラ16には、
温度センサ15からの検出信号を受けながら、前記リモ
コン17で設定された出湯温度になるように、比例制御
弁11を調整操作して出湯温度を設定温度と一致させる
温度調整機能と、設定温度が所定の値以下(例えば50
℃以下)の場合に限って、出湯温度が設定温度より所定
の値以上高くなる状態が所定時間続いた場合には、異常
と判断して警報や燃焼停止等の処理を行う安全機能とが
備えられているが、特にここでは、異常と判断するまで
の所定時間を出湯温度に応じて可変するようになってい
る。この所定時間の可変は、先に示したやけど曲線に対
応する温度と時間との関係によって与えられるものであ
る。以下その安全機能を図2のフローチャートに従って
説明する。まず、ステップ1(以下単にS1と略称す
る)で蛇口7の開栓により水量センサ13が検知した流
量が、所定の流量以上であるか否かが判断され、YES
の場合はS2でバーナコントローラ16が点火制御を行
い、S3で着火が確認されると、S4で比例制御弁11
の調整操作によってリモコン17で設定された温度で出
湯するように湯温制御がなされる。次にS5で、リモコ
ン17で設定された設定温度が50℃以下であるか否か
が判断され、YESの場合は、S6で出湯温度to が5
5℃から58℃の間であるか否かをチェックする。この
範囲内であれば、図3のやけど曲線aに応じて導き出さ
れる安全な領域で短い方の時間、即ち58℃に対応する
時間5秒の経過をS7で判断して、5秒経過時点で燃焼
異常と判断して元弁等の電磁弁を閉弁させ、ガス供給を
遮断して直ちに燃焼停止させる。又S6でのチェックが
NOであれば、続いてS8で、出湯温度to がS6より
高い58℃から60℃の間であるか否かをチェックす
る。この温度範囲では、やけど曲線aでは60℃で経過
時間2秒弱となっているから、判断時間をやや早めの2
秒に設定している。よってS9で2秒経過を確認すれ
ば、直ちに燃焼停止させることになる。そしてS8での
チェックがNOであれば、S10で、出湯温度to が6
0℃以上であるか否かをチェックすることになるが、や
けど曲線aでは65℃で経過時間1秒となっているか
ら、ここでは判断時間が1秒に設定されて、S11で1
秒経過を確認すると直ちに燃焼停止させるのである。The burner controller 16 includes:
While receiving the detection signal from the temperature sensor 15, the proportional control valve 11 is adjusted so that the hot water temperature set by the remote controller 17 is adjusted, and the temperature adjusting function for matching the hot water temperature with the set temperature is set. Below a predetermined value (eg 50
Only in the case of (° C or lower), when the hot water temperature exceeds the set temperature by a predetermined value or more for a predetermined time, it is judged as an abnormality and a safety function is provided to perform processing such as alarm and combustion stop. However, here, in particular, the predetermined time until it is determined to be abnormal is variable according to the hot water temperature. The change of the predetermined time is given by the relationship between the temperature and time corresponding to the burn curve shown above. The safety function will be described below with reference to the flowchart of FIG. First, in step 1 (hereinafter simply referred to as S1), it is determined whether or not the flow rate detected by the water amount sensor 13 by opening the faucet 7 is equal to or higher than a predetermined flow rate, and YES.
In the case of S1, the burner controller 16 performs ignition control in S2, and when ignition is confirmed in S3, the proportional control valve 11 is operated in S4.
The hot water temperature control is performed so that the hot water is discharged at the temperature set by the remote controller 17 by the adjustment operation. Next, in S5, it is determined whether or not the set temperature set by the remote controller 17 is 50 ° C. or lower. If YES, the tap water temperature t o is 5 in S6.
Check if between 5 ° C and 58 ° C. Within this range, the shorter time in the safe area derived according to the burn curve a in FIG. 3, that is, the time corresponding to 58 ° C., which is 5 seconds, is judged in S7 and when 5 seconds have elapsed When it is determined that the combustion is abnormal, the solenoid valve such as the main valve is closed, the gas supply is shut off, and the combustion is immediately stopped. Also if the check is NO in S6, followed by S8, checking whether the hot water temperature t o is between 60 ° C. from the higher 58 ° C. than S6. In this temperature range, the burn curve a has a lapse time of less than 2 seconds at 60 ° C., so the judgment time is slightly earlier than 2 seconds.
Set to seconds. Therefore, if it is confirmed that 2 seconds have passed in S9, the combustion is immediately stopped. And, if the check is NO at S8, in S10, the hot water temperature t o 6
Whether or not the temperature is 0 ° C. or higher is checked. However, since the burn curve a has an elapsed time of 1 second at 65 ° C., the determination time is set to 1 second here and 1 is set in S11.
The combustion is stopped immediately after confirming the elapse of seconds.
【0008】このように上記実施例では、50℃以下と
いう、使用者が意識して湯に触れようとする温度で設定
温度が指示された場合には、実際の出湯温度とやけど曲
線とを対応させて、異常を判断する時間を変更し、やけ
どが生じる前に燃焼停止させるようにしたから、安全性
はより高められる。逆に上記安全機能を働かせる設定温
度の範囲外、例えば設定温度60℃で出湯温度80℃の
場合には異常判断がなされないから、そのまま給湯が継
続され、又設定温度が低くて出湯温度が高い場合には異
常判断する所定時間が長くなるから、何れにしても使い
勝手の低下は生じないのである。尚上記実施例では、5
5〜58℃、58〜60℃、60℃以上と3つの範囲で
夫々判断時間を変更するものとしたが、チェックする温
度範囲を更に細かく分けたり、逆により広くしたりする
ことも可能で、又安全機能を適用する設定温度の上限
は、使用者が意識して湯に触れ得る温度と考えられる5
0℃を最適値として挙げたが、これも適宜変更しても差
し支えなく、下限を設定することも可能である。又上記
ではソーラーシステムを考慮して任意の設定温度範囲外
では異常判断を行わない例で説明したが、給湯装置のタ
イプによっては、任意の範囲外の設定温度では、出湯温
度が設定温度より所定温度以上高い状態で一定時間続い
た場合には異常判断する従来の安全機能を付与するよう
にしても良い。更に上記は給湯器に用いた例で説明した
が、給湯器付風呂装置等他の給湯装置にも適用できるの
は勿論である。As described above, in the above embodiment, when the set temperature is instructed by the user at a temperature of 50 ° C. or less, which is the temperature at which the user consciously touches the hot water, the actual hot water temperature and the burn curve are associated with each other. By changing the time to judge the abnormality and stopping the combustion before a burn occurs, the safety is further enhanced. On the contrary, if the temperature is outside the set temperature range for operating the above-mentioned safety function, for example, when the set temperature is 60 ° C. and the hot water temperature is 80 ° C., no abnormality judgment is made. Therefore, hot water supply is continued, or the set temperature is low and the hot water temperature is high. In this case, the predetermined time for determining the abnormality becomes long, and therefore the usability does not deteriorate in any case. In the above embodiment, 5
Although the judgment time was changed in each of the three ranges of 5 to 58 ° C., 58 to 60 ° C., and 60 ° C. or higher, the temperature range to be checked can be further divided into smaller ranges, or conversely wider. The upper limit of the set temperature to which the safety function is applied is considered to be the temperature at which the user can consciously touch the hot water.
Although 0 ° C. is given as the optimum value, this value may be appropriately changed, and the lower limit can be set. Further, in the above description, the solar system is taken into consideration in the example in which the abnormality determination is not performed outside the set temperature range, but depending on the type of the hot water supply device, at the set temperature outside the set range, the hot water outlet temperature is set to be higher than the set temperature. A conventional safety function for determining an abnormality may be added when the temperature is higher than the temperature and continues for a certain period of time. Further, although the above description has been made with respect to the example used for the water heater, it is needless to say that it can be applied to other water heaters such as a bath device with a water heater.
【0009】[0009]
【発明の効果】以上本発明は、作動異常を判断する所定
時間を、任意の設定温度の範囲に限り、やけどをする可
能性のある温度と時間の関係に従って、出湯温度が高温
となるに連れて短くなるようにしたことで、使用者が湯
に触れようとする温度範囲でやけどを起こす前に異常判
断が行え、安全な使用ができる。逆に前記任意の設定温
度範囲以外では、出湯温度が高くなることがあっても、
やけどと温度と時間との関係での異常判断がなされない
から、給湯が継続され、使い勝手は損なわれない。又任
意の設定温度範囲の上限の50℃は、使用者が意識して
湯に触れ得る温度の上限として最適値と考えられる。As described above, according to the present invention, the predetermined time for judging an abnormal operation is limited to a range of an arbitrary set temperature, and the hot water outlet temperature becomes high according to the relationship between the temperature and the time at which there is a possibility of burn. By making the length shorter, it is possible to judge abnormalities before a burn occurs in the temperature range where the user tries to touch the hot water, and it is possible to use safely. On the contrary, even if the hot water temperature rises outside the arbitrary set temperature range,
Since no abnormality judgment is made regarding the relationship between burns, temperature, and time, hot water supply continues and usability is not impaired. Further, the upper limit of 50 ° C. of the arbitrary set temperature range is considered to be the optimum value as the upper limit of the temperature at which the user can consciously touch the hot water.
【図1】給湯器の概略図である。FIG. 1 is a schematic view of a water heater.
【図2】安全機能のフローチャートである。FIG. 2 is a flowchart of a safety function.
【図3】皮膚のやけどに対する時間と温度の関係を示す
グラフである。FIG. 3 is a graph showing the relationship between time and temperature for skin burns.
【図4】従来の安全機能のフローチャートである。FIG. 4 is a flowchart of a conventional safety function.
【符号の説明】 1・・ハウジング、2・・燃焼室、3・・ガスバーナ、
4・・熱交換器、5・・通水管、6・・給水管、8・・
出湯管、9・・ガス供給管、10・・元弁、11・・比
例制御弁、13・・水量センサ、14,15・・温度セ
ンサ、16・・バーナコントローラ。[Explanation of symbols] 1 ・ ・ Housing, 2 ・ ・ Combustion chamber, 3 ・ ・ Gas burner,
4 ・ ・ Heat exchanger, 5 ・ ・ Water pipe, 6 ・ ・ Water pipe, 8 ・ ・
Hot water supply pipe, 9 ... Gas supply pipe, 10 ... Main valve, 11 ... Proportional control valve, 13 ... Water amount sensor, 14, 15 ... Temperature sensor, 16 ... Burner controller.
Claims (2)
手段と、出湯される湯の温度を検出する温度検出手段
と、前記温度設定手段で設定された設定温度と温度検出
手段で検出された出湯温度とを所定の条件で比較して作
動異常の判断をする判断手段とを備えた給湯装置におい
て、 前記条件を、任意の設定温度の範囲で、出湯温度が設定
温度より所定の温度以上高い状態で所定時間以上続いた
場合に異常とみなすものとすると共に、前記所定時間
を、やけどをする可能性のある温度と時間との関係に従
い、出湯温度が高温となるにつれて短くなるようにした
ことを特徴とする給湯装置。1. A temperature setting means for setting a temperature of hot water to be discharged, a temperature detecting means for detecting a temperature of hot water to be discharged, and a set temperature set by the temperature setting means and a temperature detecting means. In the hot water supply device, the hot water supply device is provided with a determination means for determining an abnormal operation by comparing the hot water discharge temperature with a predetermined temperature, and the hot water discharge temperature is a predetermined temperature or more higher than a predetermined temperature in an arbitrary set temperature range. It is considered as abnormal when it continues for a predetermined time or more in a high state, and the predetermined time is shortened as the hot water temperature rises according to the relationship between the temperature and the time at which burns may occur. Hot water supply device characterized in that.
℃とした請求項1に記載の給湯装置。2. The upper limit of the range of the arbitrary set temperature is 50.
The hot water supply apparatus according to claim 1, wherein the temperature is set to ° C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15809695A JPH0914751A (en) | 1995-06-23 | 1995-06-23 | Hot water heater |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15809695A JPH0914751A (en) | 1995-06-23 | 1995-06-23 | Hot water heater |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0914751A true JPH0914751A (en) | 1997-01-17 |
Family
ID=15664223
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15809695A Pending JPH0914751A (en) | 1995-06-23 | 1995-06-23 | Hot water heater |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0914751A (en) |
-
1995
- 1995-06-23 JP JP15809695A patent/JPH0914751A/en active Pending
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