JPH0878747A - Lamination-type piezoelectric body - Google Patents

Lamination-type piezoelectric body

Info

Publication number
JPH0878747A
JPH0878747A JP6266520A JP26652094A JPH0878747A JP H0878747 A JPH0878747 A JP H0878747A JP 6266520 A JP6266520 A JP 6266520A JP 26652094 A JP26652094 A JP 26652094A JP H0878747 A JPH0878747 A JP H0878747A
Authority
JP
Japan
Prior art keywords
piezoelectric
metal mesh
plates
laminated
plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6266520A
Other languages
Japanese (ja)
Other versions
JP3250918B2 (en
Inventor
Katsuhiko Onizuka
克彦 鬼塚
Shuichi Fukuoka
修一 福岡
Kazutaka Uchi
一隆 内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyocera Corp
Original Assignee
Kyocera Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyocera Corp filed Critical Kyocera Corp
Priority to JP26652094A priority Critical patent/JP3250918B2/en
Publication of JPH0878747A publication Critical patent/JPH0878747A/en
Application granted granted Critical
Publication of JP3250918B2 publication Critical patent/JP3250918B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE: To provide a lamination-type piezoelectric body which can positively join piezoelectric plates and at the same time prevent electrodes from being short-circuited. CONSTITUTION: In a lamination-type piezoelectric body with a plurality of laminated piezoelectric plates 11, a metal mesh 15 which is included between the piezoelectric plates 11 and at the same time is provided with a protruding part 17 for connection, and a conductive adhesive layer 13 which is included between the piezoelectric plates 11 and at the same time where the metal mesh 15 is buried, the metal mesh 15 laid out at both sides of the piezoelectric plate 11 is used as a metal mesh 19 for positive electrode and a metal mesh for negative electrode, at the same time the protruding parts 17 for connection of the metal mesh 21 for negative electrode are electrically connected, and the protruding parts 17 for connection of the metal mesh 21 for negative electrode are electrically connected.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、例えば、光学装置等の
精密位置決め装置や振動防止用の駆動素子に使用される
積層型圧電体に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a laminated piezoelectric material used for a precision positioning device such as an optical device or a drive element for preventing vibration.

【0002】[0002]

【従来技術】従来から、圧電板を複数枚積層して、積層
型圧電体(積層型のアクチュエーター)を作製する方法
が多数開示されている(例えば特公昭56ー50434
号公報参照)。特に圧電板の接合方法により接合状態が
大きく変化し、積層後の特性の変動が大きく、素子間で
の特性ばらつきが大きくなるため様々な信頼性向上の方
法が示されている。
2. Description of the Related Art Conventionally, a number of methods for manufacturing a laminated piezoelectric body (laminated actuator) by laminating a plurality of piezoelectric plates have been disclosed (for example, Japanese Patent Publication No. 56-50434).
(See the official gazette). In particular, various methods of improving reliability have been disclosed because the bonding state greatly changes depending on the bonding method of the piezoelectric plates, the characteristics after stacking greatly vary, and the characteristics vary among the elements.

【0003】積層型の圧電アクチュエータを作製する方
法としては、同時焼成による方法がある。この同時焼成
による方法では、圧電板の厚みを薄く作製することが比
較的容易であり、印加電界を高くできるために低電圧高
変位が可能であるが、圧電板材料(例えば、Pb(Zr
Ti)O3 等のセラミックスからなる)と同時焼成を行
なうための内部電極材料としては、PdやPt等の貴金
属を使用する必要があり、積層数が増すにしたがってコ
スト高になるという問題点があった。
As a method of manufacturing a laminated piezoelectric actuator, there is a method of simultaneous firing. In this method by simultaneous firing, it is relatively easy to make the piezoelectric plate thin, and the applied electric field can be increased, so that low voltage high displacement is possible, but the piezoelectric plate material (for example, Pb (Zr
Ti) made of ceramics such as O 3 ) and an internal electrode material for performing the co-firing, it is necessary to use a noble metal such as Pd or Pt, and the cost increases as the number of laminated layers increases. there were.

【0004】そこで、コストを低減するために、圧電板
を何らかの導電性接着材を使用して積層接合する方法
が、例えば、特開昭60−121784号公報に開示さ
れている。この公報には、圧電板間に圧電板と同一形状
の電極用金属板を挟み込み、銀ペースト等の導電性ペー
ストの接着力により接合する方法が開示されている。
Therefore, in order to reduce the cost, a method of laminating and bonding the piezoelectric plates using some kind of conductive adhesive is disclosed in, for example, Japanese Patent Laid-Open No. 60-121784. This publication discloses a method in which a metal plate for an electrode having the same shape as the piezoelectric plate is sandwiched between the piezoelectric plates and bonded by the adhesive force of a conductive paste such as silver paste.

【0005】[0005]

【発明が解決しようとする問題点】しかしながら、この
方法では、圧電板間にこの圧電板と同一形状の電極用金
属板を挟み込むために、電極用金属板と圧電板との接合
が不十分になるという問題があった。このため、圧電板
の積層数を増加するにしたがって接合界面での剥離等の
発生確率が増加するという問題があった。この結果、圧
電アクチュエータとして使用中に接合界面で剥離し、使
用不能になるという問題があった。
However, in this method, since the electrode metal plate having the same shape as the piezoelectric plate is sandwiched between the piezoelectric plates, the bonding between the electrode metal plate and the piezoelectric plate is insufficient. There was a problem of becoming. Therefore, there is a problem that the probability of occurrence of peeling at the bonding interface increases as the number of stacked piezoelectric plates increases. As a result, there is a problem that the piezoelectric actuator peels off at the bonding interface during use and becomes unusable.

【0006】また、圧電板の積層中に導電性ペーストが
電極用金属板により押し出されて圧電板の側面にはみ出
し、圧電板の間にそれぞれ介装された正電極と負電極を
構成する金属板同士が短絡するという問題があった。
Further, during the lamination of the piezoelectric plates, the conductive paste is extruded by the metal plate for electrodes and sticks out to the side surface of the piezoelectric plates, and the metal plates forming the positive electrode and the negative electrode respectively interposed between the piezoelectric plates are separated from each other. There was a problem of short circuit.

【0007】本発明は、圧電板同士の接合を確実に行う
ことができるとともに、電極同士の短絡を防止すること
ができる積層型圧電体を提供することを目的とする。
It is an object of the present invention to provide a laminated piezoelectric body which can surely bond piezoelectric plates to each other and can prevent a short circuit between electrodes.

【0008】[0008]

【問題点を解決するための手段】本発明の積層型圧電体
は、積層された複数の圧電板と、これらの圧電板の間に
それぞれ介装されるとともに接続用突起部を有する金属
メッシュと、前記圧電板の間に介装されるとともに前記
金属メッシュを埋設する導電性接着層とを有する積層型
圧電体であって、前記圧電板の両側に配置された金属メ
ッシュをそれぞれ正電極用金属メッシュおよび負電極用
金属メッシュとするとともに、前記正電極用金属メッシ
ュの接続用突起部同士を電気的に接続し、前記負電極用
金属メッシュの接続用突起部同士を電気的に接続してな
るものである。
The laminated piezoelectric body of the present invention comprises a plurality of laminated piezoelectric plates, a metal mesh interposed between the piezoelectric plates and having a connecting projection, and A laminated piezoelectric body having a conductive adhesive layer embedded between the piezoelectric plates and burying the metal mesh, wherein the metal meshes disposed on both sides of the piezoelectric plate are a positive electrode metal mesh and a negative electrode, respectively. And the connecting projections of the positive electrode metal mesh are electrically connected to each other, and the connecting projections of the negative electrode metal mesh are electrically connected to each other.

【0009】このような積層型圧電体は、例えば、複数
の圧電板の両面にそれぞれ導電性ペーストを塗布し、こ
の導電性接着層用ペーストを乾燥した後、複数の圧電板
の間に接続用突起部を有する金属メッシュを介装して積
層し、この後加熱しながら加圧し前記複数の圧電板を相
互に接合し、前記圧電板の間に金属メッシュを埋設する
導電性接着層を形成し、前記圧電板の両側に配置された
金属メッシュを正電極用金属メッシュおよび負電極用金
属メッシュとするとともに、前記正電極用金属メッシュ
の接続用突起部同士を電気的に接続し、前記負電極用金
属メッシュの接続用突起部同士を電気的に接続すること
により製造される。
In such a laminated piezoelectric material, for example, a conductive paste is applied to both surfaces of a plurality of piezoelectric plates, the conductive adhesive layer paste is dried, and then a connecting protrusion is provided between the plurality of piezoelectric plates. And then pressurizing while bonding the plurality of piezoelectric plates to each other to form a conductive adhesive layer for embedding the metal mesh between the piezoelectric plates. With the metal mesh for the positive electrode and the metal mesh for the negative electrode arranged on both sides of the, the connecting projections of the metal mesh for the positive electrode are electrically connected to each other, and the metal mesh for the negative electrode is It is manufactured by electrically connecting the connecting protrusions.

【0010】使用する金属メッシュは、導電性を有する
もので、例えば、真鍮、銅、ステンレス等の金属が好ま
しい。金属メッシュの厚さは、接合後の状態で導電性接
着層用ペースト中に隙間なく金属メッシュが埋設するよ
うになるのが好ましく、このためには、金属メッシュの
厚みは導電性接着層用ペーストの厚さと同程度か、もし
くは、それ以下が望ましい。また、金属メッシュのメッ
シュ径は、メッシュ内へのペーストの充填の点および圧
電板の接合力の点から300μm以下であれば使用で
き、特に100μm以下のものが望ましい。
The metal mesh used has conductivity, and for example, metals such as brass, copper and stainless steel are preferable. The thickness of the metal mesh is preferably such that the metal mesh is embedded in the paste for conductive adhesive layer in the state after bonding without any gap. For this purpose, the thickness of the metal mesh is the paste for conductive adhesive layer. It is desirable that the thickness is equal to or less than the thickness of. Further, the mesh diameter of the metal mesh can be used as long as it is 300 μm or less from the point of filling the paste into the mesh and the bonding force of the piezoelectric plate, and particularly preferably 100 μm or less.

【0011】また、圧電板を構成する圧電材料は、例え
ば、チタン酸ジルコン酸鉛を主成分とする圧電セラミッ
クス材料などが使用されるが、これに限定されるもので
はなく、圧電性を有するセラミックスであれば何れでも
良い。この圧電体を構成する圧電材料としては、圧電歪
み定数d33が高いものが望ましい。
As the piezoelectric material forming the piezoelectric plate, for example, a piezoelectric ceramic material containing lead titanate zirconate as a main component is used, but the piezoelectric material is not limited to this, and a ceramic having piezoelectricity. Any of them can be used. A piezoelectric material having a high piezoelectric strain constant d 33 is desirable as the piezoelectric material forming the piezoelectric body.

【0012】また、本発明の積層型圧電体は、積層され
た複数の圧電板と、これらの圧電板の間にそれぞれ複数
介装されるとともに接続用突起部を有する細長金属板
と、前記圧電板の間に介装されるとともに前記細長金属
板を埋設する導電性接着層とを有する積層型圧電体であ
って、前記圧電体の両側に配置された細長金属板をそれ
ぞれ正電極用細長金属板および負電極用細長金属板とす
るとともに、前記正電極用細長金属板の接続用突起部同
士を電気的に接続し、前記負電極用細長金属板の接続用
突起部同士を電気的に接続してなるものである。
Further, the laminated piezoelectric body of the present invention includes a plurality of laminated piezoelectric plates, a plurality of elongated metal plates which are respectively interposed between the piezoelectric plates and have a connecting projection, and the piezoelectric plates. What is claimed is: 1. A laminated piezoelectric body having a conductive adhesive layer which is interposed and which embeds the elongated metal plate, wherein the elongated metal plates disposed on both sides of the piezoelectric body are elongated metal plates for positive electrodes and negative electrodes, respectively. Elongated metal plate for electrical connection, the connecting protrusions of the elongated metal plate for the positive electrode are electrically connected to each other, and the connecting protrusions of the elongated metal plate for the negative electrode are electrically connected to each other. Is.

【0013】金属板としては、圧電板の幅よりも小さい
幅を有するものであり、その材料および厚みは、金属メ
ッシュと同様の理由により同様の材料、厚みが望まし
い。
The metal plate has a width smaller than that of the piezoelectric plate, and its material and thickness are preferably the same as those of the metal mesh for the same reason.

【0014】[0014]

【作用】本発明の積層型圧電体では、電極としての金属
メッシュや複数の細長金属板を圧電板の間に介装するた
め、積層時に加圧すると導電性接着層用ペーストが金属
メッシュの間に入り込み、または細長金属板の回りに入
り込み、圧電板同士を強固に接合する。
In the laminated piezoelectric material of the present invention, since the metal mesh as the electrode and the plurality of elongated metal plates are interposed between the piezoelectric plates, when the pressure is applied during the lamination, the conductive adhesive layer paste gets into the space between the metal meshes. , Or around the elongated metal plate to firmly bond the piezoelectric plates together.

【0015】また、導電性接着層用ペーストが金属メッ
シュの間に入り込むため、また、導電性接着層用ペース
トが細長金属板の回りに入りこむため、圧電板の積層中
に導電性接着層用ペーストの圧電板側面へのはみ出しを
抑制することができる。
Further, since the conductive adhesive layer paste enters between the metal meshes and the conductive adhesive layer paste enters around the elongated metal plate, the conductive adhesive layer paste is formed during the lamination of the piezoelectric plates. Can be suppressed from protruding to the side surface of the piezoelectric plate.

【0016】[0016]

【実施例】以下、本発明を図を用いて説明する。The present invention will be described below with reference to the drawings.

【0017】図1は本発明の積層型圧電体を示すもの
で、符号11は円板状の圧電板を示している。これらの
圧電板11はPb(ZrTi)O3 (以下PZTと略
す)を主成分とする焼結体であり、直径20mm、厚み
0.5mmの円板状とされている。
FIG. 1 shows a laminated piezoelectric material of the present invention, and reference numeral 11 denotes a disk-shaped piezoelectric plate. The piezoelectric plate 11 is a sintered body containing Pb (ZrTi) O 3 (hereinafter abbreviated as PZT) as a main component, and has a disc shape with a diameter of 20 mm and a thickness of 0.5 mm.

【0018】そして、複数の圧電板11が積層されてお
り、その間には、例えば、ガラス成分を含むAgからな
る導電性接着層13が形成され、導電性接着層13内に
は、例えば、真鍮製の金属メッシュ15が埋設されてい
る。これらの金属メッシュ15には、図2に示すよう
に、接続用突起部17が形成されており、圧電板11の
径方向に突出している。また、接続用突起部17は、図
1に示したように交互に180度反対を向くように、金
属メッシュ15が圧電板11の間に介装されており、こ
れらの金属メッシュ15は、その接続用突起部17の位
置により正電極用金属メッシュ19,負電極用金属メッ
シュ21とされている。そして、正電極用金属メッシュ
19の接続用突起部17が折曲され、相互に電気的に接
続され、また、負電極用金属メッシュ21の接続用突起
部17が折曲され、相互に電気的に接続されている。
A plurality of piezoelectric plates 11 are laminated, and a conductive adhesive layer 13 made of, for example, Ag containing a glass component is formed between them. Inside the conductive adhesive layer 13, for example, brass is used. The metal mesh 15 made of metal is embedded. As shown in FIG. 2, these metal meshes 15 are formed with connecting projections 17 and project in the radial direction of the piezoelectric plate 11. In addition, as shown in FIG. 1, the connecting projections 17 have metal meshes 15 interposed between the piezoelectric plates 11 so as to alternately face each other by 180 degrees. The metal mesh 19 for the positive electrode and the metal mesh 21 for the negative electrode are formed depending on the position of the connecting protrusion 17. Then, the connecting projections 17 of the positive electrode metal mesh 19 are bent and electrically connected to each other, and the connecting projections 17 of the negative electrode metal mesh 21 are bent and electrically connected to each other. It is connected to the.

【0019】このような積層型圧電体は、圧電板11の
両面にそれぞれ導電性ペーストを塗布し、この導電性接
着層用ペーストを乾燥した後、複数の圧電体11の間、
即ち、ペースト間に接続用突起部17を有する金属メッ
シュ15を介装して積層し、この後加熱しながら加圧
し、複数の圧電板11を相互に接合し、圧電板11の間
に、金属メッシュ15を埋設する導電性接着層13を形
成することにより形成される。
In such a laminated piezoelectric material, a conductive paste is applied to both surfaces of the piezoelectric plate 11, the conductive adhesive layer paste is dried, and then a space between the plurality of piezoelectric materials 11,
That is, the metal mesh 15 having the connecting protrusions 17 is interposed between the pastes, and then the pastes are heated and pressed to bond the plurality of piezoelectric plates 11 to each other. It is formed by forming the conductive adhesive layer 13 in which the mesh 15 is embedded.

【0020】そして、圧電板11を挟持している正電極
用金属メッシュ19および負電極用金属メッシュ21の
接続用突起部17をそれぞれ接続する。即ち、正電極用
金属メッシュ19の接続用突起部17同士を電気的に接
続し、負電極用金属メッシュ21の接続用突起部17同
士を電気的に接続することにより製造される。
Then, the connecting projections 17 of the positive electrode metal mesh 19 and the negative electrode metal mesh 21 sandwiching the piezoelectric plate 11 are connected. That is, it is manufactured by electrically connecting the connecting projections 17 of the positive electrode metal mesh 19 to each other and electrically connecting the connecting projections 17 of the negative electrode metal mesh 21 to each other.

【0021】以上のように構成された積層型圧電体は、
電極としての金属メッシュ15を圧電板11の間に介装
するため、積層時に加圧すると導電性接着層用ペースト
が金属メッシュ15のメッシュ間に入り込み、圧電板1
1同士を強固に接合し、高電界の繰り返し印加によって
発生する界面での剥離等を防止することができ、積層型
圧電体の信頼性を向上することができる。
The laminated piezoelectric material having the above structure is
Since the metal mesh 15 as an electrode is interposed between the piezoelectric plates 11, when pressure is applied during lamination, the conductive adhesive layer paste enters between the meshes of the metal mesh 15 and the piezoelectric plate 1
It is possible to firmly bond one to the other, prevent peeling at the interface that occurs due to repeated application of a high electric field, and improve the reliability of the laminated piezoelectric body.

【0022】また、導電性接着層用ペーストが金属メッ
シュ15の間に入り込むため、圧電板11の積層中に導
電性接着層用ペーストが圧電板11により押し出されて
側面にはみ出すことがなく、正電極用金属メッシュ19
の接続用突起部17と負電極用金属メッシュ21の接続
用突起部17の電気的な導通を防止し、正電極用金属メ
ッシュ19と負電極用金属メッシュ21との短絡を防止
することができる。
Further, since the conductive adhesive layer paste enters between the metal meshes 15, the conductive adhesive layer paste is not pushed out by the piezoelectric plate 11 during the lamination of the piezoelectric plates 11 and does not stick out to the side surface. Metal mesh for electrodes 19
It is possible to prevent electrical connection between the connecting protrusion 17 and the connecting protrusion 17 of the negative electrode metal mesh 21, and to prevent a short circuit between the positive electrode metal mesh 19 and the negative electrode metal mesh 21. .

【0023】さらに、接合部における機械的損失を小さ
くすることができるため、電界印加時に発生する変位ヒ
ステリシスが小さく、繰り返し使用後の変位量の低下が
小さく、寿命の長い積層型圧電体を提供することができ
る。
Further, since the mechanical loss at the joint can be reduced, the displacement hysteresis generated upon application of an electric field is small, the displacement amount after repeated use is small, and the long-life piezoelectric body is provided. be able to.

【0024】実施例1 PZTを主成分とする焼結体の両面を研磨して直径20
mm、厚み0.5mmの円板状の圧電板11を形成し
た。この圧電板11の両主面にガラス成分を含む電気伝
導性のAgペーストを40〜60μmの厚みになるよう
に印刷した後、100℃にて乾燥した。厚さ50μm、
メッシュ径100μmの真鍮製メッシュを、図2に示し
たような2mm×2mmの接続用突起部17を有する直
径20mmの円形に打ち抜き、金属メッシュ15とし、
この金属メッシュ15を圧電板11の間に挟み込み、圧
電板11を100層積層して積層型圧電体を形成した。
Example 1 Both sides of a sintered body containing PZT as a main component were ground to a diameter of 20.
A disk-shaped piezoelectric plate 11 having a thickness of 0.5 mm and a thickness of 0.5 mm was formed. An electroconductive Ag paste containing a glass component was printed on both main surfaces of the piezoelectric plate 11 so as to have a thickness of 40 to 60 μm, and then dried at 100 ° C. 50 μm thickness,
A brass mesh having a mesh diameter of 100 μm is punched out into a circular shape having a diameter of 20 mm having a connecting projection 17 of 2 mm × 2 mm as shown in FIG.
The metal mesh 15 was sandwiched between the piezoelectric plates 11, and 100 layers of the piezoelectric plates 11 were laminated to form a laminated piezoelectric body.

【0025】尚、金属メッシュ15の接続用突起部17
は一層おきに同じ位置にくるように、他方は180度反
対側に来るように配置した。圧電板11を100層積層
した圧電体は、位置ずれが生じないように軽く圧力を加
えた後、積層体の上部に約4kgの重りを乗せて、65
0℃、1時間で加圧接合した。
The connecting projection 17 of the metal mesh 15
Are placed in the same position every other layer, and the other is placed 180 degrees on the opposite side. For a piezoelectric body in which 100 layers of the piezoelectric plate 11 are laminated, light pressure is applied so as not to cause positional displacement, and then a weight of about 4 kg is placed on the top of the laminated body.
Pressure bonding was performed at 0 ° C. for 1 hour.

【0026】次に、図1に示したように、圧電板11の
径方向に突出した接続用突起部17を軸方向に折曲げ、
一層おいた隣の接続用突起部17と接続し、正電極用金
属メッシュ19の接続用突起部17同士を電気的に接続
するとともに、負電極用金属メッシュ21の接続用突起
部17同士を電気的に接続した。これを80℃のシリコ
ンオイル中で3kv/mmの直流電圧を30分間印加し
て分極処理を行なった。
Next, as shown in FIG. 1, the connecting projection 17 protruding in the radial direction of the piezoelectric plate 11 is bent in the axial direction,
The connection protrusions 17 of the positive electrode metal mesh 19 are electrically connected to each other by connecting the adjacent connection protrusions 17 to each other, and the connection protrusions 17 of the negative electrode metal mesh 21 are electrically connected to each other. Connected to each other. This was subjected to polarization treatment by applying a DC voltage of 3 kv / mm for 30 minutes in silicon oil at 80 ° C.

【0027】得られた積層型圧電体に200Vの直流電
圧を印加した結果、15μmの変位量が得られた。更に
この積層型圧電体に0Vから+200Vの交流電界を1
0Hzの周波数にて印加した結果、印加回数3×108
回までこの変位量を維持した。これに対して、圧電板と
同一形状の金属板を電極として挿入した従来例において
は、0Vから+200Vの交流電界を10Hzの周波数
にて印加した回数が5×106 回で積層界面に剥離が生
じ、変位量に変化が生じた。
As a result of applying a DC voltage of 200 V to the obtained laminated piezoelectric material, a displacement amount of 15 μm was obtained. Further, an AC electric field of 0V to + 200V is applied to the laminated piezoelectric body 1
As a result of applying at a frequency of 0 Hz, the number of times of application is 3 × 10 8
This displacement amount was maintained up to times. On the other hand, in the conventional example in which a metal plate having the same shape as the piezoelectric plate is inserted as an electrode, the AC electric field of 0 V to +200 V is applied at a frequency of 10 Hz for 5 × 10 6 times and peeling occurs at the lamination interface. Occurred, and the amount of displacement changed.

【0028】尚、変位量の測定は、試料を防振台上に固
定し、試料上面にアルミニウム箔を張り付けて、レーザ
ー変位計により、素子の中心部及び周囲部3箇所で測定
した値の平均値で評価した。
The amount of displacement was measured by fixing the sample on a vibration isolation table, attaching an aluminum foil to the upper surface of the sample, and averaging the values measured by a laser displacement meter at the central portion and the peripheral portion of the element. The value was evaluated.

【0029】実施例2 PZTを主成分とする焼結体の両面を研磨して直径15
mm、厚み0.35mmの円板状の圧電板11を形成し
た。この圧電板11の両主面にガラス成分を含む電気伝
導性のAgペーストを20μmの厚みになるように印刷
した後、120℃にて乾燥した。厚さ20μm、メッシ
ュ径200μmの真鍮製メッシュを図2に示したような
2mm×2mmの接続用突起部17を有する直径15m
mの円形に打ち抜き、金属メッシュ15を作成した。該
金属メッシュ15を圧電板11の間に挟み込み、圧電板
11を200層積層して積層型圧電体を形成した。
Example 2 A sintered body containing PZT as a main component was polished on both sides to have a diameter of 15
A disk-shaped piezoelectric plate 11 having a thickness of 0.35 mm and a thickness of 0.35 mm was formed. An electrically conductive Ag paste containing a glass component was printed on both main surfaces of the piezoelectric plate 11 so as to have a thickness of 20 μm, and then dried at 120 ° C. A brass mesh having a thickness of 20 μm and a mesh diameter of 200 μm having a connecting projection 17 of 2 mm × 2 mm as shown in FIG.
The metal mesh 15 was created by punching into a circle of m. The metal mesh 15 was sandwiched between the piezoelectric plates 11, and 200 layers of the piezoelectric plates 11 were laminated to form a laminated piezoelectric body.

【0030】尚、金属メッシュ15の接続用突起部17
は一層おきに同じ位置に来るように、他方は180度反
対側に来るように配置した。圧電板11を200層積層
した圧電体は、位置ずれが生じないように軽く圧力を加
えた後、積層体の上部に約3kgの重りを乗せて、60
0℃、1時間で加圧接合した。次に、図1に示したよう
に、圧電板11から外側に出た接続用突起部17を軸方
向に折曲げ、一層おいた隣の接続用突起部17と接続
し、正電極用金属メッシュ19の接続用突起部17同士
を電気的に接続するとともに、負電極用金属メッシュ2
1の接続用突起部17同士を電気的に接続した。これを
80℃のシリコンオイル中で2kv/mmの直流電圧を
30分間印加して分極処理を行なった。
Incidentally, the connecting projection 17 of the metal mesh 15
Are placed in the same position every other layer, and the other is placed 180 degrees on the opposite side. For a piezoelectric body in which 200 layers of the piezoelectric plate 11 are laminated, light pressure is applied so as not to cause positional displacement, and then a weight of about 3 kg is placed on the top of the laminated body.
Pressure bonding was performed at 0 ° C. for 1 hour. Next, as shown in FIG. 1, the connecting projection 17 protruding outward from the piezoelectric plate 11 is bent in the axial direction, and is connected to the adjacent connecting projection 17 that has been left one layer, and the positive electrode metal mesh is formed. The connection projections 17 of 19 are electrically connected to each other, and the negative electrode metal mesh 2 is also provided.
The connecting protrusions 17 of No. 1 were electrically connected to each other. This was subjected to polarization treatment by applying a DC voltage of 2 kv / mm for 30 minutes in silicon oil at 80 ° C.

【0031】得られた積層型圧電体に200Vの直流電
圧を印加した結果、31μmの変位量が得られた。更に
この積層型圧電体に0Vから+200Vの交流電界を1
0Hzの周波数にて印加した結果、印加回数が3×10
8 回までこの変位量を維持した。これに対して、圧電板
と同一形状の金属板を電極として挿入した従来例におい
ては、0Vから+200Vの交流電界を10Hzの周波
数にて印加した回数が1×106 回で積層界面に剥離が
生じ、変位量に変化が生じた。変位量の測定について
は、上記実施例1と同様にして測定した。
As a result of applying a DC voltage of 200 V to the obtained laminated piezoelectric material, a displacement amount of 31 μm was obtained. Further, an AC electric field of 0V to + 200V is applied to the laminated piezoelectric body 1
As a result of applying at a frequency of 0 Hz, the number of times of application is 3 × 10.
This displacement amount was maintained up to 8 times. On the other hand, in the conventional example in which a metal plate having the same shape as the piezoelectric plate is inserted as an electrode, the AC electric field of 0 V to +200 V is applied at a frequency of 10 Hz for 1 × 10 6 times, and peeling occurs at the lamination interface. Occurred, and the amount of displacement changed. The amount of displacement was measured in the same manner as in Example 1 above.

【0032】実施例3 PZTを主成分とする焼結体の両面を研磨して一辺10
mm、厚み0.3mmの正方形状の角板からなる圧電板
11を形成した。この圧電板11の両主面に電気伝導性
を有するペースト、例えばガラス成分を含むAgペース
トを40乃至50μmの厚みになるように印刷した後、
120℃にて乾燥した。厚さ40μm、メッシュ径50
μmの真鍮製メッシュを図3に示すような2mm×2m
mの接続用突起部17を有する一辺10mmの正方形状
に打ち抜き、該金属メッシュ15を圧電板11の間に挟
み込み、圧電板を300層積層して積層型圧電体を形成
した。
Example 3 Both sides of a sintered body containing PZT as a main component were ground to form one side 10
A piezoelectric plate 11 formed of a square rectangular plate having a thickness of 0.3 mm and a thickness of 0.3 mm was formed. After printing an electrically conductive paste, for example, an Ag paste containing a glass component, on both main surfaces of the piezoelectric plate 11 to a thickness of 40 to 50 μm,
It was dried at 120 ° C. Thickness 40μm, mesh diameter 50
The brass mesh of μm is 2mm × 2m as shown in Fig. 3.
The metal mesh 15 was punched into a square shape having a connecting protrusion 17 of m and a side of 10 mm, sandwiched between the piezoelectric plates 11, and 300 layers of the piezoelectric plates were laminated to form a laminated piezoelectric body.

【0033】尚、金属メッシュ15の接続用突起部17
は一層おきに同じ位置に来るように、他方は180度反
対側に来るように配置した。圧電板を300層積層した
積層型圧電体は、位置ずれが生じないように軽く圧力を
加えた後、積層体の上部に約2kgの重りを乗せて、6
00℃、1時間で加圧接合した。次に、図1に示したよ
うに、これらの外側に出た接続用突起部17を軸方向に
折曲げ、一層おいた隣の接続用突起部17と接続し、正
電極用金属メッシュ19の接続用突起部17同士を電気
的に接続するとともに、負電極用金属メッシュ21の接
続用突起部17同士を電気的に接続した。これを80℃
のシリコンオイル中で2kv/mmの直流電圧を30分
間印加して分極処理を行なった。
Incidentally, the connecting projection 17 of the metal mesh 15
Are placed in the same position every other layer, and the other is placed 180 degrees on the opposite side. For a laminated piezoelectric body in which 300 layers of piezoelectric plates are laminated, light pressure is applied so that no displacement occurs, and then a weight of about 2 kg is placed on the upper part of the laminated body,
Pressure bonding was performed at 00 ° C. for 1 hour. Next, as shown in FIG. 1, these connecting protrusions 17 that are exposed to the outside are bent in the axial direction, and are connected to the adjacent connecting protrusions 17 that have been placed further, and the positive electrode metal mesh 19 The connecting protrusions 17 were electrically connected to each other, and the connecting protrusions 17 of the negative electrode metal mesh 21 were electrically connected to each other. 80 ° C
Polarization treatment was performed by applying a direct current voltage of 2 kv / mm for 30 minutes in the silicon oil.

【0034】得られた積層型圧電体に50Vの直流電圧
を印加した結果、12μmの変位量が得られた。更にこ
の積層型圧電体に0Vから+50Vの交流電界を10H
zの周波数にて印加した結果、印加回数が7×108
までこの変位量を維持した。
As a result of applying a DC voltage of 50 V to the obtained laminated piezoelectric material, a displacement amount of 12 μm was obtained. Further, an AC electric field of 0V to + 50V is applied to this laminated piezoelectric body for 10H.
As a result of applying at the frequency of z, this displacement amount was maintained until the number of applications was 7 × 10 8 .

【0035】これに対して、圧電板と同一形状の金属板
を電極として挿入した従来例においては、0Vから+5
0Vの交流電界を10Hzの周波数にて印加した回数が
2×106 回で積層界面に剥離が生じ、変位量に変化が
生じた。変位量の測定につていは、上記実施例1と同様
にして測定した。
On the other hand, in the conventional example in which a metal plate having the same shape as the piezoelectric plate is inserted as an electrode, 0V to +5 is applied.
When the AC electric field of 0 V was applied at a frequency of 10 Hz for 2 × 10 6 times, delamination occurred at the laminated interface and the displacement amount changed. The displacement amount was measured in the same manner as in Example 1 above.

【0036】実施例4 PZTを主成分とする焼結体の両面を研磨して直径12
mm、厚み0.3mmの円板状の圧電板11を形成し
た。この圧電板11の両主面にガラス成分を含む電気伝
導性のAgペーストを10〜20μmの厚みになるよう
に印刷した後、100℃にて乾燥した。厚さ20μm、
メッシュ径100μmの真鍮製メッシュを、図2に示し
たような2mm×2mmの接続用突起部17を有する直
径12mmの円形に打ち抜き、金属メッシュ15とし、
この金属メッシュ15を圧電板11の間に挟み込み、圧
電板11を100層積層して積層型圧電体を形成した。
Example 4 A diameter of 12 was obtained by polishing both surfaces of a sintered body containing PZT as a main component.
A disk-shaped piezoelectric plate 11 having a thickness of 0.3 mm and a thickness of 0.3 mm was formed. An electroconductive Ag paste containing a glass component was printed on both main surfaces of the piezoelectric plate 11 so as to have a thickness of 10 to 20 μm, and then dried at 100 ° C. 20 μm thickness,
A brass mesh having a mesh diameter of 100 μm is punched into a circle having a diameter of 12 mm having a connecting protrusion 17 of 2 mm × 2 mm as shown in FIG.
The metal mesh 15 was sandwiched between the piezoelectric plates 11, and 100 layers of the piezoelectric plates 11 were laminated to form a laminated piezoelectric body.

【0037】尚、金属メッシュ15の接続用突起部17
は一層おきに同じ位置にくるように、他方は180度反
対側に来るように配置した。圧電板11を100層積層
した圧電体は、位置ずれが生じないように軽く圧力を加
えた後、積層体の上部に約2kgの重りを乗せて、65
0℃、30分間で加圧接合した。
Incidentally, the connecting projection 17 of the metal mesh 15
Are placed in the same position every other layer, and the other is placed 180 degrees on the opposite side. For a piezoelectric body in which 100 layers of the piezoelectric plate 11 are laminated, light pressure is applied so that the displacement does not occur, and then a weight of about 2 kg is placed on the top of the laminated body,
Pressure bonding was performed at 0 ° C. for 30 minutes.

【0038】次に、図1に示したように、圧電板11の
径方向に突出した接続用突起部17を軸方向に折曲げ、
一層おいた隣の接続用突起部17と接続し、正電極用金
属メッシュ19の接続用突起部17同士を電気的に接続
するとともに、負電極用金属メッシュ21の接続用突起
部17同士を電気的に接続した。これを80℃のシリコ
ンオイル中で3kv/mmの直流電圧を30分間印加し
て分極処理を行なった。
Next, as shown in FIG. 1, the connecting projection 17 protruding in the radial direction of the piezoelectric plate 11 is bent in the axial direction,
The connection protrusions 17 of the positive electrode metal mesh 19 are electrically connected to each other by connecting the adjacent connection protrusions 17 to each other, and the connection protrusions 17 of the negative electrode metal mesh 21 are electrically connected to each other. Connected to each other. This was subjected to polarization treatment by applying a DC voltage of 3 kv / mm for 30 minutes in silicon oil at 80 ° C.

【0039】得られた積層型圧電体に100Vの直流電
圧を印加した結果、6μmの変位量が得られた。更にこ
の積層型圧電体に0Vから+100Vの交流電界を10
Hzの周波数にて印加した結果、印加回数5×108
までこの変位量を維持した。
As a result of applying a DC voltage of 100 V to the obtained laminated piezoelectric material, a displacement amount of 6 μm was obtained. Further, an AC electric field of 0V to + 100V is applied to this laminated piezoelectric body for 10 minutes.
As a result of applying at a frequency of Hz, this displacement amount was maintained up to 5 × 10 8 times of application.

【0040】これに対して、圧電板と同一形状の金属板
を電極として挿入した従来例においては、0Vから+1
00Vの交流電界を10Hzの周波数にて印加した回数
が2×106 回で積層界面に剥離が生じ、変位量に変化
が生じた。
On the other hand, in the conventional example in which a metal plate having the same shape as the piezoelectric plate is inserted as an electrode, 0 V to +1
When the AC electric field of 00 V was applied at a frequency of 10 Hz for 2 × 10 6 times, delamination occurred at the laminated interface and the displacement amount changed.

【0041】図4は本発明の他の実施例を示すもので、
PZTを主成分とする焼結体の両面を研磨して直径18
mm、厚み0.35mmの円板状の圧電板31を形成し
た。
FIG. 4 shows another embodiment of the present invention.
Both sides of the sintered body containing PZT as the main component were polished to a diameter of 18
A disk-shaped piezoelectric plate 31 having a thickness of 0.35 mm and a thickness of 0.35 mm was formed.

【0042】この圧電板31の両主面にガラス成分を含
む電気伝導性のAgペーストを25μmの厚みになるよ
うに印刷した後、100℃にて乾燥した。幅2mm、厚
さ25μm、長さ20mmの細長金属板33を、図4に
示すように、圧電板31のペースト32の上に2本平行
に配置し、圧電板31の間に挟み込み、圧電板31を1
50層積層して積層型圧電体を形成した。
An electrically conductive Ag paste containing a glass component was printed on both main surfaces of the piezoelectric plate 31 so as to have a thickness of 25 μm, and then dried at 100 ° C. As shown in FIG. 4, two elongated metal plates 33 having a width of 2 mm, a thickness of 25 μm, and a length of 20 mm are arranged in parallel on the paste 32 of the piezoelectric plate 31 and sandwiched between the piezoelectric plates 31 to form a piezoelectric plate. 31 to 1
A laminated piezoelectric body was formed by laminating 50 layers.

【0043】尚、細長金属板33の端部は、図1に示し
たように、接続用突起部37は一層おきに同じ位置にく
るように、他方は180度反対側に来るように配置し
た。圧電板31を150層積層した圧電板31は、位置
ずれが生じないように軽く圧力を加えた後、積層体の上
部に約3kgの重りを乗せて、650℃、1時間で加圧
接合した。
As shown in FIG. 1, the ends of the elongated metal plate 33 are arranged such that the connecting projections 37 are located at the same position every other layer and the other is located on the opposite side by 180 degrees. . The piezoelectric plate 31 in which 150 layers of the piezoelectric plate 31 were laminated was lightly pressed so as not to be displaced, and then a weight of about 3 kg was placed on the upper part of the laminated body and pressure-bonded at 650 ° C. for 1 hour. .

【0044】次に、図1に示したように、圧電板31の
径方向に突出した接続用突起部37を軸方向に折曲げ、
一層おいた隣の接続用突起部37と接続し、正電極用金
属メッシュ19の接続用突起部17同士を電気的に接続
するとともに、負電極用金属メッシュ21の接続用突起
部17同士を電気的に接続した。これを80℃のシリコ
ンオイル中で3kv/mmの直流電圧を30分間印加し
て分極処理を行なった。
Next, as shown in FIG. 1, the connecting projection 37 protruding in the radial direction of the piezoelectric plate 31 is bent in the axial direction,
The connecting protrusions 37 of the positive electrode metal mesh 19 are electrically connected to each other by connecting to the adjacent connecting protrusions 37, and the connecting protrusions 17 of the negative electrode metal mesh 21 are electrically connected to each other. Connected to each other. This was subjected to polarization treatment by applying a DC voltage of 3 kv / mm for 30 minutes in silicon oil at 80 ° C.

【0045】このような積層型圧電体では、上記実施例
とほぼ同様の効果を得ることができる。さらに、この場
合には、細長金属板33を2本平行に配置したため、圧
電板31同士を平行に積層することができる。
With such a laminated piezoelectric material, it is possible to obtain substantially the same effects as in the above embodiment. Further, in this case, since the two elongated metal plates 33 are arranged in parallel, the piezoelectric plates 31 can be laminated in parallel.

【0046】得られた圧電積層体に300Vの直流電圧
を印加した結果、35μmの変位量が得られた。更にこ
の積層体に0Vから+300Vの交流電界を10Hzの
周波数にて印加した結果、印加回数が2×108 回まで
この変位量を維持した。これに対して、圧電板と同一形
状の金属板を電極として挿入した従来例においては、0
Vから+300Vの交流電界を10Hzの周波数にて印
加した回数が1×106 回で積層界面に剥離が生じ、変
位量に変化が生じた。変位量の測定につていは、上記実
施例1と同様にして測定した。
As a result of applying a DC voltage of 300 V to the obtained piezoelectric laminate, a displacement amount of 35 μm was obtained. Further, as a result of applying an AC electric field of 0 V to +300 V at a frequency of 10 Hz to this laminated body, this displacement amount was maintained until the number of times of application was 2 × 10 8 . On the other hand, in the conventional example in which a metal plate having the same shape as the piezoelectric plate is inserted as an electrode,
When the AC electric field of V to +300 V was applied at a frequency of 10 Hz for 1 × 10 6 times, delamination occurred at the laminated interface and the displacement amount changed. The displacement amount was measured in the same manner as in Example 1 above.

【0047】尚、上記実施例では、圧電板31の間に細
長金属板33を2枚平行に配置した例について説明した
が、本発明では上記実施例に限定されるものではなく、
圧電板の間に細長金属板を3枚以上配置しても良い。ま
た、細長金属板は必ずしも平行に配置する必要はない。
In the above embodiment, the example in which the two elongated metal plates 33 are arranged in parallel between the piezoelectric plates 31 has been described, but the present invention is not limited to the above embodiment.
Three or more elongated metal plates may be arranged between the piezoelectric plates. Further, the elongated metal plates do not necessarily have to be arranged in parallel.

【0048】[0048]

【発明の効果】以上詳述した通り、本発明によれば、電
極としての金属メッシュを圧電板の間に介装するため、
積層時に加圧すると導電性接着層用ペーストが金属メッ
シュの間に入り込み、圧電板同士を強固に接合し、高電
界の繰り返し印加によって発生する界面での剥離等を防
止することができ、積層型圧電体の信頼性が向上するこ
とができる。また、圧電板の幅よりも小さい幅を有する
細長金属板を、電極として圧電板の間に介装した場合も
同様である。
As described in detail above, according to the present invention, since the metal mesh as the electrode is interposed between the piezoelectric plates,
When pressure is applied during lamination, the conductive adhesive layer paste will enter between the metal meshes, firmly bond the piezoelectric plates together, and prevent peeling at the interface caused by repeated application of a high electric field. The reliability of the piezoelectric body can be improved. The same applies to the case where an elongated metal plate having a width smaller than that of the piezoelectric plate is interposed between the piezoelectric plates as an electrode.

【0049】また、導電性接着層用ペーストが金属メッ
シュの間や細長金属板のまわりに入り込むため、圧電板
の積層中に導電性接着層用ペーストが圧電板により押し
出されて側面にはみ出すことがなく、金属メッシュ同士
の短絡や細長金属板同士の短絡を防止することができ
る。
Further, since the conductive adhesive layer paste enters between the metal meshes and around the elongated metal plate, the conductive adhesive layer paste may be extruded by the piezoelectric plate during the lamination of the piezoelectric plates and stick out to the side surface. Therefore, it is possible to prevent a short circuit between metal meshes and a short circuit between elongated metal plates.

【0050】さらに、本発明では、接合部における機械
的損失を小さくすることができるため、電界印加時に発
生する変位ヒステリシスが小さく、繰り返し使用後の変
位量の低下が小さく、寿命の長い積層型圧電体を提供す
ることができる。
Further, according to the present invention, since the mechanical loss at the joint can be reduced, the displacement hysteresis generated when an electric field is applied is small, the displacement amount after repeated use is small, and the long life of the laminated piezoelectric element is small. The body can be provided.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の円柱状の積層型圧電体を示す側面図で
ある。
FIG. 1 is a side view showing a cylindrical laminated piezoelectric body of the present invention.

【図2】図1の金属メッシュを示す平面図である。2 is a plan view showing the metal mesh of FIG. 1. FIG.

【図3】正方形状の金属メッシュを示す平面図である。FIG. 3 is a plan view showing a square metal mesh.

【図4】圧電板の上に細長金属板を2本平行に配置した
状態を示す平面図である。
FIG. 4 is a plan view showing a state in which two elongated metal plates are arranged in parallel on a piezoelectric plate.

【符号の説明】[Explanation of symbols]

11,31・・・圧電板 13・・・導電性接着層 15・・・金属メッシュ 17,37・・・接続用突起部 19・・・正電極用金属メッシュ 21・・・負電極用金属メッシュ 33・・・細長金属板 11, 31 ... Piezoelectric plate 13 ... Conductive adhesive layer 15 ... Metal mesh 17, 37 ... Connection protrusion 19 ... Positive electrode metal mesh 21 ... Negative electrode metal mesh 33 ... Elongated metal plate

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】積層された複数の圧電板と、これらの圧電
板の間にそれぞれ介装されるとともに接続用突起部を有
する金属メッシュと、前記圧電板の間に介装されるとと
もに前記金属メッシュを埋設する導電性接着層とを有す
る積層型圧電体であって、前記圧電板の両側に配置され
た金属メッシュをそれぞれ正電極用金属メッシュおよび
負電極用金属メッシュとするとともに、前記正電極用金
属メッシュの接続用突起部同士を電気的に接続し、前記
負電極用金属メッシュの接続用突起部同士を電気的に接
続してなることを特徴とする積層型圧電体。
1. A plurality of laminated piezoelectric plates, a metal mesh interposed between these piezoelectric plates and having a connecting projection, and a metal mesh interposed between the piezoelectric plates and embedded with the metal mesh. A laminated piezoelectric body having a conductive adhesive layer, wherein the metal meshes arranged on both sides of the piezoelectric plate are respectively a positive electrode metal mesh and a negative electrode metal mesh, and the positive electrode metal mesh A laminated piezoelectric body, characterized in that the connecting projections are electrically connected to each other, and the connecting projections of the negative electrode metal mesh are electrically connected to each other.
【請求項2】積層された複数の圧電板と、これらの圧電
板の間にそれぞれ複数介装されるとともに接続用突起部
を有する細長金属板と、前記圧電板の間に介装されると
ともに前記細長金属板を埋設する導電性接着層とを有す
る積層型圧電体であって、前記圧電体の両側に配置され
た細長金属板をそれぞれ正電極用細長金属板および負電
極用細長金属板とするとともに、前記正電極用細長金属
板の接続用突起部同士を電気的に接続し、前記負電極用
細長金属板の接続用突起部同士を電気的に接続してなる
ことを特徴とする積層型圧電体。
2. A plurality of laminated piezoelectric plates, a plurality of elongated metal plates each interposed between the piezoelectric plates and having a connecting projection, and an elongated metal plate interposed between the piezoelectric plates. In the laminated piezoelectric body having a conductive adhesive layer for embedding, the elongated metal plates arranged on both sides of the piezoelectric body are elongated metal plates for positive electrode and elongated metal plate for negative electrode, respectively, and A laminated piezoelectric body characterized in that the connecting projections of the elongated metal plate for the positive electrode are electrically connected to each other, and the connecting projections of the elongated metal plate for the negative electrode are electrically connected to each other.
JP26652094A 1994-06-30 1994-10-31 Multilayer piezoelectric element Expired - Fee Related JP3250918B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26652094A JP3250918B2 (en) 1994-06-30 1994-10-31 Multilayer piezoelectric element

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP14949194 1994-06-30
JP6-149491 1994-06-30
JP26652094A JP3250918B2 (en) 1994-06-30 1994-10-31 Multilayer piezoelectric element

Publications (2)

Publication Number Publication Date
JPH0878747A true JPH0878747A (en) 1996-03-22
JP3250918B2 JP3250918B2 (en) 2002-01-28

Family

ID=26479368

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26652094A Expired - Fee Related JP3250918B2 (en) 1994-06-30 1994-10-31 Multilayer piezoelectric element

Country Status (1)

Country Link
JP (1) JP3250918B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001102701A (en) * 1999-09-28 2001-04-13 Kyocera Corp Wiring board
JP2020205370A (en) * 2019-06-18 2020-12-24 Tdk株式会社 Piezoelectric element

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7006476B2 (en) 2018-04-17 2022-01-24 株式会社デンソー Semiconductor integrated circuit equipment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001102701A (en) * 1999-09-28 2001-04-13 Kyocera Corp Wiring board
JP2020205370A (en) * 2019-06-18 2020-12-24 Tdk株式会社 Piezoelectric element

Also Published As

Publication number Publication date
JP3250918B2 (en) 2002-01-28

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